THIRD SEMESTER EXAMINATION APRIL-

2009
CHEMISTRY-XII
Class: XII (Pre-Engineering) Dated: 07-04-2009
Time: 3 Hors !" !ar#: 7$
NOTE: Attempt any FIVE questions. Select TWO questions
from each section.
%ECTI&'-I
Q.NO.1(a) State Modern Periodic Law. What are the advantages of Modern Periodic Table 0$
(b) What do !o" #now abo"t Mendeleev$s Periodic Table 0$
(c) Mention the si%ilarities of h!drogen with &' gro"( (al#ali ele%ents). 0$
Q.NO.) (a) What are h!drides *ow are the! classified +,(lain ionic and covalent h!drides 0(
with e,a%(les.
(b) -efine &soto(es and disc"ss the isoto(es of h!drogen. 04
(c) Write down the ind"strial %ethod of the (re(aration of h!drogen gas. 0$
Q.NO..(a) What are s/bloc# ele%ents -escribe the following (ro(erties of s/bloc# ele%ents. 0(
(i) 'to%ic Si0e (ii) &oni0ation Potential (iii) +lectronegativit!
(iv) *!dration +nerg!.
(b) *ow sodi"% %etal is e,tracted b! -own$s (rocess 04
(c) -efine allotro(! and disc"ss the allotro(ic for%s of carbon. 0$
Q.NO.1(a) E)*lain t+e ,ollo-ing s.ienti,i. terms: 0(
(i) Wh! %elting and boiling (oints decrease fro% to( to botto% in the sa%e
gro"(
(ii) 'l#ali %etals are strong red"cing agents
(iii) -ia%ond is bad cond"ctor of electricit!
(iv) 2ra(hite is good cond"ctor of electricit!
(v) 'to%ic si0e increases fro% to( to botto%
(vi) +lectrical cond"ctivit! increases fro% left to right in the (eriod
(b) What are Transition ele%ents -escribe the following (ro(erties of ele%ents 0$
in transition ele%ents.
(i) 3or%ation of colo"red co%(o"nds. (ii) 4ariable O,idation State
(iii) Magnetic Pro(erties. (iv) 5o%(le, 3or%ation.
(c) Write down the short on an! one of the following6 04
(i) 7ho%bic s"l(h"r (ii) 5orrosion (iii) 'to%ic *!drogen

5ont8. P 9 )
%ECTI&'-II
Q.NO.:(a) What are 'l#!l *alides and *ow are the! classified Write its (re(aration. 0$
(b) What is (ol!%eri0ation +,(lain its vario"s t!(es. 0$
(c) What are the nat"ral so"rces of organic co%(o"nds 0$
Q.NO.;(a) *ow h!drocarbons are classified What are o(en chain and close chain 0(
h!drocarbons
(b) *ow %ethane is (re(ared fro% sodi"% acetate< %eth!l iodide and 2rignard$s 0(
reagent What is halogenation of %ethane
(c) -efine and e,(lain &so%eris%. 03
Q.NO.=(a) What are carboh!drates *ow are the! classified Write down the (ro(erties 0(
of gl"cose
(b) Write short notes on an! three of the following6 3/3/3
(i) Protein (ii) -etergents (iii) 3ertili0ers
(iv) &so%eris% (v) 5rac#ing (vi) S"crose
Q.NO.>(a) 0rite I1P2C names o, an3 TE' o, t+e ,ollo-ing .om*onds" 40
(i)
5*.?5* @ 5* A 5 @ 5*)
B
5*.
(ii)

5O A (5*) A 5*.))
(iii)
(5*. ).A 5 A Cr
(iv)
(5*.). A 5 A (5*))1?5*.
(v)
5*.
B

(vi)
O*
5l B 5l
B
5l
(vii)

5*.?5* A 5O A 5*.
B
5*.

(viii)
5OO*?5*) A 5*) A 5OO*
(i,)
5*.?5* A 5 @ 5*
B B
O* O*

(,)
5*.?5*) A 5* 5/5*O
(,i)
5*.?5O // 5*) A 5 @ 5*)
B
N*)
(,ii)
5*. A 5*) A 5OO?5*) A5*.
(b) 0rite do-n t+e str.tre o, an3 ,i5e o, t+e ,ollo-ing .om*onds: 0$
(i) )/+tho,! C"tane (ii) ./%eth!l )<1/(entandione
(iii) )/Pentanol (iv) C"t!l (entanoate
(v) dieth!l #etone (vi) )<:/dichloro/./%eth!l/./ he,ane
(vii) Methanoic acid (viii) )<1<;/trichloroc!clohe,anol
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