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INSTRUCTIONS
H
H
H
H
H
H
in
Chemistry,
Physics and
Chose the best option, out of 4 options given under each question and mark separately in Key-Sheet.
Maximum time allowed for answering and marking is 3 hrs.
Question numbers 2, 10, 19, 23, 26, 30, 31, 32, 42, 44, 52, 55, 61, 64, 66, 69, 70 and 75 carries each
8 marks. An incorrect attempt carries 2 marks each.
All other questions carries each 4 marks. An incorrect attempt carries 1 mark.
Maximum number of marks in each subject is 144 and a Grand Total of 432 marks.
CHEMISTRY
1.
2) CH3 CH 2 C H CH3
1) CH CH CH CH
3
2
3
3) CH3 CH 2 CH 2 CH 2
4) CH 5 CH 2 CH2 C H2
2.
The spin only magnetic moments of Mnx+ is 5.97 BM. Based on the data, the value of 'x' is predicted
as
1) 1
2) 2
3) 3
4) 4
3.
4.
CaCO3 C }}
m X CO2 ; X+N 2 }}
m Y C; Y H 2 O }}
m Z CaCO 3.
excess
C6 H 5 NO2
NaNO2 , HCl,00 C
H 3 PO2
3) ethylbenzene
4) benzene
4) A, C, D
7.
4) Xenontetroxide
8.
9.
10. At a pressure of 100 torr and 400 torr, separately, 0.1 gram and 0.2 gram of a gas is observed
adsorbed on one gram of activated charcoal. Assuming that data obeys Freundlich isotherm, the
value of n is reported as
1) 1
2) 2
3) 3
4) 4
11. Kc for the reaction, Fe2+ + Zn
1) + 1.36 K cal mol1
}}m Zn
2++Fe
12. Number of structures possible with C4H8 which can decolourise pink permanganate solution
1) 5
2) 4
H+, MnO4
13.
3) 3
4) 2
Heat
A condensation polymer nylon6,6 is obtained from the monomeric substances, X and Y. The
emperical formula of Y is
2) C2NH3
3) C3N2H8
4) C2NH4
1) C3NH8
14. Which of the following is not a characterstic of chemical equilibrium
1) change in concentration, temperature or pressure may change the position of equilibrium
2) at equilibrium, the sum of the concentration of reactants and that of the products is same
3) chemical equilibrium is not static but dynamic, because both forward and backward reactions are not
stopped
4) addition of a catalyst to the reaction does not change the position, though the establishment of
equilibrium is hastened.
15. A small amount of ethyl alcohol is added to brine solution in the Nelsons Cell. The cell is closed and
electrolysed. The final organic product formed is
1) CH3CHO
2) CCl3CHO
3) CHCl3
4) CCl3COOH
The set of quantum number of the electron referred in the above process is
1) (4, 2, +2,
1
)
2
2) (4, 1, +1, +
1
)
2
3) (5, 2, 2, +
2
1
)
2
4) (5, 0, 0, +
1
)
2
17. The change in free energy ( %G0 ) vs temperature (T) of Ellingham plot is a straight line with a
negative slope for the oxidation of
1) aluminium to aluminium oxide
2) carbon to carbonmonoxide
3) iron to ferrous oxide
4) carbon to carbondioxide
18. The pK of acetic acid is 4.8. The pH of a buffer solution prepared by mixing 100ml of 0.2M CH3COOH
and 50ml of CH3COOK is 4.8. Molarity of CH3COOK used to prepare the buffer is
1) 0.1 mol L1
2) 0.2 mol L1
3) 0.4 mol L1
4) 0.8 mol L1
19. A, B and C are the elements of the same period in the long form of the periodic table. Oxide of A is
amphoteric, B is acidic and C is basic. The increasing order of atomic numbers of the elements is
1) C < A < B
2) C < B < A
3) A < C < B
4) B < A < C
20. Dioxides of carbon and silicon do not differ in
1) physical state
3) type of hybridisation
21. Ni 2 2e }}
m Ni; E0 0.25V
Cu 2 2e }}
m Cu; E0 0.34V
Al 3 3e }}
m Al; E0 1.71V
Ag e }}
m Ag; E 0 0.79V
Based on the standard potentials given, correct among the following statements is
2) 1.6
3) 2.6
3.6
OCH3
25.
C(CH3)3
OH
The compound with the above structure is
1) an artificial sweeting agent
3) a norcotic analgesic
2) a food preservative
4) a detergent of washing cloths
3
70 C
H 2O
26. C 2 H 4 H 2 SO4 }}}
m A }}}
mB
H , Cr2 O7
C MnO, 300 C D LiAAH 4 E.
B
In the above sequence, the organic substances giving positive iodoform test are
1) A, B and C
2) B, C and D
3) B, D and E
4) A, C and E
27. Which of the following is not separated as metal hydroxide with ammonium hydroxide in the presence
of ammonium chloride
1) Zn2+
2) Mg2+
3) Fe3+
4) Cr3+
log
1)
(a x)
a
log
2)
(a x)
a
log
3)
time
a
(a x)
log
4)
time
time
a
(a x)
time
PHYSICS
1
31. The graph between stopping potential(V0) and is shown in the figure. G 1 , G 2 and G 3 are work
M
functions. Which of the following is/are incorrect?
G1
V0
0.001
G2
0.002
1) G1 : G2 : G3 1: 2 : 4
G3
0.004
nm
1
3) tan R t
2) G1 : G2 : G3 4 : 2 :1
hv
e
32. Figure below shows a cylindrical tube of volume V0 divided in two parts by a frictionless seperator.
The walls of the tube are adiabatic but the seperator is conductor. Ideal gases are filled in the two
parts. When the separator is kept in the middle, the pressures P1 and P2 in the left part and right
part respectively. The seperator is slowly slide and is released at a position where it can stay in
equilibrium. Then volumes of two parts are
p2
p1
P1
P2
1) P V0 ; P V0
2
1
P1V0
P2 V0
2) P P ; P P
1
2
1
2
P1
P1
3) 1 P V0 ; 1 P V0
2
2
4)
P1
P2 V0
P1
P1 +P2 V0
P1
33. A particle is found to be a at rest when seen from frame S1 and moving with a constant velocity
when seen from another frame S2 . Make out the correct option
1) S1 is inertial and S2 in noninertial frame
34. A student finds a small air bubble at depths 6cm from on side of glass slab and 4cm from other side
of glass slab of refractive index 3/2, then the thickness of slab is
1) 10cm
2) 9 cm
3) 15cm
4) 12 cm
35. Two blocks of mass 2.9 kg and 1.9 kg and suspended from a rigid support 's' by two
inextensible wires each of length 1m. The upper wire has negligible mass and the
S
1.9 Kg
lower wire has uniform mass 0.2 kg/m. The whole system of blocks and support has
an upword acceleration of 0.2 ms-2. The tention at the midpoints of lower and upper
2.9 Kg
2) 50N, 30N
3) 30N, 30N
4) 50N, 50N
37. The elevator shown in figure is descending with an acceleration of 2ms2. The mass of block A
is 0.5Kg. The force exeted by the block A on block B is (g =10m2)
2m 2
A
B
1) 8N
2) 6N
3) 4N
4) 2N
38. Two different coils have selfinductances L1 = 8mH; L2 = 2mH. The current in one coil is increased
at a constant rate. The current in the second coil is also increased at the same rate. At certain
instant of time, the power given to the two coils is same. At that time, the current, induced voltage
and energy stored in the first coil are I1, V1, and W1, corresponding values for the second coil of
the same ratio are I2, V2 and W2 respectively. Then
l1 3
1) l 4
2
2)
W1
3) W 4
2
l1
4
2
V2 1
4) V 4
1
39. The relation between time t and distance is t = ax2 + bx, where a and b are constants. The
acceleration is
1) 2av3
2) 2av3
3) 2av2
4) 2bv3
40. A wire of density 9 103 kg/m3 is stretched between two clamps 1m apart and is subjected to an
extension of 4.9 104m. If the youngs modulus of the wire is 9 1010 N/m2, then the lowest frequency
of transverse vibration in the wire is
1) 30Hz
2) 35Hz
3) 40Hz
4) 45 Hz
41. An ideal gas is expanding such that PT2 = constant. The coefficient of volume expansion of the gas
is
1)
1
T
2)
2
T
3)
3
T
4)
4
T
42. A uniform disc of radius R lies in XY plane with its centre at origin. Its moment of inertia about an
axis x = 2R and y = 0 is equal to the moment of inertia about an axis y = d and z = 0, where d is equal
to
1)
4R
3
2)
17
R
2
3)
4)
13R
15
R
2
43. The potential field depends on x and y coordinates as V = (x2 y2) correspanding electic field lines
in x y plane are as
Y
1)
2)
3)
Y
X
4)
44. A large solid sphere with uniformly distributed positive charge has a smooth narrow tunnel through
its centre. A small particle with negative charge, initially at rest far away from the sphere, approaches
it along the line of the tunnel reaches its surface with a speed V and passes through the tunnel. Its
speed at the centre of the sphere will be
4) 1.5 V
1) 0
2) V
3) 2 V
45. In the experiment to determine the speed of sound using resonance column
1) prongs of the tuning fork are kept in a vertical plane
2) prongs of the tuning fork are kept in a horizontal plane
3) in one of the two resonance observed, the length of the resonating air column is close to the wavelength
of sound in air
4) In one of the two resonance observed, the length of the resonating air column is close to half of the
wavelenth of sound in air.
46. Two spherical bodies of same mass and surface area raised to a temperature T are allowed to cool
in the same environment. The curve of temperature versus time is as shown in the figure. Emissivity
and absorptivity are ex, ey and Ax, Ay respectively, then
T
Y
X
t
1) ex > ey : Ax > Ay
2) ex < ey : Ax > Ay
3) ex > ey : Ax < Ay
4) ex < ey : Ax < Ay
47. A plane concave lens fits into a plane convex lens and their plane surfaces are parallel to each outer.
If lenses are made of different materials having refractive indices N1and N 2 and the radius of
eurvature of curved surface is R, then focal length of the system is
N1
N2
1)
N 2 N1
R
2) N N
2
1
R
3) N N
1
2
4))
N1 N 2
R
48. A resistance of 2
is connected across one gap of a meter bridge and an unknown resistance
is connected across the other gap. When these resistances are inter-changed, the
greater then 2
balance point shifts by 20 cm, then the unknown resistance in
2) 4 8
3) 5 8
4) 6 8
1) 3 8
49. Figure shows three resistor configurations P,Q and R connected across 3V cell. If the power
descipated by the configuration P, Q and R are P1, P2 and P3 respectively, then
8
3v
3v
1
3v
1) p1 > p2 > p3
2) p1 > p3 > p2
3) p2 > p1 > p3
7
4) p3 p2 > p1
50. Students A,B and C perform an experiment for determining acceleration due to gravity (g) using a
simple pendulum. They use different lengths and record time for different number of scillations. The
observations are shown in the table.
Least count for length = 0.1 cm
Least count for time = 0.1 sec
Student
No of oscillations
(n)
Timeperiod
(sec)
64.0
128.0
16.0
64.0
64.0
16.0
20.0
36.0
9.0
%g
2) EA is minimum
3) EA = EB
4) EB is minimum
51. Which of the following statements is wrong in the context of x-rays generated from x-ray tube ?
1) Wavelength of characterestic x-rays decrease when the atomic number of the target increases
2) Cut-off wavelength of the continuous x-rays depends on the atomic number of the target
3) Intensity of characterestic x-rays depends on the electrical power given to the x-rays tube
4) Cut-off wavelength of continuous x-rays depends on the energy of the electrons in the x-ray tube
52. A canon fires successively two shells with velocity u, the first at an angle R1 and the second at an
angle R 2 to the horizontal. Neglecting the air resistance, the time interval between the firings leading
to the collision of the shells will be.
2u sin(R1 R2 )
1) g cos(R R )
1
2
2u sin(R1 R2 )
2) g cos R cos R
1
2
2u sinR1 sinR2
3) g cos R cos R
1
2
2u sin(R1 R2 )
4) g cos(R R )
1
2
53. In the circuit shown in the figure, switch S is closed at time t = 0. Select the incorrect statements(s)
2R
2C
2) Halved
3) Doubled
8
4) Quadrapled
55. Two blocks of masses m1 and m2 connected by an ideal spring rests on a horizontal surface. The
coefficient of friction between the blocks and the surface is N . The minimum constant force to be
applied in the horizontal direction to the block of mass m1 in order to displace other block, if
m2 > m1.
F
1) g m1
m2
2
m2
m1
2) Ng m1
m2
2
m1
3) Ng
m2
4) Ng(m1 m 2 )
56. The magnetic moment of the loop as shown in the figure given below
Y
I
S
1)
Q
2
b2 Ik
2)
Q
2
b2 Ik
3)
Q
2
b2 Ik
4)
b2 Ik
57. From a building two balls A and B are thrown such that A is thrown upwards and B
downwards with same initial velocity. If they reach the ground within velocities VA and VB in
times tA and tB, then
1) VA = VB and tA = tB 2) VA > VB and tA > tB
600
300
3
3m
3m
58. The speed of the block at point B immediately after it strikes the second incline is
1)
60ms1
2)
45 ms1
3)
30 ms1
4)
75 ms1
59. The speed of block at point C, immediately before it leaves the second incline is
1)
120ms1
2)
105ms1
3)
90 ms1
4)
75 ms1
60. If collision between the block and the plane is completely elastic, then the vertical (up ward)
component of the velocity of the block at point B, immediatily after it strikes the second incline is
1)
30 ms1
2)
15 ms1
3) 0
9
4) 15 ms1
MATHEMATICS
61. If the circles |z 1| = 3 and |z z0| = 4 intersect orthogonally, then
1) z0 r 3
2) 3 b z0 b 5
3) 4 b z0 b 6
62. If B and C are the roots of 4x2 16x + c = 0, c > 0 such that 1 <
of integer values of c is
1) 2
2) 3
3) 4
4) 2 b z0 b 4
1 0 0
1 2
1
63. If A 0 1 1 and A ( A cA dI ) then c and d are
6
0 2 4
1) 6, 11
2) 6, 11
3) 6, 11
4) 6, 11
2 ax
b
2( ax b) 2 ax 2 b 1
2 ax b 1
1
2 ax b
1 2
( x 5 x 8)
4
2)
1 2
( x 3 x 6)
3
3)
1 2
( x 10 x 4)
2
4) x 2 x 2
(2 r 1)
d
66. If
1)
r 1
Q2
24
2) M 3, N 10
Q2
8
3) M 3, N x 10
4) M x 3, N x 10
r1
d
then
2)
r 1
Q2
3)
Q2
6
4)
Q2
12
c
67. The straight line joining the points (0, 3) and (5,2) is a tangent to the curve y
. Then the
x1
value of c is
1) 1
2) 2
3) 2
4) 4
68. Statement I : The function f(x) = 2sinx + cos2x (0 b x b 2Q ) has minimum at x
x
5Q
3
Q
3
and maximum at
Q
Q 5Q
Statement II : The above function f(x) decreases on 0, increases on , and decreases on
3 3
3
5Q
, 2Q
3
1) Statement I is true, statement II true; statement II is the correct explanation of statement I
2) Statement I is true, statement II is true; statement II is not the correct explanation of statement I
3) Statement I is true, statement II is false
4) Statement I is false, statement II is true
10
(2, 3) (3, 4)
1 cos 2 t
I2 2
sin t
1 cos 2 t
I1 2
sin t
x f x(2 x ) dx and
I1
f ( x(2 x )) dx . The I is equals to
2
1) 2
2) 1
3) 4
4) 1/2
y = x2 + 2x + 4, x [0, 2] is
1)
10
7
2)
10
3
3)
3
5
4)
4
3
72. Total number of divisors of n = 35.57.79 that are of the form 4 M 1, M r 0 is equal to
1) 240
2) 30
3) 120
4) 15
p 1
x sin , x x 1
x
73. If f ( x )
is continuous but not differentiable at x = 0, them
0
, x0
1) p (1,0)
2) p (0,2]
3) p (0,1]
,
b
1) b
2) 1/b
4) p [1,2)
x x 0 is continuous at x = 0, is equal to
x0
3) b
4) 1/b
x y
75. The equation of the curve y = f(x) satisfying the differential equation
dy
x2 y2 and passing
dx
2) y2 = x 1
3) x( x 1) = y2 (x2 y2)
4) (2x 3) +
1
x y2
2
0
76. If P be a point on the line y = x such that PA + PB is minimum, where A = (3, 4) and B = (7, 3), then
co-ordinates of P is
1)
13 13
,
7 7
2)
23 23
,
7 7
3)
11
31 31
,
7 7
4)
33 33
,
7 7
77. Let f(x,y) = x2 + y2 + 2ax + 2by + c = 0 represents a circle. If f(x,0) = 0 has equal roots, each being 2
and f(0,y) = 0 has its roots 2 and 3 then center of the circle is
1) 2,
5
2
2) 2,
5
2
5
2
3) 2,
78. A circle is drawn to pass through the extremities of the latusrectum of the parabola y2 = 8x. If the
circle touches directrix of the parabola, then radius =
1) 4
2)
3) 3
21
4) 2b
79. The plane 2x 3y + 6z 11 = 0 makes an angle sin 1 (M ) with x axis. The value of M is
1)
3
2
2)
2
3
3)
min. \ f ( t ) : 0 b t b x^ ,
,
sin x 1
2
7
4)
3
7
x [0, Q ]
then
xQ
1) g(x) is discontinuous at x = Q
3) g(x) is differentiable at x = Q
(w p.n )n
n
2) s P
(q p.n )n
n
3) s P
( p.n )n
n
4) s P
(q p.n )n
n
83. Let N denote the set of all natural numbers and R be the relation on N s N defined by (a,b) R(c,d) if
ad (b + c) = bc (a + d) then R is
1) Symmetric only
2) Reflexive only
3) Transitive only
4) an equivalence relation
84. Four integers are selected randomly and are multiplied. The probability of this product being divisible
by 5 but not 10 is
1)
175
10
2)
369
10
3)
3471
10
4)
1
32
85. Three children are selected at random from a group of 6 boys and 4 girls. In this group exactly one
boy and one girl belong to the same parents. The probability that the selected group of children
have no blood relation is
1
13
14
2
2)
3)
4)
1)
15
15
15
15
86. The minimum value of 27cosx + 81sinx is
1)
2
3 3
2)
3)
3 3
12
2
9 3
4)
4
9 3
d s (a s d )
d
2) d
is always equal to
3) b
4) c
88. If
i 1
1) 4/9
2) 9/4
3) 3/2
18
is
4) 4
89. The contrapositive of the statement if x has courage then x will win is
1) If x will win then x has courage
2) If x has no courage then x will not win
3) If x will not win then x has no courage
4) If x will not win then x has courage
e
I m I m 2
90. Let Im (log x) m dx . If
= e then the values of K and L are
1
K
L
1) 1 m,
1
m
2)
1
1 m
,m
3)
m(m 2)
1 m m 1
1
4)
m
,m 2
m 1
ANSWERS
CHEMISTRY
1) 1
2) 2
3) 2
4) 2
5) 4
6) 3
7) 4
8) 1
9) 2
10) 2
11) 4
12) 4
13) 1
14) 2
15) 3
16) 4
17) 2
18) 3
19) 1
20) 4
21) 3
22) 1
23) 4
24) 3
25) 2
26) 3
27) 2
28) 3
29) 2
30) 3
PHYSICS
31) 2
32) 2
33) 4
34) 3
35) 1
36) 1
37) 3
38) 4
39) 1
40) 2
41) 3
42) 2
43) 1
44) 4
45) 1
46) 1
47) 3
48) 1
49) 3
50) 2
51) 2
52) 2
53) 1
54) 4
55) 2
56) 3
57) 3
58) 2
59) 2
60) 3
MATHEMATICS
61) 3
62) 2
63) 3
64) 1
65) 3
66) 3
67) 4
68) 1
69) 2
70) 2
71) 2
72) 1
73) 3
74) 2
75) 4
76) 3
77) 4
78) 1
79) 2
80) 1
81) 2
82) 2
83) 4
84) 2
85) 3
86) 3
87) 4
88 ) 3
89) 3
90) 1
13