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1.

What is the sum of all coefficients when the following equation is balanced using the smallest possible whole numbers? __ C2H2 + __O2 __CO2 + __H2O A " C % ! # $$ $&
(Total 1 mark)

2.

$ # g of 'a'O& (Mr ) *!+ is dissol,ed in water to prepare - 2- dm& of solution What is the concentration of the resulting solution in mol dm.&? A " C % - -$ -$ -2 $(Total 1 mark)

3.

What is the sum of all coefficients when the following equation is balanced using the smallest possible whole numbers? __ C2H2 + __O2 __CO2 + __H2O A " C % ! # $$ $&
(Total 1 mark)

IB Questionbank Chemistry

4.

$ # g of 'a'O& (Mr ) *!+ is dissol,ed in water to prepare - 2- dm& of solution What is the concentration of the resulting solution in mol dm.&? A " C % - -$ -$ -2 $(Total 1 mark)

5.

How man/ molecules are present in a drop of ethanol0 C 2H!OH0 of mass 2 & 1 $-.& g? (L ) 2 - 1 $-2& mol.$+ A " C % & - 1 $- $3 & - 1 $-22 - 1 $-22 - 1 $-22
(Total 1 mark)

6.

Which sample has the greatest mass? A " C % $ mol of 4O2 2 mol of '2O 2 mol of Ar 5 mol of 'H&
(Total 1 mark)

IB Questionbank Chemistry

7.

6he relati,e molecular mass of a gas is !2 and its empirical formula is CH 2 What is the molecular formula of the gas? A " C % CH2 C2H5 C&H2 C5H*
(Total 1 mark)

8.

7thanol is used as a component in fuel for some ,ehicles One fuel mi8ture contains $- 9 b/ mass of ethanol in unleaded petrol (gasoline+ 6his mi8ture is often referred to as :asohol 7$(a+ Assume that the other 3- 9 b/ mass of :asohol 7$- is octane $ -- ;g of this fuel mi8ture was burned CH&CH2OH(l+ + &O2(g+ 2CO2(g+ + &H2O(l+ <HO ) .$&2# ;= mol.$ <HO ) .!5#- ;= mol.$

$ C*H$*(l+ + $2 2 O2(g+ *CO2(g+ + 3H2O(l+

(i+

Calculate the mass0 in g0 of ethanol and octane in $ -- ;g of the fuel mi8ture

(1)

(ii+

Calculate the amount0 in mol0 of ethanol and octane in $ -- ;g of the fuel mi8ture

(1)

IB Questionbank Chemistry

(iii+

Calculate the total amount of energ/0 in ;=0 released when $ -- ;g of the fuel mi8ture is completel/ burned

(3)

(b+

>f the fuel blend was ,apori?ed before combustion0 predict whether the amount of energ/ released would be greater0 less or the same 78plain /our answer

(2) (Total 7 marks)

9.

What mass0 in g0 of h/drogen is formed when & mol of aluminium react with e8cess h/drochloric acid according to the following equation? 2Al(s+ + 2HCl(aq+ 2AlCl&(aq+ + &H2(g+ A " C % &5! 23(Total 1 mark)

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10.

What is the total number of h/drogen atoms in $ - mol of ben?amide0 C 2H!CO'H2? A " C % # 2 - 1 $-2& & - 1 $-25 5 2 1 $-25
(Total 1 mark)

11.

What is the sum of the coefficients for the equation when balanced using the smallest possible whole numbers? __'2H5(g+ + __O2(g+ __'O2(g+ + __H2O(g+ A " C % ! 2 # *
(Total 1 mark)

12.

Chloroethene0 C2H&Cl0 reacts with o8/gen according to the equation below 2C2H&Cl(g+ + !O2(g+ 5CO2(g+ + 2H2O(g+ + 2HCl(g+ What is the amount0 in mol0 of H2O produced when $- - mol of C2H&Cl and $- - mol of O2 are mi8ed together0 and the abo,e reaction goes to completion? A " C % 5 -* -$- 2- (Total 1 mark)

IB Questionbank Chemistry

13.

A fi8ed mass of gas has a certain ,olume at a temperature of !- @C What temperature is required to double its ,olume while ;eeping the pressure constant? A " C % $-- A &2& A &#& A 252 A
(Total 1 mark)

14.

What is the concentration of 'aCl0 in mol dm.&0 when $- - cm& of - 2-- mol dm.& 'aCl solution is added to &- - cm& of - 2-- mol dm.& 'aCl solution? A " C % - 5!- &-- !-- *-(Total 1 mark)

15.

Which amount of the following compounds contains the least number of ions? A " C % 2 mol of 'aOH $ mol of 'H5Cl 2 mol of CaCl2 $ mol of Al2O&
(Total 1 mark)

IB Questionbank Chemistry

16.

What is the appro8imate molar mass0 in g mol.$0 of Bg4O5C#H2O? A " C % $2$&$&* 252
(Total 1 mark)

17.

Which is both an empirical and a molecular formula? A " C % C!H$2 C!H$C5H* C5H$(Total 1 mark)

18.

$2 molecules of h/drogen gas0 H2(g+0 and ! molecules of o8/gen gas0 O2(g+0 were mi8ed together under conditions which allowed the reaction to go to completion0 according to the following equation 2H2(g+ + O2(g+ 2H2O(g+ 6he following diagram represents the mi8ture of reactants

IB Questionbank Chemistry

Which diagram represents the reaction mi8ture when the reaction was complete? A

"

(Total 1 mark)

IB Questionbank Chemistry

19.

"rass is a copper containing allo/ with man/ uses An anal/sis is carried out to determine the percentage of copper present in three identical samples of brass 6he reactions in,ol,ed in this anal/sis are shown below 4tep $D Cu(s+ + 2H'O&(aq+ + 2H+(aq+ Cu2+(aq+ + 2'O2(g+ + 2H2O(l+ 4tep 2D 5>.(aq+ + 2Cu2+(aq+ 2Cu>(s+ + >2(aq+ 4tep &D >2(aq+ + 242O&2.(aq+ 2>.(aq+ + 45O22.(aq+

(a+

(i+

%educe the change in the o8idation numbers of copper and nitrogen in step $ CopperD

'itrogenD
(2)

(ii+

>dentif/ the o8idi?ing agent in step $


(1)

(b+

A student carried out this e8periment three times0 with three identical small brass nails0 and obtained the following results Bass of brass ) - 5!2 g E - --$ g

Titre Initial volume of 0.100 mol dm 3 !2"32 (# 0.05 $m3) %inal volume of 0.100 mol dm 3 !2"32 (# 0.05 $m3) &olume added of 0.100 mol dm 3 !2"32 (# 0.10 $m3) 'vera(e volume added of 0.100 mol dm 3 !2"32 (# 0.10 $m3)

1 - -2* !2* !-

2 - -2* 22* 22* !-

3 - -2* 52* 5-

IB Questionbank Chemistry

(i+

Calculate the a,erage amount0 in mol0 of 42O&2. added in step &

(2)

(ii+

Calculate the amount0 in mol0 of copper present in the brass

(1)

(iii+

Calculate the mass of copper in the brass

(1)

(i,+

Calculate the percentage b/ mass of copper in the brass

(1)

(,+

6he manufacturers claim that the sample of brass contains 55 2 9 copper b/ mass %etermine the percentage error in the result

(1)

IB Questionbank Chemistry

10

(c+

With reference to its metallic structure0 describe how brass conducts electricit/

(1) (Total 10 marks)

20.

What is the coefficient of Fe&O5 when the following equation is balanced using the lowest whole numbers? __ Al(s+ + __ Fe&O5(s+ __ Al2O&(s+ + __ Fe(s+ A " C % 2 & 5 !
(Total 1 mark)

21.

What is the mass0 in g0 of one molecule of ethane0 C2H2? A " C % & - 1 $-.2& ! - 1 $-.2& &$ * 1 $-2!
(Total 1 mark)

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11

22.

Which molecular formula is also an empirical formula? A " C % GCl& C2H5 H2O2 C2H$2O2
(Total 1 mark)

23.

Which of the following is consistent with A,ogadroHs law?

P T ) constant (V0 n constant+ V T ) constant (P0 n constant+


Vn ) constant (P0 T constant+

" C

V n ) constant (P0 T constant+


(Total 1 mark)

24.

6he percentage b/ mass of calcium carbonate in eggshell was determined b/ adding e8cess h/drochloric acid to ensure that all the calcium carbonate had reacted 6he e8cess acid left was then titrated with aqueous sodium h/dro8ide (a+ A student added 2# 2- cm& of - 2-- mol dm.& HCl to - $** g of eggshell Calculate the amount0 in mol0 of HCl added

(1)

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12

(b+

6he e8cess acid requires 2& *- cm& of - $-- mol dm.& 'aOH for neutrali?ation Calculate the amount0 in mol0 of acid that is in e8cess

(1)

(c+

%etermine the amount0 in mol0 of HCl that reacted with the calcium carbonate in the eggshell

(1)

(d+

4tate the equation for the reaction of HCl with the calcium carbonate in the eggshell

(2)

(e+

%etermine the amount0 in mol0 of calcium carbonate in the sample of the eggshell

(2)

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13

(f+

Calculate the mass and the percentage b/ mass of calcium carbonate in the eggshell sample

(3)

(g+

%educe one assumption made in arri,ing at the percentage of calcium carbonate in the eggshell sample

(1) (Total 11 marks)

25.

2 - mol of aluminium reacts with o8/gen to form aluminium o8ide What is the amount of o8/gen0 in mol0 needed for complete reaction? 5Al(s+ + &O2(g+ 2Al2O&(s+ A " C % $! &5! 2(Total 1 mark)

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14

26.

What is the total number of nitrogen atoms in t)o mol of 'H5'O&? A " C % 5 2 -2 1 $-2& $ 2- 1 $-25 2 5$ 1 $-25
(Total 1 mark)

27.

On anal/sis0 a compound with molar mass 2- g mol.$ was found to contain $2 g of carbon0 2 g of h/drogen and $2 g of o8/gen What is the molecular formula of the compound? A " C % CH2O CH5O C2H5O C2H5O2
(Total 1 mark)

28.

7qual masses of the metals 'a0 Bg0 Ca and Ag are added to separate samples of e8cess HCl(aq+ Which metal produces the greatest total ,olume of H 2(g+? A " C % 'a Bg Ca Ag
(Total 1 mark)

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15

29.

6he graph below represents the relationship between two ,ariables in a fi8ed amount of gas

Which ,ariables could be represented b/ each a8is? x*a+is A " C % pressure ,olume pressure temperature y*a+is temperature temperature ,olume ,olume
(Total 1 mark)

30.

* ! g of 'H& are dissol,ed in H2O to prepare a !-- cm& solution Which statements are correct? > >> >>> A " C % 'H& is the solute and H2O is the solution 6he concentration of the solution is $# g dm.& I'H&J ) $ - mol dm.&

> and >> onl/ > and >>> onl/ >> and >>> onl/ >0 >> and >>>
(Total 1 mark)

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16

31.

Consider the following sequence of reactions


reaction 1 reaction 2 reaction 3 KCH "r KCH OH KCOOH KCH& 2 2

KCH& is an un;nown al;ane in which K represents an al;/l group

(a+

6he al;ane contains *$ # 9 b/ mass of carbon %etermine its empirical formula0 showing /our wor;ing
(3)

(b+

7qual ,olumes of carbon dio8ide and the un;nown al;ane are found to ha,e the same mass0 measured to an accurac/ of two significant figures0 at the same temperature and pressure %educe the molecular formula of the al;ane
(1)

(c+

(i+

4tate the reagent and conditions needed for reaction 1


(2)

(ii+

4tate the reagent(s+ and conditions needed for reaction 3


(2)

(d+

Reaction 1 in,ol,es a freeLradical mechanism %escribe the stepwise mechanism0 b/ gi,ing equations to represent the initiation0 propagation and termination steps
(4)

(e+

6he mechanism in reaction 2 is described as 4'2 (i+ 4tate the meaning of each of the s/mbols in 4'2
(1)

(ii+

78plain the mechanism of this reaction using curl/ arrows to show the mo,ement of electron pairs0 and draw the structure of the transition state
(3) (Total 16 marks)

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17

32.

&-- cm& of water is added to a solution of 2-- cm& of - ! mol dm.& sodium chloride What is the concentration of sodium chloride in the new solution? A " C % - -! mol dm.& - $ mol dm.& - 2 mol dm.& - & mol dm.&
(Total 1 mark)

33.

6he molar mass of a compound is appro8imatel/ !2 g mol .$ Which formula is possible for this compound? A " C % 'a'O& AgOH BgO AOH
(Total 1 mark)

34.

Which compound has the empirical formula with the largest mass? A " C % C2H2 C2H5 C2H2 C&H2
(Total 1 mark)

IB Questionbank Chemistry

18

35.

What is the coefficient for O2(g+ when the equation for the combustion of $ mole of pentane is balanced? C!H$2(g+ + _O2(g+ _CO2(g+ + _H2O(g+MN A " C % ! 2 * $2
(Total 1 mark)

36.

What is the ma8imum mass0 in g0 of magnesium o8ide that can be obtained from the reaction of o8/gen with 2 5 g of magnesium? A " C % 25 &5!2
(Total 1 mark)

37.

! dm& of carbon mono8ide0 CO(g+0 and 2 dm& of o8/gen0 O2(g+0 at the same temperature and pressure are mi8ed together Assuming complete reaction according to the equation gi,en0 what is the ma8imum ,olume of carbon dio8ide0 CO2(g+0 in dm&0 that can be formed? 2CO(g+ + O2(g+ 2CO2 A " C % & 5 ! #
(Total 1 mark)

IB Questionbank Chemistry

19

38.

Which statement about solutions is correct? A " C % When ,itamin % dissol,es in fat0 ,itamin % is the sol,ent and fat is the solute >n a solution of 'aCl in water0 'aCl is the solute and water is the sol,ent An aqueous solution consists of water dissol,ed in a solute 6he concentration of a solution is the amount of sol,ent dissol,ed in $ dm & of solution
(Total 1 mark)

39.

"iodiesel ma;es use of plantsH abilit/ to fi8 atmospheric carbon b/ photos/nthesis Ban/ companies and indi,iduals are now using biodiesel as a fuel in order to reduce their carbon footprint "iodiesel can be s/nthesi?ed from ,egetable oil according to the following reaction

(a+

>dentif/ the organic functional group present in both ,egetable oil and biodiesel
(1)

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20

(b+

For part of her e8tended essa/ in,estigation into the efficienc/ of the process0 a student reacted a pure sample of a ,egetable oil (where K ) C $#H&&+ with methanol 6he raw data recorded for the reaction is below Bass of oil Bass of methanol Bass of sodium h/dro8ide Bass of biodiesel produced ) $-$& - g ) 2-- - g ) &!g ) *$$ - g

6he relati,e molecular mass of the oil used b/ the student is **! 2 Calculate the amount (in moles+ of the oil and the methanol used0 and hence the amount (in moles+ of e8cess methanol

(3)

(c+

6he re,ersible arrows in the equation indicate that the production of biodiesel is an equilibrium process (i+ 4tate what is meant b/ the term dynamic equilibrium

(1)

(ii+

Osing the abbre,iations I,egetable oilJ0 ImethanolJ0 Igl/cerolJ and IbiodieselJ deduce the equilibrium constant e8pression (Kc+ for this reaction

(1)

(iii+

4uggest a reason wh/ e8cess methanol is used in this process

(1)

IB Questionbank Chemistry

21

(i,+

4tate and e8plain the effect that the addition of the sodium h/dro8ide catal/st will ha,e on the position of equilibrium

(2)

(d+

6he reactants had to be stirred ,igorousl/ because the/ formed two distinct la/ers in the reaction ,essel 78plain wh/ the/ form two distinct la/ers and wh/ stirring increases the rate of reaction

(2)

(e+

Calculate the percentage /ield of biodiesel obtained in this process

(2)

(f+

When biodiesel is combusted it produces carbon dio8ide 78plain wh/ the use of biodiesel as a fuel does not significantl/ contribute to global warming

(1) (Total 14 marks)

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22

40.

6he percentage of iron(>>+ ions0 Fe2+0 in a ,itamin tablet can be estimated b/ dissol,ing the tablet in dilute sulfuric acid and titrating with standard potassium manganate(P>>+ solution0 ABnO5(aq+ %uring the process iron(>>+ is o8idi?ed to iron(>>>+ and the manganate(P>>+ ion is reduced to the manganese(>>+ ion0 Bn2+(aq+ >t was found that one tablet with a mass of $ 5& g required $$ 2 cm& of 2 -- 1 $-.2 mol dm.& ABnO5(aq+ to reach the endLpoint (a+ (i+ 4tate the halfLequation for the o8idation of the iron(>>+ ions
(1)

(ii+

4tate the halfLequation for the reduction of the BnO5. ions in acidic solution
(1)

(iii+

%educe the o,erall redo8 equation for the reaction


(1)

(b+

(i+

Calculate the amount0 in moles0 of BnO5. ions present in $$ 2 cm& of 2 -- 1 $-.2 mol dm.& ABnO5(aq+

(1)

(ii+

Calculate the amount0 in moles0 of Fe2+ ions present in the ,itamin tablet

(1)

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23

(iii+

%etermine the percentage b/ mass of Fe2+ ions present in the ,itamin tablet

(2) (Total 7 marks)

41.

What is the number of o8/gen atoms in one mole of Cu4O 5C!H2O? A " C % ! 3 2 - 1 $-2& ! 5 1 $-25
(Total 1 mark)

42.

Which sample has the greatest mass? A " C % 2 - 1 $-2! molecules of h/drogen ! - mol of neon atoms $ 2 1 $-25 atoms of sil,er $ # 1 $-2 g of iron
(Total 1 mark)

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24

43.

What ,olume of sulfur trio8ide0 in cm&0 can be prepared using 5- cm& sulfur dio8ide and 2- cm& o8/gen gas b/ the following reaction? Assume all ,olumes are measured at the same temperature and pressure 24O2(g+ + O2(g+ 24O&(g+ A " C % 252*(Total 1 mark)

44.

Which sample of nitrogen gas0 '20 contains the greatest number of nitrogen molecules? A " C % $ 5 g '2 $ 5 dm& of '2 at $ -$ 1 $-! Ga and 2#& A $ 5 1 $-2& '2 molecules $ 5 mol '2
(Total 1 mark)

45.

Aspirin0 one of the most widel/ used drugs in the world0 can be prepared according to the equation gi,en below

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25

(a+

4tate the names of the t,ree organic functional groups in aspirin

(3)

(b+

A student reacted some salic/lic acid with e8cess ethanoic anh/dride >mpure solid aspirin was obtained b/ filtering the reaction mi8ture Gure aspirin was obtained b/ recr/stalli?ation 6he following table shows the data recorded b/ the student & $! E - -2 g 2 !- E - -2 g

Bass of salic/lic acid used Bass of pure aspirin obtained

(i+

%etermine the amount0 in mol0 of salic/lic acid0 C 2H5(OH+COOH0 used

(2)

(ii+

Calculate the theoretical /ield0 in g0 of aspirin0 C 2H5(OCOCH&+COOH

(2)

(iii+

%etermine the percentage /ield of pure aspirin

(1)

IB Questionbank Chemistry

26

(i,+

4tate the number of significant figures associated with the mass of pure aspirin obtained0 and calculate the percentage uncertaint/ associated with this mass

(2)

(,+

Another student repeated the e8periment and obtained an e8perimental /ield of $!- 9 6he teacher chec;ed the calculations and found no errors Comment on the result

(1) (Total 11 marks)

46.

4mog is common in cities throughout the world One component of smog is GA' (pero8/ac/lnitrate+ which consists of 2- 2 9 C0 $$ 5 9 '0 2! 3 9 O and 2 !- 9 H b/ mass %etermine the empirical formula of GA'0 showing /our wor;ing

(Total 3 marks)

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27

47.

Which nonLmetal forms an o8ide QO2 with a relati,e molecular mass of 2-? A " C % C ' 4i 4
(Total 1 mark)

48.

How man/ o8/gen atoms are there in - 2- mol of ethanoic acid0 CH &COOH? A " C % $ 2 1 $-2& 2 5 1 $-2& & - 1 $-25 2 - 1 $-25
(Total 1 mark)

49.

5 -- mol of a h/drocarbon with an empirical formula of CH 2 has a mass of 2*- g What is the molecular formula of this compound? A " C % C2H5 C&H2 C5H* C!H$(Total 1 mark)

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28

50.

What will be the concentration of sulfate ions in mol dm .& when - 2- mol of AAl(4O5+2 is dissol,ed in water to gi,e $-- cm& of aqueous solution? A " C % -2 $25(Total 1 mark)

51.

6he ,olume of an ideal gas at 2# - @C is increased from & -- dm & to 2 -- dm& At what temperature0 in @C0 will the gas ha,e the original pressure? A " C % $& ! !5 &2# 2-(Total 1 mark)

52.

6he data below is from an e8periment used to determine the percentage of iron present in a sample of iron ore 6his sample was dissol,ed in acid and all of the iron was con,erted to Fe 2+ 6he resulting solution was titrated with a standard solution of potassium manganate(P>>+0 ABnO5 6his procedure was carried out three times >n acidic solution0 BnO 5. reacts with Fe2+ ions to form Bn2+ and Fe&+ and the end point is indicated b/ a slight pin; colour

titre initial -urette readin( . $m3 %inal -urette readin( . $m3 /ass of iron ore . ( $on$entration of 0/n"4 solution . mol dm
3

1 $ -25 2-

2 2& 252 $& 2*2 1 $-.$ 2 $!2 1 $-.2

3 $- -&2 !-

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29

(a+

%educe the balanced redo8 equation for this reaction in a$idi$ solution

(2)

(b+

>dentif/ the reducing agent in the reaction


(1)

(c+

Calculate the amount0 in moles0 of BnO5. used in the titration

(2)

(d+

Calculate the amount0 in moles0 of Fe present in the & 2*2 1 $- .$ g sample of iron ore

(2)

IB Questionbank Chemistry

30

(e+

%etermine the percentage b/ mass of Fe present in the & 2*2 1 $- .$ g sample of iron ore

(2) (Total 9 marks)

53.

Which coefficients would balance this equation? __ BnO2 + __ HCl __ BnCl2 + __ Cl2 + __ H2O /n"2 12l 2 & 5 5 /n2l2 $ $ $ $ 2l2 $ $ $ 2 12" $ $ 2 2
(Total 1 mark)

A " C %

$ $ $ $

54.

What ,olume of carbon dio8ide0 in dm& under standard conditions0 is formed when # -- g of ethene (C2H50 Mr ) 2* $+ undergoes complete combustion?

22 5 2* $ # -22 5 # -2* $ 2 22 5 2* $ # -2 22 5 # -2* $


(Total 1 mark)

"

IB Questionbank Chemistry

31

55.

How man/ h/drogen atoms are in one mole of ethanol0 C2H!OH? A " C % $ --1$-2& & 2$1$-25 ! -2 -(Total 1 mark)

56.

What is the coefficient for H24O5(aq+ when the following equation is balanced0 using the smallest possible integers? __Bg&'2(s+ + __H24O5(aq+ __Bg4O5(aq+ + __('H5+24O5(aq+ A " C % $ & 5 #
(Total 1 mark)

57.

Air bags in cars inflate when sodium a?ide decomposes to form sodium and nitrogenD 2'a'&(s+ 2'a(s+ + &'2(g+ Calculate the amount0 in moles0 of nitrogen gas produced b/ the decomposition of 2 !2 mol of 'a'&(s+ A " C % $ 2* 2 !2 & #* # !2
(Total 1 mark)

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32

58.

What ,olume0 in cm&0 of - 2-- mol dm.& HCl(aq+ is required to neutrali?e 2! - cm & of - 2-mol dm.& "a(OH+2(aq+? A " C % $2 ! 2! !- #! (Total 1 mark)

59.

- 2-- mol of aluminium h/dro8ide is mi8ed with - 2-- mol of sulfuric acid0 and the following reaction occursD 2Al(OH+&(s+ + &H24O5(aq+ Al2(4O5+&(aq+ + 2H2O(l+

(a+

%etermine the limiting reactant

(2)

(b+

Calculate the mass of Al2(4O5+& produced

(2)

IB Questionbank Chemistry

33

(c+

%etermine the amount (in mol+ of e8cess reactant that remains

(1)

(d+

%efine a Brnsted-Lo ry acid and a Le is base "rRnstedLSowr/ acid

Sewis base
(2)

(e+

H24O5(aq+ is a strong acid 4tate the name and the formula of an/ wea; acid

(1) (Total 8 marks)

60.

A to8ic gas0 A0 consists of !& * 9 nitrogen and 52 2 9 carbon b/ mass At 2#& A and $ -$1$-! Ga0 $ -5* g of A occupies 522 cm& %etermine the empirical formula of A Calculate the molar mass of the compound and determine its molecular structure
(Total 3 marks)

IB Questionbank Chemistry

34

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