Test Series

IIT-JEE 2010


R a n j e e t S h a h i C h e m i s t r y C l a s s e s
S CO 4 8 , I I
n d
Fl o o r , S e c t o r 2 0 C, CHANDI GARH Ph : 2 7 2 5 7 4 8 , 3 0 4 0 6 6 0
S C F 7 2 , S e c t o r 1 0 , P a n c h k u l a , P h : 3 9 1 4 8 4 4 T e s t - 1 0

1
Written and composed by Ranjeet Shahi

M.Tech, Ph.D IIT-DELHI

PRACTICE TEST CHEMISTRY
f ff for IIT-JEE 2010
Instruction
1. This question paper contain 31 questions in six sections.
2. Section A has 8 multiple choice questions with single correct answer. Each questions of this
section carries 3 marks and minus one(-1) for every wrong answer.
3. Section B has four multiple choice questions with multiple correct answers. Each questions of
this section carries 4 marks and minus one(-1) for every wrong answer.
4. Section C has four Assertion/Reason type questions. Each questions of this section carries 4
marks and minus one(-1) for every wrong answer.
5. Section D has multiple choice questions based on passages. Each questions of this section
carries 4 marks and minus one(-1) for every wrong answer.
6. Section E two matrix matching type questions, each carrying 8 marks. There is partial marking
in this section and no negative marking.
7. Section F has four single integer answer type questions, each carrying 6 marks. There is no
negative marking for this section.

SectionA

1. A concentration cell is constructed with copper
electrodes and Cu
2+
in each compartment. In
one compartment, the [Cu
2+
] = 1.0 x 10
-3
M
and in the other compartment, [Cu
2+
] = 2.0 M.
Calculate the potential for this cell at 25
o
C.
(a) 0.098 V (b) 0.195 V
(c) 0.32 V (d) 0.68 V

A
2. What is the highest pH at which 0.050 M Mn
2+

remains entirely in a solution that is saturated
with H
2
S, at a concentration of, [H
2
S] = 0.10 M .
Given: For the reaction,
MnS(s) Mn
2+
+ S
2-
, K
sp
= 3.6x10
-15
.
For H
2
S: K
a1
= 9.2x10
-8
and K
a2
= 1.2x10
-15

(a) 2.9 (b) 3.9
(c) 4.4 (d) 4.9

D
3. Fact:
19
O is unstable and radioactive. In that
case, which process could lead to stability, and
what nuclide would be produced?
(a) Its n/p ratio is too low , it should undergo
alpha emission to produce
23
Ne
(b) Its n/p ratio is too low, it should undergo
either electron capture or positron emission to
produce
19
F.
(c) Its n/p ratio is too high, it should undergo
beta emission to produce
19
F.
(d) Its n/p ratio is too high, it should undergo
positron emission to produce
19
F.

C
4. Consider the following radial distribution
function diagrams.

Which of the following has the correct matching
of Curve and orbital?
(a) I(3s), II(3p), III(3d)
(b) I(3d), II(3p), III(3s)
(c) I(3p), II(3d), III(3s)
(d) I(3s), II(3d), III(3p)


5. At what temperature will a reaction become
spontaneous if H for the reaction is 75 kJ
and S is +10.5 J/K ?
(a) 7100 K
(b) 7100 C
(c) 0.710 K
(d) The reaction is spontaneous at all
temperatures.

C

Duration: 1.0 hr 30 min
MM: 132
Test Series
IIT-JEE 2010


R a n j e e t S h a h i C h e m i s t r y C l a s s e s
S CO 4 8 , I I
n d
Fl o o r , S e c t o r 2 0 C, CHANDI GARH Ph : 2 7 2 5 7 4 8 , 3 0 4 0 6 6 0
S C F 7 2 , S e c t o r 1 0 , P a n c h k u l a , P h : 3 9 1 4 8 4 4 T e s t - 1 0

2
Written and composed by Ranjeet Shahi

M.Tech, Ph.D IIT-DELHI

6. Consider the chemical reaction,
N
2
(g) + 3H
2
(g) 2NH
3
(g)
The rate of this reaction can be expressed in
terms of time derivatives of concentration of
N
2
(g), H
2
(g) or NH
3
(g). Identify the correct
relationship amongst the rate expressions:

(A) Rate =
2 2 3
[N ] 1 [H ] 1 [NH ]
3 2
d d d
dt dt dt
= =
(B) Rate =
2 2 3
[N ] [H ] [NH ]
3 2
d d d
dt dt dt
= =
(C) Rate =
2 2 3
[N ] 1 [H ] 1 [NH ]
3 2
d d
dt dt dt
= =
(D) Rate =
2 2 3
[N ] [H ] [NH ] d d d
dt dt dt
= =

C
7. When mercuric iodide is added to the aqueous
solution of potassium iodide:
(A) freezing point is raised
(B) freezing point is lowered
(C) freezing point does not change
(D) boiling point does not change

B
8. According to the molecular orbital model, the
highest occupied molecular orbital of O
2
is
(a)
2s
(b)
2p

(c) *
2p
(d) *
2p


C
SectionB

9. Which of the following sets of quantum numbers
can be assigned to an electron in a 4d orbital?
(a) {4,3,2, +1/2} (b) {4,2,1,0}
(c) 4,2,-2, +1/2} (d) {4,2,1,-1/2}

C
D
10. Which of the following pairs do not show inert
pair effect?
(a) Cu and Al (b) Si and Ge
(c) Tl and Pb (d) Bi and Sn

A
B
11. The given is arrangement of
atoms in a crystallographic
plane: Which plane correctly
represents the above drown
structure?



(a) Face plane in FCC
(b) Body diagonal plane in FCC
(c) Face plane in BCC
(d) Body diagonal plane in BCC
A
D
12. Which of the following statements regarding
compression factor is/are correct?
(a) Z for an ideal gas is independent of
temperature and pressure.
(b) Z for an ideal gas is greater than one.
(c) Z for a non-ideal gas can be greater than or
less than unity depending on temperature and
pressure.
(d) When Z < 1, intermolecular attraction
dominates over intermolecular repulsion.

A
C
D
SectionC
Following Four questions consist of a assertion
followed by the reason:
In each question, choose the correct description and
reason from the list below:
(a) The statement and reason are both factually true,
and reason is the correct explanation of statement.
(b) The statement and reason are both factually true,
but the reason is not correct explanation of
statement.
(c) The statement is true but the reason is false.
(d) The statement is false but reason is true.


13. Assertion: Ammonia has higher critical
temperature than water.
Reason: There is stronger intermolecular force
of attraction between the molecules of water
than between ammonia molecules.

D
14. Assertion: CH
3
(CH
2
)
16
COONa has smaller
critical micelle concentration than the same of
CH
3
(CH
2
)
10
COONa.
Reason: When dissolved in water, larger alkyl
chain of the salt has greater tendency to
associate than the smaller alkyl chain.

A
15. Assertion: Between the same initial and final
volume, less work is required to be done in
reversible isothermal compression of an ideal
gas as compared to the irreversible isothermal
compression.
Reason: Reversible processes have greater
efficiency than the any other thermodynamic
processes.

A
16. Assertion: Chemisorption of gas on solid
surface is usually mono-molecular layer in
nature.
Reason: Chemisorption has greater activation
energy than physical adsorption.

B
Test Series
IIT-JEE 2010


R a n j e e t S h a h i C h e m i s t r y C l a s s e s
S CO 4 8 , I I
n d
Fl o o r , S e c t o r 2 0 C, CHANDI GARH Ph : 2 7 2 5 7 4 8 , 3 0 4 0 6 6 0
S C F 7 2 , S e c t o r 1 0 , P a n c h k u l a , P h : 3 9 1 4 8 4 4 T e s t - 1 0

3
Written and composed by Ranjeet Shahi

M.Tech, Ph.D IIT-DELHI

SectionD
Following questions are based on passages. Read
the passage carefully and answer the questions
that follow.


Passage-1
Figure 1 shows a graph of the logarithm of the
relative abundance of the elements in the
universe as a function of mass number A. The
dominant process for the synthesis of elements
heavier than iron (Fe) is neutron capture. In
neutron capture, energetic neutrons bombard a
target nucleus which absorbs one or more of
them to form an unstable isotope. The unstable
nucleus then undergoes beta decay until it
becomes stable. A nucleus produced by one or
more beta decays is called a beta decay
daughter.
There are two situations in which
neutron capture occurs. The first case is called
the s-process and results when the neutron
density of the environment is moderate. The
capture process is slow, and the time that it
takes the target nucleus to absorb a neutron is
large compared to the time that it takes for the
resulting unstable nucleus to beta decay.
Certain nuclei with a magic number of
neutrons have a small probability for capture.
Therefore, beta decay daughters with magic
neutron numbers N = 50, 82, and 126 account
for the abundance peaks in Figure 1 at A = 90,
138, and 208.
The second situation in which neutron
capture occurs is called the r-process and
results when the neutron density of the
environment is very high. In this case the rate
of capture is very rapid compared to the beta
decay rate of the resulting unstable nucleus.
Therefore, a nucleus captures many neutrons
before undergoing beta decay. Since an
unstable nucleus with a magic number of
neutrons has a low probability of absorbing
more neutrons, its beta decay daughter will
have a relatively high abundance. This
accounts for the second set of peaks in Figure
1 at A = 80, 130, and 194.


L
o
g
a
r
i
t
h
m

o
f

r
e
l
a
t
i
v
e

A
b
u
n
d
a
n
c
e

Mass number
50 100 150 200
2
0
2
4
6
8
10
H
He
Fe
N=50
N=82
N=126
Li-Be-B
D
Figure-1

17. Which of the following nuclear reactions will
maximize the production of heavy elements by
neutron capture?
(A)
13 4 16
6 2 8
C He O n + +
(B)
1 2 3
1 1 2
H H He +
(C)
8 8
5 4
B Be e
+
+
(D) n p + e

A
18.
A
111
48
Cd atom is exposed to a high density of
neutrons and absorbs 7 of them before it beta
decays. After the neutron flux discontinues,
what is the final stable isotope produced?
(A)
118
48
Cd (B)
122
50
Sn
(C)
118
50
Sn (D)
119
49
In

C
19. What is the ratio of the abundance of hydrogen
in the universe to that of iron?
(A) 1:10
4
(B) 1:10
3
(C) 10
5
:1 (D) 10
6
:1

C
Passage-2
At 25
o
C, K
sp
of Ag
3
PO
4
is 2.7 x 10
19
M
4
. Answer
the next three questions.


20. What will be the molar concentration of Ag
+
ion
is a saturated solution of Ag
3
PO
4
at 25
o
C?
(A) 10
5
M (B) 3 x 10
4
M
(C) 10
6
M (D) 3 x 10
5
M

D
Test Series
IIT-JEE 2010


R a n j e e t S h a h i C h e m i s t r y C l a s s e s
S CO 4 8 , I I
n d
Fl o o r , S e c t o r 2 0 C, CHANDI GARH Ph : 2 7 2 5 7 4 8 , 3 0 4 0 6 6 0
S C F 7 2 , S e c t o r 1 0 , P a n c h k u l a , P h : 3 9 1 4 8 4 4 T e s t - 1 0

4
Written and composed by Ranjeet Shahi

M.Tech, Ph.D IIT-DELHI

21. If 10 ml of a saturated solution of Ag
3
PO
4
is
mixed with 10 ml 0.10 M Na
3
PO
4
solution,
concentration of [Ag
+
] in the resulting solution
would be?
(A) 5.4 x 10
18
M (B) 2.3 x 10
9
M
(C) 1.7 x 10
6
M (D) 3.4 x 10
7
M

C
22. If, in a separate experiment, to 10-ml of a
saturated solution of Ag
3
PO
4
, 10 ml of 0.10 M
AgNO
3
solution is added, concentration of
PO
4
3
ion in the resulting solution would be?
(A) 5.4 x 10
18
M (B) 2.3 x 10
9
M
(C) 2.16 x 10
12
M (D) 2.16 x 10
15
M

D
Passage-3
For a first order reaction, the following relationship
between rate constant and temperature exist:
1
12340
log (min ) 5.7 k
T

=


23. The minimum value of half life possible for this
reaction is:
(A) 5 x 10
5
min (B) 1.4 x 10
6
min
(C) 2 x 10
6
min (D) 1.4 x 10
6
min

B
24. The value of activation energy in kJ unit is:
(A) 103 (B) 206
(C) 236 (D) 309

C
25. The half of reaction will be 6.93 min when the
reaction temperature will be closest to:
(A) 2460 K (B) 1842 K
(C) 1234 K (D) 617 K

B
SectionE
Matrix Matching Type Questions


26. Match the followings
Column-I Column-II
(A) PCl
5
(P) sp
3

(B) ClO
4

(Q) Tetrahedral
(C) XeF
2
(R) Trigonal bipyramidal
(D) SO
4
2
(S) sp
3
d
Ans: (A:RS, BPQ), (C:S, D:PQ)

27. Match the followings
Column-I Column-II
(A) For an isothermal,
reversible process
(P) H = 0, E = 0
S = 0
(B) For a reversible,
cyclic process
(Q) dq = 0
(C) For an adiabatic
process
(R) dv = 0
(D) For an isochoric
process
(S) E = 0
Ans: (A: S), (B:PRS), (C:Q), (D:R)

SectionF
Single Integer Answer Type Questions


28. Following is the plot of logT vs logV for an ideal
gas.
l
o
g

T

1
2
3
4
5
6
2 4 6 8 10
log V

The atomicity of the gas is..?

2
29. XCl
4
is a neutral, but non-planar molecule with
one of the ClXCl bond angle close to 120
o
.
How many atomic orbitals X are involved in
hybridization?

5
30. 19 g of a salt MCl
x
(At. Wt of M = 48) is
dissolved in 500 g of water. The resulting
solution freezes at
1.86
o
C. If K
f
of water is 1.86 KKg/mol, what is
x?
Assume 100% ionization of MCl
x
.

4
31. A 500 ml CuSO
4
(aq) solution is electrolyzed
using a current of 4mA for 20 minute. What will
be the pH of solution at the end of electrolysis?
Faradays constant is 96500C.
4





Test Series
IIT-JEE 2010


R a n j e e t S h a h i C h e m i s t r y C l a s s e s
S CO 4 8 , I I
n d
Fl o o r , S e c t o r 2 0 C, CHANDI GARH Ph : 2 7 2 5 7 4 8 , 3 0 4 0 6 6 0
S C F 7 2 , S e c t o r 1 0 , P a n c h k u l a , P h : 3 9 1 4 8 4 4 T e s t - 1 0

5
Written and composed by Ranjeet Shahi

M.Tech, Ph.D IIT-DELHI

Answer
1.
A
11.
A D
21.
C
2.
D
12.
ACD
22.
D
3.
C
13.
D
23.
B
4.
C
14.
A
24.
C
5.
C
15.
A
25.
B
6.
C
16.
B
26.
(A:RS, BPQ),
(C:S, D:PQ)
7.
B
17.
A
27.
(A: S), (B:PRS),
(C:Q), (D:R)
8.
C
18.
C
28.
2
9.
C D
19.
C
29.
5
10.
A B
20.
D
30.
4




31.
4