Mtg-Nov Issue-Physics For You-Iit Jee Paper

[1]
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MTG-NOV ISSUE-PHYSICS FOR YOU-IIT JEE PAPER
Answer key & Solutions
C H E M I S T R Y
P H Y S I C S
M AT H E M AT I C S
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
c c d c c c abd abc ac a b b a d c
16
a
21 22 23 24 25 26 27 28 29 30 31 32 33 34 35
b a b a a b bd bd d bc d a d a b
36
d
41 42 43 44 45 46 47 48 49 50 51 52 53 54 55
c c a c d a bd ad bc cd c d a c a
56
d
17. A
max
=
1
s
x
k
mg
= 3 18. N= 14 N
19. (A) p,s, (B) q,r, (C) p,s, (D) q,r 20. (A) p, (B) p , (C) p , (D) p,s
37.
155
38. 9.6 10
2
=10
39. (A) p, (B) r, (C) s, (D) q 40. (A) q,r ; (B) p,s ; (C) p, r ; (D) q,r
57.a + b = 23 58.f (1) = 3
59.(A) r, (B) s, (C) p,q,r,s , (D) p 60.(A) q, (B) s, (C) r , (D) p
[2]
A
C
B
P H Y S I C S
1.(c) Consider the motion of the rod as pure rotational motion about an axis passing through A and perpendicular
to the rod
Then by conservation of mechanical energy
2 2
1 1
( ) ( ) 2
2 2
B C B C
I I m g l m gl + = +
2
2 2 2
1 1
( ) 3
2 2 4
l
m l m mgl + =
2
5
24
8
l g =

24
5
g
l
=
Minimum horizontal speed to be imparted to (2 ) B l =
24
5
gl
=
.

(c) is correct.
2.(c) Since collision is elastic, kinetic energy is conserved.
Before collision rod has only translational kinetic energy after collision rod will have translational as well as
rotational kinetic energy.

1
H H <

(c) is also correct.
3.(d) (Pressure) force due to liquid acts normal to the surface everywhere producing no net torque about O.
(d)
4.(c)
2 2 2
2 I f a v =
, max .2
10
p
v
v a a f = = =

2
2 2
2
400
v
a f
=

(c)
5.(c)
PV nRT =
;
dV nR
dT P
=
n
P
is same in both cases. Therefore straight line B is both cases.
(c)
6.(c) The velocity of the particle will first increase then decrease. Thus total potential energy will first decrease and
then increase.
7.(a,b,d)Since only six different wavelengths are emitted, therefore highest excited state is
4 n =
, therefore (a) is
correct.
In the emitted radiations two wavelengths are shorter than
o
it means that initially atoms were in the
excited state therefore (b) is also correct.
Therefore (b) is also correct.
Transitions corresponding to
4 1, 3 1, 2 1 belong to Lyman series.
(d) is also correct.

[3]
pressure node
/ 8
mid pt.
15/32
8.(a,b,c)Capacitive resistance
1
159.2
2
C
X
fC
= =
Current in the capacitive branch
20
0.126
159.2
S
C
C
V
I A
X
= = =
(b) is correct.
Current in the resistive branch
20
0.2
100
S
R
V
I A
R
= = =

(a) is correct.
Total current
T R C
I I jI = +
| | 0.24
T
I A

(c) is also correct.
9.(a,c) DX =
D
yd
for central maxima DX = 0, hence y = 0. (Does not depend upon l)
B =
d
D
d
D m
d
D n
2 1

=
n 4500 = m 6000
3n = 4m.

n = 4, m = 3.
10.(a)
12420
0.62
20000
cutoff
A A = =
=62pm
11.(b) At the middle of the column (i.e. at C).
distance of C from the closest node N,
9.375
8
NC cm
= =
At C, pressure ampl.
0 0 0
2 1
sin sin ( )
8 2
P P kx P P

| |
= = =
|
\
12.(b) For II overtone
5 5 5 330 15
93.75
4 4 4 440 16
v
L m cm
v
= = = = =
13.(a) At closed end, Max pressure
0 0
P P = + . Minimum pressure
0 0
P P =
14.(d) The distance travelled by the atom between two consecutive collisions (2 1) 2 m m = =
Time interval between two consecutive collisions
2
rms
v
=
[4]
15.(c) Average kinetic energy
3
2
kT =
(for monoatomic gas)
23 21
3
1.38 10 / 160 3.31 10
2
J K J

= =
16.(a) Pressure of gas,
2
1
3
rms
m
P v
V
=
m= mass of gas,
V =
volume of box.

4
2 2
3 3 100 1
3 10
(1000)
rms
PV
m kg
v

= = =
17.[Ans. 3 ] Suppose origin is at the equilibrium position and the direction of increasing x is toward the right. If
the blocks are at the origin, the net force on them is zero. If the blocks are a small distance x to the right of
the origin, value of the net force on them is 4kx. Applying Newton's second law to the two-block system
gives
4kx = 2ma
Applying Newton's second law to the lower block gives
k(x
1
x) f = ma
where x
1
= initial stretch and f is the magnitude of the frictional force.
f = k(x
1
+ x)
The maximum val ue for x is the amplitude A and the maximum value f or f is
s
mg. Thus,
s
mg = k(x
1
+ A
max
). Solving for A
max
gives
A
max
=
1
s
x
k
mg
= 3
18:[Ans: 14]
B
r
is uniform
F
r
= I L
r
B
r
here L
r
=
OA = 0.25 i
+ j
B
r
= 4(cos60 i
+ sin60 j
)
F
r
= 12(0.25 i
+ j
) 4(cos60 i
+ sin60 j
) = 4.8
|
\
|
k
60 cos k
60 sin
4
1
= 4.8
k
2
1
8
3
|
|
\
|
= 4.8
k
8
4 3
|
|
\
|

= 6
( )k
4 3
= 13.8 N= 14 N
19. (A) p,s, (B) q,r, (C) p,s, (D) q,r
20. (A) p, (B) p , (C) p , (D) p,s
[5]
C H E M I S T R Y
21.(b) 50N = 30 x 0.2 = 6
25
3
50
6
N = =
50 ml HA + 20 ml NaOH HA + NaA
6 meq 4 meq 2 meq 4 meq
pH = pKa + log
2
4
5.8 = pKa + log 2
pKa = 5.8 - log 2
= 5.8 - 0.3 = 5.5 (b) ]
22.(a) A(s) + 2B (aq) 2C (s) + D (aq) K = 10
20
20
2 2
10
] B [
6
1
] B [
] D [
K = = =
[B] = 4 x 10
11
M (A) ]
23.(b)
e.g. of Anionotropy.

+
O H
3

3
NH

RMgX

CH
3
NH
2
+

+
O H
3
[6]
24.(a)
25.(a) NaNO
2
+

HCl converts NH
2
into OH ]
26.(b)
27.(bd)
more substituted carbon get H, D or T from BH
3
or BD
3
or
BT
3
.
Less substituted get, H, D or T from or ]
28.(bd)
29.(d) Acetal hydrolyse
(d)]
30.(bc)
31.(d) bottle 2 + bottle 3
colourless gas
carbon dioxide
sodium carbonate + acid

It suggests bottle 2 and 3 contain sodium carbonate and HCl.
Bottle
3 4 +
blue precipitate confirms the
2
Cu
+
in either of bottle considering available sulphate, chloride
nitrate and carbonate.
Precipitate must be carbonate.
Hence,
3
carbonte
sodium carbonate
4
2
Cu
+
2 HCl
(from above)
32.(a) As bottle
3
sodium carbonate
[7]
4
copper sulphate
2
hydrochloric acid
Hence, bottle
1
lead nitrate
Now,
3 2 4 3 2 4
white ppt. soluble
( ) ( ) Pb NO CuSO Cu NO PbSO + +
33.(d) Bottle
4 4
CuSO
2 2
3 3 4
( ) 4 ( ) ( ) ( )
distinctive blue colour
Cu aq NH aq Cu NH aq
+ +
+
34.(a)
3 2 2
2 6 2 3 3 HBrO HI HBr I H O + + +
3
HBrO gets reduced,
35.(b)
1 x
K
at a x
=
3
300
2.92 10 K

=
3
600
3.057 10 K

=
3
1200
2.99 10 K

=
Hence, order
2 n =
36.(d)
18
log 4 61.5 /
2.303 8.314 301 3.19
E
kJ mol
= =

37(155) A CrO
2
Cl
2
B H
2
CrO
4
CHCl
) C ( ) B (
4 2 2
) A (
2 2
HCl CrO H O H Cl CrO + +
) E ( ) D (
4 2
) A (
2 2
NaCl CrO Na NaOH Cl CrO + +
) yellow (
4 2
) D or B (
2
4
BaCrO BaCl CrO +

+ +
3
HNO . dil in le lub Inso
3
) E or C (
NO AgCl AgNO Cl
3
Molecular weight of A(CrO
2
Cl
2
) = 155 ]
38.

0.1 M AgNO
3
0.01 M AgNO
3
+
+ e ) NH ( Ag
M 1 . 0
2 3
Ag +
1 . 0
3
) NH ( 2
Ag +
2 . 0
3
) NH ( 2
+
+ e ) NH ( Ag
01 . 0
2 3
[8]
1 . 0
2 3
) NH ( Ag
+
+ Ag +
2 . 0
3
NH 2 Ag +
1 . 0
3
) NH ( 2 +
01 . 0
2 3
) NH ( Ag
+
E
cell
= 0.0
( )
( ) ( )
2
2
2 . 0 1 . 0
1 . 0 01 . 0
log
1
06 . 0
= 9.6 10
2
]
39. (A) p, (B) r, (C) s, (D) q
(A) CH
3
CH=CH
2
) P ( HBr
3 3
CH CH CH
|
Br

(Markownikoff addition)
(B) CH
3
CH=CH
2
) peroxide (
) R ( HBr

CH
3
CH
2
CH
2
Br (Peroxide effect)
(C) CH
3
CH-CH
2

on substituti Alkylic
) S ( NBS

2 2
CH CH CH
|
Br
=
(D) CH
3
CH=CH
2
) Q ( Br
2

2 3
CH CH CH
| |
Br Br

40. (A) q,r ; (B) p,s ; (C) p, r ; (D) q,r
Complex Oxidation state Type Magnetic property
4
6
[ ( ) ] Fe CN

+2
2 3
d sp inner orbital complex Diamagnetic
2
2 6
[ ( ) ] Fe H O
+
+2
3 2
sp d outer orbital complex Paramagnetic
2
3 4
[ ( ) ] Cu NH
+
+2
2
d sp inner orbital complex Paramagnetic
2
4
[ ( ) ] Ni CN
+
+2
2
d sp inner orbital complex Diamagnetic
[9]
M AT H E M AT I C S
41.(c) Z = i + 2i
2
+ 3i
3
+ + 2007i
2007
Use method of difference to get Z = 1004 1004i
\ Re(Z) + Im(Z) = 2008 ]
42.(c)
10
C
4
=
1 2 3 4
7 8 9 10
1 2 3 4
7 8 9 10
= 210]
43.(a) y =
2
x
2
tan 30=
2
t
t 2
3
1
=
t
2
t =
3 2
l(OP) =
3 4
Ans. ]
44.(c) f (0) = f (1) = 0 (obviously) ]
45.(d) Using LMVT in [2, 5]
4

7
) 2 ( f ) 5 ( f

3
28
f (5) f (2)
21 ]
46.(a) y = ln x

x = e
y
A =
b n
a n
dy x
l
l
=
b n
a n
y
dy e
l
l
= (e
ln b
) (e
ln a
) = b a Ans. ]
47.(bd) Let the roots are a d, a, a + d
\ a d + a + a + d = 6

a = 2
again the product of roots taken 2 at a time
a(a d) + a(a + d) + (a + d)(a d) = 24
a
2
ad + a
2
+ ad + a
2
d
2
= 24
3a
2
d
2
= 24
d
2
= 36

d = 6 or 6
Hence the AP's are
4, 2, 8, ............
or 8, 2, 4, .........
now S
n
=
2
n
[ 8 + (n 1) 6] = n[ 4 + 3(n 1)] = n(3n 7) Ans.
or S
n
=
2
n
[16 + (n 1)(6)] = n[8 3(n 1)] = n(11 3n) Ans. ]
48.(a,d) We must have ( )
2
2
2 10 16 4 2 4 x x + = + + .
49.(b,c) If PON = then as P is ( ) acos ,bsin ( ) NP cos tan a sin = = .
which is not true since
NP b sin = is given Choice (a) is false.
QON = then ON acos = ( ) OQ a = Q
and putting x a cos = in
2 2
2 2
1
x y
a b
+ =
We get y DN b sin = Choice (b) is correct.
Now normal at q will pass through origin since Q lies on circle
2 2 2
x y a + =
Q
P
N
O
[10]
50.(c) differentiating
) x ( g
0
dt ) t ( f = x
2
\ ( ) ) x ( g f g ' (x) = 2x ....(1)
since f and g inverse of each other hence ( ) ) x ( g f = x.
Hence (1) becomes x g'(x) = 2x or g'(x) = 2
integrating g (x) = 2x + C
but the initial condition shows C = 0
hence , g (x) = 2x
its inverse f (x) =
2
x
C, D ]
51.(c) Let the focus of parabola be ( )
1 1
x , y
SP = distance of P from directrix
Here P are (0,2) and (0,-2)
Equation of directrix si
3 xcos y sin + =
( ) ( )
2 2
2
1 1
2 2 3 x y sin + = .....(i)
and ( ) ( )
2 2
2
1
2 2 3 x y sin + + = + .....(ii)
Subtract, we get
1
8 24 y sin =
1
3
y
sin =
Adding, (i) and (ii),
( ) ( )
2 2 2
1 1
2 4 2 4 9 x y sin + + = +
2
2 2 1
1 1
4 4 9
9
y
x y + + = +
2 2 2
1 1 1
9 9 36 4 81 x y y + + = +
2 2
1 1
9 5 45 x y + =
Locus of focus is
2 2
1
5 9
x y
+ =
52.(d)
( ) ( ) ( )
2
2 2
0 0 2 x y + =
53.(a)
2
14 45 0 <
2
45
0
14
< <
54.(c)
55.(a)
56.(d)
( ) 0 2 ,
( ) 0 2 ,
[11]
57. Equation of the line is
=
+
=
2
5 z
3
2 y
1
2 x
....(1)
hence any point on the line (1) can be taken as
x = l + 2
y = (3l + 2)
z = (2l + 5)
for some l point lies on the plane
2x 3y + 4z = 163 ....(2)
2(l + 2) + 3(3l + 2) + 4(2l + 5) = 163
This gives 19l = 133 l = 7
Hence, P (9, 23, 19)
Also (1) intersect YZ plane i.e. x = 0 l + 2 = 0, hence l = 2
\ Q(0, 4, 1)
So, PQ =
2 2 2
18 27 9 + +
= 9
2 2
2 3 1 + +
=
14 9
\ a = 9 and b = 14
Hence, a + b = 23 ]
58. sin
18
= sin 10, sin 30=

2
1
also sin 30= 3 sin 10 4 sin
3
10
2
1
= 3 sin 10 4 sin
3
10
8 sin
3
10+ 0 sin
2
10 6 sin 10+ 1 = 0 ....(1)
f (sin 10) = 0
a sin
3
10+ b sin
2
10+ c sin 10+ d = 0 ....(2)
comparing (1) and (2)
a = 8, b = 0, c = 6, d = 1
hence f (1) = a + b + c + d
f (1) = 3 Ans. ]
59.(A) r , (B) s , (C) p,q,r,s (D) p
Soln.
(A) Put x = 1 and x = 5 and find f (1).
(B)
3
2 3
0
3
1 3
x
x sin x x k sinh x
lim
cos x x x
+
+
3 5 3 5
3
2 4
0
2 3
3
3 5 3 5
1 1 3
2 4
x
x x x x
x x .. x k x ..
lim
x x
..... x x
| | (
+ + + + +
| (
\

+ +
`
)

( )
3 5
2 4
0
3
1
4 1
2 6
3
3
2 4
x
k
k x x x ......
lim
x x
x ......
| |
+ + +
|
\
+
For limit to exist
4 0 4 k k = =
(C) For
1 n =
we have
( ) 0
x
f x , x
x
=
This is not differentiable at origin
For ( ) 0 n , f x x , = = not differentiable at origin . If n is a positive integer
[12]
1
0 0 0
0
1 0
n
h
h h n
h h
lim lim h .h limh h ,
h
= = > =
Then limit exists and so ( ) 0 f ' exists.
Hence ( ) f x is differentiable at
0 x =
.
Thus ( )
n
f x x x = is differentiable at the origin if n is any positive integer. .
(D)
( ) ( ) { }
0
1
x
f x sin t t dt =
( ) ( ) ( ) ( ) 1 0 1 0 f ' x sin x x f ' x sin x x = = =

( ) 1 0 2 x x , , =
Thus
2 2
0 x x n x x n = + =
1 1 4
2
n
x

=
For real roots to exist
1
1 4
4
n n
> <
Thus 0 n = or negative values.
( ) ( ) { } ( ) 1 1 2 f ' x cos x x . x =
( ) ( ) 0 1 0 1 0 f '' , f'' 1 = > = <
But ( ) f x is maximum at
1 x =
60.(A) q, (B) s, (C) r , (D) p
(A) Consider,
x sin
x 3 sin

x cos
x 3 cos
=
x cos x sin
x sin x 3 cos x cos x 3 sin
=
x cos x sin
x 2 sin
= 2
x 2 sin
x 2 sin
= 2
so
x sin
x 3 sin

3
1
= 2
or
x sin
x 3 sin
= 2 +
3
1
=
3
7
(C) [Hint:
! 2
! 3
! 2
! 3
1 = 9 1 = 8]
(D) Volume of the tetrahedron
0 0 0 1
1 1 1 1 1 0
1 1 1 1 1 1 1
2 1 1 0 1 1
2 1 1 1 6 6 6
1 2 1 0 1 0
1 2 1 1
= = =
( ) { }
1 1
0 1
6 6
= =
(D) If quadratic equation
2 2
3 4 0 x kx k + =
(s) [ ) 0, 3
has roots of opposite sign then | | k belongs to
( ) f x x =

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[1]

(d) is also correct.

sodium carbonate + acid

= sin 10, sin 30=

( ) ( ) ( ) ( ) 1 0 1 0 f ' x sin x x f ' x sin x x = = =

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