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Chromatography and Laboratory Products 2014

Chromatography and Laboratory Products

2014

Chromatography and Laboratory Products 2014
Chromatography and Laboratory Products 2014

Ordering - Sales, Terms, & Conditions

Phone:

866-SORBTEC (767-2832)

Mail:

Fax:

770-936-0326

Email:

sales@sorbtech.com

Online:

www.sorbtech.com

Sorbent Technologies, Inc. 5955 Peachtree Corners East Suite A Norcross, GA 30071

Payment Terms:

Payment by valid credit card unless otherwise stated, FOB, Norcross, Georgia.

Net 30 days is subject to approval and agreement.

Shipping and Insurance are prepaid and added to invoice.

A charge of 1.5% interest per month late charge will be applied to accounts after net 30.

Orders (domestic and international) may be payable by wired funds.

Pricing and Discounts:

To better serve our customers each order is custom quoted.

Quantity and blanket order discounts are available.

Purchase Orders:

Please call us at 866-SORBTEC (767-2832) or Int’l 770-936-0323 to be approved for an online PO. Once your name and company is approved, you may do future online POs under an online user name that you created upon registration on www.sorbtech.com.

Credit Cards:

We accept Mastercard, Visa, Discover & American Express

Include your credit card number, expiration date, and CV code if ordering by credit card.

International Orders:

Please call +1-770-963-0323 to place your international order.

Because shipping and insurance are prepaid and added to the invoice, we do not accept international orders online.

All international orders must be prepaid.

Orders under $400 may be paid by credit card (Visa, Mastercard, Discover or American Express) or wired funds.

Orders over $400 are payable by wired funds only.

Return Policy:

Please contact us immediately if an item is to be returned.

We will issue a R.A.N. (Return Authorization Number) when and where appropriate.

Returns are subject to approval and may incur a 25% restocking fee.

If a product was shipped in error, no restocking fee will be incurred.

Damaged Goods:

Please inspect your shipment upon receipt. If external damage, accept only after driver has noted damage on all copies of delivery receipt.

If you receive Damaged Goods or a shortage, contact the carrier immediately to make a claim. Save all packing materials to be inspected by carrier. • All claims must be made within 5 days of receipt of shipment.

Warranty

Sorbent Technologies, Inc. warrants its products to be free from known defects and shall conform to the description and specifications of

such products as specified on the label, and in the catalog, data sheets, or literature at the time of the sale. Specifications are subject to change without notice.

Sorbent Technologies, Inc.’s warranty is strictly limited to the value of the product sold.

This warranty is exclusive, and Sorbent Technologies, Inc. makes no other warranty, express or implied, including without limitation any implied

warranties of merchantability and/or fitness for any particular purpose.

Sorbent Technologies, Inc. is not responsible for any direct, indirect, special, incidental, compensatory, or consequential damages.

If you are not fully satisfied with any Sorbent Technologies, Inc.’s products, contact us within 30 days of purchase and we will (at our discretion) provide replacement or credit.

All trademarks are properties of their respective owners. Copyright ©2014 Sorbent Technologies, Inc. All rights reserved.

SORBTECH

SORBENT

TECHNOLOGIES

Providing Purity and Performance, Service and Selection

Page

About Sorbent Technologies

4

Silica Gel

5

Granular

6

Silica Gel for ASTM D1319-01 & ISO 3837

9

Spherical

10

Bonded Phases

13

Dry Column Chromatography

16

Alumina

18

Alumina Solvent Purification

21

Specialty Adsorbents

24

Polymeric Resins

26

SPE Cartridges

33

CHROMABOND®

33

QuEChERS

43

Vacuum Manifold

44

Jordi

46

TLC Plates

48

Flash Cartridges

57

EZ Flash System

61

EZ Mini Pump

61

EZ Fraction Collectors

61

EZ Flash Detectors

62

FPLC Columns

66

SNAP®

66

Econoline® and Econoline® LP

68

Upscale & IsoKrom

69

Syringe Filters

70

HPLC Columns

72

Sorbtech Purity

72

Macherey-Nagel

73

MCI

GEL®

80

Jordi

83

HPLC Column Packing System

85

GC Columns

86

Laboratory Equipment

96

Centrifan PE - Personal Evaporator

96

Variable Speed Rocker and Orbital/Linear Shaker

98

Hotplate Stirrers

99

Pipettors and Serilogical Pipets

100

Pipet Tips

101

Bottle Dispensers/Weigh Dishes/ Cuvettes

102

PCR

Products

103

Tubes

104

Racks and Gloves

105

Microscopes

106

Visit our website for our complete product selection and to search our application database.

www.sorbtech.com

Sorbent Technologies, Inc.

3

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About Sorbent Technologies, Inc.

Your Success is Our Goal!

When chromatography is the means to the success of weeks or even years of hard work, industry leaders and researchers rely on Sorbent Technologies’ superior products, information and consultation. That is because we are committed to the success of your work and we partner with our customers to provide the most effective solutions for your projects’ unique challenges.

Chromatography is our expertise. Our trained product specialists will assist you with method development and optimization from analytical methods to full scale process. Furthermore, we provide an extensive applications database to describe methods for LC, HPLC, SPE, TLC and GC which includes both mobile and stationary phases for your target compound. We understand the importance of your work and the necessity for high-quality information and products.

This catalog displays a sampling of our product offerings and product information. To find out more about our full line of chromatography products, visit www.sorbtech.com or contact one of our product specialists at 866-SORBTECH.

Highest Quality

Since 2000 Sorbtech has been providing the highest-quality adsorbents for chromatography and purification from laboratory to pilot to full-scale production. Manufactured to the highest standards, all of our adsorbents offer:

The highest purity

Standardized activities

Narrow particle and pore distributions

Consistent particle shape and surface symmetry

Excellent mechanical and structural properties for pressure stability

Exceptional bonding techniques

properties for pressure stability • Exceptional bonding techniques 4 www.sorbtech.com Sorbent Technologies, Inc.

4

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Sorbent Technologies, Inc.

Silica Gel

Silica Gel

Selection Guides

Silica Gel is our specialty. We offer the largest selection of silica gels with pore diameters ranging from 60 Å to 1000 Å, particle sizes from 2 μm to 500 μm, and bonded phases from C18 to SAX (HPLC, MPLC, Flash & Gravity Grades). Sorbent Technologies offers the best selection of granular silica gels for chromatography including TLC, MPLC, Flash, and Gravity grades. Use the Silica Guides below to help you find the right silica for your application.

Broadest Selection

Sorbent Technologies offers a full range of standardized granular silica gels in premium and standard grades. Our complete selection of silica gel products designed to perform simple to complex analytical and preparative chromatographic techniques for laboratory, pilot, and industrial process applications.

Granular and Spherical

Particle sizes for analytical to preparative to process applications from 2.0 μm to 3 mm

Pore sizes for small to large molecule separations (proteins & peptides) from 60 Å to 1000 Å

C18, C8, C4, C2, Amino, Cyano, Phenyl, Diol, and Custom Bonded Phases

Modified aluminas with three pH levels and specific Brockmann activities

Ion exchange resins with superior physical and chemical properties

With all of these adsorbents available at Sorbtech, finding appropriate adsorbents is easy and convenient. Allow a Sorbtech product specialist to help you develop or optimize your application or process.

Compound

to be

Purified

your application or process. Compound to be Purified Functionality Chemistry Solubility C a p a c
your application or process. Compound to be Purified Functionality Chemistry Solubility C a p a c

Functionality

Chemistry

Solubility
Solubility

Capacity

Molecular

Weight

Chemistry Solubility C a p a c i t y Molecular Weight Selectivity Separation Difficulty Non
Chemistry Solubility C a p a c i t y Molecular Weight Selectivity Separation Difficulty Non

Selectivity

Separation

Difficulty

i t y Molecular Weight Selectivity Separation Difficulty Non Aqueous Non to Low Polarity Silica Aqueous
i t y Molecular Weight Selectivity Separation Difficulty Non Aqueous Non to Low Polarity Silica Aqueous

Non Aqueous

Weight Selectivity Separation Difficulty Non Aqueous Non to Low Polarity Silica Aqueous MW<1,000D Low

Non to Low Polarity

Silica

Aqueous

MW<1,000D

Aqueous MW<1,000D Low to Medium Polarity Medium to High Polarity Organic Molecules 6 0 Å C4
Aqueous MW<1,000D Low to Medium Polarity Medium to High Polarity Organic Molecules 6 0 Å C4

Low to

Medium

Polarity

Medium to

High Polarity

Organic

Molecules

60 Å

C4 & C8

C18

70 Å

MW<10,000D

Peptides

MW<50,000D

Polypeptides

Bio-polymers

100

Å

500

Å

200

Å

800

Å

300

Å

1000

Å

α < 1.2

1.2

< α < 1.5

1.5 < α < 2.0

α < 2.0

3 & 5 μm

20

μm

10

μm

40

μm

40-75 μm

75-200 μm

15

μm

20 - 45 μm

Sorbent Technologies, Inc.

5

www.sorbtech.com

Silica Gel

Granular Silica Gel - TLC, MPLC, Flash, & Gravity LC Phases

Premium Rf™ silica gel is the finest granular silica gel on the market. This high purity product provides narrow particle and pore distribution and is designed to increase yield, making it ideal for every-day chromatography and complicated separations. With Premium Rf™ your lab can enjoy bulk quantities for large-scale applications, no scale-up limitation, and secured lots offered for process use.

Granular or irregular-shaped silica gel is commonly used for the following applications: Medium Pressure Liquid Chromatography (MPLC), Flash Chromatography, and Classic Column Chromatography. Silica gels used for these applications are normally 60 Å or sometimes 100 Å. For larger porosities please visit our Spherical Silica Gel pages later on in this catalog and also available online at www.sorbtech.com. For granular bonded phase silica gel, see the Bonded Phase Section.

Recommended Applications:

• Aflatoxins

• Chloramphenicol

• Pesticides

• Steroids

• Vitamins

• Chloramphenicol • Pesticides • Steroids • Vitamins Advantages of Premium Rf™ Flash Silica Gel 1.

Advantages of Premium Rf™ Flash Silica Gel

1. Narrow particle distribution: 40-75 μm +/- 5% versus leading brands +/- 10-12%.

Better and easier packing.

No channeling in the bed, leading to tighter bands, thus better separation.

Lower pressure drop (fewer fine particles), leading to faster flow, thus faster run time.

2. Small pore volume: Higher bulk density.

More silica gel per column volume, leading to greater loadability.

Lower dead volume, leading to less solvent use.

3. Narrow pore size distribution: Minimum small pores.

Maximum targeted surface area available, leading to greater loadability.

Minimum risk of product trapped in pores, leading to increased yield and longer life time of the silica gel.

4. Purity: 99.95% SiO 2

Our high purity (low metal impurities) ensures maximum resolution as compared to the competition.

5. Side by side comparison tests of every major silica gel show our Premium Rf to give the best results.

• Easier to pack

• More fractions

• Faster run time

• Better resolution

•Increased yield

Silica Gel - Granular

Catalog

Particle

Porosity

pH

LOI

Bulk

Surface Area

Water Soluble

No.

Dist

Value

Density

Matter

Premium Rf

52200

15

- 40 μm

60

Å

~ 7

5%

0.5

g/ml

450-550 m 2 /g

-

Premium Rf

52300

20

- 45 μm

60

Å

~ 7

5%

0.5

g/ml

450-550 m 2 /g

-

Premium Rf

52500

40

- 75 μm

60

Å

~ 7

5%

0.5

g/ml

470-570 m 2 /g

-

Premium Rf

52700

75

- 200 μm

60

Å

~ 7

5%

0.5

g/ml

470-570 m 2 /g

-

Premium Grade

40930M

40

- 63 μm

60

Å

~ 7

2 - 4%

0.5

g/ml

460-550 m 2 /g

-

Standard Grade

11610

5 - 15 μm

60

Å

~ 7

-

0.4

g/ml

500-600 m 2 /g

0.2%

Standard Grade

10910

12

- 26 μm

60

Å

~ 7

-

0.4

g/ml

500-600 m 2 /g

0.2%

Standard Grade

10920

18

- 32 μm

60

Å

~ 7

-

0.4

g/ml

500-600 m 2 /g

0.2%

Standard Grade

10930

32

- 63 μm

60

Å

~ 7

-

0.4

g/ml

500-600 m 2 /g

0.2%

Standard Grade

30930M

40

- 63 μm

60

Å

~ 7

< 9%

0.5

g/ml

450-550 m 2 /g

-

Standard Grade

40930

40

- 63 μm

60

Å

~ 7

< 7%

0.5

g/ml

450-550 m 2 /g

-

Standard Grade

10940

63

- 200 μm

60

Å

~ 7

-

0.5

g/ml

500-600 m 2 /g

0.2%

Standard Grade

30940

63

- 200 μm

60

Å

~ 7

< 9%

0.5

g/ml

450-550 m 2 /g

-

Standard Grade

40940

63

- 200 μm

60

Å

~ 7

< 7%

0.5

g/ml

450-550 m 2 /g

-

Standard Grade

10400

100

- 200 μm

60

Å

~ 7

-

0.5

g/ml

500-600 m 2 /g

0.2%

Standard Grade

10950

200

- 500 μm

60

Å

~ 7

-

0.5

g/ml

500-600 m 2 /g

0.2%

Standard Grade, Active

10800

18

- 32 μm

60

Å

~ 7

< 5%

0.4

g/ml

500-600 m 2 /g

0.2%

Standard Grade, Active

10810

32

- 63 μm

60

Å

~ 7

< 5%

0.4

g/ml

500-600 m 2 /g

0.2%

Standard Grade, Active

10820

32

- 100 μm

60

Å

~ 7

< 5%

0.5

g/ml

500-600 m 2 /g

0.2%

Standard Grade, Active

10830

63

- 100 μm

60

Å

~ 7

< 5%

0.5

g/ml

500-600 m 2 /g

0.2%

Standard Grade, Active

10840

63

- 200 μm

60

Å

~ 7

< 5%

0.5

g/ml

500-600 m 2 /g

0.2%

Standard Grade, Active

10850

100

- 200 μm

60

Å

~ 7

< 5%

0.5

g/ml

500-600 m 2 /g

0.2%

Standard Grade, Active

10860

200

- 500 μm

60

Å

~ 7

< 5%

0.5 g/ml

500-600 m2/g

0.2%

6

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Sorbent Technologies, Inc.

Silica Gel

TLC Silica Gels - Granular

Sorbent Technologies offers an assortment of silica gels for the making of analytical and preparative TLC plates. Our Silica Gel for TLC (Cat. #11610) and Silica Gel for Prep. TLC (Cat. #52200) contain neither an inorganic nor an organic binder. They can also be used in a packed column format for extra high resolution.

TLC Slurry preparation for soft layer coating:

1. Silica Gel and small amount of calcium sulfate (gypsum) is mixed with water.

2. This mixture is spread as a thick slurry on a clean glass plate.

3. The resultant plate is dried and activated by heating in an oven for thirty minutes at 110 °C.

The thickness of the absorbent layer is typically around 0.1 – 0.25 mm for analytical purposes and around 0.5 – 2.0 mm for preparative TLC.

Cat. #

Product

Part. Dist.

Size

11610-05

Silica Gel for TLC, Standard Grade, 60 Å

5-15 μm

500

g

11610-25

Silica Gel for TLC, Standard Grade, 60 Å

5-15 μm

25

kg

11620-05

Silica Gel for TLC, Standard Grade, 60 Å, w/UV254

5-15 μm

500

g

11620-25

Silica Gel for TLC, Standard Grade, 60 Å, w/UV254

5-15 μm

25

kg

11630-05

Silica Gel for TLC, Standard Grade, 60 Å, w/ Gypsum

5-15 μm

500

g

11630-25

Silica Gel for TLC, Standard Grade, 60 Å, w/ Gypsum

5-15 μm

25

kg

11640-05

Silica Gel for TLC, Standard Grade, 60 Å, w/ Gypsum and UV254

5-15 μm

500

g

11640-25

Silica Gel for TLC, Standard Grade, 60 Å, w/ Gypsum and UV254

5-15 μm

25

kg

52200-1

Silica Gel for Prep. TLC, Premium Rf™, 60 Å

15-40 μm

1

kg

52200-25

Silica Gel for Prep. TLC, Premium Rf™, 60 Å

15-40 μm

25

kg

11650-1

Silica Gel for Prep. TLC, 60 Å, w/UV254

5-50 μm

1

kg

11650-5

Silica Gel for Prep. TLC, 60 Å, w/UV254

5-50 μm

5

kg

11660-1

Silica Gel for Prep. TLC, 60 Å, w/Gypsum and UV254

5-50 μm

1

kg

11660-5

Silica Gel for Prep. TLC, 60 Å, w/Gypsum and UV254

5-50 μm

5

kg

MPLC Silica Gels - Granular

Improve Your Resolution with MPLC

When working with difficult separations that give very low Rf-values on initial screenings by TLC and require larger volumes of flash grade silica, you need the improved resolution power that Sorbtech MPLC grades provide. By using a smaller particle size, a higher number of theoretical plates are achieved using the same volume of silica which in turn increases the resolution.

Cat. #

Product

Part. Dist.

Size

10910-05

Silica Gel for MPLC, Standard Grade, 60 Å

12-26 μm

500

g

10910-1

Silica Gel for MPLC, Standard Grade, 60 Å

12-26 μm

1

kg

10910-2.5

Silica Gel for MPLC, Standard Grade, 60 Å

12-26 μm

2.5

kg

10910-5

Silica Gel for MPLC, Standard Grade, 60 Å

12-26 μm

5

kg

10910-25

Silica Gel for MPLC, Standard Grade, 60 Å

12-26 μm

25

kg

10920-05

Silica Gel for MPLC, Standard Grade, 60 Å

18-32 μm

500

g

10920-1

Silica Gel for MPLC, Standard Grade, 60 Å

18-32 μm

1

kg

10920-2.5

Silica Gel for MPLC, Standard Grade, 60 Å

18-32 μm

2.5

kg

10920-5

Silica Gel for MPLC, Standard Grade, 60 Å

18-32 μm

5

kg

10920-25

Silica Gel for MPLC, Standard Grade, 60 Å

18-32 μm

25

kg

52300-05

Silica Gel for MPLC, Premium Rf™, 60 Å

20-45 μm

500

g

52300-1

Silica Gel for MPLC, Premium Rf™, 60 Å

20-45 μm

1

kg

52300-2.5

Silica Gel for MPLC, Premium Rf™, 60 Å

20-45 μm

2.5

kg

52300-5

Silica Gel for MPLC, Premium Rf™, 60 Å

20-45 μm

5

kg

52300-25

Silica Gel for MPLC, Premium Rf™, 60 Å

20-45 μm

25

kg

For more selections and sizes, visit our website or contact your personal Product Specialist.

 

Sorbent Technologies, Inc.

7

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Silica Gel

Flash Silica Gels - Granular

Sorbtech offers high-quality flash and granular silica gels. Our extensive range of silicas have been selected for high performance and optimal reproducibility while offering a wide range of particle sizes and pore diameters. * For Reversed-Phased Silica Gels, see Bonded Phase Silica Gels section.

Cat. #

Product

Grade

Part. Dist.

Size

52500-05

Silica Gel, Premium Rf™, 60 Å

Flash

40-75 μm (200x400 mesh)

500

g

52500-1

Silica Gel, Premium Rf™, 60 Å

Flash

40-75 μm (200x400 mesh)

1

kg

52500-2.5

Silica Gel, Premium Rf™, 60 Å

Flash

40-75 μm (200x400 mesh)

2.5

kg

52500-5

Silica Gel, Premium Rf™, 60 Å

Flash

40-75 μm (200x400 mesh)

5

kg

52500-25

Silica Gel, Premium Rf™, 60 Å

Flash

40-75 μm (200x400 mesh)

25

kg

40930M-05

Silica Gel, Premium, 60 Å

Flash

40-63 μm (230x400 mesh)

500

g

40930M-1

Silica Gel, Premium, 60 Å

Flash

40-63 μm (230x400 mesh)

1

kg

40930M-2.5

Silica Gel, Premium, 60 Å

Flash

40-63 μm (230x400 mesh)

2.5

kg

40930M-5

Silica Gel, Premium, 60 Å

Flash

40-63 μm (230x400 mesh)

5

kg

40930M-25

Silica Gel, Premium, 60 Å

Flash

40-63 μm (230x400 mesh)

25

kg

30930M-05

Silica Gel, Standard Grade, 60 Å

Flash

40-63 μm (230x400 mesh)

500

g

30930M-1

Silica Gel, Standard Grade, 60 Å

Flash

40-63 μm (230x400 mesh)

1

kg

30930M-2.5

Silica Gel, Standard Grade, 60 Å

Flash

40-63 μm (230x400 mesh)

2.5

kg

30930M-5

Silica Gel, Standard Grade, 60 Å

Flash

40-63 μm (230x400 mesh)

5

kg

30930M-25

Silica Gel, Standard Grade, 60 Å

Flash

40-63 μm (230x400 mesh)

25

kg

40930-05

Silica Gel, Standard Grade, 60 Å

Flash

40-63 μm (230x400 mesh)

500

g

40930-1

Silica Gel, Standard Grade, 60 Å

Flash

40-63 μm (230x400 mesh)

1

kg

40930-2.5

Silica Gel, Standard Grade, 60 Å

Flash

40-63 μm (230x400 mesh)

2.5

kg

40930-5

Silica Gel, Standard Grade, 60 Å

Flash

40-63 μm (230x400 mesh)

5

kg

40930-25

Silica Gel, Standard Grade, 60 Å

Flash

40-63 μm (230x400 mesh)

25

kg

For more selections and sizes, visit our website or contact your personal Product Specialist.

Gravity Silica Gels - Granular

Silica gels for normal phase, classical column chromatography.

Cat. #

Product

Grade

Part. Dist.

Size

52700-05

Silica Gel, Premium Rf™, 60 Å

Gravity

75-200 μm (70x200 mesh)

500

g

52700-1

Silica Gel, Premium Rf™, 60 Å

Gravity

75-200 μm (70x200 mesh)

1

kg

52700-2.5

Silica Gel, Premium Rf™, 60 Å

Gravity

75-200 μm (70x200 mesh)

2.5

kg

52700-5

Silica Gel, Premium Rf™, 60 Å

Gravity

75-200 μm (70x200 mesh)

5

kg

52700-20

Silica Gel, Premium Rf™, 60 Å

Gravity

75-200 μm (70x200 mesh)

20

kg

30940-05

Silica Gel, Standard Grade, 60 Å

Gravity

63-200 μm (70 x 230 mesh)

500

g

30940-1

Silica Gel, Standard Grade, 60 Å

Gravity

63-200 μm (70 x 230 mesh)

1

kg

30940-2.5

Silica Gel, Standard Grade, 60 Å

Gravity

63-200 μm (70 x 230 mesh)

2.5

kg

30940-5

Silica Gel, Standard Grade, 60 Å

Gravity

63-200 μm (70 x 230 mesh)

5

kg

30940-25

Silica Gel, Standard Grade, 60 Å

Gravity

63-200 μm (70 x 230 mesh)

25

kg

40940-05

Silica Gel, Standard Grade, 60 Å

Gravity

63-200 μm (70 x 230 mesh)

500

g

40940-1

Silica Gel, Standard Grade, 60 Å

Gravity

63-200 μm (70 x 230 mesh)

1

kg

40940-2.5

Silica Gel, Standard Grade, 60 Å

Gravity

63-200 μm (70 x 230 mesh)

2.5

kg

40940-5

Silica Gel, Standard Grade, 60 Å

Gravity

63-200 μm (70 x 230 mesh)

5

kg

40940-25

Silica Gel, Standard Grade, 60 Å

Gravity

63-200 μm (70 x 230 mesh)

25

kg

10840-05

Silica Gel, Active, 60 Å

Gravity

63-200 μm (70 x 230 mesh)

500

g

For more selections and sizes, visit our website or contact your personal Product Specialist.

8

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Sorbent Technologies, Inc.

Silica Gel

Silica Gel for ASTM D1319-02a and ISO 3037

Quality Silica Gel

Our Silica Gel #51600 is a high purity silica and is manufactured to conform to the specifications of ASTM D1319-02a Test Method for Hydrocarbon Types in Liquid Petroleum Products by Fluorescent Indicator Adsorption & ISO 3037 Liquid Petroleum Products-Determination of Hydrocarbon Types-Fluorescent Indicator Adsorption Method. Sorbtech Silica Gel #51600 can be used in place of W.R. Grace’s product (Code 923.) See table below.

ASTM D1319-02a

This method covers the determination of hydrocarbon types over the concentration ranges from 5 to 99 volume % aromatics, 0.3 to 55 volume % olefins, and 1 to 95 volume % saturates in petroleum fractions that distill below 315° C. This test method may apply to concentrations outside these ranges, but the precision has not been determined. Samples containing dark-colored components that interfere in reading the chromatographic bands cannot be analyzed.

ISO 3037

The determination of the total volume percent [% (V/V)] of saturates, olefins, and aromatics in petroleum fractions is important in characterizing the quality of petroleum fractions as gasoline blending components and as feeds to catalytic reforming processes, and in characterizing petroleum fractions and products from catalytic reforming and from thermal and catalytic cracking as blending components for motor and aviation fuels. This information is also important as a measure of the quality of aviation turbine fuels.

Cat #51600, Silica Gel, Premium Rf, 30 Å, 75-150 μm - Typical Product Specifications

 

Item

Unit

ASTM D1319-02a

Results

 

Year

   

2002

-

Surface Area

m

2 /g

430-530

515

pH

 

5.5-7.0

5.99

Loss of Ignition

mass %

4.5-10.0

4.87

Fe 2 O 3

Mass ppm

50

max

-

Particle Size Distribution

     
 

on 250 μm

 

0

0

 

on 180 μm

1.2

max

0

 

on 150 μm

5 max

0

 

75 to 150 μm

1.2

max

94.4

 

Thru 75 μm

 

5.6

Pore Volume

 

ml/g

15

max

0.39

H

2 O

 

%

 

-

0.66

Laser APS

 

μm

 

-

141.23

 

SiO 2

 

%

 

-

99.95

Na

 

ppm

 

-

29

Mg

 

ppm

 

-

0.8

Al

 

ppm

 

-

5

Ca

 

ppm

 

-

5.1

Fe

 

ppm

 

-

3.8

Zr

 

ppm

 

-

15

Ti

 

ppm

 

-

102

Cr

 

ppm

 

-

0.18

 

Mn

 

ppm

 

-

0.02

Co

 

ppm

 

-

0.17

Ni

 

ppm

 

-

0.06

Zn

 

ppm

 

-

0.2

Cd

 

ppm

 

-

0.02

Pb

 

ppm

 

-

0.13

Sorbent Technologies, Inc.

9

www.sorbtech.com

Silica Gel

Spherical Silica Gel - HPLC, MPLC, Flash & Gravity LC Phases

Spherical vs. Granular

1. Physical Properties

Spherical has lower pore-volume and high bulk density Higher loading in the same column volume

Spherical has high specific resistance. Low impurity content

Spherical has high transparency. Low content of fine particles

2. Particle Size Distribution

Spherical has lower mean particle size and sharper distribution Higher efficiency Lower pressure drop and easier flow rate

Spherical Shape Stable chromatography bed No fine generations

3. Chemical Properties / Impurities

Spherical has lower impurity levels, especially for calcium No undesirable tailing of polar compounds

4. Flash Chromatography Test

Flash chromatography conditions:

Column:

20 x 500 mm glass column

Sample weight:

25 g

Mobile phase:

1. Benzene 2. Dimethyl phthalate n-hexane / ethyl acetate (90-10) w%

Flow rate:

5 cm/min (15.7 ml /min)

Detection:

UV 254 nm

Spherical Silica shows higher resolution. The reasons are:

Smaller particle size.

Homogeneous packing due to the spherical particle shape.

5a. Adsorption Curve

A long break through time (point A) indicates higher capacity

A short mass transfer time (A-B) indicates higher equilibrium

short mass transfer time (A-B) indicates higher equilibrium Both silica gels were packed in 4.6 x

Both silica gels were packed

in 4.6 x 250 mm stainless

steel columns by dry packing.

Capacity of dimethyl phthalate (DMP):

Flow rate

2 ml/min

d

(solvent)

0.65 g/ml or

DMP (1%)

1.3 g/min 13 mg/min

Capacity (mg) 13 x A

5b. Elution / Desorption Curve

Short mass transfer time (Short equilibrium) (D-E) indicates lower solvent consumption

equilibrium) (D-E) indicates lower solvent consumption 10 www.sorbtech.com Spherical Silica Cat. #63700

10

www.sorbtech.com

Spherical Silica

Cat. #63700

Competitor A

100 Å, 75-200 μm

Granular Silica

100 Å, 60-200 μm

Items

Unit

Spherical

Granular

Surface area

(m 2 /g)

272

281

Pore volume

(ml/g)

0.81

1.14

Bulk density

(g/ml)

0.51

0.40

Loss on drying

(%)

6.43

1.65

pH (5% suspension)

7.8

7.5

Specific resistance

- (Ωcm)

57,100

15,700

Transparency Particle Size

(%)

76

33

d50 (Average)

µm

103

143

 

d10

µm

141

228

d90

µm

80

9

d10/d90

-

1.8

2.5

Chemical Impurities Na

μg/g

298

530

Ca

μg/g

90

1100

Fe

μg/g

18

60

Column height (mm)

172

235

Retention time (DMP) min

10.61

11.44

k’

(DMP)

2.48

3.50

N

(DMP)

241

118

Symmetry (DMP)

 

1.6

2.1

(DMP) 241 118 Symmetry (DMP)   1.6 2.1 Adsorption Times Unit Spherical Granular Point A (min)

Adsorption Times

Unit Spherical

Granular

Point A

(min)

24.0

19.3

Point B

(min)

25.3

21.5

Segment A-B

(min)

1.3

2.2

Column Capacity

(mg)

312

251

Silica capacity

(mg/g)

146

155

Elution Times

Point C

(min)

2.3

1.9

Point D

(min)

5.8

4.1

Point E

(min)

10.5

10.8

Segment C-E

(min)

8.2

8.9

Segment D-E

(min)

4.7

6.7

C-E: Elution time D-E: Concentration change time (Mass transfer zone)

6. Conclusion

When using spherical silica gel you will have

Increased loading - up to 30% more

Greater reproducibility of process

Sharper peaks and cost savings (less solvent consumption & labor)

Longer bed lifetime (decrease cost of labor and silica consumption)

Better chromatographic results without switching to costly HPLC equipment.

Increased yield with tighter pore symmetry

Sorbent Technologies, Inc.

Silica Gel

Spherical Silica Gel - HPLC, MPLC, Flash & Gravity LC Phases

High purity silica gel for normal phase column chromatography.

Catalog No.

Particle

Porosity

pH

Loss on

Bulk

Surface

Pore

Compound

Dist.

Value

Drying

Density

Area

Volume

Size

72200

5

μm

70

Å

4.0

- 7.0

2.0%

0.45

g/ml

500

m 2 /g

0.80

ml/g

<1,000 Daltons

73200

5

μm

100

Å

4.0

- 7.0

2.0%

0.45

g/ml

270

m 2 /g

0.80

ml/g

<10,000 Daltons

74200

5

μm

150

Å

4.0

- 7.0

2.0%

0.45

g/ml

175

m 2 /g

0.80

ml/g

<10,000 Daltons

75200

5

μm

200

Å

4.0

- 7.0

2.0%

0.45

g/ml

130

m 2 /g

0.80

ml/g

<10,000 Daltons

76200

5

μm

300

Å

4.0

- 7.0

2.0%

0.45

g/ml

90

m 2 /g

0.80

ml/g

<10,000 Daltons

77200

5

μm

500

Å

4.0

- 7.0

2.0%

0.45

g/ml

60

m 2 /g

0.80

ml/g

<50,000 Daltons

78200

5

μm

800

Å

4.0

- 7.0

2.0%

0.45

g/ml

45

m 2 /g

0.80

ml/g

<50,000 Daltons

79200

5

μm

1000

Å

4.0

- 7.0

2.0%

0.45

g/ml

30

m 2 /g

0.80

ml/g

<50,000 Daltons

72300

10

μm

70

Å

4.0

- 7.0

2.0%

0.45

g/ml

500

m 2 /g

0.80

ml/g

<1,000 Daltons

73300

10

μm

100

Å

4.0

- 7.0

2.0%

0.45

g/ml

270

m 2 /g

0.80

ml/g

<10,000 Daltons

74300

10

μm

150

Å

4.0

- 7.0

2.0%

0.45

g/ml

175

m 2 /g

0.80

ml/g

<10,000 Daltons

75300

10

μm

200

Å

4.0

- 7.0

2.0%

0.45

g/ml

130

m 2 /g

0.80

ml/g

<10,000 Daltons

76300

10

μm

300

Å

4.0

- 7.0

2.0%

0.45

g/ml

90

m 2 /g

0.80

ml/g

<10,000 Daltons

77300

10

μm

500

Å

4.0

- 7.0

2.0%

0.45

g/ml

60

m 2 /g

0.80

ml/g

<50,000 Daltons

78300

10

μm

800

Å

4.0

- 7.0

2.0%

0.45

g/ml

45

m 2 /g

0.80

ml/g

<50,000 Daltons

79300

10

μm

1000

Å

4.0

- 7.0

2.0%

0.45

g/ml

30

m 2 /g

0.80

ml/g

<50,000 Daltons

72400

15

μm

70

Å

4.0

- 7.0

2.0%

0.45

g/ml

500

m 2 /g

0.80

ml/g

<1,000 Daltons

73400

15

μm

100

Å

4.0

- 7.0

2.0%

0.45

g/ml

270

m 2 /g

0.80

ml/g

<10,000 Daltons

74400

15

μm

150

Å

4.0

- 7.0

2.0%

0.45

g/ml

175

m 2 /g

0.80

ml/g

<10,000 Daltons

75400

15

μm

200

Å

4.0

- 7.0

2.0%

0.45

g/ml

130

m 2 /g

0.80

ml/g

<10,000 Daltons

76400

15

μm

300

Å

4.0

- 7.0

2.0%

0.45

g/ml

90

m 2 /g

0.80

ml/g

<10,000 Daltons

77400

15

μm

500

Å

4.0

- 7.0

2.0%

0.45

g/ml

60

m 2 /g

0.80

ml/g

<50,000 Daltons

78400

15

μm

800

Å

4.0

- 7.0

2.0%

0.45

g/ml

45

m 2 /g

0.80

ml/g

<50,000 Daltons

79400

15

μm

1000

Å

4.0

- 7.0

2.0%

0.45

g/ml

30

m 2 /g

0.80

ml/g

<50,000 Daltons

72600

20-45 μm

70

Å

6.0

- 8.0

2.0%

0.45

g/ml

500

m 2 /g

0.80

ml/g

<1,000 Daltons

73600

20-45 μm

100

Å

6.0

- 8.0