Let's examine water vapor in the atmosphere and how it varies with temperature dry-bulb wet-bulb Click tabs to navigate!!! DT Relative Humidity Data for Washington, DC National Airport FALSE How does relative humidity,%RH, vary during the day? Why? Sinex 2010 to get data: http://www.accuweather.com/forecast-past24-us.asp?partner=accuweather&zipcode=20001&metric=1 20 25 30 35 0 15 30 45 60 75 90 1:00 PM 2:00 PM 3:00 PM 4:00 PM 5:00 PM 6:00 PM 7:00 PM 8:00 PM 9:00 PM 10:00 PM 11:00 PM 12:00 AM 1:00 AM 2:00 AM 3:00 AM 4:00 AM 5:00 AM 6:00 AM 7:00 AM 8:00 AM 9:00 AM 10:00 AM 11:00 AM 12:00 PM T, o C %RH Time add temperature data to graph midnight 7/27 - afternoon 7/28 - noon 27-28 July 2009 Time Temp. o C %RH 1:00 PM 31 54 -50 2:00 PM 32 52 -50 3:00 PM 32 49 -50 4:00 PM 33 44 -50 5:00 PM 32 48 -50 6:00 PM 32 52 -50 7:00 PM 31 56 -50 8:00 PM 29 62 -50 9:00 PM 29 66 -50 10:00 PM 28 71 -50 11:00 PM 27 73 -50 12:00 AM 27 73 -50 1:00 AM 26 76 -50 2:00 AM 26 78 -50 3:00 AM 26 75 -50 4:00 AM 26 73 -50 5:00 AM 25 78 -50 6:00 AM 24 84 -50 7:00 AM 24 81 -50 8:00 AM 25 81 -50 9:00 AM 26 78 -50 10:00 AM 26 75 -50 11:00 AM 26 73 -50 12:00 PM 27 66 -50 Determining Relative Humidity with a Psychrometer Dry-bulb temperature = 25 o C atmospheric pressure = 1013 mb 760 torr Wet-bulb temperature = 20 o C difference in temperature = 5.0 o C Sea Level Pressure Why is the temperature of the wet-bulb thermometer lower? Calculated quantities: amount of water vapor maximum water vapor that found in air can exist in air actual vapor pressure = 19.9 mb saturated vapor pressure = 31.7 mb 15.0 torr 23.8 torr actual vapor density = 14.6 g/m 3 saturated vapor density = 23.1 g/m 3 Relative Humidity = 63.0 % Dew Point Temperature = 17.5 o C Formulas for calculated quantities from: click here http://www.4wx.com/wxcalc/formulas/rhTdFromWetBulb.php Sinex 2010 Saturated Vapor Density of Water Mathematical Model for Saturated Vapor Density (VD) saturated vapor density, g/m 3 as a function of temperature (T) over the range of 0-40 o C FALSE T, o C measured calculated error 0 4.85 -50 5 6.80 -50 10 9.40 -50 This is the 11 10.01 -50 maximim 12 10.66 -50 amount of 13 11.35 -50 water vapor 14 12.07 -50 that can exist 15 12.83 -50 in air at a 20 17.30 -50 specific 25 23.00 -50 temperature. 30 30.40 -50 37 44.00 -50 40 51.10 -50 Vapor density is the mass of water vapor in grams found in one cubic meter of air. Similar to vapor pressure curve. VD = 0.00036T 3 + 0.00543T 2 + 0.37067T + 4.81865 R 2 = 1.00 data from: http://hyperphysics.phy-astr.gsu.edu/HBASE/Kinetic/watvap.html#c1 Sinex 2010 click here The model results here are slightly different. 0 10 20 30 40 50 60 0 5 10 15 20 25 30 35 40 VD g/m 3 Temperature, o C fit model Relative Humidity How does the temperature change influence the relative humidity? temperature saturated actual vapor density of air = 14.5 g/m 3 17 vapor density, g/m 3 (measured ) 170 - - - - - T, o C calculated relative humidity 0 4.82 300.9 Dew Point 5 6.85 211.6 0 100 TRUE Temperature 10 9.43 153.8 40 100 11 10.03 144.5 (Find this 12 10.67 135.9 point on the 13 11.35 127.8 graph for 14 12.06 120.2 your 15 12.82 113.1 conditions.) 20 17.28 83.9 25 23.10 62.8 30 30.55 47.5 37 44.20 32.8 40 51.37 28.2 Saturated vapor T %RH density removed How does dew form? 17 100.29 14.46 0.04 g o C g/m 3 water condenses based on: http://hyperphysics.phy-astr.gsu.edu/HBASE/Kinetic/relhum.html#c3 Sinex 2010 click here saturation 0 50 100 150 200 250 300 350 0 5 10 15 20 25 30 35 40 r e l a t i v e
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temperature, o C add saturation line Temperature point on the add saturation line