MATERIAL SAFETY DATA SHEET

Suppliers Name Address Tyco Fire & Safety 73 Reserve Rd, Artarmon NSW, 2064 Prepared By SECTION 1 - IDENTITY Common Name (used on lable) (Trade Name and Synonyms) Chemical Name Formula SECTION 2 - INGREDIENTS PART A HAZARDOUS INGREDIENTS Pricipal Hazardous Component(s) (chemical and common name(s)) 2,2 Dichloro-1,1,1-Trifluoroethane (HCFC 123) Isopropenyl-1Methyl cyclohexene PART B OTHER INGREDIENTS Other Component(s) (chemical and common name(s)) Chlorodifluoromethane (HCFC 22) 2 Chloro 1,1,1,2-Tetraflurothane (HCFC 124) 82.00 9.50 75-45-6 2837-89-0 Not Established Not Established Wt.% CAS No. ACGIH TLV 4.75 3.75 306-83-2 5989-27-5 580 ppm (mixture) Not Established Wt.% CAS No. ACGIH TLV NAF S III HCFC Blend A Mixture N/A Chemical Family CAS No. N/A Technical Services Date Prepared Other Information Calls

NAFS III
133 166 or 000 133 166 24 Hrs April 2004

Emergency Telephone No.

Blend of HCFCs plus a detoxifier

Acute Toxicity Data

Oral LC50 (rabbit & skin) 2000mg/kg Oral LC50 (rat) 4400mg/kg

Acute Toxicity Data

Inhalation 280,000 ppm Inhalation 570,000 ppm

SECTION 3 Physical & Chemical Charateristics (Fire & Explosion Data) Boiling Point Percent Volatile by Volume (%) Solubility in Water Appearance & Odour Flash Point Negligible -38.3C 100 Specific Gravity (H20 = 1) Vapour Density (air = 1) Reactivity in water 1.2 @ 25C 3.2 Vapour Pressure (mm Hg) Evaporation Rate (Air =1) Unreactive 825kPa @ 20C N/A Gas at room temperature

Colourless Gas and Citrus Odour N/A Flammable Limits in Air % by Volume N/A Extinguisher Media THIS IS AN EXTINGUISHING AGENT Auto-Ignition Temp N/A

Special Fire Fighting Procedures

THIS IS A FIRE EXTINGUISHING AGENT. Use water to cool fireexposed cylinders or other containers. Self-conained breathing apparatus with full face piece and protective clothing when re-entering unventilated fire areas where product has been used.

Unusual Fire & Explosion Hazards

Containers are equipped with pressure and temperature relief devices, but rupture may occur under fire conditions and toxic decompisition by-products may be formed if used in fires over 500C.

SECTION 4 Physical Hazards Stability Incompatibility (materials to avoid) Hazardous Decomposition Products Unstable Stable X Conditions to avoid Decomposes under fire conditions above 500C

Active metals, aluminum dust and fires involving metal hydrides. Thermal decomposition at temperatures above 500C forming hydrogen fluoride and hydrogen chloride. These by-products have a sharp irritating odour. They are dangerous in low concentrations, and in sufficient concentrations can result in personal death or injury.

Hazardous Polymerization SECTION 5 Health Hazards Threshold Limit Value Routes of Entry

May Occur

Will Not Occur

Conditions to avoid

N/A

580 ppm is the TLV/TWA or WEEL. Note: the effects of exposure to NAF S III should disappear quickly after removal from exposure. Eye Contact : Liquid form of this material can produce chilling Skin Contact: Evaporation of liquid from the skin

sensations and discomfort.

can produce chilling sensations. Frostbite can occur

Inhalation:

Vapour is heavier that air and can cause suffocation by reducing oxygen available for breathing. Breathing very high concentrations of vapour can cause lightheadedness, giddiness, shortness of breath, and may lead to narcosis, cardiac irregularities, unconciousness or even death.

Ingestion:

Ingestion is not likely to occur since this material is a gas at room temperature.

Signs & Symptons Acute Overexposure Signs & Symptons Chronic Overexposure Medical Conditions Generally Aggravated by Exposure Chemical Listed as Carcinogen or Potential

Dizziness, impaired coordination, reduced mental activity, and cardiac effects an occur. Unconciousness or even death in high concentrationswith longer exposures. None know when occupational exposures are below the TLV.

Cardiac problems.

National Toxicology Program:

No

I.A.R.C Monographs:

No

OSHA:

No

SECTION 6 Emergency & First Aid Procedures Eye Contact Immediatly flush eyes with plenty of water for at least 20 minutes while holding lids open. If redness, itching or a burning sensation develops, get medical attention. Treat for frostbite if necessary. Skin Contact Wash the material off the skin with copious amounts of soap and water for at least 15 minutes. If redness, itching or a burning sensation develops, get medical attention. Treat for frostbite if necessary. Do not give adrenaline/ epinephrine. Inhalation Remove the victim to frresh air. If cough or other respiratory symptoms occur, consult medical personnel. If not breathing give artificial respiration, preferably mouth to mouth. If breathing is difficult, give oxygen. Consult medical personnel. Ingestion Ingestion is not likely to occur since this material is a gas at room temperature.

SECTION 7 Special Protection Information Respiratory Protection (Specify Type) Ventilation Not normally necessary if controls are adequate. For high concentrations exceeding 10% (NOAEL), or if exposure is prolonged, use positive pressure air supplied respirator. Local Exhaust: Recommended to control exposures. Protective Gloves Neoprene or Viton if working with liquid Mechanical (General): Eye Protection Recommended in low areas or indoors where vapours may collect. Chemical goggles recommended. Full faceshield in addition or if splashing of liquid form is possible. Other Protective Clothing or Equipment SECTION 8 Special Precautions & Spill/Leak Procedures Precautions to be Taken in Handling & Storage Other Precautions Steps to be Taken in Case Material is Released/Spilled Waste Disposal Methods Store as liquified compressed gas in AS2030 complying cylinders away from high temperatures. If cylinders are not connected to a system, they must have safety caps to protect against actuation of valva and erlease of agent. Note incompatibility information section 4. Evacuate area; ventilate to outside atmosphere. Cool or remove hot metal surfaces or sources of non-extinguished flames. Dispose of in compliance with local, state and federal regulations. Eye wash and safety showers are good safety practice in work areas when working with liquified product.

SECTION 9 Transport Information Australian Dangerous Goods Code Hazard Class or Division 2.2 Liquified Gas, N.O.S UN 3163 2RE SP109, SP274 3.8.2 DANGEROUS GOOD NON - HAZARDOUS SUBSTANCE

Hazardous Material Identification System Ratings Hazard Index Health 4 Severe, 3 Serious, 2 Moderate, 1 Slight, 0 Minimal hazard,

N/A Not applicable, 1

NDA No Data Available, Flammability 0

N/E None Established Reactivity 0