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Natural fibers are not only strong and lightweight but also relatively very cheap. Coconut coir can be used as a potential reinforcing material for many structural and nonstructural applications.
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studies on the effect of reinforcement of polypropylyne wit coir
Natural fibers are not only strong and lightweight but also relatively very cheap. Coconut coir can be used as a potential reinforcing material for many structural and nonstructural applications.
Natural fibers are not only strong and lightweight but also relatively very cheap. Coconut coir can be used as a potential reinforcing material for many structural and nonstructural applications.
AbstractFiber-reinforced polymer composites have played a
dominant role for a long time in a variety of applications for their
high specific strength and modulus. The fiber which serves as a reinforcement in reinforced plastics may be synthetic or natural. Past studies show that only synthetic fibers such as glass, carbon etc., have been used in fiber-reinforced plastics. Although glass and other synthetic fiber-reinforced plastics possess high specific strength, their fields of application are very limited because of their inherent higher cost of Production and also they are not biodegradable. The usage is restricted for commercial applications since this leads to environmental problems. In this connection, an investigation has been carried out to make use of coir, a natural fiber abundantly available in India. Natural fibers are not only strong and lightweight but also relatively very cheap. The usage of composite material for engineering applications is increasing to derive various advantages such as reduction in weight, corrosion resistance, ability to tailor designing, manufacturing process flexibility. The present work describes the development and characterization of a new set of natural fiber based polymer composites consisting of coconut coir as reinforcement. The newly developed composites are characterized with respect to their mechanical characteristics. Experiments are carried out to study the effect of fiber content on mechanical behavior of these composites. In the present work, coir composites are developed and their mechanical properties are evaluated. Scanning electron micrographs obtained from fractured surfaces were used for a qualitative evaluation of the interfacial properties of coir/epoxy. These results indicate that coir can be used as a potential reinforcing material for many structural and non- structural applications. Finally, the SEM of fractured surfaces has been done to study their surface morphology. This work can be further extended to study other aspects of such composites like effect of fiber orientation, loading pattern, fiber treatment ,fiber length on mechanical behavior of coconut coir based polymer composites. KeywordsPolypropelene with coir, DTA/TGA, DSC, Thermo- Mechanical Properties Analysis. I. INTRODUCTION VERVIEW OF COMPOSITES: Many of modern technologies require materials with unusual combinations of properties that cannot be met by the conventional metal alloys, and metals. This is especially true for material that are needed for aerospace, underwater, and transportation N. Shiva Shanker is with the University College of Technology, Osmania University, Hyderabad-500 007 India (phone: +91-9908247532; e-mail: sivashankern@gmail.com). B.Vijayalakshmi, was with Jawaharlal Nehru Govt. Polytechnic, Ramanthapur, Hyderabad-500 013 India (e-mail: vijayatony@gmail.com). Khalid Mohamed Hassan Ali, with the University College of Technology, Osmania University, Hyderabad-500 007 India (phone: +919000064198; e- mail: khalidscd10@yahoo.com). B.Rajam, is with the University College of Technology, Osmania University, Hyderabad-500 007 India (phone: +919346764226; e-mail: rajam_ouct@rediffmail.com). application. for example aircraft engineers are increasingly searching for structural materials that have low densities, strong, stiff, abrasion and impact resistant, and not easily corroded. This is rather formidable combination of characters. Frequently strong materials are dense also increasing the strength generally results in a decrease in impact strength. The advantage of composite materials over conventional materials stem largely from their higher specific strength, stiffness and fatigue characteristics, which enables structural design to be more versatile. By definition, Composite material is a material system composed of two or more dissimilar materials (1-2), differing in forms, and insoluble in each other, physically distinct and chemically inhomogeneous. The resulting products properties are much different from the properties of constituent materials. Composites are materials that comprise strong load carrying material (known as reinforcement) imbedded in weaker material (known as matrix). Reinforcement provides strength and rigidity, helping to support structural load. The matrix or binder (organic or inorganic) maintains the position and orientation of the reinforcement. Significantly, constituents of the composites retain their individual, physical and chemical properties; yet together they produce a combination of qualities which individual constituents would be incapable of producing alone. The reinforcement may be platelets, particles or fibers and are usually added to improve mechanical properties such as stiffness, strength and toughness of the matrix material[13] . Composites are used because the overall properties of the composite are superior to those of the individual components. Typically, reinforcing materials are strong with low densities while the matrix is usually ductile, or tough, material. If the composite is designed and fabricated correctly, it exhibits the strength of the reinforcement with toughness of the matrix to achieve a combination of desirable properties not available in any single material. Figure 1: Life Cycle Diagram of Natural Fiber Reinforced Plastics Studies on the Effect of Reinforcement of Polypropylene with Coir Siva Shanker N, Vijaya Lakshmi. B, Khalid Mohamed Hassan Ali, Rajam. B O World Academy of Science, Engineering and Technology 73 2013 1726 In the present study we used a thermoplastic polymer (polypropylene) as the matrix and a lignocellulosic material (Coconut coir ) as the reinforcing filler to prepare a particle- reinforced composite to study the effect of using these fibers ion polypropylene on various properties such as mechanical, thermal and impact strength. II. EXPERIMENTAL PROCEDURE A. Materials The matrix employed in the preparation of composite samples was commercial PP (HO30SG) provided by Reliance Industries Ltd. in the form of homopolymer pellets. Its density was 0.895. Melt flow index is 3.0g/10min and its melting temperatures is of 165171 C. The coir, used as reinforcing filler, was obtained from a local coconut coir factory in Rajamandry. The average length of the coir fiber used is 0.3 - 0.5 mm respectively. B. Fabrication of composites and test specimens Coir processed as mentioned above was initially mixed thoroughly with PP granules at 5/95, 10/90, 20/80 and 30/70 wt. % mixing ratios. The compounding of reinforcement and matrix was carried out with a JSW Twin Screw Extruder at a temperature of 220 o c. A standard polyolefin screw with a 25mm diameter. With a speed of 355 RPM was employed. The extruded composites were cut into long pieces. All the pieces were then crushed into smaller granules using a pelletizer attached to the extruder. The granules were dried in a hot air oven at 80C for 2 h and then fed into an Automatic injection-molding machine for making specimens. The specimens for tensile flexural, impact and hardness tests were prepared as per ASTM D standards from dried granules using the Automatic injection-molding machine (Japan steel works, Japan) at a molding temperature profile of 180 C.to 230 0 c Figure 2: 0.3-0.5 mm length of coconut coir fiber
Figure 3: (a) & (b)Tested specimens
Figure 4a: JSW Injection moulding Figure 4b: Extrusion process C. Mechanical testing Determination of the Mechanical Properties, After fabrication the test specimens were subjected to various mechanical tests as per ASTM standards. D.Tensile Properties Tensile elongation and tensile modulus measurements are among the most important indications of strength in a material and are the most widely specified properties of plastic materials. Tensile test is a measurement of the ability of a material to withstand forces that tend to pull it apart and to determine what extent the material stretches before breaking. Tensile modulus is an indication of the relative stiffness of a material can be determined from stress strain diagram. Tensile properties of composite samples were measured using universal testing machine (-SHIMADZU, JAPAN). The load capacity was 50KN and cross-head speed was 100 mm/min using gauge length of 115 mm. tensile test is generally performed on a flat specimens. Test specimens were molded in a size of 13.5 mm (width), 63.66 mm (length) and 3.90 mm (thickness). Tensile stiength = Foice (loau )(lb) Cioss section aiea ( sq. in) Tensile mouulus = Biffeience in stiess Biffeience in coiiesponuing stiain Stress is a ratio of applied load to the original cross sectional area. Strain is the change in length per unit of the original length (l /Al) E. Bending Properties Flexural strength is the ability of the material to withstand bending forces applied perpendicular to its longitudinal axis. Flexural properties of composite samples were measured using universal testing machine (-SHIMADZU, JAPAN). For bending tests, cross-head speed was 2.5mm/min and span distance was 96 mm. tensile tests and three-point bending tests were carried out following ASTMD638 and ASTMD790 standard methods respectively. For each treatment level, three replicated specimens were tested. World Academy of Science, Engineering and Technology 73 2013 1727 Fi de sc us Sh in nu ar w sli in fir fo su du is igure 5: Exper specimen F. Hardness Hardness is eformation, cratching. Dur sed for meas hore hardness ndentation by umber, the gr re most comm with relatively ightly harder nstrument is sh The test is c rst placing the oot of the inst ure that it is urometer hard in firm conta Figure 6: Sh Figure 7: H rimental setup s for tensile t Properties defined as particularly rometer hardn uring the rel s is a measur y 3 spring-lo reater the resi monly used- Ty soft materials r materials. hown in fig. 6 arried out usi e specimen on trument is pr parallel to th dness is read w act with the sp hore or durom Hardness comp p and loading test and three p the resistanc permanent ness test or sh lative hardnes e of the resis oaded indente istance. Two ype A and Typ s while Type D Durometer h . ing ASTMD 2 n a hard, flat s essed onto th he surface of within 1 sec a ecimen.
meter hardness parison scale o arrangements point bend tes ce of a mate deformatio hore hardness ss of soft ma stance of mat er. The high types of duro pe D .Type A D Durometer hardness me 2240 test met surface. The p he specimen, f the specime fter the pressu s testing mach of some mater s for the st. erial to on or s test is aterials. terial to her the ometers is used is with easuring thod by pressure making en. The ure foot hine rials Em nu dir str im the Figur Figu
mpirical relati umber. G.Impact Stre The impact rectly related rength is a me mpact tester (C e samples w re 8: Hardness re 9: Compari ions between ength (IS) properties o to the overall easure of toug CEAST-6546 were condition s units conver ison of hardne n Tensile stre of the polym l toughness of ghness. It was ) according t ned at 23 0 c+ sion table ess scales ength and Ha meric materia f the material. s measured us to ASTMD25 +2 and50% r ardness als are . Imact sing an 56. All relative World Academy of Science, Engineering and Technology 73 2013 1728 humidity. Values reported were average of three measurements. The impact strengths of the composites were conducted on a notched specimens .The charpy impact strength is calculated by dividing the indicator reading by the thickness of the specimen. . Figure 10: IZod impact testing machine H.Water Absorption Test Water uptake values of composite samples were calculated by dipping the samples in a static bath containing water at 25 0 C.The water absorption tests were carried out immersing the specimens for 24hrs in cold water. After immersion, the excess water on the surface of the specimens was wiped up using a piece of soft cloth and the final weights of the specimens were taken. From the difference of weights of the specimens percentage of water absorption was calculated. I. Termo Gravimetric Analysis(TGA) It was used in the determination of decomposition temperatures and rates, as well as thermal stability kinetic studies.TGA experiments were performed with a SDT Q600 thermo gravimetric analyzer (TA Instrument Inc. New Castle, Deleware, USA).Tests were done under nitrogen at a scan rate of .20C/min in a programmed temperature range of 20 0 c to 600C. A sample of 5 to 10 mg was used for each run. The weight change was recorded as a function of temperature. Derivative peak temperature (DTp) was taken as the maximum temperature acquired from the differentiation of the weight change as a function of time. Figure 11: Gravimetric analyzer (TGA) J. Differential Scanning Calorimetry (DSC) DSC is a thermal analysis that measures the quantity of energy absorbed or evolved by a sample in calories as its temperature is changed. It has been used to measure melting points, heats of fusion and crystallization, oxidative induction time and glass transition temperature .Differential scanning calorimetry (DSC) experiments were performed with a DSC Q20 system(TA Instrument Inc New castle, Deleware,(U.S.A) Each sample was heated and cooled at a scanning rate of 20C/min under nitrogen atmosphere in order to prevent oxidation. A test sample of 5 to 10 mg was placed in an aluminum capsule and heated from 30 to 300C for each run. The melting temperature(Tm), enthalpy(Hm), crystallization temperature (Tc), were determined. Figure 12: Differential scanning calorimetry (DSC) III. RESULTS AND DISCUSSIONS The mechanical properties of the coir fiber reinforced composites prepared for this investigation. Details of processing of the composites and the tests conducted on them have been described in the previous chapter. The results of various characterization tests are reported here. This includes evaluation of tensile strength, flexural strength, impact strength and hardness has been Studied and discussed. The interpretation of the results and the comparison among various compositions of composite samples are also presented. 3.1 Mechanical Characteristics of Composites The characterization of the composites reveals that the different composition of fiber is having significant effect on the mechanical properties of composites. The properties of composites with different compositions of fiber under this investigation are presented in TABLE I. TABLE I: Mechanical Properties of the PP-Coir Composites Comp- osites Tensile strength (MPa) Tensile modulus (GPa) Flex- ural strength (MPa) Flex-ural modulus (GPa) Impact energy (KJ/m2) Hard- ness (shore)D PP 35.9727 0.57 27.24 1.15 45.89 57 C1 37.2373 0.678 34.47 1.39 65.4 58.9 C2 38.624 0.6727 35.156 1.50 88.8 59.9 C3 41.2031 0.787 36.41 1.64 111.2 63.4 C4 40.3436 0.806 38.69 1.76 119.1 67.7 Where, World Academy of Science, Engineering and Technology 73 2013 1729 PP =Polypropylene : C1= composition prepared with 5% coir in pp; C2 = composition prepared with 10% coir in pp; C3 = composition prepared with 20% coir in pp; C4 = composition prepared with 30% coir in pp; Tensile Properties The effect of fiber addition on tensile strength of pp-coir composites is shown in Fig. 13. Figure 13: Tensile strength for coir reinforced pp composites The strength of a composite may increase or decrease with the introduction of natural fibers to the polymer matrix. Normally fibers are able to improve strength but some of the fibers are not consistent or irregular in shape influences the strength of the composite. In the study, poor reinforcement of the fiber in the pp matrix is the main cause of the lower tensile strength value [8-10]. It reveals that the tensile strength increases with the increase of fiber addition upto certain percentage (20 %) and after that it decreases. It is to be noted that, the tensile strength values remained higher compared to that of neat PP. Upto this composition (increasing region) the fiber and the polymer are well distributed.Up to 20% treated fiber addition the fiber and matrix bear the load and make resistance to slip as in the case of age hardening of metals. Up to 20% the short fibers are finely distributed and the interfacial bonding between the fiber and matrix is good, after that fibers are present as bundle of fibers and fiber-fiber bonding strength is lesser and the interfacial bonding between the fiber and matrix is poor. After that the fiber are coagulated as bundle of fibers, bundle of fibers fractured during load to slips and does not make resistance to slips. Consequently, after 20% fiber addition the tensile strength decreases. Similar effect was found by asad akhter[14], C.Y Lai[4],Nazrul Islam[3 ], . S. Y. Lee and some researchers. In the following sections the results were published by performing different tests by Universal Testing Machine with computer integration were performed in the CIPET Hyderabad and the date is tabulated in TABLE II as below. TABLE II: Tensile Properties of Composites composites Max.displace- Ment mm Stress MPa Strain % Yield point MPa Breaking force. N PP 6.318 35.9727 0.63 9.34854 1837.11 C1 8.2055 37.2373 0.58 9.5436 1898.54 C2 6.714 38.624 0.57 9.88557 1970.47 C3 6.555 41.2031 0.52 9.66761 1865.63 C4 7.33 40.3436 0.50 9.249 1768.61 Graphs obtained between strain and strain curves of the composites for different filler loadings from the computer of UTM are shown in fig. 4. 20% of coir( virgin pp) 5% of coir.
10% of coir 20% of coir
Figure 14: Stress-strain diagrams for different compositions Fig 14 shows the Youngs modulus of the composites of coir at different coir loading. It is clear in the Figure that incorporation of fiber has significantly increased the modulus with increasing coir loading, as modulus is considered to be a World Academy of Science, Engineering and Technology 73 2013 1730 linear function of coir concentration. Since coir has higher modulus than PP, incorporation of the filler into the matrix has improved the stiffness of the composites. Youngs modulus is a measure of stiffness of a material. Figure 15: youngs modulus with filler loading for reinforced pp composites The tensile properties of the composites made with the twin-screw extruding system were better than those of the composites made with the single-screw extruding system, due to the improved dispersion of the filler. The tensile strength and modulus of the lignocellulosic fillerPP composite made with the twin-screw extruding system were improved in the case of the composite made without any compatibilizing agent.[2] Flexural Properties Flexural strength and modulus of the composites of reinforced PP composites are shown in Figs. 15 and 16, respectively. In both cases, addition of fiber has increased the flexural strength of the composites. However, the values remain almost constant for 10% to 25% filler Loaded composites. Similar effect was found by asad akhter[14], C.Y Lai[ 4], Nazrul Islam[3 ]. For 0% fiber the polymer strength was obtained 27.24 MPa. The flexural properties of composites are presented in TABLE III. TABLE III: Flexural Properties of Composites Composites composition Max-force Kg Flexural stress (MPa) Strain% Flexural modulus (MPa) PP 126.3 27.3 6.4 1.15 C1 129.1 34.47 7.0 1.399 C2 136.1 35.156 7.3 1.505 C3 138.8 36.407 6.2 1.645 C4 171.5 38.69 5.3 1.7679
Figure 16: flexural strength vs filler loading Incorporation coir has resulted in an increase in the flexural modulus of the composites, which is found to be in line. The values of flexural modulus of composites are found to increase with the increasing coir content. Figure 17: Flexural modulus for coir reinforced pp composites Since coir is high modulus material higher fiber concentration demands higher stress for the same deformation and higher degree of interfacial adhesion between the coir and the matrix provides better stress transfer from the matrix to the coir. Impact Strength Figure 18 shows the impact strength behavior of coir-PP composites as a function of coir content. It is evident in the Figure that up to 30% coir content the impact strength shows a linear increase and then show a plateau with a little increase in the values up to 25% coir content. The impact strength of composites is governed mainly by two factors: first, the capability of the coir to absorb energy that can stop crack propagation and second, poor interfacial bonding which induces micro-spaces between the coir and the matrix, resulting in easy crack propagation [10,11]. Probably these two factors offset each other when the coir content exceeds 15%, showing a steady behavior in the impact strengths of the composites. youngsmodulus vs wt% of coir 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 0 10 20 30 40 wt% of coir y o u n g s
m o d u l u s ( M P a ) youngsmodulus vs wt% of coir f lexural strength vs wt% of coir 0 5 10 15 20 25 30 35 40 45 0 10 20 30 40 wt%of coir f l e x u r a l
s t r e n g t h ( M P a ) f lexural strength t% f flexural modulus vs wt% of coir 0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.6 1.8 2 0 10 20 30 40 wt% of coir f l e x u r a l
m o d u l u s ( M P a ) flexural modulus t% World Academy of Science, Engineering and Technology 73 2013 1731
Figure 18: impact strength for coir reinforced pp composites The impact strength of the composite depends on the amount of fiber and the type of testing. i.e whether the samples were notched or un-notched. In case of notched samples, the impact strength increases with the amount of fibers added until a plateau is reached at about 45% fiber weight. Addition of the fibers creates regions of stress concentration that require less energy to initiate a crack. Hardness Hardness of a particular sample refers to its stiffness or resistance of being broken to have its shape changed permanently when load is applied to it. It is an indication of the composite to resist crack propagation when subjected to a sudden impact on it. For composite materials it depends on the distribution of filler into the matrix [11,12].
Figure 19: hardness for coir reinforced pp composites As shown in Fig. 19, the incorporation of coir reinforced composites increased their hardness further increases in filler content. This indicates a decrease in flexibility and an increase in stiffness of the composites with increasing coir content. Water Absorption Behavior Figure 20 shows the water absorption behavior of coir-PP composites in water as a function of filler content. With increasing filler content the number of hydroxyl groups in the composites increased which consequently increased the water absorption. It has been reported that water absorption can significantly be minimized if the filler is thoroughly encapsulated by the matrix [1].yang and coworkers [15,16] reported that natural fiber polymer composites show remarkable water absorption due to the presence of voids. In the present work, we have measured the dimensions of samples after the immersion tests. No dimensional changes were observed within the time span of the experiments, which might be attributed to encapsulation of the fiber into the matrix. This indicates that water absorption takes place mainly in the micro-spaces of the fillermatrix interface.
TABLE IV: Physical Properties of Coir composites Water absorption (%) PP 0.015 C1 0.31 C2 0.62 C3 0.72 C4 1.54
Figure 20: Water absorption behavior of coir Thermal Properties TGA results: TGA curves of PP are shown in Figure 21. With the addition of coir, an average decrease in decomposition temperature compared to neat PP was observed. The decrease in decomposition temperature is attributed to of volatile decomposition products caused by the dispersed coir particles in the PP matrix. The derivative peak temperature (DTp) of neat PP was 437.53C.Due to the presence of coir, the decomposition grade increases. Hence there is decrease in order of the degradation temperature. DSC results: TABLE IV shows the DSC results of PP results used in this study. All systems had a higher melting temperature (Tm), compared to neat PP. Neat PP had the lowest Tm (166.15C) .The increased loading level of coir had no significant effect on the Tm of the hybrids. At 5 phr loading of coir, the Tm increased up to 5C with increasing coir content However, at the 10 and 20 phr coir loading level, the effect of coir on the change of Tm was not significant (TABLE IV). The enthalpy (Hm) of caloric processes was determined at the heating rate of 10C/min (TABLE I).The Hm of neat PP at transition temperature was 21.85 J/g, but the Hm with different loading levels ranged from 10.6 to 24.54 J/g, indicating an increasing thermal stability. Meanwhile, the addition of coconut coir from5 to 20 phr increased the Hm from 10.60 to 14.27 J/g. This result indicates that coir variation of impact strength with wt% of coir 0 20 40 60 80 100 120 140 0 10 20 30 40 wt% of coir i m p a c t
s t r e n g t h ( J / m ) Series1 HARDNESS VS WT% OF COIR 56 58 60 62 64 66 68 70 0 10 20 30 40 wt% of coir h a r d n e s s ( s h o r e ) HARDNESS VS WT% variation of water absorption with the wt % of coir 0 0.05 0.1 0.15 0.2 0.25 0.3 0 10 20 30 40 wt% of coir w a t e r
a b s o r p t i o n ( % ) Series1 World Academy of Science, Engineering and Technology 73 2013 1732 absorbed more heat energy in the melting of the composites as the Hm of coir was much lower than that of neat PP [5]. The crystalline peak temperature (Tc) of the composites is shown in TABLE I. The Tc of PP was 110.26C, and the addition of coir (at 5wt%) increased the Tc to 113.41C. coir act as nucleating agents, which increase the crystallization temperature of pp. [6,7]. The addition of coir (10 to 30 phr) to the composites increased the Tc to 115.49C . This result indicates that the nucleating effect of composite was further strengthened by the addition of coconut coir. With increase in coir crystallization properties increased. TABLE V: Thermal Properties of PP/Coir Systems PP/Coir Thermal properties Tm( o c) Hm(J/g) T 0 c PP 100/0 162.05 25.34 110.26 C1 95/5 161.3 12.66 113.41 C2 90/10 160.88 15.07 113.51 C3 80/20 160.14 14.04 113.98 C4 70/30 160.96 42.99 115.49 Where Tm melting point, Hm=enthalphy, Tc= crystalline temperature TGA thermographs of PP/coir: Fig 21(a) TGA thermographs for virgin pp Fig 21(b) TGA thermographs for 5 wt% of coir
Fig. 21(c) TGA thermographs for 10 wt% of coir Fig. 21(d) TGA thermographs for 20 wt% of coir Fig. 21(e) TGA thermographs for 30 wt% of coir Fig. 21(f) TGA thermographs of pp/coir DSC melting results of PP/coir: (i) Exo heat flow; (ii) Endo heat flow Fig. 22(a) DSC melting result of pp/coir Fig. 22(b) DSC melting result of pp of 5% coir
Fig. 22(c) DSC melting result of pp of 10%coir Fig. 22(d) DSC melting result of pp of 20%coir TGA thermographs of (a) PP/coir TGA thermographs of pp having the coir composition of 10% TGA thermographs of pp having the coir composition of 20% TGA thermographs of pp having the coir composition of 30% TGA thermographs of pp/coir DSC melting results of pp/coir DSC melting results of pp having the coir composition of 5% DSC melting results of pp having the coir composition of 10% DSC melting results of pp having the coir composition of 20% World Academy of Science, Engineering and Technology 73 2013 1733 Fig. 22(e) DSC melting result of pp of 30%coir
Fig 23(a) DSC results Exo heat flow Fig 23(b) ) DSC results Endo heat flow IV. CONCLUSION In the present study, the effect of fiber content on the mechanical properties of coir reinforced pp composites has been investigated. This experimental investigation leads to the following conclusions. For coir-PP composites, the values of tensile strength are initially increased up to 20% and then shown decreasing trend to 30% with further increases in coir content. It is to be noted that for coir-PP composites, the tensile strength values remained higher compared to that of neat PP. Other mechanical properties such as flexural strength, flexural modulus and hardness of coir reinforced PP composites are found to be much higher as increase of coir increases the hardness and stiffness. Water absorption behavior in water immersion tests reveals that in lower amount of water absorption is higher with the increase of coir content as the coir is hygroscopic. So, by reinforcement of some hydrophobic component (water repellent), the water absorption can be reduced. The addition of coir decreased the decomposition temperature and increasing the melting temperature. With the increase of coir content, the crystallization properties were increased. As the coir loading increased, morphological study revealed more coir particles This suggests that due to the nature of coir the degradable studies can be studied which are helpful in biodegradable composites. Main functioning of the composite is reduction of plastic materials and also increasing of biodegradable nature. REFERENCES 1. Khan, M.A., Khan, R.A., Haydaruzzaman and Ghoshal, S. (2008). Study on the Physico-techanical Properties of Starch Treated Jute Yarn Reinforced Polypropylene Composites: Effect of Gamma Radiation, J. Polym. Plast. Tech. Eng., 48: 542548. 2. Recent Development in Natural Fiber Reinforced Polypropylene Composites RAMAKRISHNA MALKAPURAM, VIVEK KUMAR AND YUVRAJ SINGH NEGI.Journal of REINFORCED PLASTICS AND COMPOSITES, vol. 28,No. 10/20098. 3. Physico-mechanical properties of chemically treated coir reinforced polypropylene composites Md. Nazrul Islam , Md. Rezaur Rahman, Md. Mominul Haque, Md. Monimul Huque 4. C.Y C. Y. Lai , S. M. Sapuan , M. Ahmad , N. Yahya and K. Z. H. M. Dahlan Mechanical and electrical properties of coconut coir fiber- Reinforced polypropylene composites 5. Lee S. Y., Doh G. H., Kang I. A.: Thermal behavior of hwangto and wood flour reinforced high density polyethylene (HDPE) composites. Mokchae Konghak, 5966 (2006).Lee et al. eXPRESS Polymer Letters Vol.2, No.2 (2008) 7887 6. Liang G., Xu J., Bao S., Xu W.: Polyethylene/maleic anhydride grafted polyethylene/ organic-montmorillonitenano composites. Preparation, microstructure, and mechanical properties. Journal of Applied PolymerScience, 91,39743980 (2004). 7. Gassan J and Bledzki A. K, Possibilities for improving the mechanical properties of jute/epoxy composites by alkali treatment of fibres, Composite Science and Technology, 59 (9), 1999, pp. 1303-1309. 8. Rana AK,Mandal A, Bandyopadhyay S.Short jute fiber reinforced Polypropylene composites: effect of compatibilizer, impact modifier and fiber Loading. Compos Sci Technol 2003;63:8016. 9. Panthapulakkal S, Sain M. Injection molded wheat straw and corn steam filled polypropylene composites. J Polym Environ 2006;14:265272. 10. Yang HS, Kim HJ, Son J, Park HJ, Lee BJ, Hwang TS. Rice-husk flour filled polypropylene composites; mechanical and morphological study. Struct 4;63:305312. 11. Jamal SM, Ahmad I, Abdullah I. Effect of rice husk filler on the mechanical and thermal properties of natural rubber compatibilized High density polyethylene/natural rubber blends. J Polym Res 6;13:315321. 12. Premlal HGB, Islamil H, Baharin A. A comparison of the mechanical properties of rice husk powder filled polypropylene composites with talc filled polypropylene composites. Polym Test 2002;21:833839. 13. Lilholt H and Lawther J.M, Comprehensive Composite Materials, chapter 1.10, 2000, Elsevier Ltd. 14. pp-coir composites-its fabrication, process parameters and properties .Md.Asad akhtar,Md nazrul islam and M.A gafur. 15. Yang HS, Kim HJ, Park HJ, Lee BJ, Hwang TS. Water absorption behavior and mechanical properties of lignocellulosic filler-polyolefin bioomposites. Struct 2006;72:429437. 16. Yang HS, Kim HJ, Park HJ, Lee BJ, Hwang TS. Effect of compatibilizing agents on rice husk flour reinforced polypropylene composites. Compos Struct2007; 77:4555.198 M.N. Islam et al. / Composites: Part A 41 (2010) 192198 DSC melting results of pp having the coir composition of 30% DSC melting results of PP/coir. Exo heat flow; DSC melting results of PP/coir. Endo heat flow; World Academy of Science, Engineering and Technology 73 2013 1734