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  • DLC Coating On Food Packaging Film Using PIII-D Technique

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    The document discusses coating food packaging films with diamond-like carbon (DLC) using plasma immersion ion implantation and deposition (PIII-D) technique. PIII-D allows for selective deposition on conducting and non-conducting materials using low power pulsed plasma. The author coated polyethylene terephthalate (PET) and polyvinylidene chloride (PVDC) films for 5, 10, and 15 minutes and found that oxygen transmission rate was reduced by up to 23% for PVDC and 21% for PET films compared to uncoated films. Characterization showed the DLC coatings increased in thickness and reduced transparency with longer deposition times.

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    DLC Coating on Food Packaging Film Using PIII-D Technique

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    The document discusses coating food packaging films with diamond-like carbon (DLC) using plasma immersion ion implantation and deposition (PIII-D) technique. PIII-D allows for selective deposition on conducting and non-conducting materials using low power pulsed plasma. The author coated polyethylene terephthalate (PET) and polyvinylidene chloride (PVDC) films for 5, 10, and 15 minutes and found that oxygen transmission rate was reduced by up to 23% for PVDC and 21% for PET films compared to uncoated films. Characterization showed the DLC coatings increased in thickness and reduced transparency with longer deposition times.

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    Attribution Non-Commercial (BY-NC)
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    238 visualizzazioni27 pagine

    DLC Coating On Food Packaging Film Using PIII-D Technique

    Caricato da

    iwpda2009
    The document discusses coating food packaging films with diamond-like carbon (DLC) using plasma immersion ion implantation and deposition (PIII-D) technique. PIII-D allows for selective deposition on conducting and non-conducting materials using low power pulsed plasma. The author coated polyethylene terephthalate (PET) and polyvinylidene chloride (PVDC) films for 5, 10, and 15 minutes and found that oxygen transmission rate was reduced by up to 23% for PVDC and 21% for PET films compared to uncoated films. Characterization showed the DLC coatings increased in thickness and reduced transparency with longer deposition times.

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    di 27

    DLC Coating on Food Packaging Film

    Using PIII-D Technique

    D. BOONYAWAN
    PBPF, Dept of Physics&Mat.Sci., Fac of Science, Chiang Mai University, Thailand
    *ThEP Center, CHE, 328 Si Ayutthaya Rd., Bangkok 10400, Thailand

    Chiang Mai University

    IWPDA2009, 2-3 July, Singapore


    Where are us?

    Chiang Mai University

    IWPDA2009, 2-3 July, Singapore


    What is PIII-D?

    Chiang Mai University

    IWPDA2009, 2-3 July, Singapore


    PIII-D benefits
    • Higher ion energy (>1 keV)
    • Low power (pulsed mode)
    • Conducting to non-c materials used
    • Selective species

    Chiang Mai University

    IWPDA2009, 2-3 July, Singapore


    DLC- benefits
    • Flexible, Reusable & Biocompatible
    • Reduced friction & wear
    • Reduced gas permeability
    (good gas barrier)
    • Well adhere to polymer

    Diamond-like Carbon ?

    Chiang Mai University

    IWPDA2009, 2-3 July, Singapore


    Experiment

    • PET & PVDC: 60 mm

    • Ar sputtering prior deposition: 5 min


    • C2H2 Deposit with – 3 kV pulse 20 mS
    @200Hz
    • Process time: 5, 10, 15 min

    Chiang Mai University

    IWPDA2009, 2-3 July, Singapore


    Characterization

    • Oxygen Transmission Rate (OTR)


    • Color/transparency
    • Atomic Force Microscope
    • Raman spectroscopy

    Chiang Mai University

    IWPDA2009, 2-3 July, Singapore


    Result : OTR

    Chiang Mai University

    IWPDA2009, 2-3 July, Singapore


    Result: Color
    Processing Times L a b ∆E
    PVDC
    0 (uncoated) 99.93 -0.01 0.02 0.00

    5 91.15 0.30 6.02 10.64

    10 90.35 0.36 13.14 16.25

    15 85.90 1.21 18.11 22.93


    PET

    0 (uncoated) 100.00 -0.01 0.00 0.00


    5 93.56 0.19 6.05 8.84

    10 92.46 0.42 12.17 14.32

    15 85.36 0.63 18.02 23.23


    Chiang Mai University

    IWPDA2009, 2-3 July, Singapore


    PET 5/10/15 min

    Chiang Mai University

    IWPDA2009, 2-3 July, Singapore


    Result: Transparency

    Chiang Mai University

    IWPDA2009, 2-3 July, Singapore


    Result: Thickness I

    PVDC 5 min PVDC 15 min

    Chiang Mai University

    IWPDA2009, 2-3 July, Singapore


    Result: Thickness II

    Chiang Mai University

    IWPDA2009, 2-3 July, Singapore


    Result: Raman PET

    Chiang Mai University

    IWPDA2009, 2-3 July, Singapore


    Result: Raman PVDC

    Chiang Mai University

    IWPDA2009, 2-3 July, Singapore


    Conclusions

    • DLC coated PET & PVDC using planar PIII-D technique


    • Growth rate ~ 10 -15 nm/min
    • OTR reduced by 23% for PVDC and 21% for PET
    • Films Transparency reached saturation same as OTR results
    • Compare with CVD, lower in film growth rate and OTR but better in
    unwanted compositions

    Chiang Mai University

    IWPDA2009, 2-3 July, Singapore


    Thank you

    Chiang Mai University

    IWPDA2009, 2-3 July, Singapore


    G- Peak

    500
    Data: Data1_B
    Model: Gauss
    400 D- Peak Equation: y=y0 + (A/(w*sqrt(PI/2)))*exp(-2*((x-xc)/w)^2)
    W eighting:
    y No weighting

    300 Chi^2/DoF = 84.52922


    R^2 = 0.99601

    y0 0 ? 0

    200 xc1 1389.13982 ? 1.02402


    w1 325.46658 ? 1.13869
    A1 115660.53285 ? 625.0784

    xc2 1557.52464 ? 0.25229

    100 w2 129.63881 ? 0.80726

    A2 45263.81962 ? 536.92968

    -100
    800 1000 1200 1400 1600 1800 2000
    Chiang Mai University

    IWPDA2009, 2-3 July, Singapore


    Force applied : Aligning:
    Start 16 weeks

    1 m.

    Chiang Mai University

    IWPDA2009, 2-3 July, Singapore


    Plasma deposition system

    Chiang Mai University

    IWPDA2009, 2-3 July, Singapore


    Dual filtered cathodic arc plasma,

    Cathodic vacuum
    arc plasma source

    Chiang Mai University

    IWPDA2009, 2-3 July, Singapore


    Chiang Mai University

    IWPDA2009, 2-3 July, Singapore


    Plasma Enhanced ALD system

    Chiang Mai University

    IWPDA2009, 2-3 July, Singapore


    Chiang Mai University

    IWPDA2009, 2-3 July, Singapore


    The picture to showed IR-heater, temperature variable from a few ten to
    390°c at 200 VAC. and substrate holder area 11×11 cm2.
    Chiang Mai University

    IWPDA2009, 2-3 July, Singapore


    (a) Bottom view (a) Bottom view

    (b) Side view


    (b) Side view

    The picture to showed beam profile of Ar with pressure 3.4×10-1 torr and
    the microwave plasma 75 watt.
    Chiang Mai University

    IWPDA2009, 2-3 July, Singapore


    Analysis Techniques :
    PIXE, RBS, RBS Channeling, Ion Luminescence

    RBS
    RBS/Channeling

    PIXE IL
    e-gun

    Sample holder
    1.7 MV Tandetron accelerator Analysis Chamber
    Chiang Mai University

    IWPDA2009, 2-3 July, Singapore

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