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1. Ahypoeutectiodplaincarbonsteelwasslowcooledfrom900Cto723CT(whereT< 1C).Whatisthecarbonconcentration(inwt%)inthecarbonsteelifitcontains5.9wt% eutectoidferriteat723CT? (Hint:At723CT,thehypoeutectoidsteelcontains3phasesproeutectoidferrite, eutectoidferriteandcementite.) ironironcarbide phasediagram Drawtimetemperaturecoolingpathsfora1080steelonanisothermaltransformation diagramthatwillproducethefollowingmicrostructures.Startwiththesteelsinthe austeniticconditionattime=0oCand850C. (a) 100%martensite (b) 50%martensiteand50%coarsepearlite (c) 100%finepearlite (d) 50%martensiteand50%upperbainite (e) 100%upperbainite (f) 100%lowerbainite Whatisthemicrostructureproducedafteraustemperingaeutectoidplaincarbonsteel? Doesanaustemperedsteelneedtobetempered?Explain. Describethefourdecompositionstructuresthatcanbedevelopedwhenasupersaturated solidsolutionofanAl4%Cualloyisaged.
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Determinethemolefractionofpolyvinylchlorideandpolyvinylacetateinacopolymer havingamolecularweightof11,000g/molandadegreeofpolymerizationof150. Howmuchsulphurmustbeaddedto70gofbutadienerubbertocrosslink3.0%ofthe mers?(Assumeallsulphurisusedtocrosslinkthemersandthatonlyonesulphuratomis involvedineachcrosslinkingbond.) Howisitpossibleforapolymerchainsuchasapolyethyleneonetokeepgrowing spontaneouslyduringpolymerization? Howdoestheamountofcrystallinityinathermoplasticaffect (a)itsdensity,and (b)itstensilestrength? Explain. Howdoesthepresenceofamethylgrouponeveryothercarbonatomofthemainpolymer chainaffecttheglasstransitiontemperatureofthismaterialwhencomparedto polyethylene?