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Implemented Project in Morocco Calcinor S.A. / Lafarge-Calcinor Maroc S.A.S.
Editorial
Dear Readers and Friends Rising fuel costs and limited availability of good limestone sources are challenges being faced by the lime industry in the entire world. Hence we as Maerz focus on technologies for an economical lime production - be it energy saving by optimising the burning process or resource saving by making the utmost use of a limestone quarrys yield. Read more about this in a presentation Maerz recently gave to the mining industry in Peru - a country with very restricted access to high quality limestone. A round-up of new orders Maerz received, some reports on Maerzs ongoing turn-key projects as well as news on our recently commissioned kilns keeps you informed about what is going on in the lime-world. I wish you, your colleagues and your families a few relaxing days over Christmas and for the New Year loads of energy and success stories. Enjoy reading our Maerz News Stephan Lechner Managing Director
Lafarge-Calcinor Maroc s Tlad Loulad lime plant with (from the left) the petcoke dust silo, the 200 tpd rectangular Maerz kiln and the new Maerz Finelime Kiln .
As reported in the Maerz News in July 2011, Calcinor LCM S.A.S successfully commissioned a 200 tpd rectangular type Maerz PFR lime shaft kiln at their Tlad Loulad Plant. The kiln of the rectangular type produces 250 tpd of burnt lime per day, processing limestone with a grain size of 40 to 90 mm and using pulverised petcoke as fuel. In 2011 the customer placed another order with Maerz, this time for the supply of engineering, license, know -how, equipment and technical assistance for a kiln of the F2S type. This kiln is to produce 300 tons of quicklime per day processing limestone with a nominal grain size of 15 to 50 mm and also using pulverised petcoke as fuel. In September this year the contractual guarantee test run was carried out and the performance and quality parameters as shown in the adjacent table were achieved.
In this edition:
New Finelime Kiln in Morocco
Lafarge-Calcinor Maroc commissioned its new Finelime Kiln in Tlad Loulad 1
Based on the results of this test run and after completing the training of the customers operating and maintenance personnel, the FAC (Final Acceptance Certificate) was established and the contract plant has been accepted by LCM.
Kiln capacity (tons/day) Limestone size (mm) Heat consumption (kcal/kg) Residual CO2-content (%) > 300 20 - 50 810 2.5
Implemented Projects
Maerz kilns have recently been commissioned at: - Anhui Hwasu Corporation , China 8 - Xinjiang Zhongtai Chemical Co. Ltd., China 8 - PT Krakatau Steel (Persero) Tbk., Indonesia 10 - McDonalds Lime Limited, New Zealand 10 - ZPW Trzuskawica SA., Kujawy, Poland 11 - Kalkfabrik Netstal AG, Switzerland 12
What is Lime?
Burnt lime or "quicklime" is the dissociation product of Calcium Carbonate (limestone), which is produced by exposing the limestone to heat. This process is also known as "calcination". The CaO in burnt lime is available for chemical processes such as neutralisation of tailings or control of the pH value of a flotation liquid. The main properties of burnt lime are (a) residual CO2-content and (b) reactivity: The residual CO2-content describes the completeness of the calcination process, i.e. how much CaO is still bound by CO2 thereby not being available for other chemical processes. It is widely used in the industry as quality parameter as it is easy to measure in comparison to the determination of "available lime", which directly measures the free CaO in burnt lime. The reactivity describes the reaction speed of the CaO with other substances. It is mainly influenced by the specific surface of the burnt lime: the larger the specific surface, the higher the reactivity is. A large specific surface is maintained by exposing the limestone to just enough heat in order to complete the calcining process. If the burnt lime is heated up further, the CaO crystallites start fusing thereby reducing the specific surface and the burnt lime's reactivity. High reactive lime is therefore often referred to as "soft burnt lime".
Figure 1: Typical cost structure of a European lime plant
Lime kilns can only influence the above-mentioned properties - contrary to a cement kiln no other chemical reactions except for calcination take place. Hence the purity of the raw material fed to the lime kiln is decisive for the quality of the burnt lime. Burnt lime is widely used in industrial process such as in the iron & steel industry for sintering of ores, as reagent for slag formation in the melting shop or for desulphurisation of pig iron. Further uses are in the building industry for the production of aerated concrete and sand-lime bricks, various mortars and plasters as well as for soil stabilisation. In the mining industry burnt lime is mainly used for the neutralisation of tailings and for the control of the pHvalue of flotation liquids.
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Hence it is vital for an overall cost effectiveness to use a kiln technology with a lowest possible fuel consumption, and optimise the yield of the limestone quarry. Until recently, mostly rotary lime kilns were used for the typically large capacity lime plants in the mining industry, despite their significantly higher fuel consumption and lower quarry yield compared to modern shaft kiln technology. The heat input required for the calcination process is the same for all lime kilns. Their specific designs do however influence the extent of heat loss. The main source of heat loss is the excess energy (sensible heat) in a lime kiln's off gas: the temperature level required for calcination has to be so high, that the off-gasses contain more energy than needed for calcination. On the other hand, the ability of the limestone to pick up heat from the off-gases in the preheating zone of any lime kiln is too low to make use of all the energy still contained in the off gasses. Hence the off-gas temperature is comparatively high (up to 350 C in some kiln types) and the contained energy is wasted. A further significant source of heat loss is radiation through the kiln shell. The rotary kilns - even modern ones equipped with efficient preheaters have comparatively high heat losses through both of the above mentioned sources (Figure 2). In the early 1960ies a kiln principle was invented in Austria to overcome
the deficiencies of rotary kilns - the Maerz PFR Kiln - which is today the most widely used lime kiln in the industry.
Both shafts are charged alternately with limestone, and lime is discharged continuously at the bottom of each shaft. Fuel is supplied to only one of the two shafts, in the phase shown in Figure 3 to the left shaft. Fuel is introduced via evenly over the cross section of the shaft distributed burner lances at the bottom end of the preheating zone. Combustion air is introduced under pressure at the top end of the preheating zone above the stone charge (blue arrows) and the system is pressurised throughout. The combustion air is then preheated in the regenerator (preheating zone) before it mixes with the fuel. The combustion gases (orange and red arrows) pass through the burning zone from top to bottom (parallel flow heating). At the same time cooling air is introduced under pressure via the discharge tables of both shafts at the bottom (blue arrows pointing up). Cooling air and combustion gases mix and leave the "burning" shaft via the slope of material to enter the "off
Figure 4: Off gas heats up the stone (left) and combustion air cools it down again in the following cycle (right)
-gas" shaft, passing upwards in opposite direction to the charge. They calcine, even if to a small degree, the limestone in the off-gas shaft. The supply of fuel and combustion air is switched from one shaft to the other at approx. 12-15 minute intervals, to effectuate the regenerative pre-heating of combustion air: The hot gasses pass through the off-gas shaft's preheating zone and thereby heat up the limestone in the preheating zone (Figure 4 left side). They transfer their excess energy (sensible heat) to the limestone and thereby cool down. In the following cycle, this shaft becomes the "burning shaft" and cold combustion air passes through the now hot stone (Figure 4 right side). The combustion air picks up the stone's sensible heat and thereby heats up. The stone is cooled down and prepared for the next cycle - the perfect regenerator! Due to this sophisticated use of heat the thermal efficiency of a Maerz PFR Kiln is 85%!
The direct comparison of the PFR kiln's heat balance with a preheater rotary kiln impressively demonstrates the energy savings:
processing. Rotary kilns typically operate on stone sizes between 15 and 50 mm, whereas classic shaft kilns commonly use 50 - 120 mm limestone.
Quarry Yield
Another important factor for the economic viability of a lime plant is the optimal use of the limestone resources. Not only in densely populated areas is it extremely difficult to expand existing quarries or to develop new limestone deposits, but also in Figure 6: Comparison between quarry yields of a rotary kiln vs. a classic Maerz PFR Kiln certain areas of the world, such as Another constraint for the limestone the Andean region, where high qualisize is the ratio between the smallest ty limestone is scarce and precious. and the largest limestone grain, Rotary kilns and shaft kilns require a minimum limestone grain size for which is classically 1:3. The reason for this is to avoid overburning of small limestone pieces and a possible incomplete calcination of oversize limestone pieces, which would leave unburnt cores in the limestone. To avoid excess generation of fines during limestone crushing and to generally reduce crushing costs the maximum stone size should be as large as possible. Although smaller size limestone may be sold as gravel for various applications, the added value for a lime plant is maximised by producing quicklime.
Figure 7: Quarry yield with a combination of classic Maerz PFR Kiln and Maerz Finelime Kiln
Figure 9: The effect of the Maerz Sandwich Charging mode on the limestone quarry yield
tween a rotary kiln and a classic Maerz PFR Kiln. The comparison assumes a linear grain size distribution after crushing and therefore demonstrates the principle only. As seen below, the rotary kiln has a significant advantage over a classic Maerz PFR kiln as the quarry yield is approx. 70% versus the PFR kiln's quarry yield of just below 60%. However, Maerz developed a PFR kiln which allows calcining limestone down to a grain size of approx. 15 mm - the Maerz Finelime Kiln. A combination of a Maerz Finelime Kiln and a classic Maerz PFR Kiln results in a significantly better quarry yield than when just using a rotary kiln (Figure 7). With this combination the quarry yield is increased to nearly 90%! Classic Maerz PFR Kilns may however also process a certain quantity of smaller stone by charging separate layers of limestone sizes. This pro-
cess developed by Maerz is called Sandwich Mode (a principle of this charging mode is shown in Figure 8) and allows also smaller lime plants with single kilns to better use their quarries. The minimum stone size may not be as small as in a Figure 8: Principle of the Maerz Sandwich Charging mode Maerz Finelime Kiln, but still reThe Maerz PFR Kiln's fuel efficiensults in a significant gain in quarry cy as well as its flexibility to use yield as shown in Figure 9. various gaseous, liquid and pulverised solid fuels reduces overall production costs together with the CO2Summary footprint of the lime plant. Modern lime shaft kiln technology i.e. the Maerz PFR Lime Kiln - is the The wide range of limestone grain most economic and ecological kiln sizes the Maerz PFR Kiln may profor large capacity lime plants which cess optimises the use of precious are usually required to serve the minlimestone resources. ing industry.
A Maerz Finelime Kiln and a Maerz PFR Kiln in Cal Qumica Mexicanas Lime Plant in San Luis Potos, Mexico
CALCITs two identical 200 tpd Maerz PFR Kilns, now to be converted to petcoke dust firing.
technical support and erection work for the conversion of the existing Maerz PFR kiln from heavy fuel oil to natural gas firing. After successful implementation of the new natural gas firing system, the heavy fuel oil equipment will no longer be used, thus allowing the continued use of an important part of the existing equipment including the burner lances. Maerzs scope of material supply comprises the new gas firing system with the appending electric, measuring and control equipment. Maerz will also be responsible for the erection work of the new equipment including any adaptation work on the existing plant which may be required. All quality and performance parameters achieved during kiln operation with heavy fuel oil will also be reached with the new gas firing system.
KFN Netstal
KFN Kalkfabrik Netstal AG, domiciled in Netstal (Glarus), Switzerland and Maerz Ofenbau signed a contract for the supply of engineering, license, know-how and equipment as well as
Industria Dayis lime plant in Progreso de Obregn, Hidalgo, Mexico and the signing of the new contract by Mr Dagda and Mr Inglin from Maerz
for carbide gas as well as key components for the electrical, measuring and control system. Furthermore Maerz will delegate experienced personnel to supervise erection and commissioning of the kilns.
A battery of Maerz PFR Kilns in one of the plants of the Xinjiang Zhongtai Chemical group
In 2010 Huaibei Mining Xinsheng International Trading Co., Ltd., as the Buyer, and Maerz Ofenbau AG, as the Seller, signed a contract for
the installation of 3 x 600 tpd Maerz PFR Lime Kilns for Anhui Hwasu Corporation, domiciled in Chuzhou City, Anhui Province.
In the meantime all three kilns were erected and commissioned and have reached the industrial production stage where the contractual performance and quality parameters as per the adjacent table have been achieved. After completing the training of the operating and maintenance personnel, the kiln plant is now operating under the responsibility of the customer.
Ground Breaking Ceremony in Zambia: Handymans Paradises first Maerz Kiln installation has begun
The existence of local lime production is one of the prime indicators of a country's economic development. Whilst there is existing lime production in Zambia, large quantities of lime still have to be imported. Handyman's Paradise will set a milestone for production of high quality lime using the most energy efficient process, thus protecting the environment we all live in. With the rapid economic growth in Zambia and the region, there is no doubt that more beneficiation of local resources will occur. The production of lime from local limestone is only one example. Handyman's Paradise Limited in a joint venture with Astro Holdings Limited Group of Companies embarked on a journey to build a lime manufacturing plant in Ndola 's Masaiti district. The project will be developed in several stages and when all phases are complete it is expected to cost in excess of US$ 50 million. Being a greenfield project the entire infrastructure for this state -of-the-art lime plant has to be built from scratch - including the access road to the plant site. In November this year the ground breaking ceremony for the new lime plant took place. With a long list of highly honourable guests - including
Franz Sidler (Maerz) and Ralf Hesemann (Polysius) hand over a traditional Swiss cowbell as a symbol of good luck to the proprietors of the new plant Michael Pasquini and Sanmukh R. Patel
several Ministers and Chiefs this was a major event well received in national newspapers. The major part of the material and equipment for the lime plant will be imported from well known suppliers world-wide. The project not only
consists of the lime kiln, but also of all required equipment up - and downstream from the kiln such as crushers, conveyor belts, silos, coal dust mill, etc. The lime plant is scheduled to be ready for start-up mid 2015.
Ready to go ...
The guests of honour at the ground breaking ceremony and the proud owners of the new lime plant.
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Kiln capacity (tons/day) Heat consumption (kcal/kg) Residual CO2-content (%) CaO content in burnt lime (%)
The new Maerz PFR Kiln in Krakataus steel plant is installed to the left of an old smaller lime kiln
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Site Report: Mexicana de Cobres Second Maerz PFR Kiln well on Track
first shaft sections as well a the off-gas filter have been erected. The steel structure, which has been manufactured in Mexico by Polysius trusted workshops, is pre-assembled on site, close to the kiln. The smooth coordination between Maerz and Polysius ensures that the lime kiln will be ready for start -up mid-2014.
In Fall 2012 Mexicana de Cobre placed an order with Maerz for another Finelime Kiln to be erected adjacent to the first Maerz PFR Kiln in their Agua Prieta lime plant. As reported in our last Maerz news, the contract for the turn -key erection of this kiln was awarded to Maerzs sister company Polysius de Mexico, domiciled in Mexico City. In the meantime the civil works have been completed and the
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Maerzs scope of supply comprised all engineering services required as well as the materials and equipment including erection work for the new gas firing plant. In early September this year the contractual guarantee test runs were carried out during several days of continuous kiln operation. The adjacent table shows the quality and performance parameters which were achieved. The conversion of the kiln firing system from heavy fuel oil to natural gas has thus successfully been completed and the plant has been taken over by the customer.
Limestone size (mm) Heat consumption (kJ/kg) Residual CO2-content (%) Reactivity t60 of burnt lime (sec.)
Chongqing is the largest city in the world and this years host to the Chinese Lime Associations meeting from 27th to 28th November. Maerz was invited to give a presentation on its latest development and technology. China is one of the most thriving lime producing countries. Maerz has been active since the 1980-ies and has built more than 60 Maerz PFR Kilns.