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391428 Rev 0214
TECHNI GOLD
25 ES
TECHNI GOLD
25 ES Page 2
Metric U.S.
Cleaning Solution Range Recommended Range Recommended
Tri-Sodium Phosphate 22.5-67.5 g/l 45 g/l 3-9 oz/gal 6 oz/gal
and/or Potassium Hydroxide 22.5-67.5 g/l 45 g/l 3-9 oz/gal 6 oz/gal
Leaching Solution
Sulfuric Acid 100 ml/l 100 ml/l 10% v/v 10% v/v
Leaching Procedure:
Please follow the recommended leaching procedure below. DO NOT install the plating solution
until the entire leaching procedure has been completed.
NOTE: If the tank walls are heavily coated with materials which cannot be removed by scrubbing,
a tank liner is recommended.
1. Remove the anodes and filters from the tank to be used. Dispose of filter cartridges and
anything else that may be contaminated with previous process chemicals.
2. Thoroughly wash down the tank and ancillary equipment with clean water.
3. Recirculate water throughout the complete system to remove water soluble materials.
4. Discard the recirculated water.
5. Add the cleaning solution to the tank and heat to 38 50 C (100 - 120 F). Recirculate
the solution throughout the tank and filter pumps for 4 - 8 hours.
6. Drain the cleaning solution and rinse the tank with clean DI water.
7. Fill the tank with clean DI water and recirculate throughout the tank and filter pumps.
8. Discard the rinse water.
9. Add the leaching solution and recirculate throughout the tank and filters pumps. Leave the
leaching solution in the tank for a minimum of eight (8) hours.
10. Drain the leaching solution and rinse the tank with clean DI water.
11. Fill the tank with clean DI water and recirculate throughout the tank and filter pumps.
12. If the tank had previously been used for lead-containing processes, analyze for lead (Pb)
and bismuth (Bi) concentrations in the rinse water. If the concentration of either is greater
than 5 ppm, discard the rinse water and repeat steps 9-12. If concentrations are both less
than 5 ppm, proceed to next step.
13. Discard the rinse water.
14. Prepare the plating solution according to the recommended specifications.
TECHNI GOLD
25 ES Page 3
SOLUTION MAKE-UP
1 liter 1 gallon
Deionized (DI) water 150 ml 15% v/v
Techni Gold
25 ES pH+ or
Techni Gold
25 ES pH- as needed.
5. Add gold as TG-25 Concentrate. Mix thoroughly.
6. Adjust to final volume with deionized water. Continue mixing and raise to operating
temperature. The solution is now ready for use.
OPERATING PARAMETERS
Range Optimum
Techni Gold
25 ES Page 4
REPLENISHMENT: TG-25 Concentrate contains 2.0 tr. oz. (62.2 gm) of gold per liter. Add one
troy ounce gold (=31.1 g or 500 ml) as TG-25 Concentrate every 4.2 ampere-hours.
pH ADJUSTMENT: The pH of Techni Gold
25 ES pH+, or with a 20-40% solution of sodium hydroxide.
The pH of Techni Gold
25 ES pH-.
SPECIFIC GRAVITY: The specific gravity of Techni Gold
25 ES Page 5
The technical statements, information and data contained herein are believed to be accurate and reliable; however, no warranties, express or implied,
including warranties of merchantability or fitness for a particular purpose, are made regarding the products described. Since many variables and factors
affect processing, application or use, it is recommended that you perform tests to determine the suitability of this product for your particular use. Any oral
statements or advice concerning product selection or use do not constitute warranties. Delivered products are warranted to meet our standard
specifications at the time of sale and all sales are subject to the TERMS AND CONDITIONS OF SALE reproduced on the reverse side of each invoice.
WASTE TREATMENT
It is the users responsibility to verify that treatment procedures comply with federal, state, and
local regulations. Working solutions should be diluted, neutralized and disposed of in accordance
with local and federal regulations. Consult your local agencies for recommendations for your
area. Consult your Technic representative for further information.
ORDERING INFORMATION
Contact your local Technic company to order products and/or Material Safety Data Sheets:
Product
Code
Product Name
Liquid
Solid
or Salt
Application
391428 Techni Gold
25 Make Up ES Liquid
For Makeup
and Replenishment
390204 TG-25E Stabilizer Salt
For Makeup
and Replenishment
391327 TG-25 Concentrate Liquid
For Makeup
and Replenishment
390210 TG-25E Additive A Salt
For Makeup
and Replenishment
390204A TG-25 Additive E Liquid
For Makeup
and Replenishment
390214B TG-25E Buffer Salts Solid
For Makeup
and Replenishment
390100 Techni Gold
25 ES pH- Liquid
For pH
Adjustment
390101 Techni Gold
25 ES pH+ Liquid
For pH
Adjustment
391427 Techni Gold
25 ES RTU Liquid
For Makeup
and Replenishment
391428 Rev 0214
TECHNI GOLD
25 ES Appendix Page 1
ANALYSIS FOR TG-25E BUFFER SALTS IN TECHNI GOLD
25 ES
Reagents:
0.1 N Iodine
Starch indicator solution
Procedure:
1. Pipette 5 ml of sample into a 1 liter Erlenmeyer flask.
2. Dilute to 500 ml with distilled water.
3. Add 5 ml of starch indicator solution.
4. Titrate with 0.1 N Iodine to a faint blue endpoint (stirring constantly).
Calculation:
oz/gal of TG-25E Buffer Salts = mls of 0.1 N Iodine x 0.1683
g/l of TG-25E Buffer Salts = mls of 0.1 N Iodine x 1.2623
Na
2
SO
3
+ I
2
+ H
2
O 2 HI + Na
2
SO
4
TECHNI GOLD
25 ES Appendix Page 2
ANALYTICAL PROCEDURE FOR TG-25E STABILIZER
Equipment:
2 ml pipette
500 ml volumetric flask
Spectrophotometer capable of absorbance measurement at wavelength of 266 nm.
Quartz cuvette
Procedure:
1. Pipet 2 ml of plating solution into a 500 ml volumetric flask. Fill to mark with DI water.
2. Using a clean cuvette, determine the absorbance of DI water at 266 nm. This is the blank
value.
3. In the same cuvette, determine the absorbance of the diluted solution at 266 nm.
4. Subtract the blank from the sample absorbance.
5. Use this net absorbance to determine the stabilizer concentration from the attached curve.
6. Useable stabilizer range is 2.5 8.0 g/l of solution. Optimum range is 4 6.5 g/l.
Calibration Curve for TG-25E Stabilizer
0
0.2
0.4
0.6
0.8
1
1.2
1.4
0 1 2 3 4 5 6 7 8 9
Stabilizer Concentration (g/l)
A
b
s
o
r
b
a
n
c
e
(
2
6
6
n
m
)
391428 Rev 0214