Safety Data Sheet according GB/T 16483-2008

Granofin PL liq
Substance key: SXR060526 Version : 1 - 2 / CHI 1) Chemical Product and Enterprise Logo Trade name Granofin PL liq Material number: 104824 Intended use of the product Industry sector: Type of use: Leather processing industry Leather tanning and retanning Page 1(9) Revision Date: 28.05.2013 Date of printing : 06.08.2013

Identification of the company Clariant Produkte (Deutschland) GmbH Benzstrasse 11 70771 Leinfelden-Echterdingen Telephone no. : +49 711 90320 Information about the substance/preparation Corp Product Stewardship BU Leather Services E-mail: PSBULS.DE@Clariant.com Emergency telephone number: +86 532-83889090 2) Hazard Summary Main physical and chemical hazard information GHS hazard class(es) The product is classified and labelled in accordance with GHS regulation and the relevant national laws. Flammable liquids Category 3 Eye irritation Category 2A Skin sensitization Category 1 Carcinogenicity Category 2 Chronic aquatic toxicity Category 3 GHS labeling UN The product is classified and labelled in accordance with GHS regulation and the relevant national laws. Symbols

Flame, Health Hazard, Exclamation mark Signal word Warning Hazard statements Flammable liquid and vapour. Causes eye irritation.

Safety Data Sheet according GB/T 16483-2008

Granofin PL liq
Substance key: SXR060526 Version : 1 - 2 / CHI May cause an allergic skin reaction. Suspected of causing cancer. Harmful to aquatic life with long lasting effects. Precautionary statements Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. Use explosion-proof electrical/ventilating/lighting/.../ equipment. Take precautionary measures against static discharge. In case of fire: Use water spray for extinction. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF ON SKIN: Wash with plenty of soap and water. IF exposed or concerned: Get medical advice/ attention. Store locked up. Store in a well-ventilated place. Keep cool. Dispose of contents/container to an approved incineration plant. Additional information No additional hazards are known except those derived from the labelling. Page 2(9) Revision Date: 28.05.2013 Date of printing : 06.08.2013

3) Ingredient/Composition information Product type: Mixture Chemical characterization aliphatic polyaldehyde, ca 50 % solution in water Hazardous ingredients China: Chemical name or generic name Formaldehyde Acetaldehyde Hazardous ingredients GHS: Chemical name or generic name Formaldehyde Acetaldehyde CAS-number 50-00-0 75-07-0 Concentration or concentration scope 4% 3% CAS-number 50-00-0 75-07-0 Concentration or concentration scope 4% 3%

4) First-aid Measures General information Remove soiled or soaked clothing immediately After inhalation Remove the casualty into fresh air and keep him calm. After contact with skin In case of contact with skin wash off immediately with soap and water

Safety Data Sheet according GB/T 16483-2008

Granofin PL liq
Substance key: SXR060526 Version : 1 - 2 / CHI Page 3(9) Revision Date: 28.05.2013 Date of printing : 06.08.2013

After contact with eyes In case of contact with eyes rinse thoroughly with plenty of water and seek medical advice After ingestion Rinse mouth thoroughly with water. When swallowed seek medical aid immediately and show the physician the packaging or the label of the packaging. Advice to doctor Symptoms No information available Hazards No additional risks are known. Treatment Treat symptomatically.

5) Fire Safety Measures Suitable extinguishing media water spray jet foam carbon dioxide dry powder Special hazards from the substance itself, its combustion products or from its vapours In case of fires, hazardous combustion gases are formed: Carbon monoxide (CO) Carbon dioxide (CO2) Nitrogen oxides (NOx) Special protective equipment for firefighting Use self-contained breathing apparatus Further information Fire residues and contaminated firefighting water must be disposed of in accordance with the local regulations.

6) Leak Emergency Treatment Personal precautions Wear personal protective equipment. Unprotected persons must be kept away. Keep away sources of ignition. Environmental precautions Do not allow to enter drains or waterways Methods for cleaning up/taking up Pick up with absorbent material (eg sand, sawdust). Rinse away rest with water When picked up, treat material as prescribed under heading "Disposal". Additional information Information regarding personal protective measures see, chapter 8.

7) Operation, Disposal and Storage

Safety Data Sheet according GB/T 16483-2008

Granofin PL liq
Substance key: SXR060526 Version : 1 - 2 / CHI Advice on safe handling Use only in well ventilated areas. Advice on protection against fire and explosion Keep away from sources of ignition - refrain from smoking. Take precautions against accumulation of electrostatic charge Further information on storage conditions Protect from heat Container should not be closed air-tight. Storage stability Storage temperature: 5 - 40 C Page 4(9) Revision Date: 28.05.2013 Date of printing : 06.08.2013

8) Exposure Control and Individual Protection Ingredients with occupational exposure limits to be monitored Formaldehyde CAS number : 50-00-0 Occupational exposure limits for hazardous agents in the workplace - Chemical hazardous agents. China. Occupational Exposure Limit for Hazardous Agents in the Workplace. Revision : : 2007-04-27 Maximum allowable concentration Values: 0.5 mg/m3 Acetaldehyde CAS number : 75-07-0 Occupational exposure limits for hazardous agents in the workplace - Chemical hazardous agents. China. Occupational Exposure Limit for Hazardous Agents in the Workplace. Revision : : 2007-04-27 Maximum allowable concentration Values: 45 mg/m3 General protective measures Avoid contact with eyes and skin Do not inhale vapours Hygiene measures Remove soiled or soaked clothing immediately. Avoid contact of the substance. Respiratory protection : Hand protection : If ventilation insufficient, use a respiratory protection apparatus Butyl rubber gloves Observe the information of the glove manufacturers on permeability and breakthrough times and other workplace requirements safety glasses protective clothing

Eye protection : Body protection :

Safety Data Sheet according GB/T 16483-2008

Granofin PL liq
Substance key: SXR060526 Version : 1 - 2 / CHI 9) Physical and Chemical Properties Physical state/shape : Color : Smell : pH value : Freezing point : Boiling range : Sublimation point : Flash point : Lower explosion limit : Upper explosion limit : Combustion number : Vapour pressure : Vapour density in relation to air : Density : Solubility in water : n-Octanol/water partition coefficient (log Pow) : Ignition temperature : Thermal decomposition : Evaporation rate : Viscosity (dynamic) : Liquid slightly yellowish slightly pungent 6 - 7 (20 C, 10 g/l) < -10 C 90 - 99 C not applicable 26 C Method : DIN 51755 (closed cup) not tested. not tested. not tested. not tested. not tested. approx. 1.2 g/cm3 (25 C) Method : DIN 51757 miscible This property is not applicable for mixtures. 430 C Method : DIN 51794 Method : DTA No decomposition upto 350 C. not tested. not tested. Page 5(9) Revision Date: 28.05.2013 Date of printing : 06.08.2013

10) Stability and Reactvity Chemical stability: Under normal conditions the product is stable. Hazardous reactions When handled and stored appropriately no dangerous reactions are known Conditions to be avoided not known Incompatible substances not known

Safety Data Sheet according GB/T 16483-2008

Granofin PL liq
Substance key: SXR060526 Version : 1 - 2 / CHI Dangerous decomposition products Formaldehyde acetaldehyde Page 6(9) Revision Date: 28.05.2013 Date of printing : 06.08.2013

11) Toxicological Information Acute oral toxicity : Acute inhalation toxicity : Acute dermal toxicity : Skin irritation or corrosion : Eye irritation or corrosion : LD50 > 5,000 mg/kg (rat) Method : OECD 401 not tested. not tested. non-irritant (rabbit) Method : OECD 404 irritant (rabbit eye) Method : OECD 405

Respiratory or skin allergies : not tested. Germ cell mutation : Carcinogenicity : Reproductive toxicity : not available not available not available not tested.

Specific target organ toxicity Remarks: - a one-time exposure (STOT single exposure) : Specific target organ toxicity - repeated exposure (STOT repeated exposure) : Repeated dose toxicity : Remarks:

not tested.

not tested.

12) Ecological Information Fish toxicity : Daphnia toxicity : Algae toxicity : Persistency and degradation (Biodegradability) : Potential biological accumulation : Dissolved Organic carbon (DOC) : Chemical oxygen demand (COD) : Biochemical oxygen demand (BOD5) : LC50 10 - 100 mg/l (96 h, golden orfe) not tested. not tested. 45 % (10 d) not readily degradable Method : OECD 301 F not tested. 210 mg/g 480 mg/g not available

Safety Data Sheet according GB/T 16483-2008

Granofin PL liq
Substance key: SXR060526 Version : 1 - 2 / CHI Bacteria toxicity : 100 - 1,000 mg/l Method : fermentation tube test Page 7(9) Revision Date: 28.05.2013 Date of printing : 06.08.2013

Behaviour in environmental compartments No known data. Remarks Product does not contain any organic bound Halogens which could lead to AOX-values.

13) Waste Disposal Residual wastes In accordance with local authority regulations, take to special waste incineration plant Contaminated container and package Disposal of wastes and containers in a safe manner.

14) Transport Information

Safety Data Sheet according GB/T 16483-2008

Granofin PL liq
Substance key: SXR060526 Version : 1 - 2 / CHI IATA Proper shipping name: Class: Packing group: UN/ID number: Primary risk: Remarks: Hazard inducer(s): IMDG Proper shipping name: Class: Packing group: UN no.: Primary risk: Remarks: Hazard inducer(s): EmS: ADR Proper shipping name: Class: Packing group: UN no.: Primary risk: Hazard no. : Remarks: Hazard inducer(s): RID Proper shipping name: Class: Packing group: UN no.: Primary risk: Hazard no. : Remarks: Hazard inducer(s): Flammable liquid, n.o.s. 3 III UN 1993 3 30 Shipment permitted ACETALDEHYDE Formaldehyde Page 8(9) Revision Date: 28.05.2013 Date of printing : 06.08.2013

Flammable liquid, n.o.s. 3 III UN 1993 3 Shipment permitted ACETALDEHYDE Formaldehyde Flammable liquid, n.o.s. 3 III UN 1993 3 Shipment permitted ACETALDEHYDE Formaldehyde F-E S-E Flammable liquid, n.o.s. 3 III UN 1993 3 30 Shipment permitted ACETALDEHYDE Formaldehyde

15) Information on Laws and Regulations Regulatory information China GB 13690-2009 : General rule for classification and hazard communication of chemicals. GB 20576 - 20599, GB 20601-20602: Safety rules for classification, precautionary labelling and precautionary statements of chemicals. Decree No. 591 of the State Council of the Peoples Republic of China: Regulations on the Control over Safety of Hazardous Chemicals. GB 6944-2012: Classification and code of dangerous goods. GB 12268-2012: List of dangerous goods. GB 190-2009: Packing symbol of dangerous goods.

Safety Data Sheet according GB/T 16483-2008

Granofin PL liq
Substance key: SXR060526 Version : 1 - 2 / CHI Page 9(9) Revision Date: 28.05.2013 Date of printing : 06.08.2013

16) Other information

The data are based on the current state of our knowledge, and are intended to describe the product with regard to the requirements of safety. The data should not be taken to imply any guarantee of a particular or general specification. It is the responsibility of the user of the product to ensure to his satisfaction that the product is suitable for the intended purpose and method of use. We do not accept responsibility for any harm caused by the use of this information. In all cases, our general conditions of sale apply.