[1] JEE Main 2014

Chemistry
61. Which one of the following properties is not shown by
NO ?
(1) It combines with oxygen to form nitrogen dioxide
(2) It's bond order is 2.5
(3) It is dimagnetic in gaseous state
(4) It is a neutral oxide
Ans. [3]
62. If Z is a compressibility factor, van der Waals equa-
tion at low pressure can be written as:
(1)
Z
Pb
RT
= 1
(2)
Z
Pb
RT
= + 1
(3)
Z
RT
Pb
= + 1
(4)
Z
a
VRT
= 1
Ans. [4] The van der Waals equation of state
P
a
V
V b RT
m
m
+
F
H
G
I
K
J
=
2
b g
At low pressure, V b V
m m

~
, the equation re-
duces to
P
a
V
V RT
m
m
+
F
H
G
I
K
J
=
2

PV
a
V
RT
m
m
+ =
Z
PV
RT
a
V RT
m
m
= = 1
63. The metal that cannot be obtained by electrolysis of an
aqueous solution of its salts is
(1) Cu (2) Cr
(3) Ag (4) Ca
Ans. [4]
64. Resistance of 0.2 Msolution of an electrolyte is 50 O .
The specific conductance of the solution is 14
1
. S m

.
The resistance of 0.5 M solution of the same electro-
lyte is 280 O . The molar conductivity of 0.5 Msolu-
tion of the electrolyte in S m mol
2 1
is :
(1) 5 10
3
(2) 5 10
2

(3) 5 10
4

(4) 5 10
3

Ans. [3]
k
k
R
R
2
1
1
2
=

k
R
R
k
2
1
2
1
=
50
280
14
1

. S m

m
k
C
Sm
mol L
= = =
1

2
1
1
3
1
4
050 4
10
050 . .
=

5 10
4 2 1
Sm mol
65. CsCl crystallises in body centred cubic lattice. If 'a' is
its edge length then which of the following expressions
is correct ?
(1) r r a
Cs Cl
+ + =
3
2
(2) r r a
Cs Cl
+ + = 3
(3)
r r a
Cs Cl
+ + = 3
(4)
r r
a
Cs Cl
+ + =
3
2
Ans. [1]
66. Consider separate solutions of 0.500 M C H OH aq
2 5
( ),
0.100 M Mg PO aq
3 4
2
b g ( ) , 0.250 M KBr (aq) and
0.125 M Na PO aq
3 4
( ) at 25C . Which stratement is
true about these solutions, assuming all salts to be
strong electrolytes ?
(1) 0.125 M Na PO aq
3 4
( ) has the highest osmotic
pressure.
(2) 0.500 M C H OH aq
2 5
( ) has the highest osmotic
pressure
(3) They all have the same osmotic pressure.
(4) 0.100 M Mg PO aq
3 4
2
b g ( ) has the highest osmotic
pressure.
Ans. [3]
67. In which of the following reactions H O
2 2
acts as a
reducing agent ?
(1) H O H e H O
2 2 2
2 2 2 + +
+
(2) H O e O H
2 2 2
2 2 +
+
(3) H O e OH
2 2
2 2 +

(4) H O OH e O H O
2 2 2 2
2 2 2 + +
+
(1) (a), (c) (2) (b), (d)
(3) (a), (b) (4) (c), (d)
Ans. [2]
68. In S
N
2 reaction, the correct order of reactivity for the
following compounds:
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CH Cl CH CH Cl CH CHCl
3 3 2 3
2
, , b g
and CH CCl
3
3
b g
is
(1) CH CH Cl CH Cl CH CHCl CH CCl
3 2 3 3
2
3
3
> > > b g b g
(2) CH CHCl CH CH Cl CH Cl CH CCl
3
2
3 2 3 3
3
b g b g > > >
(3) CH Cl CH CHCl CH CH Cl CH CCl
3 3
2
3 2 3
3
> > > b g b g
(4) CH Cl CH CH Cl CH CHCl CH CCl
3 3 2 3
2
3
3
> > > b g b g
Ans. [4]
69. The octahedral complex of a metal ion M
3+
with four
monodentate ligands L L L
1 2 3
, , and L
4
absorb wave-
lengths in the region of red, green, yellow and blue,
respectively. The increasing order of ligand strength
of the four ligands are
(1) L L L L
3 2 4 1
< < < (2) L L L L
1 2 4 3
< < <
(3) L L L L
4 3 2 1
< < < (4) L L L L
1 3 2 4
< < <
Ans. [4]
70. For the estimation of nitrogen, 1.4 g of an organic com-
pound was digested by Kjeldahl method and the
evolved ammonia was absorbed in 60 mL of
M
10
sul-
phuric acid. The unreacted acid required 20 mL of
M
10
sodiumhydroxide for complete neutralization. The
percentage of nitrogen in the compound is:
(1) 3 % (2) 5 %
(3) 6 % (4) 10 %
Ans. [4] %
.
.
% N=

=
14
1000
100 01 100
14
10
71. The equivalent conductance of NaCl at concentration
Cand at infinite dilution are
C
and

, respectively.
The correct relationship between
C
and

is given
as : (where the constant B is positive)
(1)
C
B C =

b g (2)
C
B C = +

b g
(3)
C
B C = +

b g (4)
C
B C =

b g
Ans. [1]
72. For the rection
SO g O g
2
1
2
2
( ) ( ) + SO g
3
( )
if K K RT)
p C
x
= ( where the symbols have usual
meaning then the value of x is: (assuming ideality)
(1)
1
2
(2) 1
(3) 1 (4)

1
2
Ans. [4]
73. In the reaction,
CH COOH A B
LiAlH PCl Alc KOH
3
4 5

.
C,
the product C is
(1) Ethylene (2) Acetyl chloride
(3) Acetaldehyde (4) Acetylene
Ans. [1]
74. Sodiumphenoxide when heated with CO
2
under pres-
sure at 125C yields a product which on the acetylation
produces C.
The major product C would be:
(1) (2)
(3) (4)
Ans. [3]
75. On heating an aliphatic primary amine with
chlooroform and ethanolic potassium hydroxide, the
organic compound formed is:
(1) an alkyl cyanide (2) an alkyl isocyanide
(3) an lakanol (4) an alkanediol
Ans. [2]
76. The correct statement for the molecule, CsI
3
is
(1) it contains Cs
3+
and I

ions
(2) it contains
Cs
+
, I

and lattice I
2
molecule
(3) it is a covalent molecule
(4) it contains Cs
+
and I
3

ions.
Ans. [4]
77. The equation which is balanced and represents the
correct product(s) is
[3] JEE Main 2014
(1) Mg H O EDTA
2
6
2
4
b g b g
+

+
excess NaOH
Mg EDTA H O +
+
b g
2
2
6
(2)
CuSO KCN K Cu CN K SO
4 2
4
2 4
4 + + b g
(3) Li O KCl LiCl K O
2 2
2 2 + +
(4) CoCl NH H Co NH Cl
3
5
2
4
5 5 b g
+
+ + +
+ + +
Ans. [4]
78. For which of the following molecule/s significant
= 0 ?
(a) (b)
(c) (d)
(1) Only (c) (2) (c) and (d)
(3) Only (a) (4) (a) and (b)
Ans. [2]
79. For the non- stoichiometre reaction 2A B C D + + ,
the following kinetic data were obtained in three sepa-
rate experiments, all at 298 K.
The rate law for the formation of C is
(1)
dc
dt
k A B =
2
(2)
dc
dt
k A =
(3)
dc
dt
k A B =
(4)
dc
dt
k A B =
2
Ans. [2]
80. Which series of reactions correctly respensents chemi-
cal relations related to iron and its compound?
(1) Fe FeCl FeCl Fe
Cl heat heat air Zn
2
3 2

,
(2)
Fe Fe O
O heat CO C
o
2
3 4
600

,
FeO Fe
CO C
o
, 700

(3) Fe FeSO
dilH SO H SO O
2 4 2 4 2
4

,
Fe SO Fe
heat
4
3
b g
(4)
Fe FeO
O heat dil H SO
2 2 4

FeSO Fe
heat
4

Ans. [2]
81. Consider the basic strength of amines in aqueous solu-
tion, which one has the smallest pK
b
value?
(1) CH N
3
3
b g (2) C H NH
6 5 2
(3) CH NH
3
2
b g (4) CH NH
3 2
Ans. [3]
82. Which one of the following base is not present in DNA?
(1) Cytosine (2) Thymine
(3) Quinoline (4) Adenine
Ans. [3]
83. The correct set of four quantumnumbers for the value
electrons of rubidium atom (Z = 37) is
(1)
5 1 1
1
2
, , , +
(2)
5 0 1
1
2
, , , +
(3)
5 0 0
1
2
, , , +
(4)
5 1 0
1
2
, , , +
Ans. [3]
84. The major organic compound formed by the reaction
of 1, 1, 1 trichloroethane with silver powder is
(1) 2 - Butyne (2) 2 - Butene
(3) Acetylene (4) Ethene
Ans. [1]
85. Given below are the half - cell reactions
Mn e Mn E V
o 2
2 118
+
+ = ; .
2 118
3 2
Mn e Mn E V
o + +
+ =
e j
; .
The E
o
for 3 2
2 3
Mn Mn Mn
+ +
+ will be
(1) 0.33 V ; the reaction will not occur
(2) 0.33 V ; the reaction will occur
(3) 2.69 V ; the reaction will not occur
(4) 2.69 V ; the reaction will occur
Ans. [3]
86. The ratio of masses of oxygen and nitrogen in a par-
ticular gaseous mixture is 1 : 4. The ratio of number of
[4] JEE Main 2014
their molecules is
(1) 1 : 8 (2) 3 : 16
(3) 1 : 4 (4) 7 : 32
Ans. [4]
N
N
O
N
2
2
1
32
4
28
7
32
= =
7 : 32
87. Which one is classified as a condensation polymer?
(1) Teflon (2) Acrylonitrile
(3) Dacron (4) Neoprene
Ans. [3]
88. Among the following oxoacids, the correct decreasing
order of acid strength is
(1) HClO HClO HClO HOCl
4 3 2
> > >
(2) HClO HClO HClO HOCl
2 4 3
> > >
(3) HOCl HClO HClO HClO > > >
2 3 4
(4) HClO HOCl HClO HClO
4 2 3
> > >
Ans. [1]
89. For complete combustion of ethanol
C H OH O g CO (g) +3H O
2 5 2 2 2
( ) ( ) l l + 3 2 b g
the amount of heat produced as measured in bomb
calorimeter, is 1364.47 kJ mol
1
at 25C . Assuming
ideality the Enthalpy of combustion, A
c
H , for the re-
action will be: (R=8.314 kJ mol
1
)
(1) 1460.50kJ mol
1
(2) 1350.50 kJ mol
1
(3) 1366.95kJ mol
1
(4) 1361.95kJ mol
1
Ans. [3] A A A H U n RT
C C
g
= + b g
= + 1364 47 1 8314 298 . . kJ J b g
= + 1364 47 2 48 . . b g kJ
= 136695 . kJ
90. The most suitable reagent for the conversion of
R CH OH R CHO
2
is
(1) CrO
3
(2) PCC(PyridiniumChlorochromate)
(3) KMnO
4
(4) K Cr O
2 2 7
Ans. [2]