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are obtained. Sample number 1 2 3 4 pH 1.655 1.607 1.601 1.625 Concentration of H+ 0.0221 0.0247 0.0251 0.0237
Use the Q test and Grubbs test to determine if any outlier should be thrown out. (show your work) 2Sample number 1 2 3 4 5 30.100 0.110 0.120 0.150 0.127 Calculate the purity (as % Na2CO3) of a 500 mg sample which required 18.25 mL of 0.1800 M Calculate the 95% and 99% confidence limits for the determination of lead in glazed ppm lead
pottery.
HCl solution for complete neutralization. First determine the reaction which is occurring in the analysis.
2)
3)
technician failed to dry the KHP completely. Did this error cause his reported concentration of hydrochloric acid to be too high, too low, or correct?
A) toohigh B) toolow C) correct D) Choosethisanswerifmoreinformationisneeded E) Choosethisansweronlyifnoneoftheaboveanswerswouldbecorrect. 4) A1.00Lsampleofwatercontains0.0036gofCl ions.Determinetheconcentrationof chlorideionsinppmifthedensityofthesolutionis1.00g/mL. A) 3.6ppm B) 5.4ppm C) 7.2ppm D) 2.8ppm E) 1.8ppm 5) Howcanyoureducetherangeofaconfidenceinterval? A) increasevariance B) increaseoutliers C) increasen D) decreasen E) Choosethisansweronlyifnoneoftheaboveanswersarecorrect. 6) Accordingtothefollowingreaction,whatvolumeof0.244MKClsolutionisrequiredtoreact exactlywith50.0mLof0.210MPb(NO 3)2solution? 2KCl(aq)+Pb(NO 3)2(aq)PbCl2(s)+2KNO3(aq) A) 86.1mL B) 97.4mL C) 43.0mL D) 58.1mL E) 116mL 7) E) 2 4)
5)
6)
7) Thefollowingnumberhashowmanysignificantfigures,20.020? A) 6 B) 3 C) 5 D) 4
B1
Form 2
8) Precisionisbestexemplifiedbythefollowingstatement(s): A) Themedianofthesetofmeasurements B) Theclosenessofthevaluestotheacceptedortruevalue C) Theclosenessofrepeatedvalues D) Alloftheabove E) Donotchoosethisanswer 9) Allanalyticalinstrumentshavesomelevelofvariabilitythatweassociatewiththe 8)
9)
followingstatements,except:
A) Determinateerror B) Bellshapecurve C) Gaussiandistribution D) Normaldistribution E) Choosethisansweronlyifnoneoftheabovearecorrect. 10) Whatistheintervalwherethepopulationaveragemaybefoundwitha95%confidence 10)
12) Givethenetionicequationforthereaction(ifany)thatoccurswhenaqueoussolutionsof Al(C2H3O2)3andLiNO3aremixed. A) Al3+(aq)+3NO3-(aq)Al(NO3)3(s) B) 3Li+(aq)+(C2H3O2)33-(aq)Li3(C2H3O2)3(s) C) Al3+(aq)+3NO 3-(aq)+Li+(aq)+C2H3O2-(aq)Al(NO3)3(aq)+LiC2H3O2(s) D) Li+(aq)+C 2H3O2-(aq)LiC2H3O2(s) E) Noreactionoccurs. 13) WhatprecipitateismostlikelyformedfromasolutioncontainingBa+2,Na+1,OH-1,and CO 3-2. A) NaOH B) Na2CO 3 C) BaCO3 D) Ba(OH)2
13)
B2
Form 2
14) Accuracyisbestexemplifiedbywhichofthefollowingstatments? A) Themedianofthesetofmeasurements B) Theclosenessofrepeatedvalues C) Theclosenessofthevaluestotheacceptedortruevalue D) Themodeofasetofmeasurements E) Alloftheabovearecorrect. 15) IdentifyHCl. A) strongelectrolyte,weakacid B) strongelectrolyte,strongacid C) weakelectrolyte,strongacid D) nonelectrolyte E) weakelectrolyte,weakacid 16) Asolutionispreparedbydissolving49.3gofKBrinenoughwatertoform473mLofsolution. Calculatethemass%ofKBrinthesolutionifthedensityis1.12g/mL. A) 11.7% B) 10.1% C) 9.31% D) 8.57% E) 10.4% 17) Amoonrockmustbesampled.Itiscomposedof3substanceswhicharedistributedinsucha waythatpocketsofsubstanceAareseentopredominaeontheoutsideoftherockwhile substancesBandCpredominateontheinsideoftherock.Thisrockwouldbeconsidered: A) segregatedheterogeneous B) randomheterogeneous C) homogeneous D) segregatedhomogeneous E) Choosethisansweronlyifnoneoftheaboveanswersarecorrect. 18) Calculatethepropagationoferrorinthefollowingcalculation: 14)
15)
16)
17)
18)
B3
Form 2
21) Whichofthefollowingareconsideredacceptableinanalyticalchemistry? A) determinateerror B) randomerror C) grosserror D) morethanoneoftheaboveisconsideredacceptable E) Itisnecesarytoremovealloftheaboveinordertocarryoutananalysisproperlay. 22) Identifytheweakestacid. A) HBr B) HI C) HF D) HCl E) notenoughinformationisavailable 23) Samplingisconsideredoneofthemostcriticalpartsofananalysisbecause: A) resultsareonlyasreliableasthelaboratorysample B) resultsobtainedfromacompromisedsamplemaybeerroneous C) thelaboratorysamplemustberepresentativeofthebulksample D) morethanoneoftheaboveiscorrect E) noneoftheabovearecorrect. 21)
22)
23)
B4
AnswerKey Testname:QUANTEXAM1
1) D 2) B 3) NoCorrectAnswerWasProvided. 4) A 5) C 6) A 7) A 8) C 9) A 10) NoCorrectAnswerWasProvided. 11) D 12) E 13) C 14) C 15) B 16) C 17) A 18) C 19) D 20) D 21) B 22) C 23) C
B5