Max. Marks: 60 CLOSED BOOK Date:30.11.2013 Note: There arc two pages with 30 questions in all.

Indicate the most appropriate answer by enloing A, 4 C brD (block capitat letters only) in the bgx provided on the right had side. Do not overwrite. Do not use pencll Each conct dBwer witl ti awaided trrc (2) tndl(s ard 05 mark wlll be dgdudd
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Comprehensive Quiz Course Title: Chemistry Laboratoyy

Birla Institute of Technology and Science, Pilani, Rajasthan 333 03f I Semester 2013-2014 Course Number: CIIEM Ftl0 Time: 60 minutes

fon errcry wrong answer. '

Useff Aaa: et Wr:Na=23,Mg=24, Ca=rt0,Cu=63: Attlo.: Cu*2g R=8314JK-tmol-l ID'No.:

Name: Scction Number: Name of Instructor:
an effectofacatalystonachemical reaction,

(A) elevation of activation enerry, (B) shift the equilibrium to the products (C) increase the equilibrium constant @) increase the rate at which equilibrium is achieved Q.2 The OH peak in the IR spectrum of potassirm copper oxalato comptex (synthesized by'you) is observed at' (A) 1234 , (D) 3394 (B) 1645 (C) 2900 cm Q.3 The molecular formula of potassium copper oxalato complex (synthesized by you) is

Q.l Which ofthe followingis

A+B S

c+D

cm't

6nfl

'

crn'r,

tr tr
'-'j :

(A) [K2Cu(CzOr)zJ'2H2A (B) KzCu(CzOr)dHzO)zI (C) K2[Cu(CzOr)z]'zWO . (D) KzlGu(Cz0*](HrO]I rt0 Q.4 If all the oxygen atoms in potassium copper oxalato complex (synthesized by yo!r) are labelledwith isotope, then the lR stretching tiequency witl i., (A) decrease for both caibonyl and hydroxyl groups @) increase for both carbonyl and,hydroxyl groups (C) Only increase for hydroxyl group @) only decrease forcarb,onyl group Q.5 In the TLC experimer*, ifwe consider different vuiable sonditions such as (l) future ofsolvent, (2) r|rltibg l ofadsorben!aad(3)volumeofsolvent(shouldnoto<ceedspottingline)tlifnrfuvaluefor'agivencornpogtld.,": will depend on '-

E
m,

(A)only(l)and(3) (B)only(l)and(2) (Opnly(2)ard(3) be

(D)all(l),(2),arld(3)

Q.6 Suppose, (R)-2-iodo-2-phenyl-butaine racts with dihite NaOH sotrxion following Spl mechanisn and r&qtion complots in 5 hours. If one collec6 the reaction mixttne efter 2 hours and checks tln p,rogress of reaction using silica 9l coaed TLC plate using mhtur of 207o ethylacel*e + 8096 le:<ane as mobile phase, : the 4pmber of spots appearing on TLC .plare under UV light will

E
tEl

'

(A)l
(A)

(B)4

(c)3

'

Q.7 In a TLC experiment, two compounds P and Q were spotted on a TLC pldo Erroh ttrat their. disanccs trcrar'the bottom Oase) ofthe TLC plal were 3 and 5 uni6, respcctively whilc thesolvcnt fioff rdn upto'9 uhit3.:tf!Sd' compounds were spotted I unit abor.e the bottom @ase) ofthe plate, the Re value ofP ard Q respoctivcly nvill be
3;t9 ,'St9

@)2

(B) v4

,ltz

(c)

5t9

,3t9

(D)

l/2, l/4

tr
EJ

Q.8 Tluee iompounds X, Y, and Z were spotted on a TLC plate as shown in Figl and the TLC was run in a solvent mixture consisting of l0% Ethyl acetate andgAo/o Hexane. Which of the following is the correct statement about the decreasing order of polarity of X, Y, and Z?

f=T1 II
l-l

tt
tlt

(A) X>Y>Z

(B) Y>X>Z

(c)

DX>Y

(D) X>z>Y

A Y,L

(A) 150 ppm (B) 100 ppm (C) 170 ppm (D) 90 ppm Q.l0 Suppose you take l0 mL calbium carbonate of strength 0.1 M in conisal flask and [hen ;udidZ mL buffer and 3-4 drops of EBT in the flask. During titration with EDTA if the end point appears after consumption,of l0 mL EDTA, then what will be the concentration of EDTA solution? (A) rM (B) 0.1 M (c) 0.0r M (D) 0.001M

Q.9 If 50 mL of the water sample consumed 10.7 mL of 0.008 M EDTA solution, then the hardness of the water sample is

Figr

Q.ll For the following reaction,.when ethyl alcohol and acetic acid are mixed in equivalent proportiols, the equilib'rium is attained after 2/3' of consumption ofthe acid and alcohol. The equilibrium. constant ofthe reaction is

CH3COOH
(A)

(A) r.7

(B) 3.3 (c) 8.7e The denticity of NatEDTA pH in the range 9-l I will be Q.13 (A) 2 (B) 3 (c) 4
i

(C) (D) 0.s moles If5 ofacetic acid and 2 moles ofethyl alcohol are used in acid catalyzed conditions to yield Q.12 ethyl acetate and water. How many moles ofacetic acid will be left ar equilibrium, ifK" ofthe reaction is 3?

4.0

C2H5OH
(B)

0.25 ==

CH3COOC2H5

H2O

E E
H

(D) 3.7e (D) ('

tr

Sn*- B
conc' of prg**-_ (c) presence of a @) initial conc. Q'fJ In the obseived rate exDrcssioq r= r tatrer", ;;i s ,r" suusfares of a murtisrep chemicar reaction' which of the fotowing stalementsisior#t "nl witi,

*.11^!11liL"l* "o.pgg1{o1a (AJ remperarure (B) iniriar

reacrioq varies

with

;e

caralyst

r""fr

to a ana B, re5pectively?

"t**no I n

r__l
I

'

subitande. The intensitv of the radiatio" ;. *a"""aio l0 cm length of the sotution. Themor* (A) 2.204 dm,mof'cm'' (B) 2.204 "urprpo-

iaii^ti;ryfr:;;ffffiJi""H4*; ]$*ilil#$#,[:#n:'*;m:n e.l6.A monochromatic radiationis incioeot on ror.ilJn

a

t(A)

'FiiryFqiiil;ild;;;"ii"are;E]ill,HlJlf:ffi''e1Tl;il.s''tr'...]' Q'2I Which of the followings is role of buffer iffi;;;ulti*ution

one
a '

;il'""*o, ff in*,,..r?ttn8 | o ;(4,)2+Q (B)3+p "itttr i.rr"*r"i-i".ifri"* "i.&*r, roa+s', ' H grin$eiq"{(""1i1u'iooor,opp.",r,con*?f,Li*r" (Aiieb'df;;-.,(Ii;.;,r*T::::*'.*"Tff#m"'" . 'E:l @)surnde Q20rn aidtioiiisoilur . ; . r-...-l ' "*u.oa. , ., r--, i ,XY$$'t pf iodine
informatiorr which
and compomds is
'

(D) ditue H,so. .. [ir'ilu"r'rr"r*o, Ejil$Iili""*ium tho rs." orsani-c co;;ffi iil ?l$nX',ti;tg,1,9}.i|,'tg;*ffil j1r(d"-**.; ' thc above

fi.ll}Ich

one of the

following rcagants is pres"nt iiiJing,isorution zr tartErate (c) c-naphthol

dm.L;i#i"

i"iii"i;ft "iJ-i"",inttr," L*.i'#liirr" ruu"tun"" i. -6'ffi;;ilffi#'r"

"i."""L"r""

o.ris ir,r

or- Jrorline"

E
g
I I

;fr;;#i;ir.

'ush

(D) r.204 dmjmor.rcm{

LgJ
I

the esiimation of coooer by iodometry, ure oie the oxiilation of

(or sodiurn bicaitonare)

r: .

:"ir"'

3f,t$?iflT,3r=fl'$*;rrs;;id;il;;;;;ffi#in{retitrationwourdbe(given,pri..or 4s4 {e) a.6e . . (c).39 . is.inconect? 1p) 7.s6 I Q-23.Which one of the followi4g . .. $ferenfs ll] lectrTe potential depends on temperaturc
(A)
,

dissolved ol vgen in the reaction mixture srppose Q22 vou are tiraiins so mL ofol rtaGlrcooH(rq) with ol5 ' MNaoII(aq) at 25"c. The pH
r

!!)

9l

$)

to ,inrease the solubjlity of tie EBT dye to prevent the reverse reaction of ca-EDTA complexation t" ensure the properpH of rhe solution - -'

indicator
,

of hardness of warer with EDTA? ,-r--, -

Pllo^q*nch

of

:,..J

.l
. ,:l
:
.

,.

. "
.
.

,i..

(u)&lass electrod does not contah silver*ilver chloride ql Bgenlial is generated across a thin g^" ,".U.J"

9ie1"*"1*u"q"p"t.;AJ;;ffi#;ffipHofthesolution elfutrode
*G"cil,
"h"hod"
llectnolye

l7l t-, I

fi rquiuur*t *ni-,irtunJJo"ian qzs

.,!ff f

no. ofariions and cations "1421ry_etec.tgtrte i 1e1 iivr sotution of the <pl erd"a-.no. of unit positive and rmit negative charse. me n"t copper oxararo complex (syrithLizrJ liyoo) tt u orr,ou" of d-elecrons on 6u "sium

ilff :1-"6iErsiK:':::::ffiffifr:.*:.*"fi,rH",K.*auschbhwldl ' r_l

sol.tioqof votume I

elitrorvte

titr

equarul#*i#"#r0"ry1" --

d)iiffi;

1*"n.F,i53,f,wins condidon!? ".

[.izio*'*vatffi.'n*or*ur"pro*in"ffJrlureofcbenzarac*n*

t,

ar'

ID

,$jg]q1,:"-*gv9.]3uraor"ono**ti-,."$r*,t?"'"-;;;r""rlr,"r"g"tuo*,nsst"*r

[l];l*tr"?Ttilfl#:ffi#{itr#e"*d;td;fi"#is

qz; ro,mation orardor rrom rne

eiroiiH;"

'$i{?#i{"'i","",.3"!?"H*'Lo or^,","01f,"!rlnill"!?*c acia <crc',c8ffiJ fi,n Tho equivarenr conductarrces of chloroac.l4 ilililil.;ioirJiinnnir. a'ution are 40.2 and 348.1 -'to''"q',

n.,"*,.

mi

tr

E|

r=l

Al5.l';t.*;o.JoJJ;iloiiationortheacid6.-'-"'-'*-'
*l**lgl:;,lJ,illii"o"o*
'

(A)3.63x104M

(B)3.63x10rM

",

zs "c ro,

J3l lir,'3r*ion or","ry,nou ,91lo?1i,"""

(c)l.lsxlo4M

*,0,

U
,--,
l_tj

(D)l.l5xtgnu

ti | + * t *t,|*t t *t **{.*i t}*:} | *