Documenti di Didattica
Documenti di Professioni
Documenti di Cultura
Compounds
Shipeng Guo, Libin Wu, Chao Wang, Jinhua Li, and Zhengyu Yang*
Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Graduate UniVersity of
Chinese Academy of Sciences, Beijing 100101, China
ReceiVed April 24, 2008. ReVised Manuscript ReceiVed July 10, 2008
Deoxy-liquefaction runs were performed at nal temperatures of 350, 400, 450, and 500 C, with only 10
wt % distilled water as medium. The inuence of the nal temperature on the properties of biopetroleum
obtained from sunower shell samples (with kernels 5 wt %) via deoxy-liquefaction was examined in relation
to the yield and distribution of products (i.e., gas, solid, liquid), especially the compositions of oil products.
Furthermore, the liquid oil with a maximum yield and H/C molar ratio of 1.99 and higher heating value (HHV)
of 46.9 MJ/kg was obtained at 450 C. The biopetroleum analyzed by gas chromatography-mass spectrometry
(GC-MS) with the National Institute of Standards and Technology (NIST) 98 MS library was mainly composed
of benzene derivatives, phenolic derivatives, and alkanes (C
7
-C
19
). What is special is that the content of
(Z,Z)-9,12-octadecadienoic acid (RT ) 21.26 min), which came from the few sunower kernels decreased
from 21.32% at 350 C to zero at 500 C. This suggested that deoxy-liquefaction in a closed system could
realize not only the deoxygenation of biomass but the deoxygenation of linoleic acid by controlling the nal
temperature. Moreover, the biopetroleum obtained can be upgraded to transport fuel or separated for chemical
products.
1. Introduction
With the increasing demand for energy and the rising
atmospheric greenhouse gas levels, renewable energy should
be widely explored to renovate the energy source structure and
keep sustainable development safe.
1
Biomass as a clean and
renewable energy resource has become more and more attractive
to industry in the past 20 years. It is estimated to contribute
10-14% of the total energy supply in the world.
2-4
In addition,
biomass has zero net emission of CO
2
and has very low contents
of sulfur, nitrogen, and ash, which gives lower emissions of
SO
2
, NO
x
, and soot than conventional fossil fuels.
1
Therefore,
it has great potential for alleviating energy problems, such as
the greenhouse effect and the depletion of fossil energy
sources.
5,6
Recently, biomass has been widely used as an alternate energy
source in developing countries because the economies of these
countries are based largely on agriculture and forestry. One of
the major drawbacks is the low efciency of using biomass. In
China, biomass is widely used for cooking and heating via
biomass combustion with a thermal efciency only between 10
and 30%.
7
In addition, storage and transport also limit the use
of biomass. On the basis of the above standpoints, the
liquefaction of biomass has attracted more attention in the world.
In the thermo-chemical conversion processes, biomass can
be converted into liquid fuels and chemicals indirectly through
gasication to syngas followed by catalytic F-T conversion
and direct liquefaction. Typical direct liquefaction processes
* To whom correspondence should be addressed. Telephone: +86-(0)10-
64888781. Fax: +86-(0)10-64879375. E-mail: zhengyuyang@vip.sina.com.
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(5) O