SAMPLE PAPER CLASS XI CHEMISTRY

Time: 3 Hours General Instructions: 1. All questions are compulsory. 2. Marks of each question are indicated against it. 3. Question nos. 1 to 8 are very short answer questions and carry 1 mark each. . Question nos. ! to 18 are short answer questions and carry 2 marks each. ". Question nos. 1! to 2# also short answer questions and carry 3 marks each. $. Question nos. 28 to 3% are long answer question and carry " marks each. #. &se log ta'les if necessary( use of calculators is not allowed. Q1 )ow are %."% mol *a 2+,3 and %."% M *a2+,3 differentQ2 )ow many su'shells are present in M shellQ3 .hich property of element is used to classify them in long form of periodic ta'leQ .rite resonance structure of ,/one or sulphurdio0ide. Q" .rite con1ugate 'ase for water and *) 2 species. Q$ .hat do you understand 'y )ydrogen economyQ# 3ind out o0idation num'er of chromium in 4 2+r2,# molecule Q8 5ndicate sigma and pie 'onds in +)26+6+)2. 1 7 8 6 8 Marks Maximum Marks: 70

Q! +alculate num'er of photons with a wavelength of 3%%%pm that provides 1 8oule of energy. 2 Marks Q1% 90plain why 'ond angle in *)3 is more than in )2, molecule though 'oth have sp3 hy'ridi/ation. its volume - .hich law governs this 'ehavior of gasesequation + )1%2 .",262+,22")2, 2 Marks 2 Marks 2 Marks 2 Marks Q11 At constant temperature if the pressure of a fi0ed mass of gas is dou'led what happens to Q12 )ow many grams of o0ygen is required for complete com'ustion of 2!g of 'utane as per the Q13 +alculate 'ond order of o0ygen molecule. :ist all the information provided 'y the 'ond a'out this molecule. Q1 +alculate the total pressure in a mi0ture of 1$ g of o0ygen and g of )ydrogen confined in a vessel of 1dm;3 at 2# degree celsius. <Molar mass of o0ygen 32 )ydrogen 2 =6 %.%83'ar dm 3 4;1mol;1> Q1" ?alance following equation in acidic medium showing all steps( ?r2 2 )2,2; ?r,2 2 )2, 2 Marks 2 Marks

Q1$)ow are silicones prepared- .rite necessary reaction. .rite two uses of silicones. 2 marks Q 1# .hat is demineralised water- )ow is it o'taineddiagonally related elements. Or @ive reasons <1> why alkali metals when dissolved in :iquid ammonia give 'lue solution<2>?eryllium and Magnesium do not impart colour to the flame while other mem'ers do. Q1! <1> Atate )eisen'erg s &ncertainty principle. <2> .rite electronic configuration of +u metal <B62!> and +r 32 ion. <3>.hich or'ital is represented 'y n6 and l63Q2% 90plain why <1> )alogens act as good o0idi/ing reagent. <2>9lectron gain enthalpy of inert gases is /ero. <3>5oni/ation enthalpy of Mg is higher than that of *a. Q21 <1> .hat do you mean 'y ?ond 9nthalpy<2> +alculate 'ond enthalpy of +l;;;+l 'ond from following data. +) <g> 2 +l2 <g>;;+)3+l<g> 2)+l <g> 3 Marks Q22 <1> .hat are e0tensive properties<2> .rite @i''s free energy equation giving meaning of each term used. <3> &nder what condition C &6 <1> Elaster of Earis <2> Quick lime <3> slaked lime. Q2 <1> .hat do you mean 'y functional isomerism<2> .hat are electrophiles<3> .hat is inductive effect - @ive an e0ample. Or <1> .rite 5&EA+ names for +$)"+)2+), and <+)3>2D+)<*)2>D+)3 <2> .rite an e0ample of geometrical isomerism. <3> .hat do you mean 'y electromeric effectQ2"<1> Fraw eclipsed and staggered conformations of ethane. <2>.rite one equation each to show .urt/ reaction and 3riedal craft alkylation. 3 Marks 3 Marks 3 Marks 3 Marks C) 3 Marks Q23.rite chemical equation only for preparation of C);6 ;;1%!.3k8 mol;1 mol ;1 ?ond enthalpy of +D) ?ond 6 13k8( +D+l ?ond 632$ k8 and )D+l ?ond 6 31k8 3 Marks 3 Marks 2 Marks Q18 .hat is the reason of diagonal relationship of elements- .rite two properties of any two

Q2$ <1> )ow nitrogen is detected in an organic compound.-.rire necessary reactions. <2> )ow a molecular formula is different from empirical formulaQ2# <1> .hat do you mean 'y green chemistry<2> 90plain terms ?,F and +,F with reference to environmental chemistry. 3 Marks Q28 <1> 3or the reaction *2<g> 2 3)2 <g>G2*)3<g> the value of 4p is 3.$ 01%2;2 2;2 at "%% 4. +alculate the value of 4c for the reaction at the same temperature. =6%.%83 'ar : 4;1 mol;1. <2> .hat do you understand 'y <1> +ommon ion effect <2> ?uffer solution. 322 Marks Or <1> 3or the reaction E+l"GE+l32+l2 at #34 the value of equili'rium constant 4c is 8.3 01%;3 <1> .rite an e0pression for 4c <2>.hat is the value of 4c for reverse reaction at same 322 Marks temperature.<3> .hat would 'e effect on 4c if pressure is increased. <2> Atate )enryHs :aw. .rite p) value of 101%;" M )+l solution. Q2! @ive reasons for <1>IAi3$2J; is known whereas IAi+l$J;2 is not known. <2> Fiamond is a covalent solid( yet it has highest Melting Eoint. <3> ?oric acid is considered a weak 'ase. < > ?33 'ehaves as :evis acid. <"> +,2 is a gas while Ai,2 is a solid at room temperature. Or <1> .hat are fullerenes-; <2> .hy is 'oric acid mono'asic<3>.hat is inert pair effect< >.hy is E'+l2 is a good o0idi/ing reagent<">.rite the formula of inorganic 'en/ene. Q3% <1> Atate MarkovnicoffHs rule. &sing this write the reaction of propene with )+l. <2> +arry out following conversions <1> 9thyl alcohol to ethane. <2> Aodium acetanilide to 'en/ene. <3> ?en/ene to nitro'en/ene. Or <1> .rite two reactions to show acidic nature of ethyne <2> +omplete the following reactions; o/oneKBnK)2, (1) +)3D+)6+)2;;;;;;;;;;;;; aquous 4Mn, 223 Marks 3 Marks

(2) +)3D+)6+)2;;;;;;;;;;;;;;;;;;;;;; (3) +)6+) 2 ?r2 water;;;;;;;;;;;;

Marking S !eme SESSIO" E"#I"$ EXAMI"ATIO" CLASS XI CHEMISTRY

%& +orrect meaning L 21K2 %' Mwo one s and one p L 21K2 %3 Atomic *um'er %( +orrect structure 1 mark %) +orrect answer L 21K2 %* correct answer 1mark %7 2$ 1mark %+ Aigma $ pie 2 1mark %, 96hN L
1

6 $.$2$ 01%;3 03%%%01%;1% 61!.8#80 1%; 1K1!.8#801%;

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8 1mark

6 ".%30 1%;3! photons L mark

%&0 +orrect e0planation with correct structure 121 mark %&& Fecreases to half( ?oyleHs :aw 121 mark %&' +orrect formula L mark +orrect values and calculation Ans. 2.%$ molK 4g L mark %&3 correct formula L mark +orrect values and calculation +orrect answer with units 1mark 1mark

L mark

%&( correct 'ond order 1mark 2 correct information 1mark %&) correct steps 01K2 62 %&* correct method 2correct uses 121 mark %&7 correct reasons 121 or correct reason 1mark2 two properties 1mark % &+ correct definition 2 ,ne correct method 121 mark %&, <1> correct definition 1mark

<2> +orrect configuration L 21K2 <3> f 1mark %'0 correct answer 1mark each %'& correct definition 1mark O ?ond enthalpy of reactants ; O ?ond enthalpy of Eroducts L mark +orrect value and calculation 1 mark Answer 23 .# k8 L mark %'' +orrect answer 1mark each %'3 +orrect method with equation 1mark each %'( +orrect Answer of each part 1mark each %') +orrect Answer of each part 1mark each %'* +orrect method with equation 2mark +orrect relation 1mark %'7 correct answer of each part 1mark each %'+ <1> +orrect relation L mark( C n6;2 L mark +orrect value and calculation 1 mark ( answer L mark <2> +orrect meaning 1mark each ,r <1> +orrect answer of each part 1mark each <2> +orrect statement 1mark( p)6" 1mark %', +orrect answer of each part 1mark each. %30 <1> +orrect rule 1 mark ( correct reaction 1mark <2> +orrect answer of each part 1mark each ,r <1> two correct reaction 2 mark <2> +orrect answer of each part 1mark each.