1.

-COOH group is knocked out if salicylic acid is:

(a) nitrated (b) brominated *(c) both correct(d) none is correct
2.
OH
COOH
Br2 HNO3 X, X and Y are:
Y water

*(a) pictic acid, 2,4,6-tribromophenol (c) o-nitro phenol, o-bromo phenol

(b) 4-nitro salicylic acid, 4-bromo salicylic acid (d) none is correct
3.
CCl4, KOH, ∆ ∆
OH A B
H+
CH3COCl C
CH3OH
D
A, B, C and D respectively are:
*(a) salicylic acid, salol, aspirin and oil of winter-green (b) salicylic acid, aspirin, salol and oil of winter-green
(c) salicylic acid, oil of winter-green, salol and aspirin (d) none is correct
4.

+ CH3CHCH2Cl AlCl3
hydrocarbon (X) X is:
CH3
CH3
(a) CH2CHCH3 (b) CCH3 (c) CH2CH2CH2CH3 (d) all correct
CH3 CH3 Ans. B
5.
OCH3

NaNH2
product A by reaction R. A and R are:
Br
OCH3 OCH3 OCH3 OCH3
NH2 Br
(a) (c) (d)
(b)
NH2
elimination elimination addition cine substitution cine substitution Ans. B
6.

Chloral + Cl conc. H2SO4 product. Product is:

(a) lindane (c) teflon *(b) D.D.T. (d) ethaneperchlorate

7.
NO2

KCN product A by reaction R. A and R are:

C2H5OH

Br
NO2 NO2 Br NO2
CN
, von Richter (d) , von Richter
(a) , SN (b) , von Richter (c)
CN
CN CN Ans. C
8.
Cl
O2N NO2
+ H2O warm product

NO2
Product can be:
*(a) picric acid (c) chlorobenzene (b) phenol (d) no reaction since (C-CI) bond is stable
9. In the reaction of p-chlorotoluene with KNH2 in liq. NH3, the major product is:
(a) o-toluidine *(b) m-toluidine (c) p-toluidine (d) p-chloroaniline
10.
Cl(1)
Cl(2)

Cl(4) Ans. A
Which chlorine is most easily replaced under nucleophilic attack?
(a) CI (1) (b) CI (2) . (c) CI (4) (d) Cl (1) and Cl(4)
11.
CH2 OH
O
CH CH2
Heat
CH
CH2
* CH2
What is the name of this reaction?
(a) Fries rearrangement *(b) Claisen rearrangement (c) Kolbe reaction (d) Riemer-Tiemann reaction
12. Which is the correct structure of the product formed in (32) in terms of position of C*?
OH OH
CH2CH CH2 CH2CH CH2
* *
(a) (b)

(c) both correct (d) none is correct Ans. B

13. Libermann's nitroso reaction is for testing of:
*(a) phenol (b) benzoic acid (c) nitrobenzene (d) aniline
∆,HCl
14. The reaction C6H5N2+Cl- +CuCI  → C6H5CI + N2 +CuCl is known as:
(a) Wurtz reaction *(b) Sandmeyer reaction (c) Gattermann reaction (d) Friedel-Crafts reaction
OH OH OH OH

(I) (II) (III) (IV)

NO2
CH3 NO2
15. In the following compounds: order of acidity is:
*(a) II<I<III<IV (b) III>IV>II>I (c) IV<III<I<II (d) IV<III <II <I
16.
H2O
MgBr + CH2-CH2 A, A is:
H+
O

CH2CH2OH (c) CH2 CH2 (d) no reaction

(a) CH2OH (b)
O Ans. B
17.
OH

NO2+
A, A can be:

CH3
OH OH OH
NO2
(a) (b) (c) (d) no SN reaction is possible
NO2 NO2
CH3 CH3 Ans. A
18. In which case, SE will not be in meta position?
(

°
one or more than one may be correct
∆