1. a) State 3 ways to achieve a noble gas configuration. b) Use VSEPR model to predict the geometry of the following molecules.

i) IF5 (square pyramidal) ii) XeF4 (square planar) iii) XeF2 (linear) c) Which of the following molecules above is a polar molecule?

2. a) What is a zwitterion and how is it formed? b) Identify compound A, B, C and D. i)

NO2

6[H]

Sn/HCl room temperature

ii)

CH3CH2CH2CN

2H2

Ni, 140oC

iii)

CH3CNH2

4[H]

1)LiAlH4 2) H2O

iv)

CH3CH2CNH2

Br2

4NaOH

c) Write a stepwise mechanism of preparing aniline from benzene.

3. a) Determine the number of significant figures in the following measurements: i) 0.043 kg (2) 22 ii) 1.310 x 10 atoms (4) b) 1.50 g oxide of metal M, MO2 reacts with excess hydrochloric acid solution, HCl to produce 386 cm3 chlorine gases at STP as given by the following equation. MO2 + HCl i) ii) MCl2 + Cl2 + H2O

Balance the above equation. Determine the relative molecular mass of MO2 and the relative atomic mass of M. (RMM MO2 = 88.2, RAM M = 56.2)

c)

One method of determining the concentration of hydrogen peroxide (H 2O2) in a solution is through titration with the iodide ion. The net ionic equation for this reaction is H2O2 + 2I +2H+ I2 + 2H2O A 50.00 mL sample of a hydrogen peroxide solution is found to react completely with 37.12 mL of a 0.1500 M KI solution. What is the concentration of hydrogen peroxide in the sample? (5.568 102 M)

d) What volume (mL) of a 0.3428 M HCl(aq) solution is required to completely neutralize 23.55 mL of a 0.2350 M Ba(OH)2(aq) solution? (32.29 mL)

4. a) Define the following terms: i) complex ion ii) ligand b) What are the systematic names for the following ions and compounds? i) [Cr(en)3]Cl3 ii) [Ni(CN)2Br2]2iii) [Ru(NH3)5(H2O)]Cl2 c) Write the formulas for each of the following ions and compounds: i) pentaamminechlorocobalt(III) chloride ii) dichlorobis(ethylenediamine)platinum(IV) nitrate iii) sodium hexanitrocobaltate(III) d) In the complex ion [ML6]n+, Mn+ has 7 d electrons and L is a weak field ligand. By showing appropriate diagram of crystal field splitting, predict the number of unpaired electrons in the complex ion. (Draw the splitting diagram, 3 unpaired electrons)

5.

a) There are 2 phenomena associated with liquids in general: surface tension and viscosity. Define each phenomenon and give evidence that related to each phenomenon. b) Solids can be divided into 2 categories: crystalline and amorphous. What is an amorphous solid? How does it differ from crystalline solid? Give one example on amorphous solid. c) Draw a simple cubic, body-centered cubic and face-centered cubic and determine their coordination number. d) What are the differences between a suspension, a colloid and a solution? Give an example for each.

6. a) State the following gas laws in words and also in the form of an equation: Boyles law, Charless law and Avogadros law. b) When coal is burned, the sulphur present in coal is converted to sulfur dioxide (SO2), which is responsible for the acid rain phenomenon. S(s) + O2(g) SO2(g)

If 2.54 kg of S are reacted with oxygen, calculate the volume of SO 2 gas in mL formed at 30.5oC and 1.12 atm. (1.76 x 106 mL) c) In alcohol fermentation, yeast converts glucose to ethanol and carbon dioxide: C6H12O6(s) 2 C2H5OH(l) + 2 CO2(g)

If 5.97 g of glucose are reacted and 1.44 L of CO2 gas are collected at 293 K and 0.984 atm at the end of the experiment, what is the percentage yield of the reaction? (90%) d) A 500.0 mL vessel containing 1.35 g of chlorine gas has a pressure of 760 mmHg. When a certain amount of oxygen gas is added to the vessel, the gas pressure rises to 865 mmHg. Assume that the gases do not react with each other and the temperature remains constant, calculate the mass of oxygen gas added into the vessel. (0.0864 g)

7. a) What are the intermolecular forces present in each of the following compound. i) F2 ii) HF iii) NH3 iv) CF4 v) H2 b) Define dipole moment. Draw and list the following molecules in order of increasing dipole moment. Show all the arrow of dipole moment. H2O, CBr4, H2S, HF, NH3, CO2 (CBr4 < H2S = CO2 < NH3 < H2O < HF, draw structure with the ) c) Predict and draw the geometries of the following species using the VSEPR method: i) PCl5 ii) NF3 iii) CCl4 8. a) Define homologous series. b) A compound X has an empirical formula C1.25H3O0.25 . If the molar mass of X is 88 g/mol, determine the molecular formula of X. (C5H5O) c) Convert the following structures to skeletal structures. i) ii) iii) CH3CH(OH)COOH C3H5COOC3H7 C6H5CH(OH)N(CH3)2

d) Redraw, circle and name all the functional groups in the following molecules and also their respective homologous series.
OH

NH2 O O

e) Identify the compounds A, B and C.

Br2 / FeBr3

HNO3/ H2SO4

CH3Cl FeCl3

9. a) On appropriate coordinate axes, draw the shapes of dx2-y2 and dxy orbitals. b) The Brackett series of the spectral line of atomic hydrogen appears in the infrared region. The wavelength for the third line in the Brackett series is 2166 nm. i) How the third line of the Brackett series is formed? (from which n to which n?) ii) Calculate the energy involved to form the third line in Brackett series? (9.2 x 10-20 J) c) The table below shows the elements P, Q and R with their respective proton numbers. Element P Q R i) ii) Proton Number 16 25 28

Give the electron configuration for P and Q. Arrange P, Q and R in order of increasing atomic size. Explain. (P<R<Q) d) The actual electronic configuration of copper and chromium show irregularity as predicted by the Aufbau principle. Show the electron configuration of chromium and copper.