UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS General Certificate of Education Ordinary Level

CHEMISTRY Paper 1 Multiple Choice Additional Materials: Multiple Choice Answer Sheet Soft clean eraser Soft pencil (type B or HB recommended)

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October/November 2009 1 hour

*8518512898*

READ THESE INSTRUCTIONS FIRST Write in soft pencil. Do not use staples, paper clips, highlighters, glue or correction fluid. Write your name, Centre number and candidate number on the Answer Sheet in the spaces provided unless this has been done for you. There are forty questions on this paper. Answer all questions. For each question there are four possible answers A, B, C and D. Choose the one you consider correct and record your choice in soft pencil on the separate Answer Sheet. Read the instructions on the Answer Sheet very carefully. Each correct answer will score one mark. A mark will not be deducted for a wrong answer. Any rough working should be done in this booklet. A copy of the Periodic Table is printed on page 16.

This document consists of 13 printed pages and 3 blank pages.

IB09 11_5070_01/5RP UCLES 2009

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2 1 In which option do the three particles each have the same number of electrons? A B C D 2 Cl F K+ Li+ Br Ne Ca2+ Na+ I Na+ Br K+

Why does neon gas, Ne, diffuse faster than carbon dioxide gas, CO2? A B C D Neon atoms have the lower mass. Neon does not form molecules. Neon is a noble gas. Neon is less dense than air.

Which reagent could be used to distinguish between dilute nitric acid and dilute hydrochloric acid? A B C D aqueous barium chloride aqueous silver nitrate aqueous sodium hydroxide copper(II) carbonate

The conical flask contains compound X which is present in solid, liquid and gaseous states.

gaseous X

solid X liquid X

Which statement is correct? A B C D A gaseous X molecule has a lower mass than a liquid X molecule. Energy is released when X changes from liquid to solid. Liquid X is at a higher temperature than solid X. Liquid X molecules vibrate about fixed positions.

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3 5 Which statement is always true when two atoms join together by a covalent bond? A B C D 6 One atom is a metal, the other atom is a non-metal. One atom loses one electron, the other atom gains one electron. The two atoms share one electron. The two atoms share two electrons.

The diagram shows the structures of diamond and graphite.

diamond
Which property do these substances have in common? A B C D 7 They are giant structures. They can act as lubricants. They can conduct electricity. They contain only covalent bonds.

graphite

Calcium reacts with phosphorus to form the ionic compound calcium phosphide. Which ions will this compound contain? A B C D Ca2+ and P3 Ca2+ and P5 Ca2 and P3+ Ca2 and P5+

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4 8 All of the following substances can conduct electricity. Which substances conductivity is not due to the movement of electrons? A B C D aluminium graphite lithium chloride mercury

1 2 A sample of hydrogen is a mixture of the two isotopes 1H and 1H .

The relative atomic mass of oxygen is 16. What are possible values of the relative molecular mass of different molecules of water formed by the combination of oxygen and hydrogen? 1 2 3 A B C D 1 only 1 and 2 only 1 and 3 only 1, 2 and 3 18 19 20

10 Calcium reacts with water as shown. Ca(s) + 2H2O(l) Ca(OH)2(aq) + H2(g) What is the total mass of the solution that remains when 40 g of calcium reacts with 100 g of water? A 58 g B 74 g C 138 g D 140 g

11 What products are formed when concentrated aqueous potassium chloride is electrolysed? at the anode (positive) A B C D chlorine chlorine oxygen oxygen at the cathode (negative) hydrogen potassium hydrogen potassium

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5 12 Hydrogen reacts with oxygen as shown in the equation below. 2H2(g) + O2(g) 2H2O(l) How much gas will remain if 2 dm3 of hydrogen are reacted with 1 dm3 of oxygen at room temperature? A 0 dm3 B 1 dm3 C 2 dm3 D 3 dm3

13 Two cells, P and Q, containing different liquids, were connected in series with a battery, a suitable lamp and inert electrodes, as shown in the diagram.

lamp

For which pair of liquids did the lamp light up? in P A B C D concentrated sodium chloride solution copper(II) sulfate solution ethanol mercury in Q concentrated sugar solution propanol molten lead(II) bromide dilute hydrochloric acid

14 The burning of hydrogen is an exothermic reaction. Which statement explains this? A B C D More bonds are broken than are formed. More bonds are formed than are broken. Overall, the bonds broken are stronger than those formed. Overall, the bonds formed are stronger than those broken.

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6 15 In the Contact process for making sulfuric acid, one step involves the oxidation of sulfur dioxide to sulfur trioxide. 2SO2(g) + O2(g) The forward reaction is exothermic. Which change would increase the amount of sulfur trioxide produced at equilibrium? A B C D adding a catalyst decreasing the pressure decreasing the temparature increasing the temperature 2SO3(g)

16 Which graph corresponds to the catalytic decomposition of 1 mole of hydrogen peroxide? 2H2O2 2H2O + O2

A 1 total number of moles of oxygen produced 1 total number of moles 1 of oxygen /2 produced 0 0 time C 1 total number of moles of oxygen produced 1 total number of moles of oxygen 1/2 produced 0 0 time 0 0

/2

time D

/2

time

17 Which row in the table describes the processes occurring at the electrodes when molten sodium chloride is electrolysed? anode (positive) A B C D oxidation reduction oxidation reduction cathode (negative) reduction oxidation oxidation reduction

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7 18 Lithium and rubidium are both in Group I of the Periodic Table. Which statement is correct? A B C D Lithium atoms and rubidium atoms have the same number of electrons in their outer shell. Lithium atoms are larger than rubidium ions. Lithium ions and rubidium ions have the same number of electrons in their outer shell. Rubidium ions are larger than rubidium atoms.

19 Which mixture would react with dilute sulfuric acid to form two different gases? A B C D copper and magnesium carbonate copper(II) carbonate and magnesium copper(II) carbonate and magnesium oxide copper(II) oxide and magnesium

20 Which salts are soluble in water? 1 2 3 4 A 1 only ammonium carbonate, (NH4)2CO3 calcium carbonate, CaCO3 lead(II) carbonate, PbCO3 sodium carbonate, Na2CO3 B 1 and 2 C 1 and 4 D 2 and 3

21 Which compound in a 1 mol / dm3 solution has the lowest pH value? A B C D ethanoic acid hydrogen chloride sodium chloride sodium hydroxide

22 In the Periodic Table, how many periods include the elements of atomic numbers 1-18? A 2 B 3 C 6 D 8

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8 23 The ionic equation shows the reaction between potassium iodide and iron(III) chloride. 2Fe3+(aq) + 2I (aq) 2Fe2+(aq) + I2(aq) Which terms describe the changes to the iron(III) ions and iodide ions? iron(III) ions A B C D oxidised oxidised reduced reduced iodide ions reduced oxidised oxidised reduced

24 Element Z is in Group VI of the Periodic Table. Which formula is incorrect? A Z 2 B Z 2O3 C

ZO 2 4

ZO3

25 Which is a property of aqueous potassium iodide? A B C D It does not conduct electricity. It is a purple solution. It is decolourised by chlorine. It reacts with aqueous bromine to form iodine.

26 The carbonate of metal X is a white solid. It decomposes when heated to form carbon dioxide and a yellow solid oxide. What is metal X? A B C D copper iron lead sodium

27 In which reaction do the products formed not include a salt? A B C D calcium(II) carbonate with hydrochloric acid copper(II) oxide with hydrogen copper(II) oxide with sulfuric acid copper(II) sulfate with sodium hydroxide

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9 28 In the manufacture of iron, using a blast furnace, which reaction generates heat? A B C D CaCO3 CaO + CO2 Fe2O3 + 3CO 2Fe + 3CO2 C + O2 CO2 C + CO2 2CO

29 Which oxide is most readily reduced to the metal by heating in a stream of hydrogen? A B C D calcium oxide lead(II) oxide sodium oxide zinc oxide

30 Which ionic equation represents the reaction taking place at the anode during the electrolysis of molten aluminium oxide? A B C D Al 3+ + 3e Al 2Al 3+ + 3O2 Al 2O3 O2 2e O2 2O2 4e O2

31 Which type of compound will liberate ammonia when heated with ammonium sulfate? A B C D an acid an alkali a reducing agent a salt

32 What is the concentration of hydrogen ions in 0.05 mol / dm 3 sulfuric acid? A 0.025 g / dm 3 B 0.05 g / dm 3 C 0.10 g / dm 3 D 2.0 g / dm 3

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10 33 Four current problems in our atmosphere are listed. 1 2 3 4 acid rain depletion of the ozone layer presence of greenhouse gases incomplete combustion of carbon compounds

Which atmospheric pollutant is responsible for each problem? W chlorofluorocarbons X Y Z 1 A B C D W X X Z sulfur dioxide carbon monoxide carbon dioxide 2 X W Z Y 3 Z Z W X 4 Y Y Y W

34 Which process takes place during photosynthesis? A B C D Carbohydrate is decomposed and oxygen is formed. Carbon dioxide is taken in and oxygen is formed. Oxygen is taken in and carbohydrate is formed. Oxygen is taken in and carbon dioxide is formed.

35 Cholesterol is an organic molecule that occurs in the blood stream. What type of compound is cholesterol? A B C D an acid an alcohol an alkane an alkene

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11 36 Substance X, molecular formula C4H8, does not react with hydrogen. What is the structural formula of X?
A H C H H C H C H H C H H C H H H H C C B H C H H H H H H C C H C H C C H H H H H C H H C D H C H C H H

37 Natural gas, petroleum and diesel are all used as energy sources. Which gas is not produced when these sources are burned? A B C D carbon dioxide carbon monoxide hydrogen water

38 The structural formula of butenedioic acid is shown.

O C H O H C H C C O H O

Which statement about butenedioic acid is not correct? A B C D It decolourises aqueous bromine. Its aqueous solution reacts with sodium carbonate. Its empirical formula is the same as its molecular formula. Its relative molecular mass is 116.

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12 39 A mixture of four gases, methane, ethane, propane and butane is cooled until the first drop of liquid is formed. What compound is most likely to be present in this drop? A B C D butane ethane methane propane

40 Which statement about Terylene is correct? A B C D It is an addition polymer. It is an alkene. It is a polyamide. It is a polyester.

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University of Cambridge International Examinations is part of the Cambridge Assessment Group. Cambridge Assessment is the brand name of University of Cambridge Local Examinations Syndicate (UCLES), which is itself a department of the University of Cambridge.

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DATA SHEET The Periodic Table of the Elements

Group III
1

I H
Hydrogen

II

IV

VI

VII

0
4

He
Helium

1 11 12 14 16 19

2 20

Li
Boron Carbon

Be
5 27 28 6 7

N
Nitrogen

O
Oxygen

F
Fluorine

Ne
Neon

Lithium

Beryllium

8 31 32

9 35.5

10 40

23

24

Na
Aluminium

Mg
13 51 52 55 56 59 59 64 65 70

Al
14

Si
Silicon

P
Phosphorus

S
Sulfur

Cl
Chlorine

Ar
Argon

Sodium

Magnesium

11

12

15 73 75

16 79

17 80

18 84

39

40

45

48

K
Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc

Ca
23 93 96 101 103 106 108 112 24 25 26 27 28 29 30

Sc

Ti

Cr

Mn

Fe

Co

Ni

Cu

Zn
31

Ga
Gallium

Ge
Germanium

As
Arsenic

Se
Selenium

Br
Bromine

Kr
Krypton

Potassium

Calcium

Scandium

Titanium

19

20

21

22

32 115 119

33 122

34 128

35 127

36 131

16

85

88

89

91

Rb
Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver

Sr
41 181 184 186 190 192 195 197 42 43 44 45 46 47

Zr

Nb

Mo

Tc

Ru

Rh

Pd

Ag
48

Cd
Cadmium

In
Indium

Sn
Tin

Sb
Antimony

Te
Tellurium

I
Iodine

Xe
Xenon

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49 201

Rubidium

Strontium

Yttrium

Zirconium

37

38

39

40

50 204 207

51 209

52

53

54

133

137

139

178

Cs
Tantalum Iridium Tungsten Rhenium Osmium Platinum

Ba
73 77 74 75 76 78

La Ta W Re Os Pt

Hf

Ir

Au
Gold

Hg
Mercury

Tl
Thallium

Pb
Lead

Bi
Bismuth

Po
Polonium

At
Astatine

Rn
Radon

Caesium

Barium

Lanthanum

Hafnium

55

56

57

72

79

80

81

82

83

84

85

86

226

227

Fr
140 141 144 150

Ra

Ac
152 157 159 162 165 167 169 173 175

Francium

Radium

Actinium

87

88

89

*58-71 Lanthanoid series 90-103 Actinoid series Ce

Cerium Praseodymium Neodymium Promethium

Pr
59 60 238 61

Nd

Pm
62

Sm
Samarium

Eu
Europium

Gd
Gadolinium

Tb
Terbium

Dy
Dysprosium

Ho
Holmium

Er
Erbium

Tm
Thulium

Yb
Ytterbium

Lu
Lutetium

58 232

63

64

65

66

67

68

69

70

71

a = relative atomic mass

Key Th
Thorium Protactinium Uranium

X Pa
91 92

X = atomic symbol
90

U
93

Np
Neptunium

Pu
Plutonium

Am
Americium

Cm
Curium

Bk
Berkelium

Cf
Californium

Es
Einsteinium

Fm
Fermium

Md
Mendelevium

No
Nobelium

Lr
Lawrencium

b = proton (atomic) number

94

95

96

97

98

99

100

101

102

103

The volume of one mole of any gas is 24 dm3 at room temperature and pressure (r.t.p.).