32

jlk;u foKku (Chemistry)

jlk;u foKku
(Chemistry)
(313)
f'k{kd va fdr ew Y;ka du i=k
Tutor Marked Assignment
~ zo
Max. Marks: 20
fVIi.kh% (i) ii ni i n ~fni z - n ~ i=n f z
Note: All questions are compulsory. The marks for each question are given at the against each.
(ii) i fni i= i ~i ~ni ni=, ~n=i, ~n i ni=,
fi ~if - ii = ffi
Write your name, enrolment number, AI name and subject etc. on the top of the first page of the
answer sheet.
1. fnnffin = fi n i i i 4oeo ii = if 2
Answer any one of the following questions in about 40-60 words :
(a) i C
6
H
12
O
6
(=i =in +so i= =i) i 18 i= =i-i i nn = 1 kg =
iii i z z f ni n i Kb f 0.52 kg =i
+
i i
ini aza.+s K z (i i)
18 g glucose, C
6
H
l2
O
6
(Molar mass = 180 g mol) is dissolved in 1 kg of water in a sauce pan. At what
temperature will this solution boil (kb for water = 0.52K kg mol
-1
B.P of pure water = 373.1 K)
(Ref. Lesson9)
(b) zso i= i f- i i ~ +so f. =i. fni- i ini z ni i
iii n i fn if (ia i)
Calculate the de-Broglie Wave length associated with a cricket ball weighing 280 g thrown at the speed
of 150 km/hr (Ref. Lesson3)
(c) f nis-in i nni = ~iin i ~ii i-i zini z fn ~iin i nni =
nis-in i i= ~in= nii = zini z i' (i4 i)
Although size of oxygen is small as compared to nitrogen but the first ionisation enthalpy of nitrogen is
higher than oxygen why? (Ref. Lesson4)
(d) (i) He
2
~i ni i nzi MO fin ~iii in if (is i)
He
2
molecule will exist or not. Explain on the basis of M.O. theory?
(ii) O
2
_
~i O
2
2+
= ~ii = ~i i zi i in if (is i)
Explain the bond order and magnetic behaviour of
2
O

and
2
2
O
+
(Ref. Lesson5)
(iii) VSEPR fin ~iii ClF
3
~i SO
2
i ~ifn ~i i nis
(is i)
33
jlk;u foKku (Chemistry)
On the basis of VSEPR theory predict the shape and hybridisation of ClF
3
and SO
2
(Ref. Lesson5)
2. fnnffin = fi n i i i 4oeo ii = if 2
Answer any one of the following questions in about 40-60 words :
(a) nni ~i inni i ni=in f i iifn ni z (iz i)
How does the temperature effect surface tension and visclocity. (Ref. Lesson7)
(b) fnnffin i 298 K emf i ini if Fe (s) / Fe
2+
(0.001M) || H
+
(IM)/H
2
g)
(lbar), Pt (S) Fe
2+
f i emf = + 0.44V fi z~i z (i+s i)
Calculate the emf of the following cell at 298 K (Ref. Lesson15)
(S) Fe (s) / Fe
2+
(0.001M) || H
+
(IM)/H
2
g) (lbar), Pt (S) (Given E
0
Fe
2+
= + 0.44V)
(c) z =inn z f K
2
SO
4
ini

ifn fiifn z, 25
0
C 2 i- = 2.5X10
-2
i=
K
2
SO
4
iin in z ii i iii i ffn if (i i)
(R = 0.02, L atom K
-1
mol
-1
) K
2
SO
4
i ~iif =in +z4 g =i
+
(Ref. Lesson9)
Determine the Osmotic Pressure of a solution prepared by dissolving 2.5x10
-2
g of K
2
SO
4
in 1Ltr.
water at 25
0
C, assuming that it is completely dissociated.
(R = 0.082 1L atm K
-1
mol
-1
, Molar mass of K
2
SO
4
= 174 g mol
-1
)
(d) i= if- i ~fifi f iis f o% fi i zin = i = % fi i zin
= i ni zini z (i+e i)
fi ~fifi i ()fnni K ni T n ii fnn =ii ~ni
ni z
log K = log A - Ea/2.303 R 1/T
f Ea ~fifi i fn i z log K i 1/T fn i iii ini z ni
4zsoK i i iii ii in zini z ~fifi f Ea i fn if
(i+e i)
(R = 8.314 JK
-1
mol
-1
=i)
For a first order reaction, show that time required for 99% completion is twice the time required for the
completion of 90% of reaction. (Ref. Lesson16)
Rate constant K of a reaction varies with temperature T according to the equation:
where E
a
is the activation energy. When a graph is plotted for K Vs 1/T, a straight line with a slope of -
4 250K is obtained. Calculate Ea for the reaction.
(R = 8.314 Jk
-1
mol
-1
)
1
log log
2.303
Ea
K A
R T
| |
=
|
\ .
34
jlk;u foKku (Chemistry)
3. fnnffin = fi n i i i 4oeo ii = if 2
Answer any one of the following questions in about 40-60 words :
(a) ~n z is= ~ i in i fi ini z' (i +s i)
Why is sulphide ore roasted before reduction (Ref. Lesson18)
(b) i=is- = i in if (i z+ i)
CCl
4
i ~i-n nzi zini z fn SiCl
4
i ~i-n zi ini z i'
finffin i IUPAC ~ni ni= ffi (i z4 i)
(i) [Co (NH
3
)
5
Cl]SO4
(ii) Na
3
[Fe (CN)
6
]
nifi ii fniin ~fifi~i f iiin zn = fiii z s f i
ii ffi
Explain thermite process (Ref. Lesson21)
CCl
4
is not hydrolysed by water but SiCl
4
is hydrolysed why?
Give IUPAC name of these complexes (Ref. Lesson24)
(i) [Co (NH
3
)
5
Cl]SO4
(ii) Na
3
[Fe (CN)
6
]
Chlorobenzene is extremely less reactive towards a nucleophilic substitution reaction. Give two reasons
for the same.
(c) ~i ffnn ' (i zs i)
(i) iin i inz~i ='
(ii) fni i z,4,e -isnis-iini = '
How will you convert (Ref. Lesson28)
(i) Propene to propane 2-ol
(ii) Phenol to 2,4,6 trinitrophenol
(d) i zini z
(i) PCl
3
i = fi ini z (i zz i)
(i) H
3
BO
3
i = fi ini z (i z+ i)
What happens when
(i) PCl
3
is heated (Ref. Lesson22)
(ii) H
3
BO
3
is heated (Ref. Lesson21)
4. fnnffin = fi i i i +oo-+so ii = if 4
Answer any one out of the following four questions in about 100 to 150 words
(a) (i) fnnffin iii i i fni = n n +iii ni ~ni fin
if ~n -n i ~if- if (i ao i)
35
jlk;u foKku (Chemistry)
CH
3
NH
2
, (CH
3
)
3
N, (CH
3
)
2
NH
Arrange the following in increasing order of their basic strength in aqueous solution. Justify your
answer. (Ref. Lesson30)
CH
3
NH
2,
(CH
3
)
3
N, (CH
3
)
2
NH
(ii) fnnffin ~fifi~i i in if (i z ao i)
Explain the following reactions (Ref. Lesson29 & 30)
(i) niii ~fifi (ii) zi=n i=i=is= ~fifi
Cannizaro reaction (ii) Hofmann bromamide reaction
(b) (i) fnn ~fifi~i = A, B ~i C i ni ffi (i ao i)
Give the structures of A, B and C in the following reaction (Ref. Lesson30)
(1)
6 5 2 2 3
/ C H N Cl Cu CN A H O H B NH C +

(2)
6 5 2 2 3
/ / / C H NO Sn HCl A NaNO HCl B H O H C
+
+

(ii) fnnffin iifn iiii i i nfn if (i za i)
Complete the following Chemical equations and balance (Ref. Lesson23)
(i) Cr
2
O
7
2-
+ Fe
2+
+ H
+
>
(ii) CrO
4
2-
+ H
+
>
(iii) MnO
4
-
+ C
2
O
4
2-
+ H
+
>
Or
fnnffin ~fif~ii i i if (i z i)
Complete the following reactions : (Ref. Lesson29)
(i)
O

2 Conc KOH H C H

(ii) CH
3
COOH
2
Br /P

(iii) Ph CHO
3 2 4
HNO /H SO

273-283 K
(c) (i) i ~i ~ini = =ii ~ii fnn i in if (i 4 i)
Explain the variations of atomic size in groups and periods. (Ref. Lesson4)
(ii) fnnffin i fiifin if
Define the following
(1) s-in zi ii (i 4 i)
Electron gain enthalpy (Ref. Lesson4)
36
jlk;u foKku (Chemistry)
(2) n ii-=ni
Electronegativity
(d) (i) fnnffin i n n z ~ifn ~ii i = fin if
(i 4 i)
Arrange the following in order of increasing ionic size (Ref. Lesson4)
3 2 2 3
, , , , N O F Na Mg Al
+ + +
(ii) ii ~i fii ii= i zin z' sn= in i i n ii= fn
~i- =in =ni zi ni z (i +o i)
What are Lyophilic and Lyophobic colloids? Which of these sol can be easily coagulated on the
addition of small amount of electrolytes?
iifn ~fiiiii ~i iifn ~fiiiii ~n i fnn ii = ffi
(i +o i)
Write the differences between physiosorption and chemosorption with respect to the following
(Ref. Lesson10)
(i) ffi-ni (ii) ni=in fnini (iii) mRdze.kh;rk(iv) iii fnn
(i +z i)
(i) Specificity (ii) Temperature dependance (iii) Reversibility and (iv) Enthalpy change
4. fnnffin = fi i i i +oo-+so ii = if 4
Answer any one out of the following four questions in about 100 to 150 words
f ~
Optional Module A
(i) i-i=i izi i zini z' z in i f i iifn ni z'
(i aa i)
What do you mean by photochemical Smog ? How does it effect the life? (Ref. Lesson33)
(ii) ~ ii i zini z' s zifni ii i zin z' (i aa i)
What is acid rain? Explain its harmful effects. (Ref. Lesson33)
(iii) in zi ii i zini z' s in i ii zin z' (i aa i)
What is green house effect? What are its effects on one's life? (Ref. Lesson33)
f
Optional Module B
(a) fnn zi i ni= ~i ni ffi (i aa i)
Write the names and structures of the monomers of the following polymers: (Ref. Lesson36)
(i) ni
Buna - S
37
jlk;u foKku (Chemistry)
(ii) fnifn
Neoprene
(b) f ~i i =sn z' fni f=--i -ii i fn i fi ini z'
(i ae i)
What do you understand by the term glazing? Why are certain clay products glazed?
(Ref. Lesson36)
(c) ~iiii ~i ii = i ~n z' ~iiii is i izi ~ni n z ffi
(i as i)
What is the difference between drug and medicine? Write any six classes of medicines with examples and
uses. (Ref. Lesson35)
6. ni i s i fini~i i i = is fini soo ii = ni if e
Make any one project out of the four given below in 500 words.
(a) ~n =i i in fin i iiii = is ~i (i +ae i)
(i) izi ini ~i iiff ~i i zin if
(ii) CH
3
OH C
2
H
5
OH i zifn
(iii) sn= in i zifni zini z
(iv) OH ~fi+ii =z in i if- ~i i=f- = ~n i
(v) iz ~iii zin CH
3
COOH nni z iz i ni= nis
Visit the chemistry laboratory of a nearby school and
(i) Identify alcohols, phenols, carboxylic acid etc.
(ii) Distinguish between CH
3
-CHO and C
2
H
5
OH
(iii) Which one of these is harmful
(iv) What is the difference between alcohol and aromatic compounds containing - OH group
(v) Oxidation of one of the alocohal CH
3
COH is formed. Name that alcohol
(b) ~n =i i iiii = is ~i = = +o n=n -i if
(i) ~i +iii ~i ii i i if
(ii) ~i ~i +iii i i if
(iii) ~ i zin if fi i ii = iiii i = zini z
(iv) +ii i zin if i f iin i=i = i zini z
(v) +ii i zin if i f f i= = i zini z
Visit Chemistry laboratory of your AI and collect chemical at least 10 samples.
(i) Prepare the list of acids, bases & salts
38
jlk;u foKku (Chemistry)
(ii) Prepare the list of strong and weak acid and bases
(iii) Indentify the acid which is generally used in our house
(iv) Identify base used as washing soda
(v) Identify base used as baking powder
(c) =i i i=i i in is ~i = = +o n=n -i if
(i) iin~i ~i ~iin~i i i if
(ii) if- ~i = i i if
(iii) ii f -nis ii i i if
(iv) ii in f ~i i iiini n
Visit a nearby scrap dealer shop and collect at least 10 samples and
(i) Prepare the list of metals, non-metals
(ii) Prepare the list of plastic, rubber etc.
(iii) Prepare the list of articles responsible for pollution
(iv) What precaution will you take to prevent pollution
(v) Prepare the list of biodegradable and non-biodegradable items.
(d) ~n =i i ~iifi i in is = = zo ffin ~iifii i i if
~i ni fnn = ii if
(i) -ii fiii
(ii) i iinii
(iii) i=inii
(iv) fn~
(v) ifni ii
Visit a nearby medical shop. Make a list of at least twenty different medicines and classify them into
(i) Antipyretics
(ii) Disinfectants
(iii) Analgesics
(iv) Antacids
(v) Contraceptives