Proof read done by CBS on 2-7-09 ADIT80A01 CBS ON 30-6-09 MID TE M E!AM C"EMIST # 1 $ar% &'e()*on( 1.

IUPAC names of : (a) o Br C6 H 4CH ( CH 3 ) CH 2CH 3 (b) H 3C CH 2 O CH ( CH 3 ) CH 2CH 3 2. Write structural formulae of: (a) 2-(2-c loro! en"l)-1-io#ooctane 3. $i%e one e&am!le eac for (a) an ambi#ent nucleo! ile 4. $i%en one use eac for (a) 'reon-12 (b) io#oform (. Arran)e t e com!oun#s in t e increasin) or#er of reacti%it" to*ar#s S N 2 substitution 1-bromo-3-met "lbutane+ 2-bromo-2-met "lbutane+3-bromo-2-met "l butane 6. W ic as t e i) est meltin) !oint amon) o+ m and !- #ic loroben,enes (b) 4-met "l!ent-3-en-2-one (b) a emiacetal

-. W ic is t e most uns"mmetrical cr"stal s"stem. /. In Cu2 O !re!are# in t e laborator"+ atomic ratio of Cu to 0 is sli) tl" less t an 2:1. W at t"!es of semi-con#utor is t is o&i#e. 2 Mar%( &'e()*on( 1. A "#rocarbon+ C( H12 #oes not react *it Cl2 in t e #ar34 but )i%es a sin)le monoc lorocom!oun#+ C( H 1 Cl + in bri) t sunli) t. W at is t e structural formula of t e "#rocarbon. 12. W " s oul# $ri)nar# rea)ents be !re!are# un#er an "#rous con#itions. 11. W " is met o&e"met ane more %olatile t an et anol. 12. 5o* is met "l ma)nesium c lori#e con%erte# to 2-met "l-2-!ro!anol. 13. 6ra* t e structures of t e follo*in): (a) c"clo!ro!anonone o&ime 14. $i%e a sim!le c emical test to #istin)uis (a) ben,al#e "#e an# aceto! enone (b) semi carba,one of acetone (b) !entan-2-one an# !entan-3-one

1(. 5o* man" atoms !er unit cell are !resent in en#-centre# ort or ombic unit cell. 16. $i%e one e&am!le eac for (a) a ferroma)netic substance (b) a ferrima)netic substance

3 Mar%( &'e()*on( 1-. W at fraction of atoms of 7i are !resent as Ni 3+ in t e o&i#e Ni2.1/O1.22 . 1/. 7iobium cr"stallises in b.c.c. Its #ensit" is /.(()8ce+ Calculate t e atomic ra#ius of 7b (its atomic mass is 13u) 11. Write t e mec anism of t e reaction of met o&"met ane *it 5I 22. Write e9uations for t e follo*in) reaction: (a) Pre!aration of ! enol from c loroben,ene (b) Crotanal#e "#e from acetal#e "#e 21. $i%e t e structural formulae of t e lettere# !ro#ucts: (i)
O CHO

Ag(NH3)2

(ii)
3 Y CH 3CH 2CH 2 OH acetone

CrO

22. 5o* #oes a :05 )rou! attac e# to a ben,ene rin) acti%ate it to*ar#s electro! ilic substitution. 23. 5o* is 1-!ro!o&"!ro!ane s"nt esi,e# from 1-!ro!anol. 24.
(i) Write the Mechanism for: OH
+

HBr

Br

(ii) NaH!O3 (a")

C5H1 O (A)
%igoro&s O'i(ation

#hite $$t
+

.2/NaOH

Ag(NH3)2

)e**o# Cr+sta*s ethanoic aci(

+

No Mirror

$ro$anic aci(

,i-e the str&ct&re of A