MATERIAL SAFETY DATA SHEET

MSDS NO. 12556 Trade Name: CALCIUM CHLORIDE (All Grades) Revision Date: 06/08/2006

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Trade Name: Chemical Family: Product Use: Emergency Telephone (24 hr.): Supplied by: CALCIUM CHLORIDE (All Grades) Mixture Oil well drilling fluid additive. MSDS covers all grades. 281-561-1600 M-I L.L.C. P.O. Box 42842 Houston, TX 77242 www.miswaco.com 281-561-1512 Joanne Galvan, Sr. Product Safety Specialist 0

Telephone Number: Contact Person: Revision Number: HMIS Rating Health: 1

Flammability: 1

Physical Hazard: 0

PPE: E

HMIS Key: 4=Severe, 3=Serious, 2=Moderate, 1=Slight, 0=Minimal Hazard. *Chronic effects - See Section 11. See Section 8 for Personal Protective Equipment recommendations.

2. HAZARDS IDENTIFICATION
Emergency Overview: Canadian Classification: UN PIN No: Not regulated. Physical State: Solid. Odor: Warning! May cause severe eye and skin irritation. May cause respiratory tract irritation. WHMIS Class: Odorless D2B Color: White

Potential Health Effects: Acute Effects Eye Contact: Skin Contact: Inhalation: Ingestion: Carcinogenicity & Chronic Effects: Routes of Exposure: Target Organs/Medical Conditions Aggravated by Overexposure: May cause severe eye irritation. May cause corneal injury. May cause skin irritation. Prolonged contact with moist skin may cause severe irritation. May be irritating to the respiratory tract. May cause gastric distress, nausea and vomiting if ingested. See Section 11 - Toxicological Information. Eyes. Dermal (skin) contact. Inhalation. Eyes. Skin. Respiratory System.

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MSDS NO. 12556 Trade Name: CALCIUM CHLORIDE (All Grades) Revision Date: 06/08/2006 Page 2/6

3. COMPOSITION/INFORMATION ON INGREDIENTS
Ingredient Calcium chloride Potassium chloride Water Sodium chloride CAS No. 10043-52-4 7447-40-7 7732-18-5 7647-14-5 Wt. % 94 - 97 1-5 1-5 1-5 Comments: No comments. No comments. No comments. No comments.

4. FIRST AID MEASURES

Eye Contact: Skin Contact: Inhalation: Ingestion: Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention. Wash skin thoroughly with soap and water. Remove contaminated clothing and launder before reuse. Get medical attention if any discomfort continues. Move person to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Dilute with 2 - 3 glasses of water or milk, if conscious. Never give anything by mouth to an unconscious person. If signs of irritation or toxicity occur seek medical attention. Persons seeking medical attention should carry a copy of this MSDS with them.

General Notes:

5. FIRE FIGHTING MEASURES

Flammable Properties Flash Point: F (C): NA Flammable Limits in Air - Lower (%): ND Flammable Limits in Air - Upper (%): ND Autoignition Temperature: F (C): ND Flammability Class: NA Other Flammable Properties: ND Extinguishing Media: Use extinguishing media appropriate for surrounding fire. Protection Of Fire-Fighters: Special Fire-Fighting Procedures: Do not enter fire area without proper personal protective equipment, including NIOSH/MSHA approved self-contained breathing apparatus. Evacuate area and fight fire from a safe distance. Water spray may be used to keep fire-exposed containers cool. Keep water run off out of sewers and waterways. Hazardous Combustion Products: Oxides of: Carbon.

6. ACCIDENTAL RELEASE MEASURES

Personal Precautions: Spill Procedures: Use personal protective equipment identified in Section 8. Evacuate surrounding area, if necessary. Contain spilled material. Avoid the generation of dust. Sweep, vacuum, or shovel and place into closable container for disposal. Do not allow to enter sewer or surface and subsurface waters. Waste must be disposed of in accordance with federal, state and local laws.

Environmental Precautions:

7. HANDLING AND STORAGE

Handling: Put on appropriate personal protective equipment. Avoid contact with skin and eyes. Avoid generating or breathing dust. Use only with adequate ventilation. Wash thoroughly after handling.

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MSDS NO. 12556 Storage: Trade Name: CALCIUM CHLORIDE (All Grades) Revision Date: 06/08/2006 Page 3/6 Store in dry, well-ventilated area. Keep container closed. Store away from incompatibles. Follow safe warehousing practices regarding palletizing, banding, shrink-wrapping and/or stacking.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure Limits (TLV & PEL - 8H TWA): Ingredient Calcium chloride Potassium chloride Water Sodium chloride CAS No. 10043-52-4 7447-40-7 7732-18-5 7647-14-5 Wt. % ACGIH TLV OSHA PEL 94 - 97 NA NA 1-5 NA NA 1-5 NA NA 1-5 NA NA Other NA NA NA NA Notes (1) (1) None (1)

Notes (1) Control as an ACGIH particulate not otherwise specified (PNOS): 10 mg/m3 (Inhalable); 3 mg/m3 (Respirable) and an OSHA particulate not otherwise regulated (PNOR): 15 mg/m3 (Total); 5 mg/m3 (Respirable). Engineering Controls: Use appropriate engineering controls such as, exhaust ventilation and process enclosure, to ensure air contamination and keep workers exposure below the applicable limits. Personal Protection Equipment All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazards present and the risk of exposure to those hazards. The PPE recommendations below are based on our assessment of the chemical hazards associated with this product. The risk of exposure and need for respiratory protection will vary from workplace to workplace and should be assessed by the user. Eye/Face Protection: Skin Protection: Dust resistant safety goggles. Wear appropriate clothing to prevent repeated or prolonged skin contact. Chemical resistant gloves recommended for prolonged or repeated contact. Use protective gloves made of: Neoprene. Nitrile. All respiratory protection equipment should be used within a comprehensive respiratory protection program that meets the requirements of 29 CFR 1910.134 (U.S. OSHA Respiratory Protection Standard) or local equivalent. If exposed to airborne particles of this product use at least a NIOSH-approved N95 half-mask disposable or re-useable particulate respirator. In work environments containing oil mist/aerosol use at least a NIOSH-approved P95 half-mask disposable or re-useable particulate respirator. General Hygiene Considerations: Work clothes should be washed separately at the end of each work day. Disposable clothing should be discarded, if contaminated with product.

Respiratory Protection:

9. PHYSICAL AND CHEMICAL PROPERTIES

Color: Odor: Physical State: pH: Specific Gravity (H2O = 1): Solubility (Water): Flash Point: F (C): Melting/Freezing Point: Boiling Point: Vapor Pressure: Vapor Density (Air=1): White Odorless Solid. ND ND Soluble NA 1422F (772C) ND NA NA

MATERIAL SAFETY DATA SHEET

MSDS NO. 12556 Evaporation Rate: Odor Threshold(s): Trade Name: CALCIUM CHLORIDE (All Grades) Revision Date: 06/08/2006 NA ND Page 4/6

10. STABILITY AND REACTIVITY

Chemical Stability: Conditions to Avoid: Materials to Avoid: Hazardous Decomposition Products: Hazardous Polymerization: Stable Keep away from heat, sparks and flame. Avoid contact with water and moist air product is hygroscopic. Oxidizers. Moisture. Water reactive materials. Methyl vinyl ether. Zinc. Sodium Bromine trifluoride. Calcium oxide. Boron trioxide. For thermal decomposition products, see Section 5. Will not occur

11. TOXICOLOGICAL INFORMATION

Component Toxicological Data: Any adverse component toxicological effects are listed below. If no effects are listed, no such data were found. Ingredient Calcium chloride Potassium chloride Sodium chloride CAS No. 10043-52-4 7447-40-7 7647-14-5 Acute Data Oral LD50: 1000 mg/kg (rat) Oral LD50: 2600 mg/kg (rat) Oral LD50: 3 g/kg (rat); Dermal LD50: >10 g/kg (rabbit); Inhalation LC50: >42 g/m3/1H (rat)

Product Toxicological Information: No toxicological data is available for this product.

12. ECOLOGICAL INFORMATION

Ingredient Calcium chloride CAS No. 10043-52-4 Data LC50 96H (static): 10650 mg/l (Lepomis macrochirus); EC50 48H: 52 mg/l (Daphnia magna); TLm 96H: 9500 mg/l (bluegill); TLm 96H: 10,650 (sunfish); TLm 96H: 13,400 mg/l (mosquito fish); TLm 48H (sea water): 2400 mg/l (marine fish); LC50 120H static: 3130 mg/l (Nitzschia linearia)

Product Ecotoxicity Data: Biodegration: Bioaccumulation: Octanol/Water Partition Coefficient:

Contact M-I Environmental Affairs Department for available product ecotoxicity data. ND ND ND

13. DISPOSAL CONSIDERATIONS

Waste Classification: Waste Management: ND Under U.S. Environmental Protection Agency (EPA) Resource Conservation and Recovery Act ( RCRA), it is the responsibility of the user to determine at the time of disposal, whether the product meets RCRA criteria for the hazardous waste. This is because product uses, transformations, mixtures, processes, etc., may render the resulting materials hazardous. Empty containers retain residues. All labeled precautions must be observed.

MATERIAL SAFETY DATA SHEET

MSDS NO. 12556 Disposal Method: Trade Name: CALCIUM CHLORIDE (All Grades) Revision Date: 06/08/2006 Page 5/6 Recover and reclaim or recycle, if practical. Should this product become a waste, dispose of in a permitted industrial landfill. Ensure that the containers are empty by the RCRA criteria prior to disposal in a permitted industrial landfill.

14. TRANSPORT INFORMATION

U.S. DOT Shipping Description: Canada TDG Shipping Description: UN PIN No: IMDG Shipping Description: ICAO/IATA Shipping Description: Not regulated for transportation by DOT, TDG, IMDG, ICAO/IATA. Not regulated. Not regulated. Not regulated. Not regulated.

15. REGULATORY INFORMATION

U.S. Federal and State Regulations SARA 311/312 Hazard Catagories: Immediate (acute) health hazard. SARA 302/304, 313; CERCLA RQ, Note: If no components are listed below, this product is not subject to the referenced California Proposition 65: SARA and CERCLA regulations and is not known to contain a Proposition 65 listed chemical at a level that is expected to pose a significant risk under anticipated use conditions. International Chemical Inventories Australia AICS - Components are listed or exempt from listing. Canada DSL - Components are listed or exempt from listing. China Inventory - Components are listed or exempt from listing. European Union EINECS/ELINCS - Components are listed or exempt from listing. Japan METI ENCS - Components are listed or exempt from listing. Korea TCCL ECL - Components are listed or exempt from listing. Philippine PICCS - Components are listed or exempt from listing. U.S. TSCA - Components are listed or exempt from listing. U.S. TSCA - No components are subject to TSCA 12(b) export notification requirements. Canadian Classification: Controlled Products Regulations Statement: This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR. WHMIS Class: D2B

16. OTHER INFORMATION

The following sections have been revised: New issue NA - Not Applicable, ND - Not Determined.

MATERIAL SAFETY DATA SHEET

MSDS NO. 12556 Disclaimer: Trade Name: CALCIUM CHLORIDE (All Grades) Revision Date: 06/08/2006 Page 6/6

MSDS furnished independent of product sale. While every effort has been made to accurately describe this product, some of the data are obtained from sources beyond our direct supervision. We can not make any assertions as to its reliability or completeness; therefore, user may rely on it only at users risk. We have made no effort to censor or conceal deleterious aspects of this product. Since we cannot anticipate or control the conditions under which this information and product may be used, we make no guartantee that the precautions we have suggested will be adequate for all individuals and/or situations. It is the obligation of each user of this product to comply with the requirements of all applicable laws regarding use and disposal of this product. Additional information will be furnished upon request to assist the user; however, no warranty, either expressed or implied, nor liability of any nature with respect to this product or to the data herein is made or incurred hereunder.