Vidyamandir Classes

VMC/Nitrogen Containing Organic Compounds 27 HWT-7/Chemistry

DATE : TIME : 25 Minutes MARKS : [ ___ /15] TEST CODE : NITRO [1]
START TIME : END TIME : TIME TAKEN: PARENTS SIGNATURE :
This test contains a total of 15 Objective Type Questions. Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct.
1. Toluene is nitrated and the resulting product is reduced with tin and hydrochloric acid. The product so obtained is diazotized and
then heated with cuprous bromide. The reaction mixture so formed contains.
(A) mixture of o-and p-bromotoluenes (B) mixture of o-and p-dibromobenzenes
(C) mixture of o-and p-bromoanilines (D) mixture of o-and m-bromotoluenes
2. The structure of the compound formed, when nitrobenzene is reduced by lityium aluminium hydride (LiAlH
4
) is :
(A) (B)
(C) (D)
3. Secondary nitroalkanes can be converted into ketones by using Y. Identify Y from the following.
(A) aqueous HCl (B) queous NaOH (C) KMnO
4
(D) CO
4. In the reaction
X is :
(A) SiC (B) (NH
4
)
2
S (C) KMnO
4
(D) Fe/HCl
5. Which of the following compounds is soluble in benzene but almost insoluble in water?
(A) C
2
H
5
OH (B) CH
3
CO
2
(C) CH
3
CHO (D) C
6
H
5
NO
2
6. The reagent that reacts with nitromethane to form methyl hydroxylamine is :
(A) Zn/HCl (B) Zn/NH
4
Cl (C) Zn/NaOH (D) Sn/HCl
7. Benzamide can be converted into benzonitrile with :
(A) H
3
O
+
(B)
2
OH / H O

(C) KCN (D) P

2
O
5
8. Ethyl isocyanide on hydrolysis in acidic medium generates
(A) ethylamine salt and methanoic acid (B) propanoic acid and ammonium salt
(C) ethanoic acid and ammonium salt (D) methylamine salt and ethanoic acid
9. In the reaction
2
2
HCl Boiling H O
3
SnCl
CH CN 2H X Y + , Then term Y is :
(A) acetone (B) ethanamine (C) acetaldehyde (D) dimethyl amine
Vidyamandir Classes
VMC/Nitrogen Containing Organic Compounds 28 HWT-7/Chemistry
10. An organic compound A having molecular formula C
2
H
3
N on reduction gave another compound B, upon treatment with nitrous
acid B gave ethyl alcohol. On warming with chloroform and alcoholic KOH, it formed an offensive smelling compound C.
The compound C is :
(A) CH
3
CH
2
NH
2
(B)
3 2
CH CH C
=
(C)
3
CH C N (D) CH
3
CH
2
OH
11. The major product of the following reaction is :
(A) (B)
(C) (D)
12. n-butylamine (I), diethylamine (II) and N, N-dimethylethlamine (III) have the same molar mass. The increasing order of their
boiling point is :
(A) III < II < I (B) I < II < III (C) II < III < I (D) II < I < III
13. Amongst the compounds given, the one that would form a brilliant coloured dye on treatment with NaNO
2
in dil. HCl followed by
addition to an alkaline solution of -naphthol is :
(A) (B) (C) (D)
14. Choose the incorrect statement.
(A) Primary amines show intermolecular hydrogen bonds
(B) Tert-butylamine is a primary amine
(C) Tertiary amines do not show intermolecular hydrogen bonds
(D) Amines have lower boiling points as compared to those of alcohols of comparable molecular mass
15.
4 3 2
aq. KOH KMnO / H NH Br
3 2
alkali
CH CH Br A B C D,
+
A A A
D is :
(A) CH
3
Br (B) (CH
3
)
3
N (C) CH
3
NH
2
(D) CHBr
3
Vidyamandir Classes
VMC/Nitrogen Containing Organic Compounds 29 HWT-7/Chemistry
DATE : TIME : 25 Minutes MARKS : [ ___ /15] TEST CODE : NITRO [2]
START TIME : END TIME : TIME TAKEN: PARENTS SIGNATURE :
This test contains a total of 15 Objective Type Questions. Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct.
1. Consider the following reaction,
6 5
Sn / HCl C H COCl
6 5 2
C H NO X Y HCl +
What is Y?
(A) Acetanilide (B) Benzanilide (C) Azobenzene (D) Hydrazobenzene
2. Why do 2 and 3

amines fail to undergo the carbylamine test?
(A) They combine with chloroform to give a stable compound
(B) They react with alcoholic KOH
(C) The nitrogen atom of the amine group does not have the required number of hydrogen atoms
(D) All the given reasons are correct
3.
2 3 3
HNO PCl NH
2 5 2
C H NH A B C .
Recognize the compound C from the following.
(A) propanenitrile (B) methylamine (C) ethylamine (D) acetamide
4. Given the following sequence of reactions,
2
NaCN OH Br / NaOH
3 2
Partial
hydrolysis
CH CH I A B C

The major product C is :
(A) CH
3
CH
2
NH
2
(B)
3 2
CH CH C NHBr
||
O

(C)
3 2 4
CH CH COONH (D)
3 2 2
CH CH C NBr
||
O

5. Which of the following is strongest base?

(A) C
6
H
5
NH
2
(B)
2 6 4 2
p NO C H NH (C)
2 6 4 2
m NO C H NH (D)
6 5 2 2
C H CH CH
6. Amino group is ortho/para-directing for aromatic electriphilic substitution. On nitration of aniline, a god amount of m-nitroanilin is
obtained. This is due to :
(A) in nitration mixture, ortho, para-activity of NH
2
group is completely lost
(B)
2 3
NH becomes NH
+
, which is m-directing
(C)
2 4
NH becomes NH SO
+
, which is m-directing
(D)
2 2
NH becomes NH NO
+
, which is m-directing
7. Comparing basic strength of NH
3
, CH
3
NH
2
and C
6
H
5
NH
2
it may be concluded that
(A) basic strength remains unaffected (B) basic strength of alkyl amines is loest
(C) basic strength of aryl amines is lowest (D) basic strength of NH
3
is highest
8. Choose the amide which on reduction with LiAlH
4
yields a secondary amine
(A) ethanamide (B) N-methylethanamide
(C) N, N-dimethylethanamide (D) Phenylmethanamide
9. From the following compounds which does not react with C
6
H
5
SO
2
Cl?
(A) C
2
H
5
NH
2
(B) CH
3
NH
2
(C) (CH
3
)
2
NH (D) (C
2
H
5
)
3
N
Vidyamandir Classes
VMC/Nitrogen Containing Organic Compounds 30 HWT-7/Chemistry
10. The correct order of increasing basic nature of the following bases is : :
(A) II < V < I < III < IV (B) V < II < I < III < IV
(C) II < V < I < IV < III (D) V < II < I < IV < III
11. C
5
H
13
N reacts with HNO
2
to give an optically active alcohol. The compound is :
(A) pentan-1-amine (B) pentan-2-amine (C) N, N-dimethylpropan-2-amine (D) N-methylbutan-2-amine
12. In the following reaction sequence predict the compound X and Y.
The compound X and Y are
(A) (B)
(C) (D)
13. Which one of the following is the strongest base in aqueous solution?
(A) Trimethylamine (B) Anilne (C) Dimethylamine (D) Methylamine
14. Decreasing order of basic nature in aqueous solutions :
(A) C
6
H
5
NH
2
> NH
3
>CH
3
NH
2
> (Ch
3
)
2
NH (B) NH
3
> C
6
H
5
NH
2
> CH
3
NH
2
> (CH
3
)
2
NH
(C) (CH
3
)
2
NH > CH
3
NH
2
> NH
3
> C
6
H
5
NH
2
(D) CH
3
NH
2
> (CH
3
)
2
NH > NH
3
> C
6
H
5
NH
2
15. Reaction of cyclohexanone with dimethylamine in the presence of catalytic amount of an acid forms a compound of water during
the reaction is continuously removed. The compound formed is generally known as :
(A) an amine (B) an imine (C) an enamine (D) a Schiffs base
Vidyamandir Classes
VMC/Nitrogen Containing Organic Compounds 31 HWT-7/Chemistry
DATE : TIME : 25 Minutes MARKS : [ ___ /15] TEST CODE : NITRO [3]
START TIME : END TIME : TIME TAKEN: PARENTS SIGNATURE :
This test contains a total of 15 Objective Type Questions. Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct.
1. The compound will react most radily with NaOH to form methanol is :
(A)
3 4
(CH ) N I
+
(B)
3 3
CH OCH (C)
3 3
(CH ) S I
+
(D)
3 3
(CH ) Cl
2. Which of the following is the strongest base?
(A) (B) (C) (D)
3. Isopropyl amine with excess of acetyl chloride will give :
(A)
3 2 3 2
(CH CO) N CH (CH ) (B)
3 2 3
(CH ) CH N COCH
|
H

(C)
3 2 3 2
(CH ) CHN(COCH ) (D)
3 2 2 3
CH CH CH N COCH
|
H

4.
3 2 3
CH NH CHCl KOH + + nitrogen containing compound + KCl
2
H O + . Nitrogen containing compound is :
(A)
3
CH C N (B)
3 3
CH NH CH (C)
3
CH N C
+
(D)
3
CH N C
+

5.
The alkene formed as a major product in the above elimination reaction is:
(A) (B)
2 2
CH CH = (C) (D)
6. Ethyl amine on acetylation gives :
(A) N-ethyl acetamide (B) Acetamide (C) Methyl acetamide (D) None of these
7. High basicity of
2
Me NH relative to
3
Me N is attributed to :
(A) Effect of solvent (B) Inductive effect of Me (C) Shape of
2
Me NH (D) Shape of
3
Me N
8. Which of the following compounds will form alcohol on treatment with
2
NaNO , HCl /
2
H O at 0 C ?
(A)
3 2 2
(CH ) CHNH (B)
6 5 2
C H NH
(C) (D)
9. Among the amines (A) C
6
H
5
NH
2
, (B) CH
3
NH
2
, (C) (CH
3
)
2
NH, (D) (CH
3
)
3
N, the order of basicity is :
(A) A < B < C < D < C (B) D < C < B < A (C) A > B > C > D (D) B < C < D < A
Vidyamandir Classes
VMC/Nitrogen Containing Organic Compounds 32 HWT-7/Chemistry
10. Aniline first reacts with acetyl chloride producing compound A. A reacts with nitric acid/sulphuric acid mixture and produces
compound B, which hydrolyses to compound C. What is the identity of C?
(A) Acetanilide (B) p-nitroacetanilide (C) p-nitroaniline (D) Aniline
11. Aniline on treatment with NaNO
2
in HCl at 0 C

followed by treatment with alkaline naphthol | gives :

(A) A violet solution (B) A red solution (C) A green solution (D) A blue precipitate
12. The basicity of compound I, II, III and IV , ) , )
3 2 3 3 6 5 2 2
2 3
I IV
II III
CH NH , CH NH, CH N, C H CH NH varies in the order.
(A) I > II > III > IV (B) II > I > III > IV (C) III > I > II > IV (D) IV > I > II > III
13. Which of the following compound does not undergo Schotten-Baumann reaction?
(A) Phenol (B) Primary amine (C) Secondary amine (D) Tertiary amine
14.
(A) (B)
(C) (D)
15. Aniline is not the major product in one of the following reactions. Identify that reaction.
(A)
2
ZnCl
6 5 3
300 C
C H OH NH +

(B)
Alcoholic KOH
6 5 2
C H NO Zn powder +
(C)
2
200 C
6 5 3
Cu
C H Cl NH high pressure +

(D)
2
Fe H O
6 5 2
HCl
C H NO 6(H)
+
+
Vidyamandir Classes
VMC/Nitrogen Containing Organic Compounds 33 HWT-7/Chemistry
DATE : TIME : 25 Minutes MARKS : [ ___ /15] TEST CODE : NITRO [4]
START TIME : END TIME : TIME TAKEN: PARENTS SIGNATURE :
This test contains a total of 15 Objective Type Questions. Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct.
1. What is Z in the following reaction?
(A) Benzoic acid (B) Cyanobenzoic acid (C) Benzamide (D) Aniline
2. Which one of the following is not the correct reaction of aryl diazonium salts?
(A)
6 5 2 2 2 6 5
C H N Cl Cu Cl C H Cl
+
+ (B)
Heat
6 5 2 4 6 5
C H N Cl HBF C H F
+
+
(C)
6 5 2 3 2 6 5 4
C H N Cl H PO C H PO
+
+ (D)
6 5 2 2 6 5 2
C H N Cl SnCl / HCl C H NHNH
+
+
3. Benzene diazonium chloride on reaction with phenol in weakly basic medium gives.
(A) diphenyl ether (B) p-hydroxy azobenzene
(C) chlorobenzene (D) benzene
4. Identify the product in the following sequence 3, 4, 5-tribromoaniline
3 2
(i) Diazotization
(ii) H PO
?
(A) 3, 4, 5-tribromobenzene (B) 1, 2, 3 3-tribromobenzene
(C) 2, 4, 6-tribromobenzene (D) 3, 4, 5-tribromonitrobenzene
5. Coupling of diazonium salts of following takes place in the order.
(A) IV < II < III < I (B) IV < III < II < I (C) II < IV < I < III (D) I < II < III < IV
*6. Which of the following compounds reacts slower than benzene in electrophilic substitution ?
(A) (B) (C) (D)
7. Aniline + excess of Br
2
H O
2
?
(A) Tribromo benzene (B) m-bromo aniline
(C) 3, 4, 5-tribromo aniline (D) 2, 4, 6-tribromo aniline
8. When aniline reacts oil of bitter almonds, condensation takes place and benzyl derivatives are formed. These are known as :
(Oil of bitter almonds : Benzaldehyde)
(A) Millons base (Hg
2
NOH.2H
2
O) (B) Schiffs reagent
(C) Benedict reagent (D) Schiffs base
Vidyamandir Classes
VMC/Nitrogen Containing Organic Compounds 34 HWT-7/Chemistry
9. Identify C in the following reaction :
(A) Benzamide (B) Benzoic acid (C) Chlorobenzene (D) Aniline
10.
The compound C is :
(A) (B) (C) (D)
11. Alkyl cyanides undergo Stephen reduction to produce :
(A) Aldehyde (B) Secondary amine (C) Primary amine (D) Amide
*12. Which one does not liberate NH
3
when undergoes hydrolysis ?
(A) Acetanilide (B) Acetonitrile (CH
3
CN)
(C) Acetamide (D) Phenyl isocyanide
13. The correct sequence of reactions to convert p-nitrophenol into quinol involves :
(A) reduction, diazotization and hydrolysis (B) hydrolysis, diazotization and reduction
(C) hydrolysis, reduction and diazotization (D) diazotization, reduction and hydrolysis
14. Aniline reacts with conc. HNO
3
is give :
(A) (B)
(C) (D)
15. In the following reaction, Aniline
Br NaNO Boiling
2 2
H O HCl (0 5 C) C H OH
2 2 5
X Y Z

. Z is :
(A) p-bromobenzene (B) o-bromobenzene
(C) 2, 4, 6-tribromophenol (D) 2, 4, 6-tribromobenzene