This document consists of 8 printed pages.

SP (CW) S76396
UCLES 2004 [Turn over
UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS
Joint Examination for the School Certificate
and General Certificate of Education Ordinary Level
CHEMISTRY 5070/03
Paper 3 Practical Test
October/November 2004
1 hour 30 minutes
Candidates answer on the Question Paper.
Additional Materials: as listed in Instructions to Supervisors
READ THESE INSTRUCTIONS FIRST
Write your name, Centre number and candidate number in the spaces at the top of this page.
Answer both questions.
Write your answers in the spaces provided on the question paper.
You should show the essential steps in any calculation and record all experimental results in the spaces
provided on the question paper.
If you are using semi-micro methods in Question 2, you should modify the instructions to suit the size of
apparatus and the techniques you are using.
The number of marks is given in brackets [ ] at the end of each question or part question.
Qualitative Analysis notes are printed on page 8.
Centre Number Index Number Name
For Examiners Use
If you have been given a label, look at the
details. If any details are incorrect or
missing, please fill in your correct details
in the space given at the top of this page.
Stick your personal label here, if
provided.
1
2
TOTAL
2
5070/03/O/N/04
1 Solution P was prepared by dissolving 3.30 g of a compound MIO
3
in 1.00 dm
3
of water. An
acidified solution of MIO
3
oxidises potassium iodide to iodine which can be titrated with
sodium thiosulphate.
MIO
3
+ 5I

+ 6H
+

M
+
+ 3I
2
+ 3H
2
O
I
2
+ 2S
2
O
3
2

2I

+ S
4
O
6
2
You are to determine the relative molecular mass of MIO
3
and hence identify M.
Q is 0.100 mol/dm
3
sodium thiosulphate.
(a) Put Q into the burette.
Pipette a 25.0 cm
3
(or 20.0 cm
3
) portion of P into a flask and add about a test-tubeful of
dilute sulphuric acid followed by about a test-tubeful of aqueous potassium iodide. The
solution should turn red-brown. Do not add the starch indicator at this stage.
Add Q from the burette until the red-brown colour fades to pale yellow, then add a few
drops of the starch indicator. This will give a dark blue solution. Continue adding Q
slowly from the burette until one drop of Q causes the blue colour to disappear, leaving
a colourless solution. Record your results in the table, repeating the titration as many
times as you consider necessary to achieve consistent results.
Results
Burette readings
Summary
Tick () the best titration results.
Using these results, the average volume of Q required was ........................ cm
3
.
Volume of solution P used was ........................ cm
3
. [12]
For
Examiners
Use
UCLES 2004
Titration number 1 2
Final reading / cm
3
Initial reading / cm
3
Volume of Q used / cm
3
Best Titration results ()
3
5070/03/O/N/04 [Turn over
For
Examiners
Use
UCLES 2004 5070/03/O/N/04
(b) Q is 0.100 mol/dm
3
sodium thiosulphate.
One mole of MIO
3
reacts with potassium iodide to produce iodine. The iodine
produced reacts with six moles of sodium thiosulphate.
Calculate the concentration, in mol/dm
3
, of MIO
3
in solution P.
Concentration of MIO
3
in P is .......................................... mol/dm
3
. [2]
(c) P contains 3.30 g/dm
3
MIO
3
.
Using your answer to (b), calculate the relative molecular mass of MIO
3
.
Relative molecular mass of MIO
3
is .......................................... [1]
(d) Using your answer to (c), and the Periodic Table provided on page 5, calculate the
relative atomic mass of M.
Relative atomic mass of M is .......................................... [1]
(e) Using your answer to (d) and the Periodic Table suggest an identity for the metal M.
Metal M is ........................................... [1]
4
5070/03/O/N/04
Question 2 starts on page 6.
5
5070/03/O/N/04 [Turn over UCLES 2004 5070/03/O/N/04
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*
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5070/03/O/N/04
For
Examiners
Use
UCLES 2004
2 You are provided with solutions R, S and T which contain the same anion. Carry out the
following experiments on each solution and record your observations in the table. You should
test and name any gas evolved.
Test
no.
Test Observations
with solution R
1
2
3
4
(a) To a portion of the solution, add
aqueous sodium hydroxide until a
change is seen.
(b) Add excess aqueous sodium
hydroxide to the mixture from (a).
(c) To a portion of the mixture from
(b) in a boiling tube, add an
equal volume of aqueous
hydrogen peroxide.
(a) To a portion of the solution, add
aqueous ammonia until a change
is seen.
(a) To a portion of solution R, add
aqueous barium nitrate and leave
the mixture to stand for a few
minutes.
(b) Add excess aqueous ammonia to
the mixture from (a).
(b) Add nitric acid to the mixture from
(a).
(a) To a portion of solution R, add
aqueous silver nitrate and leave
the mixture to stand for a few
minutes.
(b) Add nitric acid to the mixture from
(a).
Conclusions
The anion (negative ion) present in R is ......................
[1]
7
5070/03/O/N/04
For
Examiners
Use
UCLES 2004
[22]
Test
no.
1
2
3
4
Observations
with solution S
Observations
with solution T
DO NOT CARRY OUT
THESE TESTS FOR
S AND T.
8
5070/03/O/N/04
CHEMISTRY PRACTICAL NOTES
Tests for anions
Tests for aqueous cations
Tests for gases
UCLES 2004
anion test
add dilute acid
acidify with dilute nitric acid,
then add aqueous silver nitrate
acidify with dilute nitric acid,
then add aqueous lead(II) nitrate
add aqueous sodium hydroxide then
aluminium foil; warm carefully
acidify with dilute nitric acid then add
aqueous barium nitrate
test result
effervescence, carbon dioxide
produced
white ppt.
yellow ppt.
ammonia produced
white ppt.
carbonate (CO
3
2
)
chloride (Cl

)
[in solution]
iodide (I

)
[in solution]
nitrate (NO
3

)
[in solution]
sulphate (SO
4
2
)
[in solution]
cation
aluminium (Al
3+
)
ammonium (NH
4
+
)
calcium (Ca
2+
)
copper(II) (Cu
2+
)
iron(II) (Fe
2+
)
iron(III) (Fe
3+
)
zinc (Zn
2+
)
effect of aqueous sodium hydroxide
white ppt., soluble in excess
giving a colourless solution
ammonia produced on warming
white ppt., insoluble in excess
light blue ppt., insoluble in excess
green ppt., insoluble in excess
red-brown ppt., insoluble in excess
white ppt., soluble in excess
giving a colourless solution
effect of aqueous ammonia
white ppt., insoluble in excess

no ppt. or very slight white ppt.

light blue ppt., soluble in excess
giving a dark blue solution
green ppt., insoluble in excess
red-brown ppt., insoluble in excess
white ppt., soluble in excess
giving a colourless solution
turns aqueous potassium dichromate(VI) green sulphur dioxide (SO
2
)
gas test and test result
turns damp red litmus paper blue
turns limewater milky
bleaches damp litmus paper
pops with a lighted splint
relights a glowing splint
ammonia (NH
3
)
carbon dioxide (CO
2
)
chlorine (Cl
2
)
hydrogen (H
2
)
oxygen (O
2
)
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