CHEM 1412 Summer 2014 Exam I (100) Name:_____key___________________

Keep your books, noes, p!one e"# $n your ba"kpa"k an% &ea'e your ba"k pa"ks near !e enran"e#
Multiple choice questions, 1-20 carry 4 points each. Show mathematical set ups clearly for questions, 21-
23, since partial credits will be i!en.
1# "hich of the followin molecules does no ha!e a dipole moment#
$% &'
2
(&'
2
)% *'
3
&% &'
3
*'
2
+% '&l
2# "hich of the followin substances should ha!e the hihest boilin point#
$% &'
4
)% &l
2
&% ,r +% &'
3
&l -% *
2
(# "hich of the followin compounds should be soluble in &&l
4
#
$% *a&l )% '
2
. &% *a.' +% &
/
'
1/

4# "hat is the molality of ethanol solution made by dissol!in 14.0 of &
2
'
1
.', in 13.0 of
water#
$% 0.00121 m )% 0.232 m &% 1.21 m +% 232 m
)# "hat is mole fraction of 4
2
in a solution made by dissol!in 23./ of 4
2
in 241 . &
0
'
14
#
$% 0.0331 )% 0.03/1 &% 0.0311 +% 0.0330
*# "hich of the followin terms refers to the resistance of a liquid to flow#
$% Surface tension +% $dhesion
)% &apillary action -% &ohesion
&% 5iscosity
+# 6or which of the followin phase chanes is the entropy chane neati!e#
$% boilin of water )% formation of snow from water !apor in clouds
&% meltin of ice cream +% sublimation of 4
2
,# "hat mass of 7i.' is required to prepare 210 m7 of a 3.11 M solution#
$% 23 )% 0.31 &% 341 +% 21 -% 0
-# "hat is the process where molecules o directly from the solid phase to the as phase#
$% deposition )% sublimation &% free8in +% condensation -% meltin
10# $ mechanism for a naturally occurrin reaction that destroys o8one is9
Step 19 .
3
:g% ; '.:g% < '.
2
:g% ; .
2
:g%
Step 29 '.
2
:g% ; .:g% < '.:g% ; .
2
:g%
"hich species is a catalyst and what type of catalysis is occurrin#
$% '., homoeneous )% '., heteroeneous
&% '.
2
, homoeneous +% '.
2
, heteroeneous
1
11# =he burnin of propane can be represented by the followin equation9
:g% ; 3 :g% < 3 :g% ; 4 .:g%.
"hich of the followin relationships is true#
$% ( )% - 3 ( ; 4
&% - 3 ( ; 3 +% ; 3 ( - 4
12# =he decomposition of dinitroen pento>ide is described by the chemical equation as i!en. 2
*
2
.
1
:g% < 4 *.
2
:g% ; .
2
:g%, 4f the rate of appearance of *.
2
is equal to 0.100 mol?min
at a particular moment, what is the rate of appearance of .
2
at that moment#
$% 0.140 mol?min )% 0.2/0 mol?min &% 1.12 mol?min +% 2.24 mol?min
1(# =he reaction shown below has the rate law9 @ate ( kA)r.
3
B
CA)r
B
CA'
;
C
2
.
)r.
3
B
:aq% ; 1 )r
B
:aq% ; 0 '
;
:aq% < 3 )r
2
:aq% ; 3 '
2
.:l%
"hat is the o!erall order of reaction#
$% first )% second &% third +% fourth
14# $ solution of fructose, , e>erts an osmotic pressure of 3/.0 torr at 21D &. "hat is the
molarity of the fructose solution# :@( 0.0/200 7 atm ? , mole%
$% 0.00412 M )% 3.12 M &% 4.21 M +% 0.00102 M
1)# &alculate the !apor pressure of a solution prepared by dissol!in 0.100 mol of a non-!olatile
solute in 231 of he>ane : ( /0.1/ ?mol% at 42.0D&. PD
he>ane
( 400.0 torr at 42.0D&.
$% 14 torr )% 114 torr &% 240 torr +% 340 torr -% 400. =orr
1*# "hat is the boilin point of a solution prepared by dissol!in 331 of sulfur :S
/
, ( 210.1
?mol% in 1210 of &&l
4
# K
b
( 1.01D&/m, boilin point of pure &&l
4
( 30.3D&%#
$% 30./D& )% 31.2D& &% 3/.2D& +% /2.0D& -% E/1D&
1+# &alculate the molarity of a solution prepared by dissol!in 3/.0 of ,6 in enouh water to
produce 221 m7 of solution.
$% 0.304 M )% 0.342 M &% 1.31 M +% 3.22 M -% 0.01 M
1,# +etermine the free8in point of a solution which contains 0.31 mol of sucrose in 131 of
water. K
f
( 1./0D&/m
$% 3.3D& )% 1.1D& &% 0.0D& +% 1.1D& -% 3.3D&
1-# =he rate constant, k, for a first-order reaction is equal to 4.2 F 10
-4
s
-1
. "hat is the half-life
for the reaction#
$% 2.2 F 10
-4
s )% 1.2 F 10
3
s &% 1.3 F 10
3
s +% 2.4 F 10
3
s
20# =he first-order reaction, 2 *
2
.:g% < 2 *
2
:g% ; .
2
:g%, has a rate constant equal to 0.30 s
-1
at 1000 ,.
'ow lon will it taGe for the concentration of *
2
. to decrease to 42H of its initial concentration#
$% 0.// s )% 1.1 s &% 1./ s +% 2.4 s
2
21# =he density of a 20.3 M &'
3
.' :methanol% solution is 0./1/ ?m7. "hat is the molality
of this solution# '
2
. is the sol!ent. 23.0 m +
+( /1/ ? 17
20.3 M ( moles? 7I moles( 20.3 I
. of &'3.' ( 20.3 > 32 ( 042.0
Molality ( 20.3? 0.20/ ( 23.0 m
22# Jlatinum has a face-centered cubic crystal structure and a density of 21.1 ?cm
3
. "hat is
the radius of the platinum atom# :1 pm ( 1.0 > 10
-12
m% *
4 > 121.0/?0.022> 10
23
( 1.220>10
-21
.
5( m?d ( 0.020> 10
-23
I a( 3.2 >10
-/
I r(1.4 > 10
-/
cm

2(# &onsider the reaction, *.
2
; .
3
*.
3
; .
2.
Kse the data shown to determine the rate law for the
reaction. +etermine the !alue of rate constant, G. +
Exper$men .N/20 M ./30 M 1ae M s
1
1 0.21 0.30 0.30 10
3
2 0.03 0.30 1./2 10
2
3 0.21 0.31 3.11 10
3
4 0.42 0.31 0.30 10
3
@ate ( G A*.
2
CA.
3
C I G( 0.043 M
-1
s
-1
3