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Pure Aluminium
in the annealed state - soft and low yield strength ~ 7-11 MPa - strengthening mechanisms possible solid solution strengthening strain hardening precipitation hardening
Strain hardening
Cold working generates a high density of dislocations dislocation density annealed 1010 m-2 cold worked 1016 m-2 dislocation entanglements resist further dislocation motion
Precipitation hardening
Requires: 1. single phase region () with marked change in solubility with temperature 2. ability to quench from single phase region into two phase region but retain supersaturated solid solution (SSSS) 2. ability to AGE the structure - SSSS decomposes to give large volume fraction of precipitates of a second phase
Typical Phase Diagram for Precipitation Hardening For composition C0 at T0 - single phase , B dissolved in A between T0 and T1 - Solubility of B in A decreases with T at T2 - two phases, &
Mechanism of Precipitation
Stage 1 Clustering of solute atoms - form zone 1-2 atoms thick within solid solution zone still coherent with parent lattice introduce significant lattice strain Guinier-Preston (GP) zones
Mechanism of Precipitation
Stage 2 intermediate precipitates may form (eg ) definite composition and crystal structure different from equilibrium phase semi-coherent with parent lattice
Mechanism of Precipitation
Stage 3 growth of ppt forms equilibrium phase total loss of coherence
7150-T651 aluminium alloy (6.2 Zn, 2.3 Cu, 2.3 Mg, 0.12 Zr) Small precipitates , equilibrium; MgZn2
Strengthening mechanisms
Before aging 1. Solid solution strengthening - Supersaturated matrix - Decreases as aging occurs
Strengthening mechanisms
4. Dislocations bow around precipitate 3. Dislocation can cut through precipitate
2. Coherency stress hardening Strain field around GP zone impedes dislocation motion
Dislocation cutting through ppt: Creates new surfaces generates new solute/solvent bonds Energy required to cut through ppt increases with size As precipitates grow: Easier to loop around and bypass obstacle (Orowan loops) smaller ppt disappear as larger ones grow and looping becomes easier
Peak Aging
strength increases to max. and then decreases aging to max. strength : peak aging when strength begins to decrease : over aged If overaged, only way to recover peak strength is to solution treat and start aging again!
notes: 1. over aging may happen if these alloys are used at elevated temperatures 2. Aging may occur during welding of Al alloys
Anneal aged 2.5Ti Anneal 4.5Al aged 0.3V, 2Ti Anneal 0.4 Al, 0.1C aged 18 Ni, 5Mo Anneal 1Ti aged
Temper designations
Because the properties of Al alloys are so depended on the thermo-mechanical history system developed to designate history
Temper designations
F O H1 H2 H3 as fabricated annealed strain hardened only strain hardened and partially annealed strain hardened and stabilised
Temper designations
T1 cooled from elevated temp. shaping process and naturally aged to stable condition T2 cooled from elevated temp. shaping process, cold worked and naturally aged to stable condition T3 solution heat treated, cold worked and naturally aged to stable condition T4 solution heat-treated and and naturally aged to stable condition
Temper designations
T5 cooled from elevated temp. shaping process and artificially aged T6 solution heat treated and artificially aged T7 solution heat treated and stabilised T8 solution heat treated, cold worked and artificially aged T9 solution heat treated, artificially aged and cold worked T10 cooled from elevated temp. shaping process, cold worked and artificially aged