Sri Chaitanya IIT- JEE Academy

RAMAN BHAVAN - VIJAYAWADA CHEMISTRY ASSIGNMENT [ELECTRO CHEMISTRY] Sr.IIT 26-07-07 ************************************************************************************ 1. When lead accumulator is charged it is ! 1" an electrolytic cell #" a gal$anic cell %" a &aniel cell '" (one o) these , #. The standard o*idation +otentials E )or the hal) reactions are as -n -n#. . #e E, / .,.01 2 3e 3e#. . #e E, / .,.'1 2 The e.m.) o) the cell 3e .# . -n -n#. . 3e is 1" ,.%4 2 #" 5,.%4 2 %" .1.10 '" 51.10 2 Strongest reducing agent is ! 1" 6 #" 7g %" Al '" I 1 + The reaction H # 8 g " + AgCl 8 s " H ( aq ) + Cl ( aq ) + Ag ( s ) occurs in the gal$anic cell # 1" Ag9AgCl8s"96Cl 8soln"99Ag(:% 8soln."9Ag #" ;t9<#8g"9<Cl 8soln"99Ag(:% 8soln."9Ag %" ;t9<#8g"9<Cl 8soln"99AgCl 8s"6Cl9Ag '" ;t9<#8g"96Cl 8soln"99AgCl 8s"9Ag The stand reduction +otentials at #4,C )or the )ollo=ing hal) reactions are gi$en against each -n#.8a>" . #e -n8s" -,.01# is E, $alue Cr%.8a>" . %e Cr8s" -,.0', is E, $alue #<. . #e <#8s" ,.,, is E, $alue

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3e.% . e 3e.# ,.00 is E, $alue Which is the strongest reducing agent ! 1" -n #" Cr %" <#8g" '" 3e.#8a>" A solution containing one mole +er litre o) each Cu8(:%"# ? (a(:%? <g# 8(:%"#? 7g8(:%"# is @eing electrolysed @y using inert electrodes increasing $oltage the se>uence o) de+osition o) metals on the cathode =ill @e 1" Ag <g Cu #" Cu <g Ag %" Ag <g Cu 7g '" 7g Cu <g Ag Which one =ill li@erated Ar# )rom 6Ar 1" <I #" I# %" Cl# '" S:# , 3rom the )ollo=ing E $alues o) hal) cells ! I" A A. . e ? E, / .1.# 2 II" A- A . e ? E, / -#.1 2 III" C C#. . #e ? E, / -,.%B 2 I2" &-# &- . e ? E, / -,.4C 2 What com@ination o) t=o hal) cells =ould result in a cell =ith the largest +otentialD 1" I and I2 #" II and III %" III and I2 '" I and II 3rom the )ollo=ing E, $alue o) hal) cells I" A%- A#- . e ? E, / 1.4 2 II" A. . e A ? E, / -,.4 2 III" C#. . e C.? E, / .,.4 2 I2" & &#. . #e ? E, / -1.4 2 What com@ination o) t=o hal) cells =ould result in a cell =ith the largest +otentialD 1" I and III #" I and I2 %" II and I2 '" III and I2 , , E )or 3# . #e #3 is #.B 2 E )or 19# 3# . e / 3 is ! 1" #.B 2 #" 1.' 2 %" 5#.B 2 '" 51.' 2 The $alue o) em) )or a )easi@le cell reaction is ! 1" E 1 #" , %" / 1 '" F , The hal) cell reduction +otential o) a hydrogen electrode at +< / 1, =ill @e ! 1" ,.4C 2 #" 5,.4C 2 %" ,.,4C 2 '" 5,.,4C 2

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<o= much =ill the reduction +otential o) a hydrogen electrode change =hen its solution initially at +< / , is neutraliGed to +< / 0D 1" Increase @y ,.,4C 2 #" &ecrease @y ,.,4C 2 %" Increase @y ,.'1 2 '" &ecrease @y ,.'1 2 ;assage o) one am+ere current through ,.1 7 (i 8(: %" # solution using (i electrodes @rings in the concentration o) solution toHHHHHHHHH in 1, second l" ,.# 7 #" ,.,4 7 %" ,.1 7 '" ,.,#4 7 Strong electrolytes are those =hich! 1" &issol$e readily in =ater #" Conduct electricity %" &issociate into ions at high dilution '" Com+letely dissociate into ions at all dilutions The one that is a good conductor o) electricity in the )ollo=ing list o) solids is ! 1" Sodium chloride #" Ira+hite %" &iamond '" Silica :ut o) Cu Ag 3e and -n the metal =hich can dis+lace all others )rom their salt solutions is ! 1" Ag #" Cu %" -n '" 3e # The charge re>uired )or the reduction o) 1 mole o) Cr#O0 ions to Cr%. is ! 1" C14,, C #" #C14,,, %" % C14,, C '" 1 C14,, C 1,B,, C o) electricity through the electrolyte de+osited #.C00g o) metal =ith atomic mass 1,1.' g mol-1. The charge on the metal cation is ! 1" .' #" .% %" .# '" .1 :ne coulom@ o) charge +asses through solution o) Ag(:% and CuS:' connected in series and the conc. o) t=o solution @eing in the ratio 1 ! #. The ratio o) amount o) Ag and Cu derosited on ;t electrode is ! 1" 1,0.C ! 1%.4' #" 4' ! %1.00 %" 1,0.C ! %1.00 '" 4' ! 1%.4' <#S:' on electrolysis sho=s the anodic reaction =ith ;t electrodes # # # 1" SO' S :' . #e #" # SO' + # H #O # H # SO' + O#
+ + %" ' H + 'e # H # '" # H #O 'e ' H + O# Electrolysis o) dil. <#S:' li@erates gases at anode and eathode 1" :# and S:# res+ecti$ely #" S:# and :# res+ecti$ely %" :# and <# res+ecti$ely '" <# and :# res+ecti$ely The electrolyte used in gold +lating o) co++er articles containing ! 1" 7olten gold #" CuS:' %" AuCl% '" AuCl% . (aC( I) the cell is s+ontaneous =hen ! 1" I is .2e #" E, is -2e %" E, is .2e '" I is -$e The most +o=er)ul reducing agent is ! 1" <Cl #" <I %" <3 '" <Ar The most +o=er)ul o*idiGing agent is ! 1" 3# #" Cl# %" Ar# '" I# -% Charge o) ion o) ( is ! 1" 3 #" #3 %" %3 '" '3 &uring electrolysis o) <#: the ratio o) <# and :# )ormed is ! 1" # ! 1 #" 1 ! # %" 1 ! % '" 1 ! 1 The +assing % )araday o) electricity through the three electrolytic cell connected in series containing Ag. Ca#. and Al.% ions res+ecti$ely. The molar ratio in =hich the three metal ions are li@erated at the electrodes is ! 1" 1 ! # ! % ! ' #" % ! # ! 1 %" 1 ! % ! # '" % ! ' ! # Conducting +o=er o) a solution is directly +ro+ortional to 1" &ilution #" (um@er o) ions %" Current density '" 2olume o) solution The conducti$ity o) a strong electrolyte 1" Increase on dilution #" &oes not change considera@ly on dilution %" &ecreases on dilution '" &e+ends u+on density 3aradays Ja=s o) electrolysis are related to the 1" Atomic num@er o) cation #" Atomic num@er o) anion %" S+eed o) ion '" E>ui$alent =eight o) electrolyte

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1" A cathode #" An anode %" Ions '" ;orous +late When a lead strong @attery is discharged 1" S:# is e$ol$ed #" Jead sul+hate is consumed %" Jead is )ormed '" <#S:' is consumed I) a salt @ridge is remo$ed @et=een the t=o hal) cells the $oltage 1" &ro+s to Gero #" &oes not change %" Increases >radually '" Increases ra+idly The re)erence electrode is made )rom =hich o) the )ollo=ing 1" <gCl# #" <g#Cl# %" -nCl# '" CuS:' Stronger is o*idiGing agent greater is the 1" Standard reduction +otential #" Ionic nature %" Standard o*idation +otential '" (one CuS:' is not stored in Aluminium @ottles @ecause 1" Cu gets o*idiGed #" Cu get reduced .# %" Cu gets reduced '" CuS:' decom+oses When a co++er =ire is +laced in a solution o) Ag(: % the solution ac>uires @lue colour. This is due to the )ormation o) 1" Cu.# ions #" Cu. ions %" Solu@le com+le* o) Cu =ith Ag(:% '" (one Which o) the )ollo=ing =ill increase the $oltage o) the cell Sn8s" . #Ag.a> Sn.# 8a>" . #Ag8s" 1" Increase in the siGe o) the sil$er #" Increase in the concentration o) Sn.# %" Increase in the concentration o) Ag. '" (one o) these E, K; )or 3e.#93e and Sn.#9Sn are 5,.'' and 5,.1' $olts res+ecti$ely. The standard em) )or cell 3e.#9Sn Sn.# . 3e is 1" .,.%, 2 #" 5,.4B 2 %" .,.4B 2 '" 5,.%, 2 In electro+lating the article to @e electro+lated ser$es as
1" Cathode #" Anode %" Electrolyte '" (one .# . The standard +otential o) -n9-n and Ag 9Ag are .,.01% and ,.0CC 2. The standard em) o) cell is ! 1" 1.41# 2 #" ,.,%1 2 %" 51.41# 2 '" ,.0CC 2 The hydrogen electr*ode is di++ed in a solution o) +< / % at #4 ,C. The reduction +otential o) hal) cell =ould @e 1" ,.100 2 #" 5,.100 2 %" ,.,B0 2 '" ,.14C 2 A dilute a>ueous solution o) (a#S:' is electrolyGed using +latinum electrodes. The +roducts at the anode and cathode are # # 1" :#9<# #" S #OB (a %" :# (a '" S #OB H # The standard reduction +otentials o) Cu #.9Cu and Cu#.9Cu. are ,.%%0 and ,.14% 2 res+ecti$ely. The standard electrode +otential o) Cu.9Cu hal) cell is 1" ,.1B' 2 #" ,.B#1 2 %" ,.4#1 2 '" ,.'C, 2 A standard hydrogen electrode has Gero electrode +otential @ecause 1" <ydrogen is highest to o*idiGe #" This electrode +otential is assumed to @e Gero %" <ydrogen at has only one electron '" <ydrogen is @e highest element :n the @asis o) +osition in the electrochemical series the metal =hich does not dis+lace hydrogen )rom =ater and acids is 1" <g #" Al %" ;@ '" Aa The correct electrochemical series can @e o@tained )ro 6 (a Ca Al 7g -n 3e ;@ < Cu <g Ag and Au @y interchanging 1" :nly Al and 7g #" :nly (a and Ca %" Aoth 1 and # '" (one The correct order o) chemical reacti$ity =ith =ater according to electrochemical series is 1" 6 F 7g F -n F Cu #" 7g F -n F Cu F 6 %" 6 F -n F 7g F Cu '" Cu F -n F 7g F 6 (ormal aluminium electrode cou+led =ith normal hydrogen electrode gi$es an em) o) 1.11 $olts. So the standard electrode +otential o) aluminium is ! 1" 51.11 2 #" .1.11 2 %" 5,.B% 2 '" .,.B% 2 In an electrolysis o) an a>ueous solution o) sodium sul+hate #.' o) o*ygen at ST; =as li@erated at anode. The $olume o) hydrogen at ST; li@erated at cathode =ould @e 1" 1.# J #" #.' J %" #.1 J '" '.B J In the electrolysis o) CuCl # solution using co++er electrode i) #.4 gm Cu is de+osited at cathode then at anode 1" BC, mJ o) Cl# at ST; is li@erated #" ''4 mJ o) :# at ST; is li@erated %" #.4 g o) co++er is de+osited '" A decrease o) #.4 g o) mass taLen +lace

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The reaction occurring at anode =hen the electrolysis o) an a>ueous solution containing (a #S:' and CuS:' is done using ;t electrodes is 1" Cu Cu #+ + #e #" # SO # + # H #O # H # SO' + O# + 'e
+ #" # H #O O# + ' H + 'e '" Cl Cl# + #e In the electrolysis o) alLaline =ater a total o) 1 mol o) gases is e$ol$ed. The amount o) =ater decom+osed =ould @e 1 # 1" 1 mol #" # mol %" mol '" mol % % In an electrolysis o) metallic chloride %.#B%g o) the metal 8 molar mass 1C0g mol 51" =as de+osited on the cathode @y the +assage o) 'B#4C o) electric charge. The charge num@er o) metal ion is 1" ,.4 #" 1 %" # '" % #. MnO In acidic medium is con$erted to 7n =hen acts as an o*idiGing agent. The >uantity o) '

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electricity re>uired to reduce ,.,4 mol o) MnO' =ould @e 1" ,.,13 #" ,.,43 %" ,.#43 '" ,.143 Which o) the )ollo=ing statement is correct D 1" Cathode is +ositi$e terminal in an electrolytic cell #" Cathode is negati$e terminal in a gal$anic cell %" Keduction occurs at cathode in either o) cells '" :*idation occurs at cathode in either o) cells Which o) the )ollo=ing statements is correct D 1" Cathode is negati$e terminal @oth in gal$anic and electrolytic cells #" Anode is +ositi$e terminal @oth in gal$anic and electrolytic cells %" Cathode is negati$e terminal in an electrolytic cell =hereas anode is negati$e terminal in a gal$anic cell '" Anode is negati$e terminal in an electrolytic cell =here as cathode is +ositi$e terminal in a gal$anic cell. T=o hal) cells ha$e +otentials 5,.01 2 and 5,.1%2 res+ecti$ely. A gal$anic cell is made )rom thses t=o hal)-cells . =hich o) the )ollo=ing statements is correct D 1" Electrode o) hal)-cell +otential 5,.01 2 ser$es as cathode. #" Electrode o) hal)-cell +otential 5,.01 2 ser$es as anode. %" Electrode o) hal)-cell +otential 5,.1% 2 ser$es as cathode. '" Electrode o) hal)-cell +otential 5,.01 2 ser$es as +ositi$e electrode and ,.1% 2 as negati$e electrode. Ii$en ! E, 8Cu#.9Cu" / ,.%%0 2 and E, 8Sn#.9Sn" / -,.1%1 2 =hich o) the )ollo=ing statements is correct D 1" Cu#. ions can @e reduced @y <#8g" #" Cu can @e reduced Sn#. %" Cu can @e o*idiGed @y <. %" Sn#. ions can @e reduced @y <# 8g" The reduction +otential o) the hydrogen hal)-cell =ill @e negati$e i) 1" +8<#" / 1 atm and [<.] / 17 #" +8<#" / 1 atm and [<.] / #7 . %" +8<#" / # atm and [< ] / 17 '" +8<#" / #atm and [<.] / #7 #. Ay ho= much =ill @e +otential o) hal)-cell Cu 9 Cu change i) the solution is diluted to 1,, times at #C, 6 D 1" Increase @y 4C m2 #" &ecrease @y 4C m2 %" Increase @y #C.4 7$ '" &ecrease @y #C.4 m2 Ii$en that EH #O N# pt = , at #CB 6 . the +ressure o) <# gas 1" 1,-0 atm #" 1,-1, atm %" 1,-1# atm '" 1,-1' atm The $alue o) EH #O H # apt 81atm " pt at #CB 6 =ould @e 1" 5,.#.0 2 #" 5,.'1' 2 %" ,.#,0 2 '" ,.'1' 2 , , , Ii$en that E Fe%+ Fe and E Fe#+ Fe are 5,.,%1 2 and -,.'%C 2 res+ecti$ely. The $alue o) E Fe%+ . Fe+% pt =ould @e 1" 8- ,.,%1-,.'%C"2 #" 8-,.,%1.,.'%C"2 %" [%8-,.,.%1".#8-,.'%C"]2 '"[%8-,.,%1-#8-,.'%C"]2

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A current o) C.14 A is dra=n )rom a &aniell cell )or e*actly 1hr. I) molar masses o) Cu and -n are 1%.4g mol-1 and 14.'g mol-1 res+ecti$ely the loss in mass at anode and gain in mass at cathode res+ecti$ely are 1" 11.'%g 11.0g #" 11.00g 11.'%g %" ##.B1g #%.4'g '" #%.4'g ##.B1g When CuCl# =as electrolysed using Cu electrodes the mass o) cathode is increased @y %.1Bg. =hat ha++ed at the anode D 1" ,.41 lit o) :# =as li@erated #" ,.41 lit o) Cl# =as li@erated %" ,.1 mole o) dissol$es Cu.# '" ,.,4 mol dissol$es as Cu.# Weight o) +roduct o@tained at cathode and anode are in the ratio 1" 1.B #" B.1 %" 1.11 '" 11.1 1, am+. o) current +assed )or 1, minutes de+osited 1g o) metal )rom its salt solution. The ECE o) that metal is ! 1" 1,-% #" 1 1,# %" # 1,1 '" 1.,# 1,% A cell contains t=o hydrogen electrodes. The negati$e electrode is in contact =ith a solution o) 1, -1 7 hydrogenous solution. The E73 o) the cell ,.11, 2 at #CB 6 . the concentrated o) <. ions at the +ositi$e electrode is 1" 1,-4 7 #" 1,-1 7 %" 1,-' 7 '" 1,-% 7 #. Electrode +otential o) co++er electrode =here the conc. :) Cu is 47 is HHHHHHHHHHH 2 i) E , o) Cu#. or Cu is ,.%' 2 1" ,.%1 2 #" 5,.%1 2 %" ,.'4 2 '" 5,.'4 2 #. Standard E73 o) the cell 3e 9 3e is ,.''2 =here as standard E73 o) the cell Cu 9 Cu #. is 5 ,.%#2. then 1" Cu o*idiGes 3e#. ion #" Cu#. o*idiGes ion %" Cu reduce 3e#. ion '" Cu#. ion reduces ion Certain >uantity o) current has li@erated 11.# lit :# same current can de+osit ho= many moles o) 7g 1" 1 #" # %" ,.4 '" ' Ii$en the E, $alues o) Ag.9 Ag 6.9 6 7g#.9 7g and Cr.%9 Cr are ,.B,2 -#.C% 2 -#.%B2 and 5 ,.0' 2 res+ecti$ely. Which o) the )ollo=ing order regarding the reducing +o=ers o) metal is correct. 1" Cr F Ag F 7g F 6 #" Ag E Cr E 7g E 6 %" Ag F Cr F 6 F 7g '" Cr F Ag F 7g F 6 T=o electrolytic cells one containing acidi)ied )errous chloride and another acidi)ied )erric chloride in series. The ratio o) ion de+osited at cathode in the t=o cells =ill @e ! 1" %!1 #" #!1 %" 1!1 '" %!# &uring the charging o) a lead storage @attery the reaction occurring at the cathode is re+resented @y ! #+ # 1" Pb #+ + #e Pb #" Pb + SO' PbSO'
+ %" Pb Pb #+ + #e '" PbSO' + # H #O # PbO# + # H # + SO' + #e The most acti$e metals are e*tracted )rom their ores @y the +rocess o) reduction 1" =ith Cr #" =ith C %" =ith <# '" Ay electrolysis <o= long =ill it taLe a current o) # am+ to de+osit all the sil$er )rom 4,, ml o) normal Ag(: % solution 1" #'1#4 sec #" 'B#4, sec %" 1#,,, sec '" C11,, sec 3or the electrolytic +roduct o) (aCl: ' )rom (aCl:% according to the reaction NaClO% + H #O NaClO' + H # ho= many )aradays o) electricity =ould @e re>uired to +roduce ,.4 mole o) (aCl:' 1" 1 #" # %" 5 % '" 1.4 When an a>ueous solution o) lithium chloride is electrolyGed using gra+hite electrodes ! 1" +< o) the resulting solution increases #" +< o) resulting solution decreases. %" as the current )lo=s +< o) the solution around the cathode increases '" as the current )lo=s +< o) the solution around the anode decreases. Electrochemical e>ui$alent o) a di$alent metal is %., 1,-' =hat is the a++ro*imate atomic =eight o) the metal! 1" 1,0.B #" 1%.1 %" 4B '" 44.B The $alues o) the standard o*idation electrode +otentials o) the )ollo=ing reaction are gi$en ! 1" Cu Cu #+ + #e E , = ,.%'4V #" Sn Sn #+ + #e E , = +,.1%1V

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%" Fe Fe #+ + #e E , = +,.'',V '" Zn Zn #+ + #e E , = +,.01#V =hich one o) the )ollo=ing is most easily reduced ! 1" Cu.# #" Sn.# %" 3e.# '" -n.# A gal$anic cell is made u+ to S.<.E. and another hydrogen electrode. The other hydrogen should @e immersed in =hich o) the )ollo=ing solutions to get ma*imum $alues o) e. m. ) 1" ,.1 7 <Cl #" ,.17 C<'C::< %" ,.17 <#S:' '" ,.17 <%;:' It is +ossi@le to increase Zn8 s " + Cu #+ 8 aq " Zn # + 8 aq " + Cu8 s " the $oltage o) a cell in =hich the reaction is

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1" concentration o) -n#. #" concentration o) Cu#. %" siGe o) the -n electrode '" siGe o) the Cu electrode The e.m.) o) a concentration cell consisting o) t=o Gine electrodes one di++ing into 79' solution o) Ginc sul+hate and the other 7911 solution o) the same salt at #4,C is 1" ,.,1#' $ #" ,.,#4, 2 %" ,.,10B 2 '" ,.,%41 2 , , Ii$en that E / - ,.,%42 the )ree energy change I )or the reaction Fe%+ + %e Fe8 s " is ! 1" 1,.'# 6J #" 4.1# 6J %" #,.B' 6J '" %.'0 6J The measured $oltage o) the cell Cd9Cd.# 81.,79 <.8D"9<#81., atm" ;t is ,.##, 2. What is the +< o) this solution D Cd a" Cd + 8 aq " + #e E , = ,.',,V H# 8g" @" # H + 8 aq " + #e E , = ,.,,V 1" %.,' #" %.0# %" 1.4# '" #.#% -inc is coated o$er iron to +re$ent rusting o) iron @ecause 1" it is chea+er than iron #" E , = Zn #+ 9 Zn" = E , 8 Fe # + 9 Fe" %" E , 8 Zn #+ 9 Zn" < E , 8 Fe #+ 9 Fe" '" E , 8 Zn # + 9 Zn" > E , 8 Fe # + 9 Fe" Which o) the )ollo=ing statements a@out this cell is incorrect D E , cell = +#.#BBV U 9 U +% = Ag + 9 Ag Ag Ag + + e E , = +,.0CC1V 1" E, cell )or the M.%9M hal)-reaction is 51.0BC 2 #" this is a gal$anic or $oltaic cell %" the M.%9M hal)- reaction occurs at the anode. '" I, )or this cell is +ositi$e What is the o$erall cell reaction )or the cell D Cr8s" 9 Cr.%817" 99 Ar- 817" 9 Ag Ar8s" Ag 1" Cr + % AgBr Cr +% + % Ag + %Br #" % Ag + Cr +% % Ag + + Cr +% %" Cr + % Ag + Cr +% + % Ag '" #Cr + %Br# #Cr + 1 Br <ydrogen electrodes are +laced in t=o solutions o) +</% and +</B at #4 ,C. A salt @ridge linLs the solutions. What is the e.m.). o) the cell thus constructed D 1" ,.%#0 2 #" ,.#C4 2 %" 5,.#00 2 '" ,.100 2 A hydrogen electrode is di++ing in a ,., 1( solution o) < #S:'. it is cou+led through a salt @ridge =ith a normal calomel electrode 8SK; / ,.#B2" =hat is the e.m.). o) the cell at #4,C 1" ,.%CB# #" ,.#B,%2 %" ,.%,%B 2 '" ,.#,B% 2 E, (i9(i.# / ,.#%1 2. i) this electrode is clu@@ed =ith hydrogen electrode =hat should @e the +< o) the acid in <# electrode to gi$e Gero cell +otential at #4,C 1" # #" 1 %" B '" ' A metal has EK; / - ,.01 $ and metal A has EK; / ,.B 2 =hich is correct D 1" A can li@erated <# )rom acid #" A can li@erated <# )rom acid %" Aoth A and A can li@erated <# )rom acid '" (on can li@erated <# )rom acid The molar conductance o) <Cl (aCl and C<%C::(a at in)inite dilution are '#1 1#1 and C14 cm# mole-1 res+ecti$ely. The molar conductance o) C<%C::< at in)inite dilution is HHHHHHs cm#mol-1 1" 411 #" %C1 %" #11 '" 11#

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1,4. 1,1. 1,0.

1,B.

The $alue o) molar conductance o) <Cl is greater than that o) (aCl a +articular tem+erature and dilution @ecause 1" 7= o) <Cl E 7= o) (aCl #" M<. F M(a. %" <Cl is acid '" <Cl ioniGes more than (aCl The )ormula = V 9 is $alid )or 1" =eaL electrolytes #" strong electrolytes %" salts '" all The increase in the molar conducti$ity o) <Cl =ith dilution is due to 1" increase in the sel) ioniGation o) =ater #" hydrolysis o) <Cl %" decrease in the sel) ioniGation o) =ater '" decrease the inter ionic )orces The unit o) cell constant is 1" ohm-1 #" ohm cm %" cm-1 '" ohm-1cm#a>-1 Mnit o) s+eci)ic conductance is 1" ohm-cm #" ohm-1cm %" ohm-1cm-1 '" ohm cm-1 =hich has ma*imum conducti$ity 1" [Cr 8 NH % "% Cl% ] #" [Cr 8 NH % " ' Cl# ]Cl %" [Cr 8 NH % "4 Cl ]Cl# '" [Cr 8 NH % " 1 Cl ]Cl% The s+eci)ic conductance o) ,.,1 ( 6Cl is N ohm -1cm-1 ha$ing conductance O ohm-1.The s+eci)ic conductance o) ,.,1 ( (aCl ha$ing conductance - ohm-1 is 1" O*9#" -*9O %" -9O* '" (one E>ui$alent conductance o) 17 C<%C::< is 1, ohm-1cm#e>-1 and that at in)inite dilution is #,, ohm-1cm#e>-1. <ence P o) ioniGation o) C<%C::< is 1" 4P #" #P %" 1P '" ' P E>ui$alent conductance o) saturated AaS:' is ',, ohm-1cm-# e>-1 and s+eci)ic conductance is B 1,4 ohm 1cm 1 . <ence 6s+ o) AaS:' is 1" ' 1,B M # #" 11,B M # %" # 1,' M # '" 11,' M # The correct order o) e>uai$alent conductance at in)inite dilution o) JiCl (aCl 6Cl is 1" JiCl F (aCl F6Cl #" 6Cl F (aCl F JiCl %" (aCl F 6Cl F JiCl '" JiCl F 6Cl F (aCl &uring electrolysis o) CuS:' a> Q g atoms o) Cu.# is reduced to Cu =hen HHHHHHHHHH coulom@s o) electricity is +assed. Cd amalgam is +re+ared @y electrolysis o) a solution o) Cd Cl # using a mercury cathode. 3ind ho= long should a current o) 4 am+. is +assed in order to +re+are 1#P Cd-<g amalgam on a cathode o) #g mercury. At =t. :) Cd/11#.' Ans. C%.04 sec. % am+. Current =as +assed through an a>ueous solution o) an unLno=n salt o) ;d )or 1 hour. #.C00 g o) ;d.n =as de+osited at cathode. 3ind RnS at =t. o) ;d/ 1,1.' Ans. ' A -n rod =eighing #4gm =as Le+t in 1,,ml o) 17 CuS: ' solution. A)ter a certain time the molarity # o) Cu.# in solution =s ,.B =hat =as molarity SO' =hat =as the =eight o) -n rod a)ter cleaning D at =t. o) -n / 14.' Ans. #%.1C# A)ter electrolysis o) a sodium chloride solution =ith inert electrode )or a certain +eriod o) time 1,, ml o) the I( solution =as le)t =hich =as )ound to @e (a:<. &uring the same time %1.B,g Cu =as de+osited in co++er $olta meter in series =ith the electrolytic cell. Calculate the P o) (a:< o@tained. At =t. :) Cu 1%.1 Ans. 4, P An acidic solution o) Cu.# salt containing ,.'g o) Cu.# is electrolyGed until all the Cu is de+osited. The electrolysis is contained )or se$en more minutes =ith the $olume o) solution Le+t at 1,,ml and the current at 1.#am+. Calculate $olume o) gases e$ol$ed at (T; during entire electrolysis. At =t. o) Cu 1%.1 Ans. 14B ml &uring the discharge o) a lead storage @attery. The intensity o) sul+huric acid )ell )rom 1.#C' gml to 1.1%Cgm9ml and sul+huric acid o) density 1.#C' gm9ml is %CP @y =eight and that o) density 1.1%C gm9ml is #,P @y =eight the @attery taLes %.4 litre o) acid and the $olume +ractically remained constant during discharge. Calculate the no. o) am+ere hour )or =hich the @attery must ha$e @een used. The charging and discharging reaction are Pb + SOH # PbSO' + #e charging PbO# + H + + SO'# + #e PbSO' + # H #O discharging Ans. #14.,' am+9hr

1. #. %. '.

4.

1.

0.

B. C.

1,.

11.

1#.

1%.

1'. 14.

11. 10.

,.4 3araday o) electricity =as +assed to de+osit all the co++er +resent in 1,,ml o) CuS: ' solution. What =as the molarity o) this solution Ans. ,.47 In starting a car the @attery deli$ers roughly 1, am+. 1" &uring the 4 seconds that might taLe to start a car ho= many gram total o) ;@ and ;@: # and consumed in the @attery. II" I) the car =ere run strictly )rom @atteries. <o= many gram total o) ;@ and ;@: # =ould @e consumed +er 6m it 4, am+. 7ade it to go at 4 6m +er hour. The cell reaction is Pb + PbO# + # H # SO' PbSO' + # H #O Ans. B%.1C gm I"What is the =eight o) sodium @romate and molarity o) solution necessary to +re+are B4.4 ml o) + ,.10# ( solution =hen the hal) cell reaction is BrO% + 1 H + 1e Br + %H #O II" =hat =ould @e the =eight as =ell as molarity i) the hal) cell reaction is # BrO% + 1# H + + 1,e Br# + 1 H #O Ans. ,.11#7 ,.1%''7 An o*ide o) metal 8 at.=t. / 11#" contain 1#.4P :# @y =eight. The o*ide =as con$erted into chloride @y treatment =ith <Cl and electrolysed. Calculate the amount o) metal that =ould @e de+osited at cathode i) a current o) ,.C14 am+ =as +assed )ro a +eriod o) 4 hours. What is $alency o) metal D Ans. 1,.,Bgm An element A 8atomic mass 11#" and element A 8 atomic mass #0" )orm chlorides solution o) these chlorides are electrolysed se+arately and it is )ound that =hen the same >uantity o) electricity is +assed 4.1 grm o) A =as de+osited =hile in other cell only ,.Cgr. o) A =as de+osited. What is $alency o) A is %. Ans. # The density o) co++er is B.C'g9ml. )ind out the num@er o) coulom@s needed to +lace an area o) 1, 1,cm # to a thicLness o) 1,-# cm using CuS:' solution as electrolyte. At =t. o) Cu / 1%.1. Ans. #01#C C <o= many grams o) sil$er could @e +lated out on a ser$ing tray @y electrolysis o) solution containing sil$er in .1o) B.'1 am+.What is the area o) the tray i) the thicLness o) the sil$er +lating is ,.,,#' cm. &ensity o) sil$er is 1,.4 g9cm% Ans. 1.,# 1,'cm# Calculate the >uantity o) electricity in coulom@ =hich li@erates enough hydrogen at the cathode during electrolysis o) acidi)ied =ater so that it can )ill a @alloon o) ca+acity 1, litres at a +ressure o) 1.4 atmos+here at #0,C. i) the o*ygen li@erated is com+leted used ion @urning methane calculate is the $olume o) methane at ST; =hich is @urnt. Ans. 1.104 1,4C %.''P An o*ide =as con$erted into chloride and then solution =as electrolysed. Calculate the amount o) metal that =ould @e de+osited at the cathode i) a current o) ,.%1B am+ere =as +assed )or a +eriod o) 4 hrs. =hat is the $alency o) metal D =hat =ill @e the )ormula o) o*ide D Ans. %.%1gm % When B,', coloum@ o) electricity is +assed through molten 73# %.14#g o) metal =as de+osited. What is the atomic =eight o) metal D ho= much o) electrons +ass through the cell in de+osition o) metal D Ans. B0.11 ;er disul+huric acid 8<#S#:B" can @e +re+ared @y electrolytic o*idation o) < #S:' as H # SO' H # S #OB + # H + + #e and :# and <# are @y +roduct. In such an electrolysis ,.B0 gm o) < # and %.%1 gm o) :# =ere generated at ST;. Calculate the total >uantity o) current +assed through solution to carry out electrolysis. Also re+ort the =eight o) <#S#:B )ormed. Ans. B%C44C '%.14gm

1B.

1C.

A 1,, =att 1,, $olt incandescent lam+ is connected in series =ith an electrolytic cell containing CdS:' solution. What =eight o) Cd =ill @e de+osited @y current )ollo=ing )or 1, hrs. At =t. o) Cd / 11#.' Ans. 1C.,1gm A current o) 14 am+ere is used to +late (i )rom (iS: ' @ath. Aoth <# and (i are )ormed at cathode. The current e))iciency o) (i )ormation is 1, P 1" <o= many grm. o) (i is +lated +er <our D #" What is the thicLness o) +lating o) cathode consists o) a sheet o) cm # =hich is coated on @oth sidesD The density o) (i is B.C g9ml

#,.

%" What $olume o) <# is )ormed +er hr. at ST;D '" What $olume o) :# is )ormed +er hr. at ST;D Ans. C.B4 gm ,.1%Bcm #.41' P %.1%' P #1. ##. A current o) %.0 am+. Is +assed )or si* hrs @et=een (i electrodes in ,.4 litre o) #7 solution o) (i8(,%"# =hat =ill @e the molarity o) solution at the end o) the electrolysis. 8Ans. #7" In a )uel cell <# and :# react to +roduce electricity in the +rocess <# gas is o*idised at the anode and :# at the cathode. I) 10.# litre o) <# at ST; reacts in 14 minutes =hat is a$erage current +roducedD I) the entire current is used )or electro de+osition o) Cu )rom Cu .#. ho= many I o) co++er are de+osited. Cathode ! O# + # H #O + 'e 'OH
Anode ! H # + #OH # H #O + #e Ans. 1C, gm A current o) 1.0,A is +assed through %,, ml o) ,.11' solution o) -nS: ' )or #%, sec. =ith a current o) e))iciency o) C, P .)ind the molarity o) -n .# a)ter the de+osition o) -n. Assume the $olume o) the solution remains constant during electrolysis. Ans. ,.14'7 1,g )airly concentrated solution o) CuS:' is electrolysed using ,.,1 )araday o) electricity. Calculate 1" the =eight o) resulting solution #" the no. o) e>ui$alents o) acid or alLali in solution at. Weight o) Cu / 1%.4.8Ans. C.1,#gm ,.,1" An electric current is +assed through t=o solution o) I" Ag(: % and ii" a solution o) 1, g CuS: ' 4<#: crystals in 4,, ml <#: +latinum electrodes @eing used in each case. A)ter %, minutes it is )ound that 1.%,0 g Ag has @een de+osited. That =as the conc. o) Cu .# e*+ressed in gm o) Cu.# reacts in the solution a)ter the electrolysis. Ans. '.%gm ' P 4, ml o) ,.17 CuS:' solution is electrolysed using ;t. electodes =ith the current o) ,.C14 am+. 3or a +eriod o) 1 minute. Assuming that $olume o) solution does not change during electrolysis # calculate [Cu.#]. [<.] and [ SO' ] a)ter electrolysis. What =ill @e the concentration o) each s+ecies i) current is +assed using Cu electrodes D Ans. ,.1 An a>ueous solution o) (aCl an electrolysis gi$es <#8g" Cl#8g" and (a:< according to reactions #Cl 8aq " + # H #O #OH 8aq " + H #8 g " + Cl#8 g "

#%. #'. #4.

#1.

#0.

#B.

#C.

%,. %1.

%#.

A direct current o) #4 am+ere =ith a current e))iciency o) 1# P o) +assed through #, $olume o) (aCl solution #, P @y the =eight. 1" =rite do=n the reaction taLing +lace at the electrodes #" <o= long =ill it taLe to +roduce 1 6g o) Cl# %" What =ill @e the molarity o) solution =ith res+ected :< - assumes no loss in $olume due to e$a+oration . A lead storage )attary is discharged =hich causes the < #S:' electrolyte to change )rom a concentration o) %'.1 P @y =eighted / 1.#11gm9ml at #4 ,C to one o) #0P @y =eight. The original $olume o) electrolyte is one liter. <o= many )aradays ha$e le)t the anode o) @attery (ote the =ater is +roduced @y the cell reaction as <#S:' is used u+ o$er all reaction is Pb8 s " + Pb#O + # H # SO'81" # PbSO'8 S " + # H #O Ans. 1.#443 Chromium metal can @e +lated out )rom an acidic solution containing Cr: % according to )ollo=ing + e>uation CrO%aq + 1 H + 1e Cr8 s " + %H #O Ans. #.144'gm 1%%1.14sec a" ho= many grams o) chromium =ill @e +lated out @y #',, coulom@D @" ho= long =ill it taLe to +late out 1.4g o) Cr @y using 1#.4 am+. Current D 1C g )used SnCl# =as electrolyGed using inert electrodes ,.11C g Sn =as de+osited at cathode. I) nothing =as gi$en out during electrolysis calculate the ratio o) =eight o) SnCl # and SnCl' in )used state a)ter electrolysis. Ans. 01.%' In an electrolysis e*+eriment current =as +assed )or B hours through t=o cells connected in series. The )irst cell contains a solution o) gold and the second contains CuS: ' solution. C.B4gm o) gold =as de+osited in the )irst cell. I) the o*idation no. o) gold is .% )ind the amount o) Cu de+osited in cathode in second cell. Also calculate the current strength in am+. At =t. o) Au / 1C0 and at =t. Cu / 1%.4 Electrolysis o) solution o) 7nS:' in a>ueous sul+huric acid is a method )or the +re+aration o) 7n: # +# + as +er reaction. Mn8 aq " + # H #O MnO#8 S " + # H 8 aq " + H # 8 g " +assing a current o) #0A )or #' hours

%%.

%'.

%4.

%1. %0.

%B. %C. ',.

'1.

gi$es one 6g o) 7n:#. =hat is the $alue o) current e))iciency . =rite the reaction taLing +lace at the cathode and at the anode the reaction. A current =as )lo= )or # hours through a 6I solution o*idiGing iodide ion to iodine 8 # + #e ". At the end o) the e*+eriment li@erated iodine consumed #1.04 ml redo* change # + S 'O1# . What =as the a$erage rate o) current )lo=n in am+ere D # + # S # O% # Ans. ,.,#'# am+. A current o) #,., A is used to +late (i )rom (iS: ' solution. @oth (i and <# are li@erated at cathode. The current e))iciency =ith res+ect to li@eration o) (i is 4, P . 8a" =hat mass (i is +lated on cathode +er hour D 8@"=hat is the thicLness o) +lating ion on @oth the sides o) mass o) the s>uare cathode o) edge length ' cmD Ii$en atomic mass o) (i / 4B.0C amu and its density / B.C g cm-# Ans. ,.,%B4gm In the electrolysis o) a CuS:' solution there are t=o +ossi@le reactions at the anode + 1" Cu Cu #+ + #e #" # H #O O# + ' H + 'e A current o) 1., A is +assed )or #hrs. the loss in mass o) the Cu anode =as 1.4,g.. ho= much $olume o) o*ygen at ST; =as li@erated D =hat )raction o) current is used in the +roduction o) Cu #. ions D Ans. ,.1%% A current o) 1,., A is +assed through 1.litre o) 1.,7 <Cl solution )or 1 hours. Calculate the +< o) the solution at the end o) e*+eriments. What is the $olume o) the total gas e$ol$ed at ST; D Ans. B%1, ml A sam+le o) gadolinium metal 8atomic mass / 140 amu" is dissol$ed in hydrochloric acid and the resulting solution is electrolyGed. When 11,BC has +assed through the cell ,.B0g o) gadolinium is )ound to @e de+osited at the cathode. Calculate the charge num@er on the gadolinium ion. Ans. % Anthracene 8C1'<1," can @e o*idiGed anodically to anthrac>uine 8C1'<B:#". What =eight o) Anthra>uinone can @e +roduced @y +assage o) a current o) 1 am+. )or 1, minutes. It current e))iciency is B, P . Ans. 1.,%'1 gm %, ml o) ,.1%7 (iS:' is electrolysed using a current o) %1, mille am+ere )or %4.% minutes. <o= much o) the metal =ould ha$e @een +lated out it current e))iciency =as only 1, P at =t. o) (i / 4B.0 Ans. ,.1%C1 gm 1# JaLe Cayuga has a $olume o) =ater estimated to @e B.# 1, litre. A +o=er station not so )ar a@o$e CayugaSs =ater +roduces electricity at the rate o) 1.4 1,1 coulom@ +er second. at an a++ro+riate $oltage. <o= long =ould it taLe to electrolyses the laLe D Ans. 1.B1 1,1 years Pb + SO'# The electrode reactions )or charging o) a lead storage @attery are PbSO' + #e
# PbO# + SO' PbSO' + # H #O + ' H + + #e The electrolyte in the @attery is an a>. Solution o) sul+huric acid . Ae)ore charging the s+eci)ic gra$ity o) li>uid =as )ound to @e 1.11 g9 ml 814.0 P < #S:' @y =eight" a)ter charging 1,,hrs. the s+eci)ic gra$ity o) li>uid =as )ound to @e 1.#Bgm9ml 8%1.CP <#S:' @y =eight" i) the @attery holds t=o litre li>uid calculate a$erage current used )or charging @attery. Assume that $olume remains constant during charging. Ans. 1.1% am+. Co++er sul+hate solution 8#4, ml" =as electrolysed using a +latinum anode and co++er cathode a constant current o) # m A =as +assed )or 11 minutes. It =as )ound that a)ter electrolysis the a@sor@ance o) the solution =as reduced to 4, P o) its original $alue calculate the concentration o) co++er sul+hate in the solution to @egin =ith. The )ollo=ing electrochemical cell has @een set u+ Pt81" 9 Fe +% Fe +# 8a = 1" 99 Ce +' Ce +% 8a = 1" 9 Pt8#"

'#.

'%.

''. '4. '1.

E , 8 Fe +% Fe +# " = ,.00V E , 8Ce +' Ce +% " = 1.11V I) an ammeter is connected @et=een the t=o +latinum electrodes. ;redict the direction o) )lo= o) current =ill the current increases or decrease =ith time. Ans. 8 -1.,'2" , , . Calculate E hal) cell Ag9Ag(:% 8 ,.1" i) E Ag 9Ag/1.12 +# +# Calculate Ecell )or Co Co,.,1M 99 Pd ,.4 M Pd Ii$en that E , Co +# 9 Co = ,.#BV E , Pd +# 9 Pd = ,.CCV Calculate the e.m.). o) the )ollo=ing cells at #4,C. Ans. 1.%#2 +# +# 1" Fe Fe,.% M 99 Sn Sn,.1M #" Fe FeSO'8 a =,.1" 99 CuSO'8 a =,.,,1" 9 Cu

%" PtH #8# atm " 9 HCl 9 H # Pt81, atm "

, , , EopH EOP Fe EOPCu and EOPSn are, ,.'' ,.%%0 and ,.1'V respect!"el#

'0. 'B.

Ans. ,.#B12 ,.0'042 -,.,#,12 The standard electrode +otential o) Cu- Cu.# is 5,.%'2olt. at =hat concentration o) Cu.# ions =ill this electrode +otential @e Gero D Ans. #.,B 1,-1#7 , Calculate the e>uili@rium constant at #4 C )or the reaction ! % 1" Hg # 8 NO% " # + # Fe8 NO% " # # Hg + # Fe8 NO% "
# 9 Hg = ,.0CV and E , Fe +%9 Fe Ii$en E , Hg + #
+#

= ,.00V + +# 8,.1 M "

Ans. '.C1

'C.

4,. 41.

4#. 4%.

+ H #8 g " 81atm" is ,.#B 2 at The e.m.). o) a cell corres+onding to reaction Zn8 S " + # H 8 aq " Zn , , .# #4 C and E -n9 -n / ,.01 2 1" =rite hal) cell reactions #" Calculate +< o) the solution at < electrode. Ans. B.1%4 +# +1 , .# Calculate the e>uili@rium constant )or the reactions! Cu + Cu #Cu gi$en E Cu 9Cu / ,.%'2 E, Cu.9Cu / ,.14 2 Ans. #.04 1,1 , .# , .# The E )or -n 9 -n and E )or Cu 9Cu are 5,.01 and ,.%'2 res+ecti$ely at #4 ,C. =hen e*cess o) -n is added to a solution o) CuS:' the Ginc dis+laces Cu till e>uili@rium is reached. What is the ratio o) concentration o) -n.# and Cu.# ion at e>uili@rium D Ans. 1.C'# 1,%0 !1 + The reaction H # + Cl# + # H #O # H %O + #Cl has e>uili@rium constant 6 / 1, '1 at #4,C. Calculate E, at #4,C )or the cell. Pt 8 H # " 9 HCl8 aq " 99 Cl# 9 Pt Ans. 1.%402 At #4,C the )ree energy o) )ormation o) <#: is 5410,, cal. mole-1. =hile that o) its ionisation to 8<. .:<-" is 1C,4, cal mol-1=hat it the re$ersi@le e. m. ) o) the cell at H #8 g " 981 atm" H + 99 OH O#8 g " 981 atm" Ans. ,.',42
+# +# +% The e. m. ) o) cell gi$en @elo= is 1.01 $olts at #4,C. Zn,.,1M 9 Zn ,.,,1M 99 Fe ,.,,1M 9 Fe ,.,1M Pt +# +# , Calculate e>uili@rium constant o) the cell reaction Zn + # Fe +% Zn + # Fe at #4 C. Ans. C.#4 1,4% O# 8 g " + ' H + + 'e # H #O is 1.#%2 in ,.1( strong acid The +otential )or the reaction ! solution. calculate the +otential o) this cou+le in a>ueous solution o) 1" +< / 1, #" +< / 1' Ans. ,.1CC2 ,.'1%2 11 3or AgI the solu@ility +roduct $ SP = 1 1, =hat =ill @e the electrode +otential o) Ag. 9 Ag , electrode at #4 C in a saturated solution o) AgI in =ater D E, Ag. 9 Ag / ,.B, 2 Ans. ,.%#B2 A sil$er =ire di++ed in ,.17 <Cl solution saturated =ith AgCl de$elo+s a +otential o) 5,.#4,2. calculate 6S; o) AgCl in+ure Water i) E, Ag 9 Ag. / -,. 0CC 2 Ans. '.C4 1,-11 The e. m. ). o) a cell ;t < # 9 <Cl 99 AgCl 8s" 9 Ag is ,.,%4#4 2 at #0 ,C and ,.,%0,4 2 at 10,C calculate heat o) reaction at #0,C. Ans. 5B.11%6J9mole The e.m.). o) the cell Ag9 AgCl 9 6Cl a> 99 < #Cl#9 <g is ,.,'44 2 at #CB 6 and the tem+erature coe))icient is %.%B 1,' V$ 1 . What 8a" reaction is taLing +lace 8@" is )ree energy change 8c" is enthal+y change 8 d" is entro+y change. Ans. 5B.0B6J 1,.146J 14.##J96 , ZnCl# + # Ag is 54#.,4 Cal. I) the e.m.) o) the The H )or the reaction at , C Zn + # AgCl cell is 1.,14 2olt =hat is tem+erature coe))icient o) the cell at ,,C D Calculate the +otential o) a cell in =hich < electrode is im+ressed in a solution =ith a +< o) %.4 and in a solution =ith a +< o) 1,.0. Ans. ,.'#42 E, o) some reactions are gi$en @elo= ! E , = + ,.4'V 1" # + #e # #" Cl# + #e #Cl

4'.

44.

41.

40. 4B. 4C.

1,. 11. 1#.

E , = + 1.%1V E , = + ,.00V E , = + 1.1,V E , = + ,.14V

%" Fe +% + e Fe +# '" Ce +' + e Ce +% 4" Sn +' + #e Sn +#

1%. 1'.

Answer !e "#$$#w%n& '(es %#ns ) a" Strongest o*idant and =eaLest o*idant. @" Strongest reductant and =eaLest reductant c" =ill 3e.% o*ides Ce.% d" =ill I# re+lace Cl# )rom 6Cl D e" What reaction =ill occur i) SnCl# and 3eCl% are mi*ed D )" Will I# @e set )ree ion addition o) 3eCl% in 6I% D Ans. a" Ce.' Sn.' @"Sn.# Ce.% c" (: d" (: )" Oes &issociation constant )or Ag8(<%".# into Ag. and (<% is 1 1,1' . Calculate Ag + + e Ag has E , = ,.0CCV Ans. ,.,1C 2 The o$erall )ormation constant )or the reactions o) 1 mol o) C( =ith co@alt 8II" is 11,1C . Calculate the )ormation constant )or the reaction o) 1 mol o) C(- =ith co@alt 8III". Ii$en that Co8CN " % + e Co8CN "1 ' E , %P = ,.B%V Co +% + e Co +' E , %P = 1.B#V Ans. 1. 1,%4 Consider the reaction ! # Ag + + Cd # Ag + Cd +# . The standard reduction +otential o) Ag + Ag and Cd +# Cd . Cou+les are .,.B, and 5,.', $olts res+ecti$ely. 1" =hat is the standard cell e.m.). E, D #" =ill the total e.m.). o) the reaction @e more .$e or 5$e i) conc. o) Cd.# is ,.1 7 rather than 17. Ans. 1.# P The standard o*idation +otential o) (i9(i.# electrode is ,.#%12 i) this is com@ined =ith a hydrogen electrode in acid solution at =hat. +< o) the solution =ill the measured e.m.). @e Gero at #4 ,C assure 8 (i.#" / 17 Ans. +< / ' e.m.). o) cell Ag9 Ag I 8s" ,.,4 76I 99 ,.,47 Ag(: % 9 Ag is C.0%B2. calculate solu@ility +roduct o) Ag I. Ans. 1.1 1.-11 , A Ginc electrode is di++ed in a ,.17 solution at #4 C. among that salt is dissociated to #,P at this dilution calculate the electrode +otential. E, -n.# 9 -n / -,.01 2. Ans. ,.B2 A cell is containing < electrodes. The negati$e electrodes is in contact =ith a solution o) 1,-1 7 <. ion. The e m ) o) the cell is ,.11B $olts at #4,C. calculate [ <.] at +ositi$e electrode. Ans. 1,-'7 3or the gal$anic cell Ag 9 AgCl 8s" 6Cl 99 6Ar. AgAr 9 8s" 9 Ag calculate the em) generated and assign correct +olarity to each electrode )or a s+ontaneous +rocess a)ter taLing and account cell reaction at #4,C. gi$en 6S; / %.% 1,1% AgCl = #.B 1,1, Ans. The edision storage cell is re+resented as 3e8s" 9 3e:8s" 9 6:<8a>"9 (i #:%9 (i:8s" the hal) o) the cell reaction are ! N!#O% + H #O + #e # N!O8 s " + #OH E, / .,.',$ FeO8 s " + H #O + #e Fe8 s " + #OH E, / - ,.B0 2

14.

11. 10. 1B. 1C. 0,.

01.

0#.

0%.

0'.

1"=hat is the cell reaction D #" What is the cell e. m. ). D <o= does it de+end on the conc. o) 6:< D %" What is the ma*imum amount o) electrical energy that can @e o@tained )rom one mole o) (i#:% D Ans. 1.#02 #'46J 3or the cell 7g8s" 9 7g.#9 8a>" 99 Ag.8a>" 9 Ag8s" calculate the e>uili@rium constant. At #4, C o) and the ma*imum =orL that can @e o@tained during o+eration o) cell . gi$en E, 7g9 7g.# / .#.%02 and E, Ag. 9 Ag / .,.B,2 K/ B.%1' J Ans. 1.11B 1, 6J + The standard reduction +otential )or the hal) cell NO% 8 aq " + # H + e NO# 8 g " + H #O is ,.0B2. 1"Calculate the reduction +otential in B7<. #" =hat =ill @e the reduction +otential o) the hal) cell in a neutral solution . assume all the other s+ecies to @e at unit concentration . Ans. ,.BB1#2 -,.,'12 + 3or the reaction H #8 g " + # AgCl8 s " + # H #O81" # Ag 8 s " + # H %O 8 aq " + #Cl at #4,C the standard )ree energy o) )ormation o) Ag Cl8s" <#:81" and 8<#: . . Cl-" are 51,C0 -#%0.# and 5 %1B.' 6T9mol. .Calculate =hat =ill @e the cell $oltage i) this reaction is run at #4,C and one atmos+here in a cell in =hich <# acti$ity is unity and <%: . a> and Cl- a> acti$ities are each at ,.,1 7 D Ans. ,.'4B2

04. 01. 00.

What is the standard electrode +otential )or the electrode MnO' 97n:# in solution. Ii$en

0B. 0C.

E, MnO' 9 7n.# / 1.412 and E, 7n:# 9 7n.# / 1.#%2 Ans. 1.02 , Ii$en that 6S; 8AgCl" F 6S; 8AgAr" F 6S; 8 Ag I " Sho= that E Cl 9AgCl 9 AgF E, Ar- 9 Ag Ar 9 Ag F E, Ag I- 9 Ag The hal) cell +otential o) a hal) cell A*. A8*.n".9 ;t. =ere )ound to @e as )ollo=s +ercentage o) at reduced )orm #'.' 'B.B Cell +otentially ,.1,1 ,.114 &etermine their $alue. 3rom the standard cell +otential gi$en @elo= calculate the indicate a cell +otential E, ! ,.4'V ,.'4V BrO% 8 aq " BrO 8 aq " O# 9 # Br#8 l " The standard +otential o) the )ollo=ing cell is ,.#%2 at 14,C and ,.#12 at %4,C. ;t 9 <#8g" 9 <Cl 8a>" 9 Ag Cl8s"9 Ag8s" 1" Write the cell reaction. #" Calculate H , and S , )or the cell reaction @y assuming that theses >uantities remain unchanged in the range 14,C to %4,C. %" Calculate the solu@ility o) AgCl in =ater at #4 ,C. gi$en the standard reduction +otential o) the Ag. 8a>" 9 Ag8s" cou+le is ,.B, 2 at #4,C. Com+ute E, )or the )ollo=ing reactions at #CB6 Ag 8 NH % "# + + e Ag + # NH % Ag 8CN " # + e Ag + #CN Ii$en that E, Ag.9Ag / ,.0CC 2
+ Ag + + # NH % Ag 8 NH % " # $ = 1.,# 1,B Ag + + #CN Ag 8CN " # $ = 1.,# 1,1

B,.

B1.

The standard +otential o) the t=o reactions M n + + ne M and M m + + me M are E, 7n.97 and E, 7m.97 are res+ecti$ely assuming n to @e greater than m sho= that the standard +otential o) the nE , M m + 9 M mE , M m + 9 M n+ m+ , . . reaction M + 8n m"e M is gi$en as E 7n 7m ;t / nm

B#. B%.

The em) o) cell -n 9 -nS:' 99 CuS:' 9 Cu at #4,C is ,.,%2 and tem+erature Coe))icient o) em) is 1.' 1,' V +er degree. Calculate the heat o) reaction. T=o electro chemical cell are assem@le in =hich )ollo=ing reactions occur V +# + VO +# + # H + #V +% + H #O E , = ,.1111V V +% + Ag + + H #O VO +# + # H + + Ag E , = ,.'%CV E , Ag + 9 Ag = ,.0CCV Calculate the E, )or hal) reaction V +% + e V +# The em) o) the gal$anic cell. Com+are t=o hydrogen electrodes is #0# milli 2olts. What is the +< o) the solution in =hich the made in immerses i) the cathode is in the solution o) +< / % D Calculate the minimum =eight o) (a:< re>uired to @e added in S.<.S to consume all the <. +resent in K. <.S. o) cell o) e. m. ). .,.0,1 2 at #4,C @e)ore its use also re+ort the e. m.). o) cell a)ter addition o) (a:< -n 9 -n.# 99 <Cl 9 ;t. <# ,.,17 1lit. 1atm. E, -n 9 -n.# / ,.01, 2 Ans. 1.#,'gm ,.%012 Calculate the e. m. ) o) cell ;t. <# 9 C<%C::< 99 (<':< 9 ;t. <# 1 atm ,.17 ,.,17 1 atm 4 4 6a )or C<%C::< / 1.B 1, ? 6@ )or (<':</ 1.B 1, Ans. ,.'4042 The $oltage o) the cell gi$en @elo= is 5,.'12 ;t. <# [8(a<S:% (a#S:%"] 99 -n.# 9 -n 8s" ,.' 7 ,.%7 1.'' 1,% 7 [ H + ][ SO%# ] +# , E = ,.01%V calculate the $alue o) 6# =here $ # = also Zn + #e Zn8 s " [ HSO% ] Ans. 1.'' 1,-B

B'. B4.

B1.

B0.

BB.

BC.

C,. C1. C#.

C%.

The )ollo=ing gal$anic cell =as -n 9 -n8(:%"# 8a>" 99 Cu8(:%"# a> 9 Cu 1,, ml 17 1,, ml 17 :+erated as an electrolytic cell using Cu as anode -n as cathode. A current o) ,.'B A =as +assed )or 1, hours and then the cell =as allo=ed to )unction as gal$anic cell. What =ould the em) o) the cell at #4,C. Assume that the only electrode reactions occurring =here those in$ol$ing Cu 9Cu.# and -n 9 -n.#. Ii$en E, Cu.# 9 Cu / ,.%'2 and E, -n.#9 -n / -,.01 2 Ans. 1.1%02 . E73 o) the cell ;t <#9 <:C( 99 Ag 8s"9Ag is ,.CB#2 1 atm 1.% 1,% 7 ,.B7 Calculate the 6a )or <:C( Ag. .e Ag8s" E, / ,.B,2 Ans. %.%% 1,-' Calculate the >uantity o) electricity deli$ered @y a &aniell call initially containing 1.,J each o) 1.,7 co++er 8II" ions and 1.,7 -inc 8II" ions =hich is o+erated until its +otential dro+s to 1.,2 Ii$en E, 8-n.# 9 -n" / -,.01% 2 and E, 8Cu.#9 Cu" is ,.%'2 Ans. 1.C#C 1,4C The standard reduction +otential )or Cu.#9 Cu / ,.%'2 calculate the standard +otential at +</ 1' )or the a@o$e cou+le 6S; o) Cu8:<"# is 1., 1,1C . Ans. ,.##,4 The standard reduction +otential o) the Ag. 9 Ag electrode at #CB6 is ,.0C# 2 . Ii$en that )or AgI 6S;/ B.0 1,10 . E$aluate the +otential o) the Ag. 9 Ag electrode in a saturated in a saturated solution o) AgI. Also calculate the standard reduction +otential o) the I-9 AgI9 Ag electrode. Calculate the em) o) the cell at #4,C. Pb PbSO' Pb # Pb saturated saturated solution solution B 6S; o) ;@S:' / 1.1 1, and 6S; o) ;@I# / B 1,C 6S; o) AgCl is 1.B 1,1, Calculate o*idation electrode +otential )or Ag 5AgCl electrode ha$ing [Cl-] 17. Ii$en E,:; Ag9Ag. / -,.0CC 2. Ans. 5,.##'12 When metallic co++er is shaLen =ith a solution o) co++er salt the reaction Cu . Cu.# #Cu. +roceeds. When e>uili@rium is esta@lished at #CB6 [Cu.#]9 [Cu.]# / 1.11 1,1 M 1 . I) the standard +otential o) the Cu.#9Cu hal) cell is ,.%%0 =hat is the standard +otential o) Cu. 9 Cu hal) cell. Ans. ,.4#12 An e*cess o) li>uid <g =as added to 1,-% 7 acidi)ied solution o) 3e.% ions. It =as )ound that only 4 P o) the ions remained as 3e.% at e>uili@rium at #4,C. calculate E, )or #<g9<g.# at #4,C )or #+ # Hg + # Fe +% Hg # + # Fe +# and E, 3e.#93e.% / ,.002
The standard reduction +otential at #4,C )or the reaction. # H #O + #e H # + #OH is 5 ,.B#002. H %O + + OH at #4,C calculate the e>uili@rium constant )or the reaction # H #O Ans. C.%4 1,-14 , , , I) E1 is standard electrode +otential )or 3e9 3e.# and E# is )or 3e.9 3e.% and E% )or 3e93e.%.&eri$e , , , a relation in @et=een E1 E# and E% . Ans. %E% / #E1.E# .# <o= much Cu ions are +resent at e>uili@rium =hen )inely di$ided (icLel is mi*ed =ith ,.,4 7 solution o) CuS:'D Ii$en Cu9 Cu.# / -,.%%02 and (i9 (i.# / ,.#42. Ans. 1.%% 1,-##7 A gal$anic cell consisting o) t=o sil$er electrodes one in a saturated solution o) AgCl and the other in a saturated solution o) Ag#Cr:' is +re+ared. What is the $alue o) E cell at #CB6 D Ii$en 6S;/ 8AgCl" / 1.1 1,1, M # and 6S; / 8Ag#Cr:'" / #.#B0 1,1# .

C'. C4.

C1.

C0.

CB. CC. 1,,.

1,1. 1,#. 1,%.

An e*cess o) solid AgCl is added to a ,.17 solution o) Br ions at #CB6. calculate the conc. Cl-. And Ar- ions at e>uili@rium Ii$en E, 8Cl-9AgCl 9 Ag" / ,.###2 and E, 8Ar- 9 AgAr9 Ag" / ,.,C42 Ans. ,.,,,,07 .# <o= much is the o*idiGing +o=er o) 817" 7n: ' 9 7n 817" cou+le decreased i) the <. concentration is decreased )rom 17 to 1,-' at #4,CD The cell ;t. <#9 atm 9 1<. +< / N normal calomel electrode has e.m.). o) ,.10 2 at #4 ,C. calculate the +< o) the solution. the o*idation +otential o) calomel electrode on < scale is 5,.#B2. A hydrogen electrode ha$ing ;<# / 1.,, atm is com@ined =ith a standard calomel electrode =hose E , = ,.#'#V . hal) reactions is Hg #Cl# 8 s " + #e # Hg 81" + #Cl

1,'.

1,4. 1,1.

1,0. 1,B. 1,C. 11,. 111.

I) the cell +otential is ,.B,, 2 =hat is the +< o) the solution around the hydrogen electrode D =hat =ill @e cell +otential @e i) the hydrogen electrode is immersed in a neutral solution.D The standard cell +otential o) ;t. <#8g" 9 <Ar 8a>"9 Ag Ar8s" 9Ag8s" =as measured o$er a range o) tem+eratures and the data =ere )itted to the )ollo=ing +olynomial # E ' & B & = ,.,01%1 '.CC 1, #CB %.'4 1, #CB E$aluate the change in I < S at V $ $ #CB6. What +ressure o) <# =ould @e re>uired to maLe the +otential o) the hydrogen electrode Gero in +ure =ater at #4,C. The )ree energy change accom+anying a gi$en +rocess is 5 B4.00 6J mole -1 at #4,C and 5B%.1B6J 9 mol-1 at %4,C. calculate the heat o) reaction o) +rocess at %4,C. Fe E, is 5,.,%12 and the standard electrode +otential )or the 3or the reaction Fe +% + %e Fe +# ,.0012 calculate the E, )or Fe +# + #e Fe Fe +% + e , +' +# , .# E$aluate E )or Sn + #e Sn . Ii$en that E Sn 9 Sn / ,.1'2 and E, Sn 9 Sn.' / ,.142. Calculate the e>uili@rium constant )or the reaction # Fe +% + % # Fe +# + e # Fe +# + % . The standard reduction +otentials in acidic conditions are ,.002 and # Fe +% + % ,.4'2 res+ecti$ely )or 3e.% 9 3e.# and I-% 9 I- cou+les. 3ind the solu@ility +roduct o) a saturated solution o) Ag#Cr:' in =ater at #C,6 i) the e.m.) o) the Ag 9 Ag. 8std. Ag#Cr:' sol." 99 Ag.8,.17"9Ag is ,.11'2 at #CB6 Calculate cell +otential o) a cell ha$ing reactions Ag # S + #e Ag + S in a solution @u))er at +</% 6a 861.6#" )or <#S / 1.1 1,-#1 [<#S] / ,.111 <ydrogen and Iodine are )ormed =hen 7gI#8a>" electrodes. In a +articular e*+eriment =ith 4,,ml o) ,.#7 7gI# the $olume o) hydrogen collected =as e*actly one litre =hen measure o$er =ater at #4,C and 0'1 hour. 2a+our +ressure o) =ater at #4,C is #' hour. 1" <o= many )aradays o) electricity is used D #" I) the current )lo=ing through the cell is 4A. ho= long did the electrolysis taLes +laces D %" calculate the conc. o) I- 9 7g.# and :<- Assume that there is no change in the $olume o) the solution. 3rom the standard +otential sho=n in the diagram calculate the +otentials E,1 and E,# ,.4' # O% O 19 E, # a" Ag
+ 8 aq "

11#. 11%.

114.

111. 110.

+ Cl 8 aq " AgCl8 g "

Ii$en ' , 8 AgCl " = 1,C () 9 mole ' , 8Cl " = 1#C () 9 mole ' , 8 Ag + " = 00 () 9 mole Ke+resent the a@o$e reaction in )orm o) a cell calculate E, o) the cell. Also solu@ility and 6S; o) AgCl. @" 1.4%C 1,# g o) metallic -n 8amu / 14.%C" =as added to 1,,ml o) saturated solution o) AgCl. [ Zn #+ ] Calculate log1, <o= many moles o) Ag =ill @e )ormedD [ Ag + ]# Ag + + e Ag E , = ,.B,V 11B. 11C. Zn #+ + #e Zn E , = ,.01V T=o students use same stocL solution o) -nS:' and a solution o) CuS:'. the em) o) one cell is ,.,% 2 higher than the other. The conc. o) CuS:' in the cell =ith higher em) $alue o) ,.47. )ind out the conc. o) CuS:' in the other cell. 8#.#,%KT93/,.,1" A sam+le o) land =eighing 1.,4gr. =as dissol$ed is smell >uantity o) (itric acid to +roduce an a>ueous solution o) ;@.# and Ag. 8 =hich is +resent as im+urity". The $olume o) the solution a= increased to %4, ml @y adding =ater a +ure sil$er electrode =as immersed ion the solution and the +otential di))erence @et=een the is electrode an standard hydrogen =as )ound to @e ,.4,%2. =here =as the +ercentage o) sil$er in the lead metal D E, / ,.0CC2 Ii$en at #4 ,C.

1#,.

Cu8 s " + Cu +# + #e Ag 8 s " + Ag + 8 aq " + e

' , = 14.,' $) ' , = 00.# $)

1#1.

=hat =ould @e the concentration o) Ag. ion in a solution containing ,.,17 o) Cu.# ion in such that @oth metals can @e de+osited together. Assume that Ag Cu do not dissol$e in one another. When sil$er chloride dissol$e in large e*cess Ammonia +ractically all gi$en ions can @e assumed to e*ist in the )orm o) a single Ionic s+ecies [ Ag*8(<%"y] *. Com+lete the $alue o) * y using t=o cells. % % A" Ag 9 ,.' 1, M AgCl 9 M NH % 99 ', 1, MAgCl 1M NH % 9 Ag Ecell = ,.11B4V at #CB $ .
% % A" Ag 9 % 1, M AgCl 9 M NH % 99 % 1, M AgCl 1M NH % 9 Ag Ecell = ,.1#1%V at #CB $ Assume that Im+ure co++er contains only irons sil$er and gold as Im+urities. Assume ;assage o) 1',A )or 'B#.4 sec the mass o) the anode decreased @y ##.#1, gm and the cathode increased in mass @y ##.,11gm. Estimate the P Irons and P o) co++er originally +resent. The molar conducti$ity o) <. and C<%C::- at in)inite dilution are %'C.B and ',.C ohm-1 cm# mole-1. the s+eci)ic conducti$ity o) ,.,17 ethanoic acid is 1.'% 1,-' ohm-1 cm-1. =hat is 6a o) ethanoic acidD S+eci)ic conductance o) a saturated solution o) AgAr is B.'B1 1,0 ohm-1cm-1 at #4,C. S+eci)ic conductance o) +ure =ater at #4,C is ,.04 1,1 ohm-1cm-#. 7olar conductance o) 6Ar Ag(:% and 6(:% are 1%0.' 1%% 1%1 8S cm#" res+ecti$ely. Calculate the solu@ility o) Ag Ar. Calculate the e>ui$alent conducti$ity o) 17 <#S:' solution I) its s+eci)ic conducti$ity is #1 1,# ohm-1cm-1. The conducti$ity o) +ure =ater in a conducti$ity cell =ith electrodes o) cross sectional area ' cm# and # cm a+art is B 1,0 S cm-1. S+eci)ic conductance o) a saturated solution o) AaS:' at #4,C is %.4C 1,4 ohm-1cm-1 and conducti$ity o) =ater is ,.11B 1,4 ohm-1cm-1. E>ui$alent ionic conductance at in)inite dilution )or 1 #+ 1 # Ba and SO' are 1%.1 and 0C.B ohm-1 cm# +er e>ui$alent res+ecti$ely. Calculate the # # solu@ility and solu@ility +roduct o) AaS:' assuming com+lete dissociation in the saturated solution. Ii$en Ag + = 11.C un!ts? Cl = 01.% un!ts . Calculate solu@ility and solu@ility +roduct o) sil$er chloride solution =ith s+eci)ic conductance 1.%1 1,1 ohm-1cm-1. Kesistance o) a ,.17 6Cl is solution in a conductance cell is %,, ohm and s+eci)ic conductance o) ,.1 7 (aCl is 1.#C 1,# ohm-1 cm-1 . The resistance o) ,.17 (aCl solution in the same cell is %B, :hm. Calculate the e>ui$alent conductance o) the ,.17 (aCl solution. 2alues o) e>ui$alent conductance at in)inite dilution o) (aCl (a:< and (<'Cl are 1#1.4 #'B.0 and 1'C.C ohm cm# res+ecti$ely. 3ind the e>ui$alent conductance at in)inite dilution o) (<':<. A solution o) ,.17 acetic acid at #4,C has a s+eci)ic conductance o) 4.##1 1,' ohm-1 cm-1. i" 3ind the e>ui$alent o) conducti$ity o) ,.17 acetic acid. ii" 3ind the e>ui$alent conducti$ity o) acetic acid at in)inite dilution .86a )or acetic acid / 1.B 1,4 " The e>ui$alent conductance at #4,C o) (94, acetic acid solution is 11.C# ohm-# cm# 9 e>ui$. The e>ui$alent ionic conductance at in)inite dilution o) <. ions C<%C::- ion are %1, and ', ohm-1 cm# 9 e>ui$. Kes+ecti$ely. Calculate dissociation constant o) acetic acid. Calculate the degree o) dissociation o) =ater at #CB6. conducti$ity o) =ater is 1.%% 1,B ohm-1cm-1. 1 # 1 # Ii$en H + = %'C.B ohm mole cm OH = 1CB.% ohm mole cm &ensity o) <#:/ ,.CC0 gm 9 ml. The s+eci)ic conductance at #4,C o) a saturated solution o) SnS:' is 1.'B# 1,' ohm-1 cm-1 =hile that o) =ater used is 1.4 1,1 ohm-1 cm-1. &etermine at #4,C the solu@ility in gm +er litre o) SnS:' in =ater. E>ui$alent ionic conductance o) Sn.# and ions at in)inite dilution are 4C.'1 and 0C.B res+ecti$ely.[Sn / B0.1 S / %# : / 11] At #4,C e>ui$alent conductance o) ,.17 a>ueous acetic acid is )ound to @e 4.# and the limiting e>ui$alent conductance o) the same %C,.1 ohm-1 cm# e>ui$.-1. calculate a" &egree o) dissociation o) ,.17 acetic acid. @" &issociation constant o) acetic acid Kesistance o) solution 8A" is 4, ohms and that o) solution 8A" is 1,, ohms. Aoth solutions @eing taLen in the same conducti$ity cell. I) e>ual $olumes o) solution RAS and RAS are mi*ed =hat =ill

1##. 1#%. 1#'.

1#4. 1#1. 1#0.

1#B. 1#C.

1%,. 1%1.

1%#. 1%%. 1%'.

1%4.

1%1.

1%0.

@e the resistance o) the mi*ture using the same cell. Assume that there is no increase in the degree o) dissociation o) RAS and RAS on mi*ing. A @ig irregular sha+ed $essel contained =ater s+eci)ic conductance o) =hich =as #.41 1,4 ohm-1 cm-1. 4,, gms o) (aCl =as then added to the =ater and the s+eci)ic conductance a)ter the addition o) (aCl =as )ound to @e %.1 1,4 ohm-1 cm-1. )ind the ca+acity o) $essel i) it is )ul)illed =ith =ater. 8 NaCl = 1'C.C "
+ @" At 1B,C the mo@ilities1%0. @" At 1B,C the mo@ilities o) NH ' and ClO' ions are ' ' 1.1 1, and 4.0 1, cm# $olt-1 sec-1 at in)inite dilution. Calculate e>ui$alent conductance o) ammonium chlorate solution. A solution o) sil$er nitrate containing 1#.1'gm sil$er in 4, ml solution =as electrolysed @et=een +latinum electrodes. A)ter electrolysis 4,ml anode solution =as )ound to contain 11.44gm o) sil$er =hile 1.#4gm o) metallic sil$er =as de+osited on the cathode. Calculate the trans+ort num@er o) Ag . and (:%- ions. In an electrolysis o) co++er sul+hate @et=een co++er electrodes the total mass o) co++er de+osited at the cathode =as ,.14% gm and masses o) co++er +er unit $olume o) the anode li>uid a)ter and @e)ore electrolysis are ,.C1 and ,.0Cgm res+ecti$ely. Calculate trans+ort num@er o) the Cu.# and SO' ions. Kation o) s+eed o) sil$er and nitrate ions in the solution o) Ag(:% electrolysed @et=een sil$er electrodes is ,.B )ind trans+ort num@er o) the t=o ions. calculate the molar ionic conductance o) Al%.ions at in)inite dilution gi$en that molar conductance o) Al#8S:'"% and molar ionic conductance o) SO' ions at in)inite dilution are B4B ohm-1cm#mol-1 and 11, ohm-1 cm# mol-1 res+ecti$ely. At #C16 the molar conducti$ities at in)inite dilution o) (< 'Cl (a:< and (aCl are 1#C.B #10.' and 1,B.C ohm-1 cm# mol-1 res+ecti$ely. I) molar conductance o) (<':< at centinormal concentration is C.%% ohm-1 cm# mol-1 =hat is +ercentage dissociation o) (< ':< at this dilution D also calculate dissociation constant and +< o) the solution.

1%B.

1%C.

1',. 1'1.

1'#.