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ABSTRACT:
A simple method has been demonstrated for the in situ
deposition of gold nanoparticles over polyanline thin films.
Polymer thin films were grown using cyclic voltammetry
technique. Gold nanoparticles was prepared by citrate
chemical reduction method which produced particles in the
range of 15-20 nm. For the fabrication of Au nanoparticles
entrapped polyaniline films, polyaniline was first deposited as
a thin film on Pt electrode by continuous cycling between -0.22
to 1.2 V vs Ag/AgCl at 50 mV/s. The chemically synthesized Au
nanoparticles were deposited on the polymer modified
electrodes using cyclic voltammetry for continuous 15 cycles.
Au nanoparticles modified electrodes showed improved
activity towards formic acid oxidation than Pt electrodes,
which might be due to the increase of electrochemically
accessible surface areas due to the combined effect of Au
nanoparticles and polymer.
DIRECT FORMIC ACID FUEL CELL:
Schematic representation of oxidation of formic acid
EXPERIMENTAL METHODS:
Synthesis of Au nanoparticles:
Effect
of
scan
rate
on
APPLICATION:
CONCLUSION: