CHEMISTRY

1.

PBr3 Mg CH 2 CH 2 CH 3 CH CH 3 A B C |

5.

OH
H 2O D

Here, D is
|

(a) (b) (c) (d) 2.

CH 3 CH O CH 2 CH 3 CH 3 CH 3 O CH CH 2 CH 3
|

6.

CH 3

CH 3 CH CH 2 CH 2 OH
|

CH 3
CH 3 CH 2 CH CH 2 OH
|

CH 3

7.

(c) I > III > II (d) III > I > II PCl5 reacts with a compound containing (a) SO 3 group (b) OH group (c) NO 3 group (d) NO group Cumene process is the most important commercial method for the manufacture of phenol. Cumene is (a) 1-methyl ethyl benzene (b) Ethyl benzene (c) Vinyl benzene (d) Propyl benzene The compound X in the reaction O 390 K 2 X Na+ CO HCl

Phenol is more acidic than OH OCH (a)

3

OH (b) NO2 (a)

COON a ON a COO H

(b)

(c) 3.

C2 H 2

(d) Both (a) and (c) product (A) 8.

(c) Reaction
OH

(d)

O H COO ON H a COON a OCOO Na

is

In the reaction,
CH 3 COONa C6 H 5 CHO (CH 3 CO )2 O ( A)

4.

is (a) Acetaldehyde (b) Cinnamic acid (c) -nephthol (d) Phenol The correct order of ease of dehydration of following is OH
I II

OH CH 2 O
acid or base

OH CH 2 OH CH 2 OH

OH
III

OH

is called (a) Lederer Manasse reaction (b) Claisen condensation (c) Benzoin condensation (d) Etard reaction
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(a) I > II > III

(b) III > II > I

Space for

9.

When phenol is reacted with CHCl 3 and NaOH followed by acidification, salicyldehyde is obtained. Which of the following species are involved in the above mentioned reaction as inter mediate O H (a) O H
CHCl
CCl 3

(a) (c) 14.

Cu
Cu 2 O

(b) (d)

CuO
Cu (OH ) 2

O
CHCl 2

The general order of reactivity of carbonyl compounds for nucleophilic addition reactions is (a) H 2 C O RCHO ArCHO R 2 C O Ar2 C O (b) (c) (d)
ArCHO Ar2 C O RCHO R 2 C O H 2 C O Ar2 C O R 2 C O ArCHO RCHO H 2 C O H 2 C O R 2 C O Ar2 C O RCHO ArCHO

(b)

(c)

OH

(d) All of these

15.

10. The order of solubility of alkanols in water is (a) Propanol < Butanol > Pentanol (b) Propanol > Butanol > Pentanol (c) Propanol > Butanol < Pentanol (d) Propanol = Butanol = Pentanol 11. Benzophenone can be converted into benzene using (a) Fused alkali (b) Anhydrous AlCl3 (c) Sodium amalgam in water (d) Acidified dichromate 12. The reagent(s) which can be used to distinguish acetophenone from benzophenone is (are) (a) 2, 4-dinitrophenyl hydrazine (b) Aqueous solution of NaHSO 3 (c) Benedict reagent (d) I 2 and Na 2 CO 3 13. When acetaldehyde is heated with Fehling solution, it gives a red precipitate of
Space for

Which of the following gives an alcohol and salt of carboxylic acid when reacted with conc. NaOH (a) CH 3 CHO (b) C 6 H 5 CHO (c)
CH 3 COCH 3

(d)

C 6 H 5 COCH 3

16.

Which of the following compounds would undergo Cannizzaro's reaction (a) Propionaldehyde (b) Benzaldehyde (c) Bromobenzene (d) Acetaldehyde 17. NaOH / H reacts with (a) C 6 H 5 OCH 3 (b) CH 3 OH
O

(c) 18.

CH 3 C CH 3

||

(d)

C 2 H 5 OH

The product of following reaction

2 O is

H / Pt

CH (a)
3

(b)

OH

O H CH

(c)
rough

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OH

(d)

19.

Which of the following aldehydes is most reactive towards nucleophilic addition reactions (a) HCHO (b) CH 3CHO (c)
C2 H 5 CHO

(a)

Cl 2 bleaches

due to reduction but

SO 2

due

(d)

CH 3 COCH 3

20.

21.

22.

23.

24.

Which one of the following gives iodoform test (a) Formaldehyde (b) Ethyl alcohol (c) Benzyl alcohol (d) Benzaldehyde If the difference in electronegativities of two elements is very large, then (a) The bond is 50% ionic (b) The bond is 100% covalent (c) The bond is more covalent than ionic (d) The bond is more ionic than covalent Which of the following elements will have the lowest electron affinity (a) Nitrogen (b) Flourine (c) Chlorine (d) Phosphorus The correct order of second ionization potential of carbon, nitrogen, oxygen and fluorine is (a) C > N > O > F (b) O > N > F > C (c) O > F > N > C (d) F > O > N > C Which of the following species has the highest ionisation potential (a) Li (b) Mg

57.

to oxidation (b) Cl 2 bleaches due to reduction but SO 2 due to reduction (c) Both of these (d) None of these When orthophosphoric acid is heated to 600 o C, the product formed is (a) Phosphine,
PH 3 P2 O 5

(b) Phosphorus pentoxide, (c) Phosphorus acid,

58.
H 3 PO3

(d) Metaphosphoric acid,

HPO3

When ammonia is passed over heated it is oxidised to (a) N 2 (b) NO 2 (c)

N 2O

CuO ,

(d)

HNO 2

59.

When chlorine water is exposed to sunlight the colour change that occurs is (a) Colourless to brown (b) Greenish yellow to colourless (c) Light blue to colourless (d) Colourless to greenish yellow

60.

N2

forms and

NCl 3 ,

whereas P can form both

PCl5

PCl5 .

Why

(a) P has low lying 3d orbitals, which can be used for bonding but N 2 does not have low lying 3d orbital (b)
N2

(c) Al (d) Ne 25. Which of the following elements are analogous to the lanthanides (a) Actinides (b) Borides (c) Carbides (d) Hydrides 26. SO 2 acts as temporary bleaching agent but Cl 2 acts as permanent bleaching agent. Why

Space for rough

atom is larger than P in size

N2

(c) P is more reactive towards Cl than (d) None of these

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