Physical Chemistry -1 ( 0303 241 )

Fall Semester 2007 / 2008

11 - 12 am, STT (Chem. 107)
Dr. M. B. Zughul
O!"e #$urs% 12 - 1 &m, STT
Textbook% Physical Chemistry, 4
th
Edition, by K. J. Laidler, J. H.
Meiser and B.C. Sanctuary, Houghton Milin, Boston (!""#).
E$ams% 1
st
E$am % Thurs'a(, 11 a.m. , )$*em+er 8, 2007.
2
,'
E$am % Thurs'a(, 11 a.m. , De"em+er 27, 2007.
%inal E$am % &o be announced later on.
-ra'!,g S(stem% 1
st
E$am% 2./, 2
,'
E$am% 2./, %inal E$am% .0/.
Course Outline
1. The Nature o Physical Chemistry an! the "inetic Theory o #ases%
Classical mechanical and e'uilibrium conce(ts, ideal gases and e'uation o
state, )inetic theory o gases, molecular collisions, barometric distribution la*,
real gases, +an der ,aals e'uation o state ( Cha(ter -, 8 #rs ).
2$ The %irst &a' o Thermo!ynamics%
E'uilibrium states and re+ersibility, energy, heat and *or) conce(ts,
thermochemistry, ideal gas relationshi(s, real gases ( Cha(ter !, 8 #rs ).
3$ The (econ! an! Thir! &a's o Thermo!ynamics%
&he Carnot cycle, irre+ersible (rocesses, entro(y conce(t and entro(y changes,
third la* o thermodynamics, e'uilibrium conditions, .ibbs ree energy,
Ma$*ell relations, .ibbs/Helmholt0 e'uation ( Cha(ter #, 8 #rs ).
4$ Chemical )*uilibrium%
E'uilibria in+ol+ing ideal and non/ideal gases, solution e'uilibrium,
heterogeneous e'uilibrium, tests o e'uilibrium, cou(led reactions, tem(erature
de(endence o e'uilibrium constants ( Cha(ter 4, 0 #rs ).
+$ Phases an! (olutions%
Phase recognition, +a(or (ressure relations, classiication o (hase transitions,
1aoult2s and Henry2s la*s, (artial molar 'uantities, solution thermodynamics,
colligati+e (ro(erties ( Cha(ter 3, 8 #rs ).
,$ Phase )*uilibria%
E'uilibria bet*een (hases, one/com(onent systems, binary systems in+ol+ing
+a(or, condensed binary systems, ternary systems ( Cha(ter 4, 8 #rs ).
1ecommended 1eerences
1$ 12h(s!"al Chem!str(,3 4
r'
5'!t!$, +( 6. 7. S!l+( a,' 6. 8. 8l+ert(, 7$h,
9!le( S$,s, )e: ;$r<, )e: ;$r< (2000).
2$ 12h(s!"al Chem!str(% a m$'er, !,tr$'u"t!$,,3 +( C. 5. D(<stra,
2re,t!"e-#all 2u+l!shers, =&&er Sa''le 6!*er (1>>7).
3$ 12h(s!"al Chem!str(,3 ?
th
5'!t!$, +( -. M. Barr$:, M"gra:-#!ll,
B$st$,, Massa"husetts (1>>?).
4$ 1The 5leme,ts $ 2h(s!"al Chem!str(,3 2
,'
5'!t!$, +( 2. 9. 8t<!,s,
O@$r' =,!*ers!t( 2ress, A$,'$,, =,!te' B!,g'$m (1>>?).
+$ 12h(s!"al Chem!str(,3 0
th
5'!t!$, +( C. ). Ae*!,e, M"-ra:-#!ll, )e:
;$r<, )e: ;$r< (1>>.).
,$ 12h(s!"al Chem!str(,3 .
th
5'!t!$, +( 2. 9. 8t<!,s, O@$r' =,!*ers!t(
2ress, A$,'$,, =,!te' B!,g'$m (1>>0).
-$ 12h(s!"al Chem!str(,3 +( -. B. Demula&all!, 2re,t!"e-#all 2u+l!shers,
5,gle:$$' Cl!s, )e: 7erse( (1>>4).
.$ 18 Te@t+$$< $ 2h(s!"al Chem!str(,3 +( B. B. Sharma a,' A. B.
Sharma, Da,! 5'u"at!$,al B$$<s, )e: Delh!, C,'!a (1>8?).
/$ 12r!,"!&les $ 2h(s!"al Chem!str( :!th 8&&l!"at!$,s t$ the B!$l$g!"al
S"!e,"es,3 +( D. Fre!el'er, 7$,es a,' Bartlett 2u+l!shers, B$st$,,
Massa"husetts (1>8.).
10$ 12h(s!"al Chem!str(,3 2,' 5'!t!$, +( 7. 2. Br$m+erg, 8ll(, a,' Ba"$,,
B$st$,, Massa"husetts (1>80).
11$ 12h(s!"al Chem!str(,3 +( B. D. Bh$sla, 6. Char', )e: Delh!, C,'!a
(1>84).
12$ 12h(s!"al Chem!str(,3 +( 9. 7. M$$re, 2re,t!"e-#all 2u+l!shers,
5,gle:$$' Cl!s, )e: 7erse( (1>72).
2