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TARGET : JEE (MAIN+ADVANCED) 2014

Date : 08-12-2013 Duration : 3 Hours Max. Marks : 288

Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.

IMPORTANT INSTRUCTIONS

1. 2. 3. 4. 5. 6. Immediately fill the particulars on this page of the Test Booklet with Blue / Black Ball Point Pen. Use of pencil is strictly prohibited. The Answer Sheet is kept inside this Test Booklet. When you are directed to open the Test Booklet, take out the Answer Sheet and fill in the particulars carefully. The test is of 3 hours duration. The Test Booklet consists of 90 questions. The maximum marks are 288. There are three parts in the question paper A, B, C consisting of Mathematics, Physics and Chemistry having 30 questions. Each part consists of Two sections. For each question in Section 1, you will be awarded 3 marks if you darken all the bubble(s) corresponding to only the correct answer(s) and zero mark if no bubbles are darkened. No negative marks will be awarded for incorrect answers in this section. For each question in Section 2 , you will be awarded 4 marks if you darken the bubble corresponding to only the correct answer and zero mark if no bubbles are darkened. In all other cases, (1) marks will be awarded. 7. There is only one correct response for each question. Filling up more than one response in any question will be treated as wrong response and marks for wrong response will be deducted accordingly as per instructions 6 above.

Filling the Top-half of the ORS : Use only Black ball point pen only for filling the ORS. Do not use Gel / Ink / Felt pen as it might smudge the ORS.

8.

Write your Roll no. in the boxes given at the top left corner of your ORS with black ball point pen. Also, darken the corresponding bubbles with Black ball point pen only. Also fill your roll no on the back side of your ORS in the space provided (if the ORS is both side printed). Fill your Paper Code as mentioned on the Test Paper and darken the corresponding bubble with Black ball point pen. If student does not fill his/her roll no. and paper code correctly and properly, then his/her marks will not be displayed and 5 marks will be deducted (paper wise) from the total. Since it is not possible to erase and correct pen filled bubble, you are advised to be extremely careful while darken the bubble corresponding to your answer. Neither try to erase / rub / scratch the option nor make the Cross (X) mark on the option once filled. Do not scribble, smudge, cut, tear, or wrinkle the ORS. Do not put any stray marks or whitener anywhere on the ORS. If there is any discrepancy between the written data and the bubbled data in your ORS, the bubbled data will be taken as final.

13.

Roll Number

I have read all the instructions and shall abide by them. -------------------------------Signature of the Candidate

I have verified all the information filled in by the Candidate. -------------------------------Signature of the Invigilator

PART-A

SECTION - I Straight Objective Type This section contains 24 questions. Each question has 4 choices (1), (2), (3) and (4) for its answer, out of which ONLY ONE is correct.

3. If A and B be positive acute angles satisfying 3 sin2 A + 2 sin2 B = 1 and 3 sin 2A 2 sin 2B = 0, then (1) B = :/4 A/2 (2) A = :/4 2B (3) B = :/2 A/4 (4) A = :/4 B/2

1. If A = sin1

2 3

2 13

2 3

(1) A = tan1

(2) A = tan1

3 2

(1) 4 (2) 1

(3) A = cosec1

(4) A = cot1

(3) 2 (4) 0

5 f (a 6 h ) 2

2 e

loge x is x

function such that f(x) > 0 for all x 7 R and [ . ] denotes greatest integer function then which of the following statements is always true ? (1) If x = a is a point of local minima then c 7 N (2) If x = a is a point of local maxima then c 7 N (3) If x = a is a point of local minima then c 7 89 (4) If x = a is a point of local maxima then c 7 89

(3) e (4)

1 e

RESONANCE

JPJMT2081213C0 - 1

sin (e x.2 1) 6. If f(x) = , x = 2 is continuous at !n ( x.1)

the slope of the tangent at any point (x, y) is x2 2x for all values of x. The point of local

, , 4* ( 3) 2* 3)

(2) + 0 , (

7. Let f(x) = xx ; x 79 (1, >) and g(x) be inverse function of f(x) then g? (x) must be (1) x (1 6 !n x ) (2) x (1 6 !n (g( x )))

1 (3) g ( x ). (1 6 !n (g ( x )) 1 1

2* (3) + 1, ( , , 3)

(4) + 2 ,

4* ( 3)

10. If f(x) = ||x|2 2|x| 3| then f(x) is non differentiable at x equal to (1) 1,0,1 (2) 1, 2

(3) 3, 1, 0, 1, 3 (4) 3, 0, 3

8. Rolle's Theorem holds for the function f(x) = x3 + bx2 + cx, 1 @ x @ 2 at x = value of b + c is (1) 2 (2) 3 (3) 4 (4) 5

4 , then the 3

11. If in a AABC, acos2 + ( + ccos2 + then the sides a, c, b (1) are in A.P. (2) are in G.P. (3) are in H.P. (4) satisfy a + c = 2b

-C* ,2)

-A* 3b (= , 2 2 , )

RESONANCE

JPJMT2081213C0 - 2

12. If f(;) = (sin ; + cosec ;)2 + (cos ; + sec ;)2 , then minimum value of f(;) is (1) 7 (2) 8 (3) 9 (4) 4

3/ 4 log x 15. If x D 3 E

6 log3 x . 5/ 4

assume (1) one positive integral value (2) one irrational value (3) two positive rational values (4) two distinct positive integral values

2.x1/2 6 3.x1/3 6 4.x1/ 4 6 ..... 6 n. x1/n (3x 4)1/2 6 (3x 4)1/3 6 ... 6 (3x 4)1/n

(here

n 7 N, n G 2) is equal to (1)

2 3

5 3 4 cot sin.1 cos 1 3 + 3 & ! % ' ! $2 - 2. 3 * * + ( 6 cos.10 + 12 ( 6 sec.1 2 ! #0 ( + 4 ( 4 ! , ) , ) 0 "1

3 2

D E

(3)

1 2

is (1) 0 (2)

: 4

(4)

1 3

17. A solution (x, y) of the system of equation x y = 1/3 and cos2 (:x) sin2 (:y) = 1/2 is

(3)

: 6

: (4) 2

(SPACE FOR ROUGH WORK)

RESONANCE

JPJMT2081213C0 - 3

18. Let R = {(3, 3), (6, 6), (9, 9), (12, 12), (6, 12), (3, 9), (3, 12), (3, 6)} be a relation on the set A = {3, 6, 9, 12}, the relation is (1) Reflexive and Transitive only (2) Reflexive only (3) an Equivalence relation (4) Reflexive and Symmetric

of 'a' for which f(x) is strictly monotonically increasing at x = 2. (1) [0, 14] (2) [4, 14] (3) R (4) (4, 14)

22. If the thrice repeated roots of equation 19. If f(x) is a differentiable function satisfying f ?(x) < 2 for all x 7 R and f(1) = 2, then greatest possible integral value of f(3) is (1) 5 (2) 6 (3) 4 (4) Data insufficient 23. The curves x3 3xy2 = a and 3x2y y3 = b, where a and b are constants, cut each other 20. Let R be the relation on the set of real numbers defined by a R b. If |a b| @ 1. Then R is (2) at an angle (1) Reflexive and symmetric (2) Symmetric only (3) Transitive only (4) Anti-symmetric only

(SPACE FOR ROUGH WORK)

(1) at an angle

: 3

: 4

: 6

RESONANCE

JPJMT2081213C0 - 4

x

f DxE F 1 2 3 6 6 . Then f(x) is x .1 x . 2 x . 3

(where [.] denotes the greatest integer function) (1) 2 (2) 1 (3) 0 (4) limit does not exist

(1) one-one (2) many one (3) monotonocally increasing function (4) monotonocally decreasing function

27. If f(x) = 1 x x3 , then all real values of x SECTION - II Straight Objective Type This section contains 6 questions. Each question has 4 choices (1), (2), (3) and (4) for its answer, out of which ONLY ONE is correct. satisfying the inequality 1 f(x) f 3(x) > f(1 5x) are (1) (2, 0) B (2, >) (2) (>, 2) (3) (1, 2) (4) (0, 2)

ax 6 b , x@2 xG3

25. If sin A + sin B = 3 (cos B cos A), then value of sin3A + sin3B is equal to (1) 0 (2) 1 (3) 2 (4) 1

!px 2 6 qx 6 1 , %

' !

4 9

(2) b = 2, q =

5 3

(3) a = 1, b = 2 (4) a = 1, q =

5 3

RESONANCE

JPJMT2081213C0 - 5

- :* L , M , N 7 + 0, 2 ( then the value of , )

f ( x ) . x is R

and h (x) =

1 , then domain of 1. x

(1) less than 1 (2) greater than 1 (3) equal to 2 (4) greater than 2

f ( f ( f ( x ))) h (h (h ( x ))) is

RESONANCE

JPJMT2081213C0 - 6

PART-B

SECTION - I Straight Objective Type This section contains 24 multiple choice questions. Each question has choices (1), (2), (3) and (4) out of which ONLY ONE is correct.

32. A c o n d u c t o r o f l e n g t h !

is placed

horizontally perpendicular to a horizontal uniform magnetic field B. Suddenly a charge Q is passed through it and it is found to jump to height h. Choose the correct relation : (Take acceleration due to gravity g)

B 2 ! 2Q2 m 2g

(1) h " 31. The r.m.s. value of current flowing through the resistor in a series L C R a.c. circuit is

I = ! / R. Now the inductor and

(2) h "

2B 2 ! 2Q 2 m2 g

capacitor are connected in parallel and joined in series with the resistor as shown in figure. The current in the circuit is now. (Symbols have their usual meaning) (3) h "

B 2 ! 2Q2 2m 2 g

(4) h "

2B 2 ! 2Q 2 mg

(1) equal to I (2) more than I (3) less than I (4) zero

RESONANCE

JPJMT2081213C0 - 7

q " # is entering in a magnetic field ratio m

34. A point charge is moving in clockwise direction in a circle with constant speed. Consider the magnetic field produced by the charge at a point P (not centre of the circle) on the axis of the circle. (1) only the magnitude of the magnetic field remains constant (2) only the direction of the magnetic field remains constant (3) magnetic field is constant in both direction and magnitude ( 4 ) b o t h m ag n i t u de a n d di r e c t i on o f magnetic field change

35. A small ring of mass m is connected with a particle of same mass by an ideal string & the whole system is released as shown in figure. Coefficient of friction between (1) angle subtended by charged particle at the centre of circular path is 2 $. (2) the charge will move on a circular path and will come out from magnetic field at a distance 4d from the point of insertion. (3) the time for which particle will be in the magnetic field is

2$ . #B

ring A and wire is 3/5, ring A will starts sliding when connecting string will make an angle % with the vertical, then % will be : (particle is free to move and ring can slide only)

(4) the charged particle will subtend an angle of 90 0 at the centre of circular path

(1) 30 (3) 60

RESONANCE

JPJMT2081213C0 - 8

36. Rod AB is placed against a block which is moving towards right with a speed of 1m/s. If at an instant when the rod makes an angle 60 0 with the horizontal and end A is sliding towards left with a speed of 1m/s. Then the speed of the point of contact 'B' of the rod is :

37. A particle starts from rest from the top of an inclined plane and again comes to rest on reaching the bottom most point of incline plane. If the coefficient of friction on some part of inclined plane is 3tan % and rest portion is smooth then the ratio of the rough length of the inclined plane to smooth length would be: (' % ' is the plane angle) (1) 3:1

(2)

sin % cos 2 %

2 :1

3 m/s 2

superposition of two SHM simultaneously and it is given x = 10(1 cos $t)m and y = 10 sin $t m : ( $ = 22/7) then distance travelled by a particle in (1) 10 m (2) 20 m (3) 70 m (4) zero

7 sec. 22

1 (3) m / s 2

(4)

7 3

m/s

RESONANCE

JPJMT2081213C0 - 9

39. A rocket is projected vertically upwards. It explo de s a t t he t o pm o st po int o f i t s trajectory into three identical fragments. One of the f ragments comes straight vertical downward in time t 1 while the other two f ragments land at a time t 2 after explosion. Then the height at which the explosion occured in terms of t 1 and t 2 .

40. Three particles each of mass m can slide on fixed frictionless horizontal circular tracks in the same horizontal plane as shown in the figure. The coefficient of restitution being e = 0.5. Assuming that m 2 and m 3 are at rest initially and lie along a radial line before impact and the spring is initially unstretched, then maximum extension in spring in subsequent motion.

(1)

g t1t 2 2

(2)

3g t1t 2 2

(1)

3 m V0 4 k

(3)

g t1t 2 2

(2) 4 V0 5 k

gt t (4) 1 2 2

(3) 4 V0 5 k

2m

(4)

3 m V0 5 k

RESONANCE

JPJMT2081213C0 - 10

41. A frame made of three uniform rod placed on smooth Horizontal surface. Which is free to move any where, shape of frame is H shown in figure A, B and C part are uniform and point B is mid point of the rod, middle rod is rigidly attached at the midpoint of rod A and rod C. Now a horizontal force F (perpendicualr rod B) is applied such as whole system move with pure trarslational motion. Then x0 in the term of !0 is.

42. In a binary star system mass 2m and 3m revolve about their centre of mass, which is at rest. If radius of star of mass 3m is r0 then the time period of revolution of binary star system is:

r0 5 $r0 2 2GM r0 GM

(1)

(2) 5 $r0

(3) 5$r0

r0 2GM

43. At t = 0 spring is in its natural length and velocity of two block shown in figure then which of the following option is incorrect

! 0 6

3m 8K

$ 2 2m 3K

(2)

! 0 12

2m 3K

(3)

!0 12

7 !0 (4) 12

(4) Acceleration of the two block never be equal to zero, while acceleration of centre of mass is always zero.

(SPACE FOR ROUGH WORK)

RESONANCE

JPJMT2081213C0 - 11

44. Initially A . and B . (ends of the conducting rod) are moving with velocity ' V ' and are connected to two stationary balls A and B with conducting wires as shown, after some time (when the rod has reached into the magnetic field) wires are cut:

" E " (E1 i , E2 j) cos(kz - /t )

then select incorrect option : (1) wave travels along positive z-direction ( 2 ) t h e a s s o c ia t e d m a g n e t i c f i el d i s

" 1 B " (E1 i , E2 j) cos(kz - /t) c

" 1 B " (E1 i - E2 j) cos(kz - /t ) c

(1) A will become positively charged & B will become negatively charged (2) A will become negatively charged & B will become positively charged (3) If rod is moving in y - direction then A become negatively charged and B positively charged. (4) If rod is moving in y - direction then A is positively charged & B is negatively charged.

46. In the fraunhaufer diffraction from a single slit illuminated by polychromatic light, the

first minimum with wavelength 0 1 is found

to be coincident with the third minimum at 0 2 . Then the relationship between these two wavelengths is (1) 3 0 1 = 2 0 2 (2) 3 0 1 = 0 2 (3) 0 1 = 3 0 2 (4) 2 0 1 = 3 0 2

RESONANCE

JPJMT2081213C0 - 12

light of intensity 10. Now the intensity of light

49. A car of mass 500 kg is accelerating up a n i n c l i n e d p l a n e 1 i n 5 0 wi t h a n acceleration 1 m/s 2.The power delivered by the engine at an instant is 600 Watts.

passing through polaroid after polarisation would be : (1) 1 0 (3) 1 0/4 (2) 1 0/2 (4) zero

The speed of the car at this instant is (neglect air resistance and rolling friction) (take g = 10 m/s 2)

48. In the given figure switch (1) is connected for long time, then at t = 0, switch '1' is opened and switch '2' is connected. Then after time t = 0, when inductor coil and capacitor both has same energy first time will be :

50. A small block of mass 4 kg is placed inside a cart of mass 2 kg placed on horizontal surface. A force 10 N is applied on the cart as shown.Neglect friction everywhere.The acceleration of the cart with respect to the ground is :

(1)

5$ LC 4

3$ LC (2) 4

(3)

$ LC 4

(4) 1m/s 2

(4)

$ LC 6

RESONANCE

JPJMT2081213C0 - 13

3 m long, which is placed on his 2

53. An electric field given by E " 4 i 3(y 2 , 2) j passes Gaussian cube of side 1m placed with one corner at origin such that its sides represents x, y and z axes. The magnitude of net charge enclosed within the cube is (1) 4 ! 0 (3) 5 ! 0 (2) 3 ! 0 (4) zero

shoulder. He holds the other end of the stick with his hand. In order that the force on his shoulder may be three times the weight hanging at the end, the distance between his hand and the shoulder should be (neglect weight of the stick) (1) 0.25 m (2) 0.3 m (3) 0.4 m (4) 0.5 m

54. Two cells of emf ! 1 and ! 2 ( ! 2 < ! 1 ) are joined as shown in figure :

52. A capacit or of capacit ance C is f ully charged by connecting it across a battery of emf V, and then disconnected and r econnect ed t o the sam e batt er y but polar it y i s r ever sed. Long t im e af t er changing polarity, the total heat dissipated in the connecting wires in the process is :

length against !1. On connecting the same potentiometer between X and Z it balances for 100 cm length against ! 1 and ! 2. Then the ratio ! is : 1

1 3

!2

(1) (1) CV 2

3 CV 2 2

(2)

(2)

3 4 1 4

2 3

(3) 2CV 2

5 CV 2 2

(3)

(4)

(4)

RESONANCE

JPJMT2081213C0 - 14

56. A uniform current carrying ring of mass m SECTION - II Straight Objective Type This section contains 6 multiple choice questions. Each question has choices (1), (2), (3) and (4) out of which ONLY ONE is correct. and radius R is connected to a massless string as shown. A uniform magnetic field B 0 exist in the region to keep the ring in equilibrium in horizontal position. The current in the ring is: (Take acceleration due to gravity g)

55. Two inductor coils of self inductance 3H and 6H respectively are connected with a

resistance 10 4 and a battery 10 V as

shown in figure. At t = 0 the switch 'S' is closed then the ratio of the magnetic flux at steady state in the inductors L 1 and L 2 is : (1) $RB clockwise as seen from above 0 the ring

mg mg

(2) $RB 0

mg

mg

RESONANCE

JPJMT2081213C0 - 15

57. In the figure shown a block A moving with velocity 10m/s on a horizontal surface collides with another block B (of same mass) at rest initially. The coefficient of

1 restitution is . Neglect friction every 2

58. A particle is acted upon by a force whose component 's variations with t ime are shown in diagrams. Then the magnitude of change in momentum of the particle in 0.1 sec will be

where. The distance between the blocks at 5s after the collision takes place is :

10m/s A B

Fx 30 N

Fy 80 N

t=0.1 sec

t=0.1 sec

Fz

t=0.1 sec 0

50 N

(1) 2 kg

m sec

(2) 10 kg

m sec

(3) 12 kg

m sec

(4) 5 2 kg sec

RESONANCE

JPJMT2081213C0 - 16

59. In the series LCR circuit as shown in figure, the heat developed in 80 seconds and amplitude of wattless current is :

60. Moment of inertia of a uniform solid cone about an axis passing through its centre of gr avit y and par allel t o it s base is (m is mass of cone, its height is h and its radius R = h) (1)

10 MR 2 3

(2)

3 MR 2 5

(3)

3 MR 2 10

(4)

3 MR 2 16

RESONANCE

JPJMT2081213C0 - 17

PART- C

Atomic masses : [H = 1, D = 2, Li = 7, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24, Al = 27, Si = 28, P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52, Mn = 55, Fe = 56, Cu = 63.5, Zn = 65, As = 75, Br = 80, Ag = 108, I = 127, Ba = 137, Hg = 200, Pb = 207]

SECTION - I Straight Objective Type This section contains 24 questions. Each question has five choices (1), (2), (3), and (4) for its answer, out of which ONLY ONE is correct. 61. D-Glucose upon treatment with brominewater gives :

H HO H H OH H OH OH CH2OH D-Glucose HO HO H H H H OH OH CH2OH D-Mannose

62.

CHO

CHO

(1)

(2)

The above structures are related to each other as : (1) identical substance (2) diastereomers (3) (4) (3) enantiomers (4) epimers

RESONANCE

JPJMT2081213C0 - 18

63. RNA forms loop structure because (1) It always contain uracyl instead of thymine (2) of presence of nearby complementary bases (3) all RNAs have to from loop structure to function (4) they are always single stranded 64. A protein attached to carbohydrate moiety is called as : (1) Lipoprotein (2) Nucleoprotein (3) Apoprotein (4) Glycoprotein

66. W hich of the following statements is correct? (1) NO2 group activates the benzene ring for attack of electrophile at ortho and para position. (2) NH2 group activates the benzene ring for attack of electrophile at ortho and para position. (3) BothNO2 group as well as NH2 group activate the benzene ring for attack of electrophile at ortho and para position. (4) Neither NO2 group nor NH2 group activate the benzene ring for attack of electrophile at ortho and para position.

65. 67. The isoelectric point of an amino acid is : The correct name of the product obtained is: (1) cis-1,2-dibromocyclohexane (2) cis-1,4-dibromocyclohexane (3) trans-1,2-dibromocyclohexane (4) trans-1,4-dibromocyclohexane (1) The pH at which it exists in the acidic form (2) The pH at which exists in the basic form (3) The pH at which it exists in the Zwitterion form (4) The pH which is equal to its pKa value

RESONANCE

JPJMT2081213C0 - 19

68. Which of the following statements is true for the reaction given below ?

70. Compound 'X' on heating with Zn dust gives compound 'Y' which on treatment with O3 followed by reaction with Zn dust gives propionaldehyde. The structure of 'X' is :

P (1) (2)

(1) P is a meso compound 2, 3-butanediol formed by syn addition. (2) P is a meso compound 2, 3-butanediol formed by anti addition. (3) P is a racemic mixture of d- and l- 2, 3butanediol formed by anti addition. (4) P is a racemic mixture of d- and l- 2, 3butanediol formed by syn addition. 69. Which one of the following combinations is found in DNA? (1) Guanine and guanidine (2) (2) Guanidine and cytosine (3) Guanine and cytosine (4) Adenine and guanidine (4) (3) (1) 71. 2, 3-Dimethylbut-2-ene when reacted with bromine forms a compound which upon heating with alcoholic KOH produce the following major product : (3) (4)

RESONANCE

JPJMT2081213C0 - 20

72. The compound which reacts with excess bromine to produce 2, 4, 6-tribromophenol, is : (1) 1, 3-cyclohexadiene (2) 1, 3-cyclohexanedione (3) salicylic acid (4) cyclohexanone 73. Ethyl acetate reacts with NH2NHCONH2 to form (1) CH3CONHCONHNH2 (2) CH3CON(NH2)CONH2 (3) CH3CONHNHCONH2 (4) CH3CH2NHNHCONH2 74. The compound X (C 7H 9N) reacts with benzensulfonyl chloride to give Y (C13H13NO2S) which is insoluble in alkali. The compound X is :

NH2

NH CH3

75. The configurations of the carbon atoms C2 and C3 in the following compound are respectively

CH3

(1)

(2)

NH2

NH2

(3)

CH3

(4)

H3C

RESONANCE

JPJMT2081213C0 - 21

CH3 + lCl Lewis acid P

Cl

(2) (3)

H3C

Cl

(4)

(3)

H3C

77. The product obtained from the following sequence of reactions is (4)

CH3

(SPACE FOR ROUGH WORK)

RESONANCE

JPJMT2081213C0 - 22

79. The correct order of dipole moment for the following molecules is :

OH NO2 Cl Cl

81. The compound that is chiral is : (1) 3-methyl-3-hexene (2) 4-chloro-1-methylcyclohexane (3) 2-phenylpentane (4) 1,3-diisopropylbenzene 82. The monomer/s of the following polymer is/ are : ( - C H 2- C H ( C H 3) - C H 2- C H ( C H 3) - C H 2CH(CH3)-)n

(I)

(II)

CH3 CH3

(III)

(2) # < ## < ### (4) ## < ### < # 83. The product (C) of the following sequence of reactions is :

80. The order of acidities of the H-atoms underlined in the following compounds is in the order : (I) (III) (1) IV>II>I>III (2) II>IV>III>I (3) III>IV>I>II (4) I>III>II>IV

(SPACE FOR ROUGH WORK)

(3)

(4)

RESONANCE

JPJMT2081213C0 - 23

84. The order of reactivity of ammonia with the following compound is : (I) CH2=CHBr (II) CH3CH2COCl (III) CH3CH2CH2Cl (IV) C(CH3)3C-Br (1) IV > II > I > III (2) II > IV > III > I (3) III > IV > II > I

85. In the following reaction sequence, the correct structures of E, F and G are :

[F] + [G]

(1) E =

F=

G = CHI3

F=

G = CHI3

(3) E = SECTION - II Straight Objective Type This section contains 6 questions. Each question has 4 choices (1), (2), (3) and (4) for its answer, out of which ONLY ONE is correct. (4) E =

F=

G = CHI3

F=

G = CH3#

RESONANCE

JPJMT2081213C0 - 24

86. A carbonyl compound P, which gives positive iodoform test, undergoes reaction with MeMgBr followed by dehydration to give an olefin Q . Ozonolysis of Q leads to a dicarbonyl compound R, which undergoes intramolecular aldol reaction to give predominantly S. P

!! ! ! ! !"

2. H , H2O 3. H2SO4 , $

%

87. Reaction

of

cyclohexanone

with

dimethylamine in the presence of catalytic amount of an acid forms a compound if water during the reaction is continuously removed. The compound formed is generally known as (1) an amine

1. MeMgBr

3 !! ! ! !"

1. O

(2) an imine (3) an enamine (4) a Schiff's base 88. In Cannizzaro reaction given below

'

2. Zn, H2O

!" R !! ! ! !

2. $

1. OH&

2Ph CHO !!!" PhCH2OH + PhCO2 The structure of the carbonyl compound P is : the slowest step is : (1) the transfer of hydride to the carbonyl group (1) (2) (2) the abstraction of proton from the carboxylic group (3) the deprotonation of PhCH2OH (4) the attack of : O H at the carboxyl group

'

:O H

..

(3)

(4)

RESONANCE

JPJMT2081213C0 - 25

89. The electrophile, E( . attacks the benzene ring to generate the intermediate )-complex. Of the following, which )-complex is of lowest energy ?

H E

90. Phenol is heated with a solution of mixture of KBr and KBrO 3. The major product obtained in the above reaction is : (1) 2-Bromophenol (2) 3-Bromophenol (3) 4-Bromophenol

(1)

NO2

(4) 2, 4, 6 -Tribromophenol

H E

(2)

NO2

(3)

H E

NO2

(4)

H

+ E

RESONANCE

JPJMT2081213C0 - 26

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