Narayana Sri Chaitanya IIT Academy 12-04-14_Sr.

IPLCO_Chemistry_Assignment
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Narayana Sri Chaitanya IIT Academy
(Sri Sarvani Educational Society)
Common Central Office Madhapur Hyderabad
SEC: SR IPLCO Assignment-2 DATE: 12-04-14
CHEMISTRY
CHEMISTRY_ASSIGNMENT
SECTION I
Straight Objective Type
This section contains 8multiple choice questions. Each question has 4 choices (A), (B),
(C) and (D), out of which ONLY ONE is correct.
1. Coagulation values of the electrolytes
3
AlCl and NaCl for
2 3
As S solution are 0.093
and 52 respectively. How many times nearly
3
AlCl has greater coagulating power
than NaCl ?
a) 930 b) 520 c) 560 d) 1000

2. 1 litre flask contains nitrogen along with a drop or two of water at 40
o
C, the total
pressure being 760 Torr. If all the contents are transfered to another flask of 0.5L
at the same temperature. The pressure of nitrogen setup in the second flask will
be (aqueous tension at 40
o
C=55 torr)
a) 1410 torr b) 1465 torr c) 1520 torr d) 1540 torr

3. Barium ions, CN

and
2
Co
+
form an ionic complex. If this complex is 75% ionized
in aqueous solution with Vant Hoff factor(i) equal to four and paramagnetic
moment is found to be 1.73 BM(due to spin only) then hybridization state of Co(II)
in the complex will be
a)
3
sp d b)
2 3
d sp c)
3 2
sp d d)
3
dsp
4. A crystal is made of particles X, Y and Z. X forms FCC packing, Y occupies all
octahedral voids of X and Z occupies all tetrahedral voids of X. If all the particles
along one body diagonal are removed, then the formula of crystal would be
a)
2
XYZ b)
2 2
X YZ c)
8 4 5
X Y Z d)
5 4 8
X Y Z
5. Bromination of salicyclic acid with
2
Br water gives
Narayana Sri Chaitanya IIT Academy 12-04-14_Sr.IPLCO_Chemistry_Assignment
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a)

b)

c)

d)

6. The end product of the following reaction is

a
)
OH
OHC
OHC
NH
2

b)
OH
OHC
C
Cl
N

c) OH
NH
2
Cl
CHO

d
)
OH
NC
Cl OHC

7. 1 mole of equimolar mixture of ferric oxalate and ferrous oxalate will require x
mole of
4
KMnO in acidic medium for complete oxidation, x is
a) 0.6 mole b) 0.9 mole c) 0.3 mole d) 1.8 mole
8. The oxidative cleavage of compounds Glucose (A) and Fructose (B) with
4
HIO leads
to the formation of acids and aldehydes. The ratios of formic acid to formaldehyde
for (A) and (B) respectively are
a) 5/1, 3/2 b) 5/2, 3/1 c) 3/2, 5/2 d) 4/2, 5/1
SECTION II
Multiple Correct Answer Type
This section contains 4 Multiple correct answer(s) type questions. Each question has 4
choices (A), (B), (C) and (D), out of which ONE OR MORE
9. Which out of the following are nonresolvable?
a
) a)

b)

c)

d
)

10. Which of the following statement(s) is/are correct ?
a) The halides of Be are electron deficient and are polymeric with halogen bridges.
b)
2
BeF is very soluble in water owing to high solvation energy of Be
2+
but fluorides
of other alkaline earth metals are almost in soluble.
Narayana Sri Chaitanya IIT Academy 12-04-14_Sr.IPLCO_Chemistry_Assignment
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c) CaO,SrO and BaO react exothermically with water forming soluble hydroxides.
d) The bicarbonates of alkaline earth metals are only stable in solutions.

Narayana Sri Chaitanya IIT Academy 12-04-14_Sr.IPLCO_Chemistry_Assignment
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11. Which of the following cannot be used as dehydrating agents for ammonia?
a) Con.
2 4
H SO b) anhydrous
2
CaCl c)
4 10
P O d) CaO
12. ( ) ( )
2
2 2
2
Fe en H O en complex(x).
+
( +

the correct statement about the complex(x) is
a) it is a low spin complex b) it is diamagnetic
c) it shows geometrical isomerism d) it is outer orbital complex
SECTION III
Linked Comprehension Type
This section contains 2 paragraphs. Based upon each paragraph, 3 multiple choice
questions have to be answered. Each question has 4 choices (A), (B), (C) and (D) out of
which ONLY ONE is correct.
Passage- I
A volatile organic compound (X) on reaction with HI gives two products (Y) and (Z). Z
gives red colour in Victor Meyer test but when (Z) is heated with conc.H2SO4
followed by hydrolysis gives (P), which immediately reacts with anhydrous
2
ZnCl HCl. + (Y) on treatment with
2 5
C H OH KOH + followed by
3 2
O / Me S gives Q. (Q)
can give haloform test. (Q) when heated with NaOH gives (R) . (R) also gives
haloform test and can decolourise
2
Br water.
13. Compound (X) is
a
) a)

b)

c)

d)

14. Compound (Y) is.
a
) a)

b)

c)

d)

15. Compound (R) is
a
) a)
b)

c)

d)

Passage- II
An unknown solid mixture contains any two of the following
3 2 3 4
CaCO ; BaCl ; AgNO ; ZnSO and NaOH. The mixture is completely soluble in water and the
solution gives pink color with phenolphthalein. When dilute HCl is gradually added to
the above solution, a precipitate is produced which with further addition of the acid
dissolves.

Narayana Sri Chaitanya IIT Academy 12-04-14_Sr.IPLCO_Chemistry_Assignment
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16. What is/are present in the solid ?
a)
3
AgNO and NaOH b)
2 2 4
BaCl and Na SO c)
4
ZnSO and NaOH d)
3 3
CaCO and AgNO
17. In a separate analysis, the aqueous solution of the mixture (as mentioned in the
passage) gives white precipitate with
2 4
K SO , then what is / are present in the
mixture ?
a)
3
CaCO b)
2 3
BaCl and AgNO c)
2
BaCl only d)
3
AgNO only
18. In a separate analysis, the aqueous solution of the mixture gives a precipitation (A)
with brine. (A) is soluble in
4
NH OH . What is present in the mixture ?
a)
2
BaCl b)
3
AgNO c)
4
ZnSO d)
3
CaCO

SECTION IV
Matrix Match Type
This section contains 3 questions. Each question contains statements given in two
columns which have to be matched. Statements (A, B, C, D) in Column I have to be
matched with statements (p, q, r, s, t) in Column I I . Any statement in Column I can have
correct matching with ONE OR MORE statement(s) in column I I . The answers to these
questions have to be appropriately bubbled as illustrated in the following example.
I f the correct matches are A p, A t, B p, B q, B-s, B-t, C p, C r C-t, and D q
then the correctly bubbled matrix should be as shown:

Match the compounds listed in column-I with characteristic(s) listed in column-II
19.
Column I Column II
(A)
2 6
B H (p) Tetrahedral hybridization
(B)
2 6
Al Cl (q) trigonal hydridisation
(C)
2
BeCl (Solid) (r) Empty orbital(s) of central atom
participate in hydridisation
(D)
( )
3
3
SiH N
(s) two types of bonds




(t) p d t t
Narayana Sri Chaitanya IIT Academy 12-04-14_Sr.IPLCO_Chemistry_Assignment
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20. Column I Column II
(A)
3
H O
R MgX HCHO Adduct
+
+
(p) Ketone
(B)

(q)
0
1 alcohol with (n+1) carbons
(C)
2
3
H O
R MgX CO Adduct
+
+
(r) Acid with (n+1) carbons
(D)
3
H O
R MgX Ph C N Adduct
+
+
(s)
0
1 alcohol with (n+2) carbons
(t) aldehyde
CHEMISTRY
Qno Key
1 C
2 B
3 D
4 D
5 C
6 D
7 B
8 A
9 A,C
10 A,B,C,D
11 A,B,C
12 A,B
13 D
14 A
15 B
16 C
17 B
18 B
19
(a p, r, s; b p, r, s;
c p, r, s; d q, t)



20
(a q; b s;
c r; d p)