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SEKTOR SEKOLAH BERASRAMA PENUH KEMENTERIAN PELAJARAN MALAYSIA _______________________________________________ PEPERIKSAAN PERTENGAHAN TAHUN

2008 KIMIA
KERTAS Sa!u "a# Ti$a Puluh Mini! JANGAN BUKA KERTAS SOALAN INI SEHINGGA DIBERITAHU 1. Tuliskan nama dan tingkatan pada ruang yang disediakan. 2. Calon dikehendaki membaca maklumat halaman 2. Untuk Kegunaan Pemeriksa Soalan Markah Penuh 18 15 17 50 Markah Diperoleh di

1 2 3 JUMLAH

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Kertas soalan ini mengandungi 9 halaman berceta

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SULIT IN.ORMATION .OR /ANDIDATES 1. This question paper consists of !hree questions. Answer all questions. 2. rite your answers for 0ue)!ion ' and 0ue)!ion * in the spaces pro!ided in the question paper.. ". #how your working. $t may help you to get marks. %. $f you wish to cancel any answer& neatly cross out the answer. '. The diagrams in the questions are not drawn to scale unless stated. (. )arks allocated for each question or part question are shown in brackets. 7. The time suggested to answer 0ue)!ion ' and 0ue)!ion * is %& #inu!e) and 0ue)!ion %& #inu!e). *. +ou may use a non,programmable scientific calculator. -. .and in this question paper at the end of the e/amination. is

)arks awarded0 Mark 3 2 1 0

De)1rip!ion !"cellent : #he best res$onse

%atis&actor' : (n a)erage res$onse *ea : (n inaccurate res$onse

No res$onse or +rong res$onse

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SULIT '2 (n e"$eriment +as conducted to &ind out the e&&ect o& tem$erature on the rate o& reaction. 50 cm3 o& sodium thiosul$hate solution 0.2 mol dm ,3 at 30 o- +as $ut into a 150 cm 3 conical &las . #hen the conical &las +as $laced on an ./0 sign on a $iece o& +hite $a$er. 5 cm3 o& sul$huric acid 1.0 mol dm,3 +as added to the sodium thiosul$hate solution and sha en. (t the same time1 the sto$ +atch +as started. #he sto$ +atch +as sto$$ed as soon as the ./0 sign +as no longer )isible. #he same ste$s o& the e"$eriment +ere re$eated &or sodium thiosul$hate solution +hich +as heated to 35 o-1 20o-1 25o- and 50o-. 3iagram 1 sho+s the reading o& the sto$ +atch &or each o& the reaction at di&&erent tem$eratures.

#ime 1t1 at 30 o -

#ime 1t2 at 35 o -

#ime 1t" at 20 o -

#ime 1t% at 25 o Dia$ra# ' 4a5

#ime 1t' at 50 o -

6ecord the time &or each reaction in the s$aces $ro)ided in 3iagram 1. 73 mar s8

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SULIT 4b5 %tate one obser)ation in this e"$eriment. 73 mar s8

4c5

-onstruct a table and record tem$erature1 time1 and 19 time &or this e"$eriment.

73 mar s8

4d5 4i5

:lot a gra$h o& tem$erature o& sodium thiosul$hate solutions against 19 time. 73 mar s8

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;ra$h o& tem$erature against 19 time

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4ii5

=ased on the gra$h in 4d5 4i51 state the relationshi$ bet+een the rate o& reaction and tem$erature. . 73 mar s8

4e5

-om$lete the #able 1.1 based on the abo)e e"$eriment. #'$e o& )ariable (ction that needs to be ta en #he +a' to mani$ulate the )ariable: ... ... ... *hat to obser)e in the res$onding )ariable: ... ... ... #he +a' to maintain the &i"ed )ariable: ... ... ...

4i5 >ani$ulated )ariable: . . . 4ii5 6es$onding )ariable: . . . 4iii5 ?i"ed )ariable: . . .

#able 1.1

73 mar s8

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SULIT *2 #he $u$il carried out an e"$eriment to construct the electrochemical series o& metals using 0.5 mol dm,3 co$$er4@@5 sul$hate solution as the electrol'te. #he set u$ o& a$$aratus o& this e"$eriment is sho+n in 3iagram 2. 3

/u

Y -o$$er4@@5 sul$hate solution

3iagram 2 #able 2 sho+s the )oltmeter readings o& each cell that obtained &rom the $airs o& metals. !"$eriment @ @@ @@@ @A :air o& metals B electrode :ositi)e electrode >agnesium @ron Cinc Dead -o$$er -o$$er -o$$er -o$$er #able 2 4a5 =ased on e"$eriment @1 4i5 *rite the o)erall ionic eEuation. 7 3 mar s 8 6eading o& )oltmeter 4A5 2.70 0.78 1.10 0.25

4ii5

=ased on the change in siFe that 'ou obser)ed at the magnesium electrode a&ter 30 minutes1 state the in&erence.

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7 3 mar s 8 4b5 :redict the )oltmeter readings o& the cell +hen Finc and lead metals are used. 7 3 mar s 8 4c5 =ased on #able 21 arrange the metals Finc1 iron1 magnesium1 lead and co$$er in an ascending order based o& their tendenc' to release electron. 7 3 mar s 8 4d5 ;i)e the o$erational de&inition o& the abo)e reaction. 7 3 mar s 8

3iagram 3 sho+s t+o bea ers containing colourless solution labelled ( and =.

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=ea er ( 3iagram 3

=ea er =

Bou are told that the t+o colourless solutions are calcium nitrate and magnesium nitrate. Bou are reEuired to label correctl' the name o& each solution in the containers. 3esign an e"$eriment to identi&' +hich is calcium nitrate and +hich is magnesium nitrate solution b' using aEueous o& ammonia solution as a reagent. Bour ans+er should include the &ollo+ing: 4a5 :roblem statement 4b5 G'$othesis 4c5 (ll )ariables 4d5 Dist o& materials and a$$aratus 4e5 :rocedure 4&5 #abulation o& data 717 mar s8

END O. 0UESTION PAPER

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