FILE NO. IIT Û 213-43 UNIT TEST - 7 - PAPER-IQP

FILE NO.
IIT 213/43
(07/11/2008)
CODE
GARSHANA

NARAYANA
I I T A C A D E M Y
UNIT TEST 07
SR IIT SPARK(500X3X2) & SR IIT FTB I
Test Date: 08
t h
NOVEMBER 2008
Time: 3 hours Maximum marks: 246
Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
INSTRUCTIONS
A. General:
1. This booklet is your Question Paper containing 69 questions.
The booklet has 2 pages.
2. The question paper CODE is printe! on the right han! top
corner o" this booklet.
#. $lank papers% clipboar!s% log tables% sli!e rules% calculators%
cellular phones% pagers% an! electronic ga!gets in any "or&
are not allo'e! to be carrie! insi!e the e(a&ination hall.
). The ans'er sheet% a &achine*rea!able Ob+ecti,e -esponse
.heet /O-.0% is pro,i!e! separately.
1. DO 2OT T34PE- 56T7 8 49T6:3TE T7E O-. O-
T7E $OO;:ET.
B. Filling the ORS
6. On the lo'er part o" the O-.% 'rite in ink% your na&e in bo(
:1% your -egistration 2o. in bo( :2 an! 2a&e o" the Centre
in bo( :#. Do not write these anywhere else.
<. 5rite your -egistration 2o. in ink% in the bo( :) pro,i!e! in
the lo'er part o" the O-. an! !arken the appropriate bubble
UNDER each !igit o" your -egistration 2o. 'ith a goo!
quality 7$ pencil.
=. The O-. has a CODE printe! on its lo'er an! upper parts.
9. 4ake sure the CODE on the O-. is the sa&e as that on this
booklet an! put your signature in ink in bo( :1 on the O-.
a""ir&ing that you ha,e ,eri"ie! this.
1. 6> T7E CODE. DO 2OT 43TC7% 3.; >O- 3 C732?E
O> T7E $OO;:ET.
C. Question paper format:
11. The question paper consists o" 3 parts (Part I:
Mathematics, Part II: Physics, Part III: Chemistry). Each
part has ) sections.
12. Section I contains 6 &ultiple choice questions. Each question
has ) choices /30% /$0% /C0 an! /D0% out o" 'hich only one is
correct.
1#. Section II contains ) &ultiple correct ans'er type questions.
Each questions has ) choices /30% /$0% /C0 an! /D0% out o"
'hich one or &ore ans'ers are correct.
1). Section III contains ) -easoning type questions. Each
question contains .T3TE4E2T*1 32D .T3TE4E2T*2.
$ubble /30 i" both the state&ents are T-9E an!
.T3TE4E2T*2 is the correct e(planation o"
.T3TE4E2T*1.
$ubble /$0i" both the state&ents are T-9E but
.T3TE4E2T*2 is 2OT the correct e(planation
o" .T3TE4E2T*1.
$ubble /C0i" .T3TE4E2T*1 is T-9E an! .T3TE4E2T*
2 is >3:.E.
$ubble /D0 i" .T3TE4E2T*1 is >3:.E an!
.T3TE4E2T*2 is T-9E.
11. Section IV contains # sets o" :inke!*Co&prehension type
question. Each set consists o" a paragraph "ollo'e! by #
questions. Each question has ) choices /30% /$0% /C0 an! /D0%
out 'hich only one is correct.
D. Marking Scheme:
16. >or each questions in Section I% you 'ill be awarded 3
marks i" you ha,e !arkene! only the bubble correspon!ing
to the correct ans'er an! @ero &ark i" no bubble is !arkene!.
6n all other cases% minus one (1) mark 'ill be a'ar!e!.
1<. >or each question in Section II% you 'ill be awarded 4
marks i" you ha,e !arkene! all the bubble/s0 correspon!ing
to the correct ans'er an! @ero &ark "or all other cases. 6" &ay
be note! that there is no negative marking for wrong
answer.
1=. >or each question in Section III% you 'ill be awarded 3
marks i" you !arken only the bubble correspon!ing to the
correct ans'er an! @ero &ark i" no bubble is !arkene!. 6n all
other cases% minus one (1) mark 'ill be a'ar!e!.
19. >or each question in Section IV% you 'ill be awarded 4
marks i" you !arken only the bubble correspon!ing to the
correct ans'er an! zero mark i" no bubble is !arkene!. 6n all
other cases% minus one (1) mark will be awarded.
Name of the Student Roll Number
I have read all the instructions and shall abide by them
AA..AAAAAAAAAAAAAAAAAAAAA
Signature of the Candidate
I have verified all the information filled in by the Candidate
AAAAAAAAAAAAAAAAAAAAA..
Signature of the Invigilator
NARAYANA IIT (1EE) ACADEMY
New Nallakunta, Hyd.
MATHS
PART I
SECTION I
Straight Objective Type
This section contains 6 &ultiple choice questions. Each question has ) choices /30% /$0% /C0 an! /D0% out o"
'hich ONLY ONE is correct.
1. 6"
an!
an!
an! are the roots o" the equations

2 2
2 % 2 ax bx c bx cx a + + + +
an!
2
2 cx ax b + + respecti,ely 'here a% b% c are positi,e real nu&bers% then
2
+
a0 B1 b0 1 c0 !0 abc
2. 6" a% b% c are in geo&etric progression an! the roots o" the equations
2
2 ax bx c + + are
an!

an! those o"
2
2 cx bx a + + are
an! then
a0

b0
an!
c0
a a c c
!0
C
#. 6" ( ) ( ) ( )
2 2
# 2 < f x x x x x a + + +
an! ( ) ( ) ( )
2 2
12 1 g x x x x x b + +
then the ,alues o" a an! b%
6" ( ) ( ) 1 ) x x +
is 7C> o" ( ) f x
an! ( ) g x
a0 1D 6 a b b0 )D 12 a b c0 12D ) a b !0 6D 1 a b
). The equation
( ) ( )
2
2 2
# ) # # ) ) x x x x x + + + + + + has
a0 all its solutions real but not all positi,e b0 only t'o o" its solutions real
c0 t'o o" its solutions positi,e an! t'o negati,e !0 none o" solutions real.
1. :et 3 be a square 4atri( all o" 'hose entries are integers. Then 'hich o" the "ollo'ing is TrueE
a0 6"
!et 1% A t
then
1
A
e(ists but all it entries are not necessarily integers.

b0 6"
!et 1% A t
then
1
A
e(ists an! all it entries are non integers.

c0 6" !et 1 A t % then
1
A
e(ists a! all its entries are integers.

!0 6" !et 1 A t %
1
A
nee! not e(ist.

6.
1 1
sin cos cos sin x x a

has at least one solution i""
a
a0 { }
b0
%
2
1
1
]
c0
#
%
2 2

1
1
]
!0 ( ) %
SECTION II
Multiple Correct Answer Type
This section contains ) &ultiple correct ans'er/s0 type questions. Each question has ) choices /30% /$0% /C0
an! /D0% out o" 'hich ONE OR MORE is8are correct.
<. 6" 3 is a square 4atri( such that ( )
)
. )
)
A AdjA
1
1
1
1
]
then
a0
) A
b0
16 adjA
c0
( )
16
adj adjA
adjA
!0
2 12= adj A
2
NARAYANA DWARKA CENTRE
201-A, Dimension Durga Tower, Plot No. 10, Sector 4 Market, Dwarka New Delhi 110075, Ph : 45621724 / 25
CODE: DWARKA -CPT-07 810 BATCH Type-I (XI STU.)
=. 6"
1% x < <

2
1
1
1
x
Tan
x

+
is equal to
a0
1
1
cos
2
x
b0
1
1
cos
2
x
+
c0
1
1
sin
2
x

!0 none
9. 6" ( )
( ) ( )
( ) ( )
( ) ( )
1 1 2 1
1 1 1 2
1 2 1 1
a b
a b
b a
x x
f x x x
x x
+ +
+ +
+ +
5here a% b are positi,e integers% then
a0 constant ter& o" ( ) f x
is b0 coe""icient o"
x
in ( ) f x
is
c0 constant ter& o" ( ) f x
is a b !0 constant ter& in ( ) f x
is a b +
1. 6"
( )
)
2 2 =
1 2 =
1 ........ ax bx a a x a x a x + + + + + + 'here
1 2 =
% % % % ..... a b a a a a R
such that
1 2
a a a + +
an!
1 2
1 1
2 1
a a a
a a a
a a a

then
a0
1 2
a a a
b0
1 2
1 a a
c0
1 2
) a a a a
!0
1
.
#2
b
SECTION III
Reasoning Type
This section contains ) reasoning type questions. Each question has ) choices /30% /$0% /C0 an! /D0% out o"
CODE
(A) STATEMENT1 is True, STATEMENT2 is True; STATEMENT2 is a correct explanation for
STATEMENT1
(B) STATEMENT1 is True, STATEMENT2 is True; STATEMENT2 is NOT a correct explanation
for STATEMENT1
(C) STATEMENT1 is True, STATEMENT2 is False
(D) STATEMENT1 is False, STATEMENT2 is True
11. .tate&ent 6D :et 3 be a
n n
&atri( such that
n
A A 'here
is a real nu&ber ( ) 1 t
then
n
A I +
is 6n,eritable.
.tate&ent 6D 3 square 4atri( possess in,erse i"" it is nonBsingular.
12. .tate&ent 6D
( )
1 2 1
cos 1 sin f x x x

-ange o" ( ) f x
is
%
1
]
.
.tate&ent 66 D ( ) f x
is an increasing "unction in its !o&ain.
1#. :et ( )
1
1
1
n
n
n
a a
D n b b
c c
'here a% b% c are non *@ero% unequal real nu&bers % n N

3
.tate&ent 6D a b c + + !i,i!es ( ) # D
.
.tate&ent 66D ( ) ( ) ( ) 1 D n a b c D n + +
1). .tate&ent 6D 6" ( ) ( )
2 1 2 1 2
sin ) 1 cos ) 1 x ax x x x x

+ + + + +
then
=
)
a
+
.tate&ent 66D Do&ain o"

1
sin x
is [ ]
1%1
an! !o&ain o"
1
cos x
is [ ]
1%1
SECTION IV
Linked Comprehension Type
This section contains # paragraphs. $ase! upon each paragraph% # &ultiple choice questions ha,e to be
ans'ere!. Each question has ) choices /30% /$0% /C0 an! /D0% out o" 'hich ONLY ONE is correct.
Paragraph for Questions Nos. 15 to 17
Consi!er the equations
( ) ( )
2
2
1 1
cos sin 1
)
a
x y

+

( ) ( )
)
2
1 1
Fcos . sin 2
16
x y

11. The co&plete set o" ,alues o" a "or 'hich the equation /10 hol!s goo! is
a0
)
% 1
_
+

,
b0
)
% 1
1
+
1
]
c0 - !0
16. The set o" ,alues o" a "or 'hich ( ) ( ) 1 F 2

posses solution is
a0
/ % 2G H2% 0
b0 ( ) 2% 2
c0
)
2% 1
1
+
1
]
!0 -
1<. The ,alues o"
x
an!
y
such that syste& ( ) ( ) 1 F 2
posses solutions "or integral ,alues o" IaJD
a0
2
1
cos %
) 2
_

,
b0
2
1
cos %
) 2
_

,
c0
2
cos % 1
)
_
t

,
!0
% x R y R
Consi!er the inequation 9 .# #
x x
a a + 'here IaJ is a real para&eter. The gi,en
inequation has
1=. 3t least one negati,e solution i"
a0 ( ) 2% # a
b0 ( ) 2% a
c0 ( ) % 2 a
!0 ( ) % # a
19. 3t least one positi,e solutions i"
a0 ( ) % 2 a
b0 ( ) % 2 a
c0 ( ) % 6 a
!0 ( ) 2% a
2. 3t least one solution in ( ) 1% 2
i"
a0 ( ) #% a
b0
=)
#%
1
a
_

,
c0
=)
%
1
a
_

,
!0 a R
4
( )
( ) ( ) ( )
( ) ( ) ( )
( ) ( ) ( )
2 2 2
2 2 2
2 2 2
cos 1 cos 1 cos
1 cos cos 1 cos
1 cos 1 cos cos
a b c ab ca
f ab b c a bc
ca bc c a b

+ +
+ +
+ +
'here a% b% c are constants.
21. ( ) f
a0 ( )
2 2 2 2
cos a b c + +
b0
( )
2
2 2 2 2
cos a b c + +
c0 ( ) ( )
2 2 2
cos a b c a b c + + + +
!0
( )
#
2 2 2 2
cos a b c + +
22. -ange o" ( )
1
f
a0 ( ) ( )
2 2 2 2 2 2
% a b c a b c
1
+ + + +
]
b0 ( ) ( )
2 2
2 2 2 2 2 2
% a b c a b c
1
+ + + +
1
]
c0 ( ) ( )
# #
2 2 2 2 2 2
% a b c a b c
1
+ + + +
1
]
!0 none
2#. ( )
82
82
f d
KKKKKKKKKK 5hen
2 2 2
% % a b c are in 3P
a0
#
2<
2
b
b0
6
2< b c0
6
2<
2
b
!0 none
PHYSICS
5
PART II
SECTION I
2). 6n the a!+oining "igure ,ariation
o" ,elocity an! its coBor!inate 'ith
respect the ti&e are gi,en. Cur,e in
parabola. Origin o" ti&e coinci!es in
both the graphs
.tate&entB6 $oth graphs are sho'ing !i""erent &otions.
.tate&entB66 6n both cases particles are co&ing to rest a"ter ) secon! "ro& the start.
a0 $oth state&ent *6 an! 66 are correct.
b0 2either 6 nor 66 are correct.
c0 Only 6 is correct.
!0 Only 66 is correct.
21. 3 'ater tank o" parallelepipe! shape is &o,ing on hori@ontal roa! 'ith spee! increasing "ro& v
to
v v
in t secon!. 6" the separation bet'een the longitu!inally opposite 'alls is l an! lateral
/ si!e0 'alls are ,ertical% an! tank is co&pletely "ille! 'ith 'ater an! !ensity o" 'ater be
then the
pressure !i""erence bet'een the opposite 'alls is / 3ssu&e at&ospheric pressure P0
a0
l v
t
b0
l v
P
t
+ c0
2
l
P
t
+ !0
2 lv
P
t
+
26. 3 rectangular uni"or& parallelepipe! slab is place! on a "i(e! incline!
plane o" inclination 'ith the hori@ontal as sho'n in the
"igure. : an! - represent the le"t an! right hal" o" the slab. >our
obser,ations "ollo'e! by correspon!ing conclusions are
gi,en belo' C Choose the correct oneD
a0 5hen the incline! plane is s&ooth "orce e(erte! by incline! plane on right hal" is greater than
that on le"t hal".
b0 5hen incline! plane is su""icient rough to present slipping the "orce e(erte! by incline! plane on
right hal" is &ore than the on le"t hal".
c0 5hen incline! plan is su""iciently rough to present slipping the "orce e(erte! by incline! plane on
right hal" is less than thatJs on the le"t hal".
!0 5hen incline! plane is su""iciently rough to present "riction the "ore e(erte! by incline! plane is
sa&e on both right an! le"t hal".
2<. 3 particle o" &ass
2 m kg
pro+ecte! at certain angle 'ith the hori@ontal. Due to air resistance the
particle &o,es in a assy&&etric cur,e. The !irection o" the acceleration o" particle 'ith the
!irection o" ,elocity% at the highest point o" tra+ectory. 5here resistance "orce is 22. is / take gL1
&s
B2
0 / 3ssu&e the resistance "orce !epen!ing on ,elocity an! acting opposite to the ,elocity 0
6
a0
)1 b0
9 c0
11 !0
221
2=. 6n the "igure sho'n a particle o" &ass & &o,ing
'ith ,elocity
v
strike a 'all / &ass is in"initely large0
&o,ing to'ar!s the particle 'ith sa&e spee!.
The 'ork !one on the particle !uring collision is
a0
2
#
2
mv
b0
2
mv
c0
2
)mv
!0
2
#mv
29. T'o hollo' he&ispheres o" &etal are "itte! together to "or& a sphere o" ra!ius -. 3ir "ro& the shall
is pu&pe! out an! pressure re&aine! le"t insi!e is
1
)
th the outsi!e at&ospheric pressure P
. The
"orce require! to separate the he&isphers is
a0
2
#
)
R P b0
2
#
2
R P c0
2
R P !0
2
1
2
R P
SECTION II
#. Three particles M% N an! O are place! on straight hori@ontal line at equal !istance "ro& one another.
Particle M starts &o,ing ,ertically up 'ith a constant ,elocity
v
an! particle @ ,ertically !o'nB'ar!
'ith constant acceleration a 'ithout initial ,elocity. .elect the correct option8s "ro& the "ollo'ing
about the &otion o" particle N so that all the three 'ill be at the sa&e straight line i" all begins to
&o,e si&ultaneously
a0 6nitial ,elocity
2
v
up'ar! b0 6nitial acceleration
2
a
up'ar!.
c0 6nitial ,elocity
2
v
!o'n'ar! !0 6nitial acceleration
2
a
!o'n'ar!.
#1. 6n the a!+oining "igure a bea! o" &ass & is "ree to sli!e
along the ro! o" length 2l 'ithout "riction. 6nitially the
bea! is at the &i!!le o" the ro! an! ro! is &o,ing
hori@ontally 'ith acceleration IaJ 'hich &akes an angle
7
'ith the ro! as sho'n. Choose the in correct option.
a0 3cceleration o" bea! 'ith respect to stationary obser,er is cos a an! !irecte! along the line o"
action o" reaction "orce.
b0 3cceleration o" bea! 'ith respect to ro! is sin a along the ro!.
c0 $oth /a0 an! /b0
!0 2one.
#2. 3 circular ring o" ra!ius - an! &ass 9 & is place! on a per"ectly s&ooth hori@ontal sur"ace. 3n ant
o" &ass & starts &o,ing along the ring. .elect the correct conclusion8s
a0 tra+ectory o" centre o" ring is a circle o" ra!ius
1
R
b0 tra+ectory o" ant is also a circle but o" ra!ius
9
1
R
c0 -atio o" linear spee! o" centre o" ring an! that o" ant is 9D1
!0 -atio o" angular spee!s about a co&&on "i(e! point is 1D1
##. 6n the "igure sho'n P is the peak o" a &ountain.
>ro& the groun! point ?C a block o" &ass
& an! 2& are li"te! slo'ly to the peak
,ia path 6 an! 66 respecti,ely. $oth paths ha,e
sa&e coBe""icient o" "riction. 6" the 'ork !one be
respecti,ely
an! C
I II
w w
Choose the correct option8s
a0
2
I II
w w
b0
I II
w w
c0 loss o" energy !ue to "riction is sa&e "or both the paths
!0
1 1
C
I II
w w /5here
1
I
w an!
1
II
w are 'ork!one per unit &ass0
SECTION III
Reasoning Type
8
CODE
(A) STATEMENT1 is True, STATEMENT2 is True; STATEMENT2 is a correct explanation for
STATEMENT1
(B) STATEMENT1 is True, STATEMENT2 is True; STATEMENT2 is NOT a correct explanation
for STATEMENT1
#). .tate&entB6D One canJt "in! e(actly
( )
v t
r
an!
( )
r t
r
i" the ti&e !epen!ence o" acceleration is gi,en.
.tate&entB66D 6" the ti&e !epen!ence acceleration is gi,en thenC "or single ,alue! solution "or
position ,ectorC boun!ary con!ition &ust be gi,en.
#1. .tate&entB6D 6nertial "orce is cause! by the physical interaction o" bo!ies.
.tate&entB66D 6nertial "orce !o not obeys the 2e'tonJs thir! la' o" &otion.
#6. .tate&entB6D The conser,ation la's !o not !epen! on the path "ollo'e! by the particle8bo!y an!
nature o" "orces acting on the&.
.tate&entB66D 6" e(ternal "orce is nonB@ero then linear &o&entu& &ay be conser,e! in nonBinertial
"ra&e o" re"erence.
#<. .tate&entB6D 6n a close! syste& total 'ork !one by all internal !issipati,e "orce is negati,e in all
"ra&e o" re"erence.
.tate&entB66D 3cceleration o" centre o" &ass is in!epen!ent o" the point o" application o" "orce on the
syste&.
SECTION IV
9
PassageB6
6n the "igure sho'n the ,elocity o" ri,er
current gro's in proportion to the perpen!icular
!istance "ro& the bank an! reaches its &a(i&u&
9 . v kmph
in the &i!!le. 3 boat is so &o,ing
in the ri,er that its ,elocity
1= v kmph
relati,e
to the 'ater is constant an! perpen!icular to the !irection o"
ri,er "lo'. 3ssu&e the 'i!th o" the ri,er is !.
an! boat starts "ro& point O 'ith re"erence
to the abo,e situation ans'er the "ollo'ing questions.
#=. 5hile going across the ri,er the acceleration o" the boat is
a0 changing its !irection but the &agnitu!e re&ains constant.
b0 both &agnitu!e an! !irection re&ains constant.
c0 changing its &agnitu!e but !irection re&ain sa&e.
!0 changing its &agnitu!e as 'ell as its !irection.
#9. 6" the boat reache! at point P on the other bank o" ri,er the ratio o" O3 an! 3$ is
a0 2D1 b0 1D 2 c0 )D1 !0 1D )
). 5ith respect to point IOJ /origin o" coBor!inate syste& as sho'n in the "igure0 location o" boat in
the ri,er / in ter&s o"
% X Y
coBor!inate 0 'hen the position ,ector o" boat is &aking angle
)1 'ith
the !eparting bank o" ri,er.
a0 ( ) .2 % .2 km km
b0 ( ) .1 % .1 km km
c0 ( ) .1 % .1 km km
!0 ( ) .# % .# km km
PassageB66
10
6n the "igure there is a trolley &o,ing uni"or&ly on hori@ontal sur"ace. There is an i!eal
spring o" spring constant ; an! there is a &an in the trolley to per"or& so&e e(peri&ent 'ith the
spring. Trolley is &o,ing 'ith ,elocity ,. $o!y posture o" &an 'hile per"or&ing e(peri&ent is not
clearly !epicte! in the "igure.
3ns'er the "ollo'ing questions.
)1. 6n his "irst e(peri&ent &an applie! "orce > to stretche! the spring an! re&aine! stan!ing in the
trolley. 6" the trolley co,ers an !istance : than the 'ork !one by &an 'ith respect to groun!
obser,er an! 'ith respect to trolley are respecti,ely
a0
% FL FL +
b0
% FL FL +
c0
2 % 2 FL FL
!0
% zer zer
)2. 2o' in his 2
n!
e(peri&ent &an stretches the spring through
x
!uring ti&e t an! !uring the sa&e
ti&e trolley co,ers a !istance :. 5hen &an stretches the spring &an &o,es opposite to the train.
5ork per"or&e! by &an is groun! "ra&e is
a0
2
1
2
kx b0
2
kx c0 ( )
2
kx
L x !0
2
.
)
k
x
)#. 6n the 2
n!
e(peri&ent 'ork!one by &an to o,erco&e the "riction in trolley "ra&e is
a0 @ero b0
2
1
)
kx c0
2
1
2
kx !0 ( )
2
kx
L x
PassageB666
T'o &en 3 an! $ each o" &ass & sit in light cages
at the en!s o" a "le(ible light rope passing o,er a s&ooth pulley
as sho'n in the "igure. 6nitially both are at rest. 3 being higher
than $ by h. .u!!enly a s&all ball o" &ass
1
m
is han!e! o,er to $
'hich he instantaneously thro's up to 3.
)). 6" the ball takes ti&e t to go "ro& the han! o" $ to that o" 3% Then !uring this internal o" ti&e 'hich
o" the "ollo'ing obser,ation is correct on the basis o" kno'n "un!a&ental Principle o" Physics.
a0 &otion o" 3 is accelerate! an! that o" $ is un accelerate!.
11
b0 &otion o" both 3 an! $ are accelerate!.
c0 &otion o" both 3 an! $ are un accelerate! but that o" ball is accelerate!.
!0 &otion o" all 3% $ an! the ball are accelerate!.
)1. 5hen 3 catches the ball% his position is shi"te! up by l . 5here l is
a0
19
h
b0
#
19
h
c0
)
#=
h
!0
#=
h
)6. 6" in the course o" &otion the &a(i&u& height atten!e! by 3 is
a0
2
19
h
b0
2
#61
lh
c0
2
#61
gh
!0
1<
#61
h
CHEMISTRY
PART III
SECTION I
12
)<. 6" ato&s o" ra!ius r "or& "aceBcentre! cubic unit cell o" e!ge length a% the correct relation isD
a0 ) # r a b0 ) # a r c0
) 2 r a
!0 2r a
)=. >or bcc lattice% the e!ge length o" the unit cell is 1 p&. The &olar ,olu&e o" the spheres lattice is
a0 <2.21 c&
#
b0 #<.6 c&
#
c0 1=.= c&
#
!0 none o" these
)9. 5hen 2aCl is !ope! 'ith
#
1. 1
&ole o" .rCl

2
% the nu&ber o" cation ,acancy is
a0
1=
6.2# 1 b0
2
6.2# 1 c0
2
2 6.2# 1 !0
2
#.11 1
1. The nonBstoichio&etric co&poun!
.9)
Fe
O is "or&e! 'hen P x o"
2
Fe
+
ions are replace! by
#
Fe
+

ions then
x
is
a0 6 b0 12 c0 11 !0 1=
51. The oxidation of oxalic acid by acidified
)
!"n#
becomes fast as the reaction progresses due to:
a) Auto catalysis by Mn
2+
b) resence of
2
)
$#

c) resence of
!
+
d) resence of
)
"n#
52. !n adding fe" drops of dil. %&l or

#
Fe&l
to freshly precipitated ferric hydroxide# a red coloured
colloidal solution is obtained. This phenomenon is $no"n as:
a) epti%ation b) &ialysis c) protection d) &issolution
SECTION II

1#. 5hich o" the "ollo'ing pair o" ions ha,e the sa&e scattering po'er o" MBraysE
a0 an! Cl 'a
+
b0 an! Cl !
+
c0 an! $r Rb
+
!0 an! $r !
+
1). 5hich o" the "ollo'ing has anti"luorite structure
a0 Ca>
2
b0 $a>
2
c0 :i
2
O !0 2a
2
O
11. 6n 2a
2
O structureD
a0
2
#

ions constitute ccp an! 2a
Q
ions occupy all the octahe!ral holes
b0
2
#

Q
ions occupy all the tetrahe!ral holes
c0
2
#

Q
ions occupy 1P o" tetrahe!ral holes an! 1 P octahe!ral holes
!0 2a
Q
ions constitute ccp an!
2
#

ions occupy hal" o" octahe!ral holes.
16. 6" the ra!ius o" the anion in an ionic soli! is 2 p&% 'hat 'oul! be the ra!ius o" the cation that "its
e(actly into a cubic hole
a0 1)6.) p& b0 =2.= p& c0 )1 p& !0 none o" these
SECTION III
Reasoning Type
13
CODE
(A) STATEMENT1 is True, STATEMENT2 is True; STATEMENT2 is a correct explanation for STATEMENT1
(B) STATEMENT1 is True, STATEMENT2 is True; STATEMENT2 is NOT a correct explanation for STATEMENT1
1<. .tate&ent 6D >renkel !e"ects are "oun! in sil,er hali!es.
.tate&ent 6D >renkel !e"ects are co&&only "oun! in ionic soli!s
1=. .tate&ent 6D :ea! @iroconate is a pie@oelectric crystal.
.tate&ent 66D :ea! @iroconate cryals ha,e no net !ipole &o&ent
19. 3ssertionD The e""ecti,eness o" catalyst has "oun! &ore applications in soli! catalyst an! gaseous
reactant syste&s.
-easonD 3 large nu&ber o" in!ustrial preparations are base! on this type o" reactions.
6. 3ssertionD :ea! tetraethyl acts as inhibitor "or co&bustion
-easonD 6t retar!s the co&bustion o" gasoline.
SECTION IV
6n an i!eal crystal there &ust be regular repeating arrange&ent o" the constituting
particles an! its entropy &ust be @ero at absolute @ero te&perature. 7o'e,er% it is i&possible to
obtain an i!eal crystal an! it su""ers "ro& certain !e"ects calle! i&per"ections. 6n pure srystal% these
!e"ects arise either !ue to !isor!er or !islocation o" the constituting partilcles "ro& their nor&al
positions or to the &o,e&ent o" the particles e,en at absolute @ero te&perature. .uch !e"ects
increase 'ith rise in te&perature. 6n a!!ition to this% certain !e"ects arise !ue to the presence o"
so&e i&purities. .uch !e"ects not only &o!i"y the e(isting properties the crystalline soli!s but also
i&part certain ne' characteristics to the&.
61. 5hen :iCl is heate! into the ,apour o" lithiu&% the crystal acquires pink colour. This is !ue to
a0 .chottkty !e"ects b0 >renkel !e"ectc
c0 4etal e(cess !e"ect lea!ing to >Bcentres !0 Electronic !e"ect
62. 3gCl is crystalli@e! "ro& &olten 3gCl containing a little C!Cl
2
. The soli! 3gCl obtaine! 'ill ha,e
a0 cataionic ,acancies equal to nu&ber o" C!
2Q
ions incorporate!
b0 cationic ,acancies equal to !ouble the nu&ber o" C!
2Q
ions
c0 anionic ,acancies
!0 neither cationic nor anionic ,acancies.
6#. The secon! or!er $raggJs !i""raction o" MBrays o" 'a,elength 1 p& "ro& a set o" parallel lattice
planes in a &etal occurs at a gra@ing angle o" #
. The spacing bet'een the successi,e scattering

planes in the crystal is
a0 1 p& b0 1 p& c0 11 p& !0 2 p&
14
.ur"actants are the substances 'hich sho' sur"ace acti,ity. Detergents possess sur"ace
acti,ity as 'ell as !etergency. .oaps are anionic class o" !etergent. 6t is the hy!rophilic part o"
!etergent &olecule 'hich possesses the ten!ency to attract 'ater &olecules 'hereas hy!rophobic
part orients a'ay "ro& 'ater. The hy!rophilicBlipopillic balance /7:$0 lea!s to aggregaton o"
anionic or nonionic or cationic part o" !etergent to "or& &icelle. Each &olecule has the !e"inite
concentration at !e"inite te&perature at 'hich it starts to aggreagate. 6t is !ue to the presence o" t'o
&oieties in their &olecules% sur"actants stabili@e e&ulsion / a 'ater * oil syste&0. Due to larger
sur"ace area% the &e!icines are &ore e""ecti,e in e&ulsion "ro&. E&ulsions are '8o or 8o' type. 3
'ater soluble !ye i&parts its colour to o8' e&ulsions.
6). 5hich is incorrect about soapsD
a0 .oaps are &etal salts o" "atty aci!s
b0 .oaps are anionic class o" sur"actants or !etergents
c0 .oaps "or& anionic &icelles i.e.% carrying *,e charge
!0 neutral &olecule o" soap act as sur"actant.
61. 5hich o" the "ollo'ing "or&s a cationic &icelleD
a0 .o!iu& !o!ecyl sulphate in 'ater
b0 .o!iu& !o!ecyl ben@ene sulphonate in 'ater
c0 .ol!iu& octanoate
!0 Do!ecyl a&&oniu& chlori!e
66. 5hich &ight ha,e lo'est ,alue o" critical &icelle concentration in 'aterD
a0 .o!iu& octanoate b0 .o!iu& !ecanoate
c0 .o!iu& he(anoate !0 .o!iu& !o!ecanoate
ParagraphD
6n a closest packe! layer o" i!entical spheres% each sphere is intouch 'ith si( spheres. 3
close! packe! three !i&ensional crystal 'ill be obtaine! by stacking close! packe! layers on top o"
one another. >or &a(i&u& utili@ation o" the space% the spheres o" the secon! layer lie in the
!epressions o" "irst layer. The thir! layer can be a!!e! in either o" t'o 'ays. 6n one% the spheres are
place! so that they repro!uce "irst layer% ie.% spheres o" "irst an! thir! layers are ,ertically aligne!.
This is kno'n as 3$ pattern o" layers 'hich consists o" spheres he(agonally packe! /hcp0.
6<. The ,acant space in bo!y centre! cubic lattice b.c.c. unit cel is aboutD
a0 #2 P b0 1 P c0 2#P !0 )6 P
6=. 7o' &any unit cells are present in a cubic shape! i!eal crystal o" 2aCl o" &ass 1. g.
a0
21
1.2= 1 unit cells b0
21
1.<1 1 unit cells
c0
21
2.1< 1 unit cells !0
21
1.1) 1 unit cells
69. 3 substance
x y
A (
crystalli@es in "ace centre! cubic / "cc0 lattice in 'hich ato&s 3 occupy each
corner o" the cube an! ato&s $ occupy the centre o" each "ace o" the cube. The co&position o"
x y
A (
isD
a0
#
A(
b0
) #
A (
c0
#
A (
!0 can not be speci"ie!
15
UNIT TEST -7 Dated : 08.11.2008
If you have any genuine question paper problems please contact the following subject
concerned persons.
PAPER
SETTER
MATHEMATICS PHYSICS CHEMISTRY
HYD-ANN
Mr. VISWANADHAM
Mobile : 9949320609
Mr. S.K.SINGH
Mobile: 9849911437
Mr. AMARESHWAR
Mobile : 9441552462
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an! are the roots o" the equations

e(ists but all it entries are not necessarily integers.

e(ists an! all it entries are non integers.

e(ists a! all its entries are integers.

nee! not e(ist.

'here a% b% c are non *@ero% unequal real nu&bers % n N

.tate&ent 66D Do&ain o"

16. The set o" ,alues o" a "or 'hich ( ) ( ) 1 F 2

&ole o" .rCl

52. !n adding fe" drops of dil. %&l or

. The spacing bet'een the successi,e scattering

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