CHEM131 - Spring 14 -April 8

Lecture April 8
1
Hour II this Thursday April 10:
acid-base reactions,
oxidation-reduction (Chap. 4)
Chap. 9 and 10
A bit more on MO Theory
Review
See Study Guide posted
CHEM131 - Spring 14 -April 8
MO Diagram of a Heteronuclear
Diatomic Molecule
2
See Figure p. 443
2p
2p
2s
2s
!*2p
!2p
"2p
"*2p
!*2s
!2s
CHEM131 - Spring 14 -April 8
Filling NO
3
2p
2p
2s
2s
!*2p
!2p
"2p
"*2p
!*2s
!2s
N
o
CHEM131 - Spring 14 -April 8
Filling the MO
4
2p
2p
2s
2s
!*2p
!2p
"2p
"*2p
!*2s
!2s
Bond
Order =
1/2 (6-1)
=2.5
CHEM131 - Spring 14 -April 8
Study Guide - Chap. 4
5
Chapter 4:
Write balanced chemical equations, and net ionic equations
for acid/base reactions.
Know the common strong acids and bases given in Table
4.2
Neutralization calculations with strong acids and bases
Concentration of a base [OH
-
] from the solubility of a
compound or the concentration of the aqueous solution.
Identify the oxidation numbers of elements in compounds,
oxidation-reduction reactions, the compound oxidized and
reduced and the oxidizing agent and reducing agent in a
reaction
CHEM131 - Spring 14 -April 8
Oxidation-Reduction Review
6
Rules on p. 164
Lead-Acid Battery
Pb(s) + PbO
2
(s) + 2 H
2
SO
4
(aq) !
2 PbSO
4
(s) + 2 H
2
O(l)
Pb 0 to +2
Pb +4 to +2
oxidation
reduction
Pb is the reducing agent
PbO
2
is the oxidizing agent
CHEM131 - Spring 14 -April 8
Acid-Base Reaction Review
7
Acid + base ! salt + H
2
O(l)
Only strong acids and bases - Table 4.2
HNO
3
(aq) + KOH(aq) ! KNO
3
(aq) + H
2
O(l)
Net ionic reaction:
H
+
(aq) + OH
-
(aq) ! H
2
O(l)
Neutralization is when n
acid
= n
base
Remember: n = MV
CHEM131 - Spring 14 -April 8
Chap. 9 and 10
8
Write Lewis Dot Structures for atoms, ions, and molecules
Write resonance structures for molecules
Predict and name the valence shell electron orbital geometries of
central atoms in a molecule.
Predict and name the molecular geometries, estimate bond angles.
Formal charge - use to select between possible structures
Predict the relative polarity of bonds and molecules
Give the orbital hybridization responsible for bonds to the central atom.
Identify sigma and pi bonds in molecules.
Structure of Benzene and other organic molecules (be able to identify
the hybridization of specific atoms in the structure.)
MO theory only for diatomic molecules and their ions (will be given
the diagram to fill in.)
CHEM131 - Spring 14 -April 8
Quiz of the Day
9
Assuming
this diagram
is valid for
the NF
system, give
the bond
order. Use .5
to designate
1/2
2p
2p
2s
2s
!*2p
!2p
"2p
"*2p
!*2s
!2s
Answer: 2.0