aloalkanes and Haloarenes - 4 Marks Questions

1. Give one example each of a) Markwonikovs addition. b) Kharasch effect. c) Sand Meyer reaction d) Diazotisation reaction e) Finkelstein reaction f) Swarts g) W rtz reaction h) W rtz Fitti! reaction i) Fitti! reaction j) Friediel"s acylation reaction of chloro #enzene k) Friediel crafts alkylation reaction. of chloro #enzene. l) nitration of chloro #enzene. m) s lphonation of chloro #enzene. n) Dehydro halo!enation $# elimination reaction% o) &atsev r le. p) chlorination of chloro #enzene. 2. 'xplain the classification of halo alkanes #ased on a) n m#er of halo!en atoms. b) compo nds havin! sp( )*+ #ond c) compo nds havin! sp, )*+ #ond d) dihalides. Give one example each and their -./0) names. 3. 0cco nt for the followin!1 1) 2alo alkanes have hi!her #oilin! point than the correspondin! parent alkane. 2) 3oilin! point of halo alkanes 4-543r54)l5 4F 3) 3oilin! point of 6*3romo # tane 5,*3romo # tane5 6*3romo* ,*methyl propane5 ,*3romo* ,*methyl propane. 4) Meltin! point of p*Dichlo #enzene is hi!her than its ortho and meta isomer. ) 2alo alkanes are polar in nat re # t sparin!ly sol #le in water. !) -odo alkane can not #e prepared #y the reaction of alcohol with K- and s lph ric acid. /hosphoric acid is sed in place of s lph ric acid. ") 7rder of reactivity of alcohol with 2+ is tert alcohol5 sec alcohol 5 primary alcohol.. #) 2alo arenes can not #e prepared #y treatin! phenol with 2+ or 8a+ in the presence of s lph ric acid.

$) -odination of #enzene is carried o t in the presence of 2-7 ( or 287(. 1%) /ropane on chlorination !ives ,*chloro propane as a ma9or prod ct and not 6*chloro propane. 11) Kharasch effect is possi#le only with 23r and not with 2)l and 2-. 12) 0lcohol reacts with thionyl chloride to !ive p re halo alkane. 13) Finkelstein reaction of halo alkane is carried o t in the presence of dry acetone. 14) 7rder of reactivity of halo alkanes as per s #stit tion #imolec lar n cleophilic is primary halide 5 secondary halide5tertiary halide. 1 ) 7rder of reaction as per s #stit tion nimolec lar is tertiary halide5secondary halide 5primary halide. 1!) 3enzylic halides and allylic halides are more reactive towards n cleophile than halo alkanes. 1") )hloro ethene is less reactive towards n cleophile than chloro ethane. 1#) 2alo arenes are less reactive towards n cleophile than halo alkanes. 1$) S86 mechanism is r led o t in the reaction of halo arenes with n cleophile. 2%) 'lectron with drawin! !ro ps like 87, at ortho and para position with respect to halo!en facilitates n cleophillic s #stit tion reaction. 21) 'lectron with drawin! !ro ps like 87, at meta position with respect to halo!en has no effect on n cleophillic s #stit tion reaction. 22) 2alo arenes are less reactive towards electrophile than #enzene. 23) 0ltho !h chlorine atom has electron with drawin! effect electrophillic s #stit tion occ r at ortho and para position. 24) 7rder of reactivity of alkyl halide 4-543r54)l54F 2 ) 2alo alkanes react with K)8 to !ive alkyl cyanide as a ma9or prod ct while it !ives alkyl isocyanide as a ma9or prod ct with 0!)8. 2!) 2alo alkanes !ive nitrito alkane with K87 , while nitro alkane with 0!87,. 2") )2(- nder!oes S8, reaction faster than )2()l. 4. 'xplain the followin! with s ita#le examples1 a) chiral and chirality b) enantiomers

c) racemic mixt re d) retention of confi! ration e) inversion of confi! ration. . Mention the differences #etween S86 and S8, mechanism of halo alkane. !. Give the prod cts and explain the mechanisms of the followin! reactions1 a) )2( )2, 3r : 72* b) $ )2(%()*3r : 72* c) n*3 3r : K72 ". )arry o t the followin! conversions1 1. /ropene to a) /ropan*6*ol b) /ropan*,*ol 2. 'thanol to # t*6*yne 3. 6*3romo propane to ,*3romo propane and vice versa. 4. ;ol ene to #enzyl alcohol. . 3enzene to a) <*#romonitro #enzene b) (*#romonitro #enzene. !. 3enzyl alcohol to ,*phenyl ethanoic acid. ". 'thanol to a) /ropane nitrle b) 'thyl isocyanide. #. 0niline a) )hloro #enzene b) 3romo #enzene c) -odo #enzene. $. ,*)hloro # tane to (=<* dimethylhexane.

1%. ,*Methyl*6*propene to ,*chloro*,*methylpropane. 11. 'thyl chloride to propanoic acid. 12. 3 t*6*ene to n*# tyl iodide. 13. ,*chloropropane to propan*6*ol 14. -sopropyl alcohol to iodoform. 1 . )hloro #enzene to a) p*nitro phenol b) p*chloronitro #enzene c) p*chloro d) p* chloro acetophenone. e) p*chloro #enzene s lphonic acid f) 6=<*Dichloro #enzene. g) #iphenyl. 1!. )hloroethane to # tane. 1". tert*# tyl #romide to iso# tyl #romide. 1#. 0niline to phenylisocyanide. 1$. /ropene to a) ,=(*dimethyl # tane b) n*hexane. 2%. ;ert*# tyl #romide to ,*methyl prop*6*ene. #. What happens when a) n*# tyl chloride is treated with alcoholic K72. b) #romo#enzene is treated with M! in the presence of dry ether. c) chloro#enzene is s #9ected to hydrolysis. d) ethyl chloride is treated with a> eo s K72. e) methyl #romide is treated with 8a in the presence of dry ether. f) methyl chloride is treated with a) K)8 b) 0!)8 c) K87, d) 0!87,

$. Write the str ct re of the ma9or or!anic prod ct in each of the followin! reactions1 acetone a) )2()2,)l : 8aheat ethanol b) $)2(%( )*3r :K72 heat ethanol c) )2()2,3r : K)8 d) )?2@78a :)2(3r e) )2()2,72 :S7)l, peroxide f) )2( )2A)2, :23r g) )2( )2A)2, :23r h) $)2(%,)A)2,: 23r i) )2()2A)$)2(%, :23r j) )2()2,)2,72:S7)l, k) )2()2,3r :8a-

: S7)l,

2eat :3r,

3r, 2eat or .B li!ht

:2-

:M! Dry ether 2,7

r) 43r :M! Dry ether

0 D,7

)2()2 $D%)2(

s) $)2(%()*)$)2(%(

4+ 0 8aCether M!Cether

3 2,7

1%. 0rran!e the compo nds of each set in order of decreasin! reactivity towards a% S8 , displacement. #% S86displacement. a) ,*#romo*,*methyl# tane= 6*#romopentane= ,*#romo pentane b) 6*#romo*(*methyl# tane= ,*#romo*,*methyl# tane=(*#romo*,*methyl# tane c) 6*#romo # tane= 6*#romo*,*methyl propane= 6*#romo*,*phenyl propane. d) Methyl chloride= Methyl #romide and Methyl iodide. 11. /rimary halide 0$)<2D3r% with alcoholic K72 !ives a compo nd 3. 3 on treatment with 23r !ives ) which is an isomer of 0. 0 on treatment with 8a in dry ether !ives a compo nd D which is different from when n*# tyl #romide is reacted with 8a in dry ether. Give the str ct ral form la of 0. Write the e> ations of the reactions involved.

12. 0n alkyl halide )E26@3r is optically active. -t reacts with K72 sol tion to !ive racemic mixt re. 'xplain the mechanism of the reaction. 13. Distin! ish chemically #etween a) )2()l= )2(3r= )2(b) )hloro #enzene and chloro methane c) chloro #enzene and #enzyl chloride d) )2)l( and ))l< 14. /rimary alkyl halide 0 $)<2D3r% react with alcoholic K72 to !ive 3.3 reacts with 23r to !ive ) which is an isomer of 0. When 0 is treated with sodi m in dry ether it !ives a compo nd D ) F26F which is different from the compo nd when n*# tyl #romide is treated with sodi m. Give the str ct ral form la of 0 and complete the reaction. 1 . Which alkyl halide from the followin! pairs wo ld yo expect to react more rapidly #y S8 , MechanismG 'xplain yo r answer. a) 6*3romo # tane and ,*3romo # tane. b) ,*3romo # tane and ,*3romo*,*methyl propane. c) )yclo hexyl chloro methane and chloro cyclo hexane. d) -odo # tane and chloro # tane. 1!. Which alkyl halide from the followin! pairs wo ld yo expect to react more rapidly #y S8 6 MechanismG 'xplain yo r answer.

1". /redict the order of reactivity of the followin! compo nds in S8 6 and S8, mechanism. a) )?2@)2,3r b) )?2@)2$)?2@% 3r c) )?2@)2$)2(% 3r d) )?2@$)2(%$)?2@% 3r. 'xplain yo r answer. 1#. 0rran!e the followin! in the increasin! order of #oilin! point. a) 3romomethane= 3romoform= )hloromethane and Di#romomethane. b) 6*)hloropropane= 6*)hloro# tane and isopropyl chloride.

1$. 0mon! the isomeric alkanes )@26, = identify the one that on photochemical chlorination yields a) 0 sin!le monochloride molec le b) ;hree isomeric monochloride molec les c) Fo r isomeric monochlorides.

lcohols&'henols and ethers - 4 Marks Questions

1. Write the e> ations of the followin! named reactions1 a) 2ydro #oration b) williamson"s synthesis c) c mene phenol process d) Kol#e"s reaction e) 4iemier ;iemann reaction 2. 'xplain H cas test with s ita#le examples 3. Distin! ish chemically #etween the followin! pairs of or!anic compo nds a) /henol and methanol b) methanol and ethanol c) propan*6*ol and propan*,*ol d) pentan*(*ol and ,*Methyl # tan ,*ol 4. 0cco nt for the followin!1 a) )72 #ond an!le in alcohol is less than tetrahedral an!le of 6ID.@ I b) )7) #ond an!le in ether is more than tetrahedral an!le of 6ID.@ I c) )*7 #ond len!th in phenol is less than that of alcohol. d) /henol has lower dipole moment than alcohol. e) /henol nder !oes electrophillic s #stit tion at ortho and para position f) 0lcohol acts as a #ronsted acid as well as #ronsted #ase. g) /henol is more acidic than alcohol. h) 0cidity of alcohol is primary alcohol5sec alcohol5tert alcohol. i) 3asicity of alcohol is tert alcohol5 sec alcohol5primary alcohol. j) -n Williamsons synthesis sec and tert halide can not #e sed.

k) para nitro phenol is less steam volatile than ortho nitro phenol. l) /resence of nitro !ro p at ortho and para position makes phenol more acidic. m) 0lcohols and phenols have hi!her #oilin! point. n) 3oilin! point of alcohol is hi!her than its isomeric ether. o) 3oilin! point of !lycerol5ethylene !lycol5 ethanol. p) Gri!nard rea!ent is a versatile rea!ent in or!anic chemistry. () )resol is less acidic than phenol. r) -n esterification reaction= water is removed as soon as it is formed. s) 7rder of reactivity of 2+ with alcohol is 2-523r52)l52F t) 0lcohol reacts with S7)l, to !ive p re halo alkane. u) 'ase of dehydration of alcohol is tert alcohol5 sec alcohol5primary alcohol. )) /henol and anisole nder!oes #romination reaction even in the a#sence of halo!en carrier. *) Methyl phenyl ether reacts with 2- to !ive phenol and methyl iodide and not methanol and iodo #enzene. +) Methoxy ethane reacts with 2- to !ive methyl iodide and ethanol and not ethyl iodide and methanol. ,) ;ert # tyl methyl ether reacts with 2- to !ive tert # tyl iodide and methanol and not not methyl iodide and tert # tyl alcohol. -) 0nisole nder!oes electrophillic s #stit tion at ortho and para position. aa) 3oilin! point of # tan*6*ol is hi!her than tert # tyl alcohol. bb) 0lcohol= phenol and ether are sol #le in water. cc) -n the reaction #etween acid chloride and alcohol a small amo nt of pyridine is added. dd) 0lcohol #ehaves as n cleophile as well as electrophile. ee) Water is a stron!er acid than alcohol. . )arry o t the followin! conversions1 a) 'thanal to ethanol.

b) 0cetone to propan*,*ol. c) 'thanoic acid to ethanol. d) 'thene to ethanol. e) /ropene to propan*,*ol. f) Methanal to ethanol. g) Methanal to #enzyl alcohol. h) 'thanal to propan*,*ol. i) 0cetone to ,*methyl propan*,*ol. j) 3 t*6*ene to # tan*6*ol. k) 3 t*,*ene to # tan*,*ol. l) )hloro #enzene to phenol. m) 0niline to phenol. n) 3enzene to phenol. o) 'thanol to ethyl ethanoate. p) 'thanol to ethene. () 'thanol to ethanal. r) ;ert # tyl alcohol to ,*methyl prop*6*ene. s) /ropan*,*ol to acetone. t) /henol to i) phenyl ethanoate. ii) ,*0cetoxy #enzoic acid. iii) ortho and para nitro phenol. i)) ,=<=?*trinitro phenol )) para #romo phenol )i) ,=<=?* tri #romo phenol )ii) salicylic acid )ii) salicylaldehyde )iii) anisole

i+) phenatole +) #enzene +i) #enzo > inone. u) 'thyl iodide to diethyl ether )) Methyl #romide to , methoxy , methyl propane. *) 3enzyl chloride to #enzyl alcohol +) 'thyl ma!nesi m chloride to propan*6*ol ,) ) mene to phenol -) 0nisole to i) phenol ii) ortho and para hydroxyl aceto phenone iii) para #romo anisole i)) ortho and para methyl anisole )) ortho and para methoxy aceto phenone )i) ortho and para nitro anisole )ii) 'thene to ethane*6=,*diol !. 'xplain the mechanism of the followin! reactions1 a) )2,A )2, : 2,7 b) )2()2,72 <<(K <6(K c) )2()2,72 )2()2,7)2,)2( )2()2,72 )2,A )2, : 2,7

d) 'xplain the mechanisms of the reactions in which alcohol acts as a) n cleophile b) electrophile ". 2ow is ethanol prepared from a) ethene b) cane s !arG Mention , ses of ethanol. #. 2ow is methanol commerciallyG Mention , ses of the same. $. 2ow is phenol prepared commerciallyG Mention , ses of the same.

1%. 0n or!anic compo nd 0 react with 8a72 nder drastic condition to !ive 3. 3 reacts with 3r ,$a>% to !ive ).) on zinc d st distillation !ives 6=(=@*;ri#romo #enzene. -dentify the compo nds and write the e> ations of the reactions involved. 11. Give the mechanism for the reactio $)2(%,)2*)2( J 72 $)2(%,)*)2( J 3r

23r

12. Write the e> ations of the followin! reactions1 a) Friedel*)rafts alkylation of anisole. b) Friedel*)rafts acylation of anisole. c) 8itration of anisole. d) 3romination of anisole in ethanoic acid medi m. e) 7xidation of /ropan*6*ol with alkaline KMn7 < sol tion f) /henol with 3r, in )S, g) /henol with dil te 287( h) /henol with chloroform in the presence of a> eo s 8a72. 13. Write the e> ation of reaction of 2- with a) 6*/ropoxy propane b) Methoxy #enzene c) #enzyl ethyl ether. d) )2(*)2,*)2$)2(%*)2,7)2,*)2( e) )?2@)2,7)?2@ )2( J f) )2(*)2,*)2,*7*)*),2@ J )2( 14. 8ame the rea!ent sed in the followin! reactions1 a) 7xidation of primary alcohol to car#oxylic acid. b) 7xidation of primary alcohol to aldehyde. c) 3romination of phenol to ,=<=?*;ri#romophenol. d) 3enzyl alcohol to #enzoic acid. e) Dehydration of /ropan*,*ol to propene. f) 3 tan*,*one to 3 tan*,*ol.

1 . Ko are !iven #enzene= concentrated s lph ric acid and 8a72. Write the e> ation involved in the preparation of phenol sin! these rea!ents. 1!. Give the prod cts of the followin! reactions1 a) )2(*)2,*)2,*7)2( :23r b) )?2@7),2@ :23r c) $)2(%()7),2@ :2d) )?2@7),2 @ conc 287(:conc 2,S7< e) )2()2A)2, 2(7: f) )2(*)2,*)2*)27 J )2(

8a32<

g) 1". Give the str ct re and -./0) names of the prod cts expected from the followin! reactions1 a) )atalytic red ction of # tanal b) 2ydration of propene in the presence of dil te s lph ric acid. c) 4eaction of propanone with methyl ma!nesi m #romide followed #y hydrolysis. 1#. ;he followin! is not the appropriate reaction for the preparation of tert*# tyl ethyl ether. ),2@78a:$)2(%()*)l $)2(%()7),2@ a) What wo ld #e the ma9or prod ct for this reaction G b) Write the reaction for the preparation of tert*# tyl ethyl ether. 1$. Give the str ct re of the prod ct yo wo ld expect when each of the followin! alcohol react with i) 23r ii) S7)l, iii) &n)l,:2)l a) 3 tan*6*ol b) ,*Methyl# tan*,*ol

2%. /redict the ma9or prod ct in the acid catalysed dehydration of a) # tan*6*ol b) 6*Methylcyclohexanol. 21. Draw the resonance str ct res of phenoxide ion of ortho and para nitrophenols. 22. Write the str ct re of ma9or prod cts formed in the followin! reactions1 a) Mono nitration of (*methylphenol. b) Dinitration of (*methylphenol. c) Mononitration of phenyl methanoate. 23. 2ow are the followin! alcohols prepared #y the reaction of Gri!nard rea!ent with 2)27G a) $)2(%,)2)2,72 b) )2,72 J

24. 0rran!e the followin! compo nds in the order of properties mentioned1 a) /entan*6*ol= /entan*,*ol= ethanol= /ropan*6*ol and methanol.$increasin! order of #oilin! point. b) /entan*6*ol= n*# tane= /entanal and ethoxyethane.$increasin! order of #oilin! point.% c) /ropan*6*ol= ,=<=?*;rinitrophenol= (*8itrophenol= (=@*Dinitrophenol= /henol and <*Methylphenol$ increasin! order of acidity

ldeh,de&.etone and /arbo+,lic acid - ! Marks Questions

1. Write e> ations for the followin! named reactions1 a) 8 cleophillic addition reaction. b) clemensen red ction. c) wolf kishner red ction. d) aldol condensation. e) crossed aldol condensation f) cannizaro reaction.

g) 4osenm nd"s red ction. h) kol#e"s electrolysis i) Stephen reaction. j) 'tard reaction. k) decar#oxylation. l) acylation. m) schotten #a mann reaction. n) Friediel craft"s acylation. o) esterification. p) Gattermann* Koch reaction. () 2ell Bolhard &elensky reaction. 2. 'xplain a) Fehlin!"s test b) ;ollen"s rea!ent test with s ita#le examples. 3. Distin! ish chemically #etween the followin! pairs of or!anic compo nds1 a) Methanal and ethanal. b) ethanal and propanone. c) pentan*,*one and pentan*(*one. d) aceto phenone and #enzo phenone. e) formic acid and acetic acid. f) #enzoic acid and ethyl #enzoate. g) phenol and #enzoic acid. h) ethanal and propanal. i) propanal and diethyl ether.

j) #enzaldehyde and acetophenone. k) ethanal and propanone 4. 0cco nt for the followin!1 a) 0ldehyde and ketone are polar in nat re. b) 0ldehyde and ketones have hi!her #oilin! point than hydro car#ons of compara#le molar mass. c) 0ldehyde and ketones have lower #oilin! point than alcohols of compara#le molar mass. d) Ketone has hi!her #oilin! point than aldehyde of compara#le molar mass. e) 7xidation of primary alcohol to aldehyde is carried o t sin! /)) as an oxidizin! a!ent. f) 4osenm nd"s red ction of acid chloride to aldehyde is carried o t sin! > inoline and s lph r. g) 0ldehyde is more reactive than ketone towards n cleophile. h) 3 tanone is less reactive than propanone. i) ,=,=?*;ri methyl cyclo hexanone is less reactive towards n cleophile than cyclo hexanone. j) /ara nitro #enzaldehyde is more reactive towards n cleophile than #enzaldehyde. k) /ara methyl #enzaldehyde is less reactive towards n cleophile than #enzaldehyde. m) 4eaction of aldehyde with alcohol to !ive acetal is carried o t in the presence of 2)l$!%. n) Formaldehyde and #enzaldehyde nder!oes cannizaro reaction and not aldol condensation. o) 0cetaldehyde nder!oes aldol condensation and not cannizaro reaction. p) 0romatic aldehyde and ketones nder!oes electrophillic s #stit tion at meta position. () )ar#oxylic acid do not show the reactions of aldehyde and ketone tho !h it has 5)A7 !ro p. r) )ar#oxylic acid has hi!her #oilim! point than aldehyde= ketone and alcohol of compara#le molar mass. s) -n semi car#azide= only one 82, !ro p is involved in the formation of semi car#azone. t) 0ldehyde= ketone and car#oxylic acid are sol #le in water. u) -n oxidation of primary alcohol to car#oxylic acid is not carried o t sin! acidified potassi m dichromate. )) )ar#oxylic acid is more acidic than alcohol.

*) )ar#oxylic acid is more acidic than phenol. +) 0cidity of ))l()7725)2)l,)7725)2,)l)7725)2()772. ,) 0cidity of F)2,)7725)l)2,)77253r)2,)7725- )2,)772. -) a chloro propanoic acid is more acidic than L chloro propanoic acid. aa) 0cetic acid is less acidic than formic acid. bb) / re acid halide is prepared #y the reaction of car#oxylic acid with thionyl chloride. cc) )ar#on in car#onyl !ro p of aldehyde and ketone acts as Hewis acid$electrophile% while oxy!en acts as Hewis #ase $ n cleophile%. dd) 3enzoic acid does not nder!o Friediel craft alkylation reaction. . 2ow is a) 2)27 b) )2()27 c) )?2@)27 prepared commerciallyG Mention two ses of each. !. 2ow is a) 2)772 b) )2()772 c) )?2@)772 prepared commerciallyG Mention two ses of each. ". )arry o t the followin! conversions1 a) 'thanol to ethanal. b) Methanol to methanal. c) /ropan*,*ol to propanone. d) Methanal to i) ethanol ii) #enzyl alcohol. e) 'thanal to

i) propan*,*ol ii) acetone. f) 0cetone to i) tert # tyl alcohol ii) ,*Methyl prop*6*ene. g) 3enzaldehyde to i) a* hydroxy phenyl acetic acid ii) (*phenyl propan*6*ol iii) 6* phenyl ethanol. i)) #enzyl alcohol and sodi m #enzoate. )) cinnamaldehyde. )i) 6=(*Diphenyl prop* ,*en*6*one )ii) #enzo phenone )iii) m*nitro #enzaldehyde i+) #enzal acetophenone. h) 3 tan*6*ol to # tanal. i) )yclo hex*,*en*6*ol to cyclo hex*,*en 6*one. j) /entan*(*en*,*ol to pent*(*en*,*one. k) 3 t*,*ene to ethanal l) /ara nitro tol ene to para nitro #enzaldehyde. m) 'thanal to # tan*,*one. n) 'thanal to # tane* 6=(* diol. o) 'thanal to # t*,*enal p) 'thanal to # t*,*enoic acid. () 'thanal to # tan*6*ol

r) 'thanal to # tanoic acid. s) /ropanone to propene. t) /ropanal to # tanone. u) 'thanal to ,*hydroxy # tanal. )) 3enzaldehyde to #enzo phenone. *) 3enzoic acid to #enzaldehyde. +) /ropanoic acid to propenoic acid. ,) 3enzene to m*nitro aceto phenone. -) 3romo #enzene to 6*phenyl ethanol. aa) 3enzoic acid to m* nitro #enzoic acid. bb) 3enzoic acid to #enzyl amine. cc) /ara nitro #enzoic acid to para nitro aniline. dd) 2exanoic acid to hexane nitrle. ee) 2exanoic acid to 6*amino pentane. ff) 2ept*6*ene to heptanal gg) 2ept*6*ene to hexanal. hh) 2ept*6*ene to heptanoic acid. ii) 2ept*6*ene to hexanoic acid. jj) 'thene to ethanal. kk) /ropene to acetone. ll) ,= (* dimethyl # t*,*ene to acetone. mm) 'thanal to lactic acid. nn) 'thanal to ethane. oo) 'thanal to 'thanoic acid.

pp) 0cetone to <*hydroxy*<*methyl pentan*,*one. (() 3enzaldehyde to #enzyl alcohol and sodi m #enzoate. rr) Methanal to methanol and sodi m methanoate. ss) ;ol ene to #enzaldehyde. tt) 'thyl #enzene to #enzoic acid. uu) 3 t*,*ene to ethanoic acid. ) )) 'thane nitrle to ethanoic acid. **) Methyl ma!nesi m #romide to ethanoic acid. ++) /ara methyl aceto phenone to #enzene*6=<* dicar#oxylic acid. ,,) )yclo hexene to hexane*6=?*dicar#oxylic acid. --) 'thanoic acid to ethanol. aaa) /ropanoic acid to a* chloro propanoic acid. bbb) Methanol to 'thanoic acid. ccc) 3enzoic acid to m*nitro #enzoic acid. ddd) 3enzoic acid to m*#romo #enzoic acid. eee) 0cetyl chloride to acetaldehyde. fff) 3enzoyl chloride to #enzaldehyde. mmm) 3enzene to aceto phenone. nnn) 3enzene to #enzo phenone. ooo) 'thanoic acid to ethanoyl chloride. sss) 'thanoic acid to ethanoic anhydride. ttt) 'thanoic acid to ethyl ethanoate. a) 'thanoic acid to ethanamine. b) 2exane nitrle to 6*amino pentane.

c) 3enzoic acid to #enzo phenone. d) 3enzoic acid to i) aceto phenone. ii) #enzaldehyde iii) #enzophenone e) 3enzene to methyl #enzoate. f) 3enzene to m* nitro #enzoic acid. g) 3enzene to p* nitro #enzoic acid. h) 3enzene to p* nitro #enzaldehyde. i) 3enzene to phenyl acetic acid. j) 'thanoyl chloride to propanone. k) 3enzene to #enzaldehyde l) 'thane nitrile to i) ethanal ii) propanal m) vinyl cyanide to prop,*enal n) p*fl oro tol ene to p*fl oro #enzaldehyde. o) cyclo hexanol to cycloheanone. p) 2exan*6*ol to hexanal () 3 tan*6*ol to # tanoic acid. r) 3enzyl alcohol to phenyl ethanoic acid. s) (*nitro #romo #enzene to (*nitro #enzoic acid t) <* methyl acetophenone to #enzene*6=<*dicar#oxylic acid. u) 3 tanal to # tanoic acid. )) 'thyl # tanoate to ethanoic acid.

*) cyclo hexane to 2exane*6=?*dicar#oxylic acid. +) 3enzene*6=<*dicar#oxylic acid to pthalimide #. 'xplain the mechanism of the followin! reaction1 )2( )27 : 2)8 )2( )2 )8 72 $. 0n or!anic compo nd 0$)F2F7% !ives oran!e red precipitate with ,=<*D8/ rea!ent. -t responds to iodoform test. -t does not respond to ;ollens rea!ent test. -t does not decolorise #romine water. 0 on oxidation sin! )r7 ( !ive 3. -dentify the compo nds and write thw e> ations of the reactions involved. 1%. 0n or!anic compo nd )D26I7 forms ,=<*D8/ derivative= red ces ;ollens rea!ent and .nder!oes cannizaro reaction. 7n vi!oro s oxidation it !ives 3enzene*6=,*dicar#oxylic acid. -dentify the compo nd. 11. 0n or!anic compo nd contain ?D.EEM ) and 66.?(M 2 and the remainin! 7. Molec lar mass of the compo nd is F? . -t does not red ce ;ollens rea!ent= !ives positive iodoform test and respond to sodi m #is lphate test. 7n oxidation it !ives acetic acid and propanoic acid. Give the str ct re of the or!anic compo nd. 12. 0rran!e the followin! in the increasin! order of property mentioned1 a) 0cetaldehyde= 0cetone= Di*tert*# tyl ketone= Methyl tert*# tyl ketone$ reactivity with 2)8% b) ,*3romo # tanoic acid= (*3romo # tanoic acid= 3 tanoic acid= (*Methyl propanoic acid $acid stren!th% c) 3enzoic acid= <*8itro #enzoic acid= (=<*Dinitro #enzoic acid= <*Methoxy #enzoic acid $acid stren!th% d) 'thanal= /ropanal= /ropanone= 3 tanone$ increasin! order of reactivity towards n cleophile% e) 3enzaldehyde= p*;ol aldehyde= p*8itro #enzaldehyde= 0cetophenone$increasin! order of reactivity towards n cleophile% f) 3 tanal= 3 tanol= 'thoxy ethane and 3 tane $increasin! order of #oilim! point% 13. )omplete each synthesis #y !ivin! missin! startin! material= reactant or prod ct.

c) )?2@)27 : 82,)78282,

d) )?2@)27 : )2()2,)27 Dil 8a72 e) )2()7)2,)77),2@ i) 8a32< ii) 2:

f) )?2@)7)?2@

ii) &n C 2,7

14. Which acid of each pair wo ld yo expect to #e stron!erG a) 'thanoicacid and fl oro ethanoic acid b) Fl oro ethanoic acid and chloro ethanoic acid c) <* Fl oro # tanoic acid and (*Fl oro # tanoic acid d) p*;rifl oro #enzoic acid and p* Methyl #enzoic acid. 1 . 0rran!e the followin! in the increasin! order of #oilin! point1 'thanal= 'thanol= 'thoxy ethane and /ropane 1!. /redict the prod ct formed when cyclohexanecar#aldehyde reacts with

a) /hM!3r:2(7: b) ;ollensrea!ent c) Semicar#azide and weak acid d) excess ethanol and acid. e) &inc amal!am and dil te 2)l 1". Give the prod cts of the followin! reactions1

c) 4)2A)27 : 82,)78282, 2: d) )?2@)7)2( : ),2@@82, 2: e) )?2?:),2@)7)l 0nhydr. 0l)l( C )S, f) $)?2@)2,%,)d : , )2()7)l g) )2(* )A)2 2!,:=2,S7<

1#. -dentify the compo nds 0=3=) and D in the followin! reactions1 )2A)?2@

i) 7( ii) &n C 2,7 0:3

8a72Ca> ethanol ): 2,7

i) 7( ii) &n C 2,7 D:0

mines - 4 Marks Questions

1. Give one example each of the followin! named reactions1 a) Sand meyer reaction b) Ga#riel pthalimide synthesis. /) )o plin! reaction d) Diazotisation reaction. e) Gatterman reaction f) 2offmann #romamide reaction 2. 'xplain the followin! tests with s ita#le examples1 a) )ar#ylamine test b) 2ins#er! test. 3. 0cco nt for the followin!1 a) Methyl chloride reacts with 0!87, to !ive nitro methane as a ma9or prod ct where as it !ives nitrito methane as a ma9or prod ct with K87, b) )*8 #ond in aniline is shorter than in aliphatic amines. c) -n ammonalysis of halo alkane = primary amine is the only prod ct when lar!e excess of ammonia is sed while > aternary ammoni m salt is the only prod ct when halo alkane is in excess. d) /rimary and sec amines have hi!her #oilin! point than tert amine. e) 0mines have lower #oilin! point than alcohol of compara#le molar mass. f) 0mines are sol #le in water. Sol #ility of amines p.amines5sec amines5tert amines g) 0mines are less sol #le in water than alcohol. h) 3asicity of amines in a> eo s sol tion is sec amine5tert amine5p.amine.

i) 3asicity of amines in vapor phase tert amine5sec amine5p.amine. j) 0niline is a weaker #ase than aliphatic amine. k) 'lectron repellin! !ro p at ortho and para position increases the #asicity while electron with drawin! !ro p at ortho and para position decreases the density of aniline. l) 0mmonalysis of halo alkane is carried o t in the presence of a #ase. m) .nlike alkylation of amines acylation stops after first styep. n) ;ert amines do not react with acid derivatives. o) 0niline nder!oes #romination even in the a#sence of halo!en carrier. p) 8itration of aniline !ives <EM meta nitro aniline. () /*tol idine is more #asic than aniline. r) 0mines are less acidic than alcohol. s) 2alo alkane reacts with K)8 to !ive alkyl cyanide as a ma9or prod ct while it !ives alkyl isocyanide as a ma9or prod ct with 0!)8. t) 0niline do not nder!o Friedel craft"s reaction. u) 0niline can"t #e prepared #y Ga#riel pthalimide synthesis. )) 0r8,+ is more sta#le than 48,+ at lower temperat re. *) 0niline is a weaker #ase than ammonia. +) 7rder of #asicity $),2@%,825$),2@%(8 5 ),2@82,582( ,) 7rder of #asicity $)2(%,825)2(82,5$)2(%(8582( 0) 3romination of aniline after acylation !ives only para #romo aniline. aa) Sandmeyer reaction is prefered over Gatterman reaction to prepare halo arenes from aniline. bb) 'thyl amine is sol #le in water # t not aniline. cc) 0> eo s sol tion of methyl amine with ferric chloride sol tion !ives #rown precipitate of ferric hydroxide.. dd) Ga#riel pthalimide synthesis is prefered to prepare primary amine. ee) p*nitro aniline is less #asic than aniline.

4. )arry o t the followin! conversions1 a) 'thanoyl chloride to i) ethanamine. ii) 8*methyl amino ethane. b) 'thanoyl chloride methanamide c) Methanamine to i) 8*methyl ethanamide. ii) methyl iso cyanide. d) Dimethyl amine to 8=8 dimethyl amine. e) 'thane nitrle to i) ethanoic acid. ii) methyl ethanoate. iii) acetone. i)) ethanamine. f) 3enzo nitrile to i) #enzoic acid ii) aniline g) 0niline to i) chloro #enzene. ii) #romo #enzene. iii) flo ro #enzene i)) iodo #enzene . )) phenol )i) #enzene. )ii) #enzoic acid. )iii) para hydroxyl azo #enzene. i+) para amino azo #enzene.

+) 8itro #enzene +i) 6=(=@*tri#romo #enzene +ii) p*#romo aniline +ii) ,=<=?*tri#romo aniline +iii) #enzyl alcohol h) <*nitro tol ene to ,*#romo #enzoic acid. i) (*methyl aniline to (*nitro tol ene. j) 'thanoic acid to a) ethanamine b) methanamine k) Methanol to ethanoic acid. l) 'thanamine to methanamine m) Methanamine to ethanamine. n) 8itro methane to dimethyl amine. o) /ropanoic acid to ethanoic acid. p) 'thanoic acid to propanoic acid. () 8itro #enzene to #enzoic acid. r) 3enzene to m*#romo phenol. s) 3enzoic acid to aniline. t) 0niline to ,=<=?* tri#romo fl oro#enzene u) 3enzyl chloride to ,*phenyl ethanamine. )) )hloro #enzene to p*chloro aniline. *) 3enzamide to tol ene !. Distin! ish chemically #etween

a) Methyl amine and aniline b) methyl amine and dimethyl amine. c) 0niline and #enzyl amine d) 0niline and 8* methyl aniline. e) dimethyl amine and trimethyl amine. ". 0n or!anic compo nd 1 on reaction with 8a72 and 3r, !ives 2. 3 on diazotization !ives /. ) when warmed with water !ives 3. D !ives violet coloration with ne tral ferric chloride sol tion. -dentify the compo nds and write the e> ations of the reactions involved. #. Give e> ation for the followin! reactions1 a) ethanolic 82( with ),2@)l b) ammonalysis of #enzyl chloride followed #y reaction with , moles of methyl chloride. c) s lphonation of aniline d) reaction of aniline with acetic anhydride. e) reaction of aniline with a> eo s #romine. $. Give the str ct re of 0=3 and ) in the followin! reactions1 8a)8 a) ),2@0 partial hydrolysis 72* 3 3r, 8a72

) )8 b) )?2@8,)l 0

2(7: 3

82( )

c) ),2@3r :K)8

0 Hi0l2<

) 287,= ,E(K

d) )?2@87, FeC2)l

0 3 8a87,:2)l

) 2(7:

e) )2()772:82( 2eat

,E(K 0 8a73r

3 ) 8a87,:2)l= ,E(K

f) )?2@87, FeC2)l

0 3 8a87,:2)l= ,E(K

) )?2@72

1%. 0n or!anic compo nd 0 on heatin! with a> eo s ammonia forms 3. 3 on treatment with 3r , and K72 !ives ) of molec lar form la )?2E8. Give the str ct re of the compo nds 0=3 and ). Write -./0) name of the each compo nd. 11. Give the e> ations of the reactions involved when aniline is reacted with a) )2)l(:K72 b) )onc s lph ric acid c) a> eo s #romine d) acetic anhydride 12. Give the e> ation of the reaction involved when #enzene diazoni m chloride is treated with a) 2(/7,: 2,7 b) i) 23F< followed #y 8a87, C ) D 13. 0rran!e the followin!1 a) increasin! order of pK# val es* ),2@82,= $),2@%,82= )?2@82)2(= )?2@82, b) increasin! order of #asic stren!th 4i) )?2@82,= )?2@8$)2(%,= $),2@%,82=)2(82, 4ii) 0niline= para nitro aniline= para tol idine

4iii) 0niline= 8*Methyl aniline= #enzyl amine 4i)) 0niline= methyl amine= dimethyl amine= trimethyl amine= #enzyl amine 4i)) 0niline= ethyl amine= diethyl amine= triethyl amine. c) decreasin! order of #asic stren!th in !as phase ) ,2@82,= $),2@%,82= $),2@%(8= 82( d) increasin! order of #oilin! point* ),2@72= $)2(%,82=),2@82, e) increasin! order of sol #ility in water* 0niline= ethyl amine= Diethyl amine 14. Write the reaction of final alkylation prod ct with excess of ethyl iodide in the presence of Sodi m car#onate sol tion. 1 . Write the chemical reaction of aniline with #enzoyl chloride and !ive the -./0) name of the prod ct formed.

iomolecules - 4 Marks Questions

1. Mention the f nction of car#ohydrates in plants. 2. 2ow are car#ohydrates classifiedG Give one example each. 3. Fr ctose is a ketohexose # t it is a red cin! s !ar. WhyG 4. What are monosaccharidesG Give two examples. . Write the e> ations of the reactions involved when !l cose is reacted with a) acetic anhydride b) 2c) 2ydroxylamine d) 2)8 e) 3r,$a>% f) concentrated 287(. Write the si!nificance of each reaction. !. 'n merate the reactions of !l cose which can not #e explained #y open str ct res. ". Draw the 2owarth str ct res of a) N*D*$:% !l copyranose b) O*D*$:% !l copyranose c) N*D*$*% fr cto f ranose d) O*D*$*% fr co f ranose #. Draw the 2owarth str ct re of

a) s crose b) maltose c) lactose. )lassify them as red cin! or 8on red cin! s !ar. P stify yo r answer. $. 'xplain the terms a) m ta rotation b) anomers. 1%. Distin! ish #etween a) starch and cell lose b) amylose and amylo pectin c) starch and Glyco!en. 11. Give the hydrolysis prod cts of a) s crose b) lactose c) maltose. d) D80 containin! thymine 12. What is invert s !arG Why is it called soG 13. What are anomersG Draw the anomers of !l cose. 0re they enantiomersG 14. )lassify the followin! as monosaccharides and disaccharides1 a) ri#ose b) ,*Deoxy ri#ose c) s crose d) !alactose e) lactose f) maltose g) fr ctose 1 . 'xplain !lycosidic linka!e with an example. 1!. 'xplain the followin! with respect to protein a) primary str ct re of protein b) secondary Str ct re of protein c) tert str ct re of protein d) > aternary str ct re of protein e) native state of protein f) denat ration of protein g) zwitter ion

1". 'xplain peptide linka!e with an example. 1#. Mention the type of #ondin! in a) N helix str ct re b) O sheet str ct re c) cross links of polypeptide chain d) D80 1$. 8ame the forces which sta#ilize secondary and tert str ct re of protein. 2%. Distin! ish #etween a) N helix and O sheet str ct re b) fi#ro s and !lo# lar protein. c) primary and secondary str ct re of protein d) n cleoside and n cleotide 21. 0cco nt for the followin!Q a) 0mino acids are more sol #le and has hi!her meltin! point than halo acids. b) 0mino acids #ehave like salts rather than amines or car#oxylic acids c) 0mino acids are amphoteric d) 7n electrolysis amino acids mi!rate towards cathode in acid sol tion and anode in alkaline sol tion. e) Mono amino mono car#oxylic acid has two pk val es. f) 0mino acids are optically active. g) on #oilin! e!! it #ecomes hard 22. 8ame and !ive the str ct re of amino acid which is optically inactive. 23. What are essential and non essential amino acidsG Give two examples each. 24. What are enzymesG 'xplain the mechanism of enzyme catalysed reaction. 2 . What are coenzymesG Give two examples. 2!. What are vitaminsG 2ow are they classifiedG 2". Mention the so rces of vitamin

a) 0 b) ) c) D d) ' e) K f) 36 g) 3, h) 3? i) 36, . 8ame the diseases ca sed d e to the deficiency of each vitamin. 2#. Bitamin ) can #e taken re! larly # t not vitamin 0 WhyG 2$. What are n cleic acidsG Mention the f nctions of n cleic acids. 3%. Show the formation of a din cleotide with an example. 31. Mention the differences #etween D80 and 480. 32. ;wo strands of D80 are not identical # t complementary. 'xplain this statement. 33. What are different types of 480 present in the cell. 34. 'xplain the terms a) transcription b) translation 3 . What is the effect of denat ration of proteinG 3!. Where does the water present in e!! !o after #oilin!G 3". 3ase se> ence in a D80 strand is 0;;G))0 Give the #ase se> ence a) in its complementary strand b) messen!er 480 3#. When 480 is hydrolysed there is no relationship amon! the > antities of different #ase o#tained. What does this fact s !!est a#o t the str ct re of 480G 3$. Draw the str ct res of s !ars present in D80 and 480.

1. 'xplain the terms

a) monomer b) polymer c) polymerization 2. What are homo polymers and co polymersG Give , examples each. 3. 0rran!e the followin! in the increasin! order of molec lar forces1 a) 8ylon ?? b) polythene c) 3 na*S*r ##er 4. 2ow are polymers classified on the #asis of their str ct reG Give , examples each. . What do yo mean #y addition and condensation polymersG Give , examples each. !. What are a) nat ral polymers b) semi synthetic polymers c) synthetic polymersG Give one example each. ". What are #iode!rada#le polymersG Give an example of #iode!rada#le a) polyester b) poly amide. #. What are poly estersG Give two examples. $. What are poly amidesG Give two examples. 1%. Give differences #etween a) thermoplastic and thermo settin! plastic b) 8ylon ? and 8ylon ?? c) 8ovolac and 3akelite d) 3 na*S and 3 na*8 r ##er. 11. 'xplain the mechanism of polymerization of ethene. 12. 2ow is a) How density polythene b) 2i!h density polythene preparedG Mention their properties and !ive two ses of each. 13. 8ame and !ive the str ct res of monomers of

a) polythene b) poly propene c) /B) d) /oly acrylo nitrile e) ;eflon f) Dacron $ ;erelene% g) Glyptal h) 8ylon ? i) 3akelite j) 8ylon ?? k) /oly styrene l) 8at ral r ##er m) 8eoprene n) 3 na*8 r ##er o) 3 na*S*r ##er p) 8ovolac 14. Write the e> ation of the reaction involved in the preparation of a) polythene b) poly propene c) /B) d) /oly acrylo nitrile e) ;eflon f) Dacron $ ;erelene% g) Glyptal h) 8ylon ? i) 3akelite j) 8ylon ?? k) /oly styrene l) 8at ral r ##er m) 8eoprene n) 3 na*8 r ##er o) 3 na*S*r ##er p) 8ovolac () 8ylon*, 8ylon*? r) /23B s) Melamine formaldehyde resin. )lassify them as i) addition or condensation polymer ii) homo polymer or co polymer. Give two ses of each. 1 . What do yo mean #y v lcanization of nat ral r ##erG What is the p rpose of v lcanizationG 1!. Draw the str ct re of nat ral r ##er. 1". 2ow does the presence of do #le #ond infl ence the str ct re and reactivity of r ##erG

1#. -s

$ 82*)2*)7%

n homo polymer or co polymerG $)7* $)2,%?*82* $)2,%?*82*%n

1$. -dentify the monomer present in the polymer

/hemistr, in e)er,da, life - 3 Marks Questions

1. 'xplain the terms a) Dr !s b) Medicine c) )hemo therapy d) ;ar!et molec le e) Dr ! tar!et 2. 2ow are dr !s classifiedG 3. 2ow does enzyme act as dr ! tar!etG 4. 'xplain the followin! terms with respect to dr ! enzyme interaction a) enzyme inhi#itor b) competitive inhi#itor c) allosteric site. . 2ow do receptors act as dr ! tar!etG !. 'xplain the followin! term with respect to respect to receptor as dr ! tar!et a) anta!onist b) a!onist. ". What are antacidsG Give two examples. #. Metal hydroxides are #etter antacids than hydro!en car#onates. WhyG $. 4anitidine and cimitidine are #etter antacids than metal hydroxides and hydro!en car#onates. WhyG 1%. Give two examples of antihistamine which are anti aller!ic. 11. While antacids and anti aller!ic dr !s interfere with the f nction of antihistamine= why they do not with the f nction of each otherG 12. What are tran> ilisersG Give two examples. 13. Why sho ld not we take medicine with o t cons ltin! doctorG

14. How level of noradrenaline is the ca se for depression. What type of dr ! is needed to c re this pro#lemG 8ame two s ch dr !s. 2ow do they reactG 1 . 8ame two tran> ilisers s ita#le for relievin! tension. 1!. 8ame the tran> iliser sed in controllin! depression and hyper tension. 1". What are #ar#it ratesG Give two examples. 1#. Which amon! the followin! are tran> ilisersG 4anitidine= vali m= serotonin= and cimetidine. 1$. What are anal!esicsG 2ow are they classifiedG Give two examples each. 2%. 2ow does aspirin act as anal!esicG 21. 2ow does aspirin prevent heart attackG 22. Why sho ld we avoid sin! narcotics as anal!esicG 23. Morphine narcotics are referred as opiates. WhyG 24. Mention chief ses of narcotic anal!esic. 2 . What are anti micro#ial dr !sG 2!. What are anti#ioticsG Give two examples. 2". What do yo mean #y #actericidal and #acteriostaticG Give three examples each. 2#. What are a) #road spectr m anti#iotics b) narrow spectr m anti#iotics c) narrow spectr m anti#ioticsG Give two examples each. 2$. 8ame the anti#iotic developed #y /a l 'hrlich for the treatment of syphills. 3%. 8ame the anti#iotic which leads to the discovery of s lpha dr !s. 31. What are s lpha dr !sG Give two examples. 32. 8ame the anti#iotic sed to c re a) typhoid b) t #erc losis.

33. )lassify the followin! as #road spectr m= narrow spectr m or limited spectr m anti#iotics1 /enicillin*G= ampicillin= amoxicillin= chloramphenicol= vancomycin and ofloxacin. 34. 8ame the anti#iotic which is toxic towards certain strain of cancer cells. 3 . What are antisepticsG Give two examples. 3!. What are disinfectantsG Give two examples. 3". 2ow do antiseptic differ from disinfectantG 3#. 8ame the s #stance which is sed as antiseptic as well as disinfectant. 3$. Mention the constit ents of Dettol. 4%. 8ame the antiseptic added to soap. 41. What is tinct re of iodineG 42. )lassify the followin! as antiseptic or disinfectant1 F racin= soframycin= tinct re of iodine= iodoform= #oric acid= I.6M phenol= 6M phenol= I., ppm= )l, and very low concentration of S7,. 43. What are antifertility dr !sG Give one example each of a) synthetic pro!esterone b) estro!en derivative which are sed as antifertility dr !. 44. What are the main cate!ories of food additivesG 4 . 8ame the artificial sweetenin! a!ent sed #y dia#etic patient. 4!. Why is aspartame limited to cold food and drinksG 4". What pro#lem arises in sin! alitame as a sweetenin! a!entG 4#. Why do we need artificial sweetenin! a!entG 4$. What is the advanta!e of s cralose as a artificial sweetenin! a!entG %. What are food preservativesG Give two examples. 1. What are soapsG Give the e> ation of the reaction involved in the preparation of soap. 2. 2ow is a) ;oilet soap b) ;ransparent soap preparedG

3. Which chemical is added to shavin! soap to prevent rapid dryin!G 4. 8ame the ! m added to make shavin! soap. . 8ame the chemicals added to la ndry soap. !. 8ame the a) sco rin! a!ent b) # ilder added to soap. Mention the f nction of each. ". Why does soap not work in hard waterG #. What are deter!entsG Mention the advanta!e and disadvanta!e of soap over deter!ent. $. 2ow are deter!ents classifiedG Give one example each. Mention the se of each. !%. Write the e> ation of the reaction involved in the preparation of a) non ionic deter!ent b) anionic deter!ent. !1. What are #iode!rada#le and non #iode!rada#le deter!entsG Give one example each. !2. -f water contain calci m #icar#onate= o t of soap and deter!ent which one will yo !3. Ha#el the hydrophilic and hydropho#ic part present in the followin! compo nds1 a) )2($)2,%6I)2,7S7(8a b) )2($)2,%6@ 8$)2(%(3r c) )2($)2,%6I)77$)2,)2,7%n)2, )2,72 se to clean clothesG

d) )D26D 7$)2,)2,7%n)2,)2,72

!4. Give one important se of each of the followin!1 i) terfenadine ii) chlordiazepoxide iii) Morphine

i)) dysidazirine )) 8orethindrone.

56'1/ 7omeclature
5) Write the -./0) names of the followin! compo nds. a) n* # tyl chloride b) iso # tyl chloride c) secondary # tyl chloride d) tertiary # tyl chloride. e) ethylidene chloride f) ethylene di chloride f% vinyl chloride. g) p* )l )?2< )2, )2 $)2(%, h) m* )l )?2< )2,) $)2(%( i) $ ))l( %( ))l j) o* 3r)?2< )2$ )2(% )2, )2( k) )2(* ) $p*)l )?2< %, )2$3r% )2( F )l J J l) )2( )*)2, )*)2( J J ),2@ ),2@ m) )2()2A)2*)2,)2,3r

o) )?2@)l p) )?2@)2,)l

55) Write the -./0) names of the followin! compo nds 1) )2(*)2*)2*)2*)2( R R R )2( 72 )2( 3) Glycerol 4) ethylene !lycol ) )2(7 )2, S)2*)2( R )2( !) )2(7 )2, )2,7 )2( ") )?2@7 )2,)2( #) )?2@7)2( 2) )2(* )2*)2,*)2*)2, )2( R R 72 72

$) )?2@7 )E26@ 87, 1%) )2( )2, )2 )2 )2$)2(%, J J )2,)l )2,72 11) p*72)?2<72 12) $)2(%()7),2@ 13) )?2@7)2( 14) )?2@7$)2,%?)2(

1 ) )?2@7)2,)2,)2)2( J )2(

1!) 1") )2,A)2*)2*)2,)2,)2( J 72 1#) $)2(%,)A)$3r%*)2,72 1$) )2(*7*)2,*)2$)2(%,

21)

555) Write the -./0) names of the followin! compo nds. 1. 2)27 2. )2()27 3. )?2@)27 4. )2()7)2( . )?2@)7)2( !. )?2@)7)?2@ ". )?2@)7)2,)2( #. )2()7)2,)7)2( $. )27

12. )2,A)2*)27

13.

14. 1 . )27 * )2,*)2$)27%*)2,*)27 1!. 2)772 1". )2()772

1#. )?2@)772

1$. )772

2%. 58) Write the -./0) names of the followin! compo nds1 1. )2()2,)2,82, 2. )2()2)2( 82, 3. )?2@82, )2( 4. )2()2,)2,8 ),2@ . 82,)2,)2A)2, !. 82,$)2,%?82, ". )2()7 8*)2( ),2@ #. $)2(%,82 $. )?2@8$)2(%, 1%. )27*)2$)27%)2,)27 11. )772*)2$)772%)2,)772

Roll Number

Code No: 056/ISG/

Model Paper 1
Time allowed: 3 hrs

II ! C"#MISTR$%Theor&'

M(Mar)s: *0

Ge+eral I+s,ru-,io+s: 1( .+swer all ,he /ues,io+s( 0( ues,io+ +umber 1 ,o 1 -arr& 1 mar) ea-h( .+swer ,hem i+ o+e word or o+e se+,e+-e ea-h( 3( 2ues,io+ +umber 3,o 11 -arr& 0 mar)s ea-h( .+swer ,hem i+ 30 words ea-h( 4( 2ues,io+ +umber 13 ,o 0* -arr& 3 mar)s ea-h( .+swer i, i+ abou, 40 words ea-h( 5( 2ues,io+ +umber 01 ,o 30 -arr& 5 mar)s ea-h( .+swer ,hem i+ abou, *0 words ea-h( 6( 5se o6 -al-ula,or +o, permi,,ed( 5se o6 lo7 ,able permi,,ed(

1. 2. 3. 4. .

2ow does molar cond ctivity of a stron! electrolyte vary with the dil tion of electrolyte sol tionG Descri#e electrophoresis #riefly. 2(/7< is triprotic acid while 2(/7( is diprotic. WhyG )alc late the n m#er of tetrahedral voids and octahedral voids in an nit cell of F)). Write the -./0) name of the compo nd1 )2()7)2,)772

6 6 6 6 6

!. ". #. $.

Give one example of Swartz reaction. Mention two f nctions of n cleic acid. Mention the monomers of the polymer Dacron. 0cco nt for the followin!1 a) Mo ntain clim#ers sometimes !et symptoms of a condition known as anoxia. b) )alci m chloride is added to clear the roads covered #y snow.

6 6 6 ,

1%. Write the e> ations of the reactions involved at each electrode when an a> eo s sol tion of dil te 2 ,S7< is electrolysed sin! /t electrode. 11.

4esistance of I.I6M )2()772 sol tion is ,,,I ohm. )ell constant is I.(?? cm*6.)alc late the de!ree , of , dissociation and dissociation constant of )2()772 at this concentration. Given HI 2)l= 8a)l= 2 ()778a are <,@=6,F and D? scm, mole*6 respectively. ,

12. )omplete the followin! ionic e> ations1

i) )r,7E,* : Fe,: : 2: ii) Mn7<* :),7<,* :2: 13. 0cco nt for the followin!1 a) /hosphor s shows marked tendency for catenation while nitro!en shows little tendency for catenation. b) 7xy!en has lesser ne!ative val e of electron !ain enthalpy than S lph r. 14. Give one example each of a) Williamson"s synthesis b) 4eimer*;iemann reaction. 1 . )arry o t the followin! conversions1 a) /henol to para #romo#enzene. b) 'thanal to 0cetone 1!. -dentify the compo nds 0=3=) and D in the followin! reaction. 0 3 8a73r 8a87,:2)l ,E(*,EFK ) 2(7
:

D &n d st

)?2?

1". Give one example each of a) Ga#riel /thalimide synthesis. b) Sand Meyer reaction. Distin! ish chemically #etween a) Dimethlamine and ;rimethylamine. b) Methanamine and Dimethlamine. 1#. Write the e> ation of the reaction involved in the preparation of 3 na*S*r ##er. 1$. )alc late the density of nit cell of 8a)l. Given molar mass of 8a)lA@F.@ . Distance #etween 8a : and )l* is ,F6pm. 0va!adro n m#erA?x6I,( mole* . What type of defect does 8a)l exhi#it -f the act al density is 6.D@ !Ccm( 2%. ;he vapo r press res of p re li> ids 0 and 3 are <@I and EII mm 2! respectively at (@IK. Find the composition of li> id mixt re if the total press re is ?II mm 2!. 0lso find the composition in vapo r phase. 21. a) )r,7( : ,0l 0l,7(:,)r G GI A * <,6 KPCmole is thermodynamically feasi#le as is apparent from ne!ative val e of G GI. Why does it not occ r at room temperat reG b) Write the reactions involved in the extraction of Fe from heamatite ore. 22. a) Give fo r differences #etween lyophilic sol and lyopho#ic sol. b) Which is more effective in stoppin! #leedin!G Fe)l ( or K)l WhyG 23. .sin! valence #ond theory explain the str ct re and ma!netic #ehavior of TFe$)8% ?U<* $ 0tomic n m#er of FeA,?% 24. 0n alkyl halide )E26@3r is optically active. -t reacts with K72 sol tion to !ive racemic mixt re. 'xplain the mechanism of the reaction.

, (

2 . 0cco nt for the followin!1 a) ;ransition metals form complexes easily. b) First ionization enthalpy of early actinoids are lesser than that of early lanthanoids. c) 7f the d< species )r,: is red cin! while Mn(: is oxidizin!. 2!. What happens when D*Gl cose is treated with a) 2b) 287( c) 0cetic anhydride. 'xplain the si!nificance of each reaction. 9: Draw the 2owarth str ct re of s crose. -s it a red cin! or non red cin! s !arG P stify yo r answer. 2". a) While antacids and anti aller!ic dr !s interfere with the f nction of antihistamine= why they do not with the f nction of each otherG b) What are cationic deter!entsG Give one example of cationic deter!ent. Mention one se of cationic deter!ents. 2#. a) Derive the expression for the half life of a zero order reaction. b) 0:@3:?) #8perime+, 1. 2. 3. 4. (H:(M %.' M 0.02 0.01 0.02 0.02 %9' M 0.02 0.02 0.04 0.02 %C' M 0.02 0.02 0.02 0.04 Ra,e M/mi+u,e 00208 0.00104 0.00416 0.00832

Determine the order with respect to each reactant. Find K .)alc late the initial rate when concentration of each reactant is I.I6M.Find the initial rate of chan!e in concentrations of 3 and H 9: a) Mention the factors which affect the rate of a reaction. b) ;he followin! data were o#tained d rin! the first order decomposition of S7,)l, at constant vol me S7,)l,$!% S7,$!% :)l,$!%

;+periment <ime4sec) <otal pressure4atm) 6 I I.@ , 6II I.? )alc late the rate when total press re is I.?@ atmospheres. 2$. a) 0cco nt for the followin!1 i) ,=,=?*;rimethylcyclohexanone is less reactive towards n cleophile than cyclohexanone. @

ii) Formaldehyde and #enzaldehyde nder!oes cannizaro reaction. b) )arry o t the followin! conversions1 i) 3enzoic acid to m*nitro#enzoic acid. ii% 3enzoyl chloride to #enzaldehyde. iii) 0cetic acid to acetone. 9: a) 0n or!anic compo nd contain ?D.EEM )ar#on and 66.?(M 2ydro!en and the remainin! 7xy!en. Molec lar mass of the compo nd is F? . -t does not red ce ;ollens rea!ent= !ives positive iodoform test and respond to sodi m #is lphate test. 7n oxidation it !ives acetic acid and propanoic acid. Give the str ct re of the or!anic compo nd. b) Give one example each of i) Decar#oxylation ii) 2B& reaction 3%. a) Draw the str ct res of i) +e7F< ii) 2)l7< iii) )lF( b) )omplete the followin! reactionsQ i) 7(:2,7:-* ii) +eF?: KF 9: a) 0cco nt for the followin!1 i) /< is more reactive than 8, ii) +e forms compo nds with fl orine and oxy!en. iii) 0ll the five #onds in /)l@ are not e> ivalent. b) Draw the str ct res of i) SF< ii) 2,S,7E @