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|.K.'s MCQs Series for Medical Entrance Examinations Exhaustive Question Bank | TLC Assertions and Reasons Model Test Papers of AIIMS, CBSE (PMT), CPMT ie Information contained in this work has been obtained by LK. Iniernational Pvt. Ltd from sources believed (0 be reliable, However. neither LK. International Pvt, Lid. nor ils authors guarantee the accuracy or completeness of any information published herein and neither publisher nor the authors stall be responsible for any errors, omissions, oF damages arising out of use of this faformation, This work is published sith the ander standing that LK. Intemational Pvt. Lid, and ils authors are supplying information but ot allempting to render any professional services, If such services are required, the assistance of an appropriate professional should he soughe Published by: LK. Intemational Pvt, Led 5. Green Park Extension Uphaar Cineme Market New Delhi 110019 (India) Esmail :ik_in@vsal.net Branch Offices A-6, Royal Industrial Estate, Naigaum Cross Road Wadala, Murmbai 490 031 (india) E-mail :tk_mumbai@vsnlnct G-4, “Embassy Centre”, 11 Cresent Road, Kumara Park East, Bangalore 560001 (India) E-mail :ik_bang @vsnl.net ISBN. 81-88237-28.0 © 2006, LK. International Pyt, Lid All rights reserved, No part of this book may be reproduced or used in any form, elestronie or mechanical, including photocop ying, recording, or by any information eval system, without written permission from the publisher. storage and ret Published by Krishan Makhijani for LK. International Pvi, Ltd. $-25, Green Park Exten- sion, Uphaar Cinema Market, New Delhi 119 016, Printed by Rekha Printers Pvt.Ltd, Okila industrial Area, Phase Hl, New Dethi 110020, Contents Prefece PART1 1,_Atoms, Molecules and Chemical Arithmetic s, their Ou and Extraction 3. Chem ical Fumilies —Periodie Properties 23 4. Bonding and Molecular Structure 31 5. Chemisiey of Non 45 6, Chemistry of Non-metals—Il 57 7. Chemisiry of Lighter Metals 69 ‘Chemistry of Heavier Metis n 9. Chemistry of Reprensative Elements 89) 10, Transition Metals including Lanthanides 99 11. Co-ordination Chemistry and Organometallics 109) 12, Nuclear Chemistry ny. PART 2 ORGANIC CHEMISTRY 1. Purification and Characterisation of Organic Compounds 147 2. Hydrocarhons (Aliphatic, Aromatic) 1s! 3. Alkyl/ Aryl Hal 7 4. Phenols! Aleohols 5. Carbonyl Compounds 213 6 Ethers 2s 7. Carboxylic acids 231 197 © xe &. Nitrogen Containing Compounds 2. Sulphur Containing Compounds 10. Synthetic and Natural Polymers IL, Biomolecules 12. Chemistry of Biological Processes 13. Chemistry in Action 14. Miscellaneous Questions ‘Assertion and Reasons PART 3 PHYSICAL CHEMISTRY 1. Atomie Structure 2_Slates of Matter 3. Bnergeties 4. Chemical Equilibrium 8 Solutions. 9. Chemical Thermodynamics 10. Electro Chemistry LL. Surface Chemistry. A er erern 1. Sample Paper=1 2. Sample Paper-2 3. Sam ple Paper: 4. Sum ple Papert 5. Sample Papers PART 5 SOLVED MODEL TEST PAPERS OF PREVIOUS THREE YEARS 1. ALLMS. 2. CBSE-PMT 3. CPMI-UP.) pS 6: 75 REBEREBE BEEER 537-575 577-610 Inorganic Chemistry : Atoms, Molecules and Chemical Arithmetic : Elements, their Occurrence and Extraction : Chemical Families - Periodic Properties : Bonding and Molecular Structure i: Chemistry of Non-metals : Chemistry of Non-metals-2 Chemistry of Lighter Metals : Chemistry of Heavier Metals : Chemistry of Reprensative Elements : Transition Metals including Lanthanides : Co-ordination Chemistry and Organometallics : Nuclear Chemistry O©OMPNOAPHOna 3 VVVVVVVVVYVVV = x Copyrighted material Atoms, Molecules and Chemical Arithmetic * Choose the Correet O ption(s) — $$$" 1 Which of following is correct? a. = Ikg! im b. 1 ce. 1 = Ikg m?>s? d. 1J= kg ms? Ikg'm s? . Pascal is the S.1. unit for: a, Energy c. Pressure b. Work d. Force . The number of atoms in 12 gm of oC? will bez a. 12 b. 6.023 x 10% c. 6 x 6.023 x 10° d. None of these }. One mole of water corresponds to:- a. 18 gm b. 22.4 litre at 1 atm and 25°C . 1 picometre is . 6.023 x 10° atoms of oxygen d. all of these 107° Is a. 10-* b. c. 10! a. 10 . Which of the following is nota ho- mogencous mixture? a. Air b. Smoke ¢. Brass d, Petrol . Which of the following is an ex- ample of Metalloid? a. Copper b. Oxygen c¢. Antimony d. None of these . One ferm a. 10 om b. 10°? em e108 em 4. 10 em oe IK's MCQs—Chemistry 9 10. 12. 13. 14. 16. Which of the following is the stan- dard for atomic mass? a iH b. ae a. Chlorine is considered as an ele- ment because: a. Itdissolves in water b. Itisa gas at room temperature c. Ithas one kind of atoms only d. None of these . The number of significant figures in 5090.80 is:- a3 b 4 e-5 d. 6 ‘The Law which states that a chemi- cal compound always contains the same element combined in a fixed ratio by mass is called as: a. Law of definite proportion b. Law of conservation of mass c. Law of reciprocal proportion d. None of these The number 0.000570 can be writ- ten as:- a 570x104 — b. 5.7 x 107 c. 5.70 x 10" d. 5.7 x 10 Significant figures in 0.00029 are:- a2 b. 3 a4 ds . The empirical formula of sucrose a. CHO C50 3H 9305, b. C(H,0)5 d. None of these S.1. unit of pressure i aN b. Nm! c. Nm? d. None of these . A compound (empirical formula = C,H,O,) has vapour dens molecular formula will be 59. Its 18. 20. 21, 22, 23. 24, b. CHO, d. None of these a, CoH,03 ©. CgHyO, The number of significant figures for the number 182, 0.182, 0.0182 ares a, 3,4, 5 respectively b. 3,4, 4 respectively d. 3, 3, 4 respectively 3, respectively . When KMnO, is converted into MnSO, its equivalent weight will bez a. M/2 c. M/S The number of moles present in 64 g of sulphur is: a. 0.25 b.1 d. None of these b. M/ 3 d. M/7 2 S.L unit of temperature is: ae vb. F « K d. Allofthe above Which of the gases contain the same number of molecules of 16 grams oxygen? a, 16 gram of SO, b. 32 gram of SO, c. 48 gram of SO; d. None of these The percentage compositions of cle- ments of H,S, SO, will explain:- a. Law of conservation of mass. b. Law of constant proportion c. Law of multiple proportion 4. Law of reciprocal proportion Which of the following has the smallest number of molecules? a. 22g of CO, gas Atoms, Molecules and Chemical Arithmetic oe 26. 27, 28. 29, 30. 3. 32, b. 11.2 litres CO; gas c. 0.1 mole of CO, gas d, Allhave same no. of molecules . I mole of oxygen gas has the same ma a, 1g atoms of oxygen b. 2g atoms of oxygen c. 16g atoms of oxygen d. 32g atoms of oxygen 112 em? of hydrogen gas at STP con- tains: a, 0.005 mole 0.5 mole b. 0.05 mole d. 5mole Crude petroleum is refined by:- a. distillation b. fractional distillation ¢. fractional crystallization d. None of these The Law of constant composition was discovered by: a, Dalton b, Lavoisier c. Proust d. None of these Avogadro Number of Helium atoms weights: a. Ig b. 4g c. 8g d. 4x 6.023 x 1039 IM solution of H,SO, is diluted from 1 litre to 5 litres. The normality of resulting solution will be a, 0.1N b. 0.2 N c. O.4N d. How many moles of H, is present in 0.224 litres of hydrogen gas at STP? a. 0.001 b. 0.01 0.1 al The specific heat of an clement of atomic weight 32 i 33. 34. 36. 37. 38. 39. 40. a. 0.16 ©. 0.32 b. 0.20 d. None of these The mass of one molecule of CO, d. 7.31 x 107 One mole of CO, contains:- a, 6.023 x 10° atoms of C b. 6.023 x 10° atoms of O c. 3gram atoms of CO, d. None of these 5. 2 gram-atom oxygen weighs: a. 2g b. 162 d. 642 10 gram of each N,, 0, and Cl, are kept in three bottles. What is the correct order of arrangement of bottles containing decreasing no. of molecules? a. Np, 03,Ch c. Cl,0,,N; ©. 328 b. O3,N3, Cl d. None of these A gas is found to have (CO), molecu- lar formula. If its vapour density is 70, ‘x’ will be: a. 3 b. 4 5 d.6 The mass of 1 x 10” molecules of CuSO ,.511,0 is a, 2.65 b. 4.13 c. 26.5 d. 413 The number of molecules present in 8 g of oxygen gas are:- b. 3.x 109 d. None of these a. 1.5 x 10% c. 6.023 x 10° The relative atomic masses of many elements are not whole number because:- a, elements have fractional atomic masses b. elements are mixtures of isotopes oe IK's MCQs—Chemistry 41. 42. 44. 45. 46. 47. 48, c. elements are mixtures of isobars d. None of these At NTP, a mixture of 2 moles of H, and I mole of He occupies a. 22.4 litres b. 44.8 litres ¢. 67.2 litres d. None of these 6.023 x 10* molecules represents:- a. 0.1 mole b. Imole c. 10 mole d. None of these . Which of the following has least weight? a. 1g atom of potassium b. 0.1 mole of sucrose c. 2.0 g mole of CO, d. 1.5 mole of water 6.023 x 10” molecules of N, at NTP will occupy a volume of:- a. 2.24 litres b. 2: c. 224 litres 4 litres d. None of these Vapour density of pure ozone is:- alo ob 24 © 32 4. 48 0.5 M solution of NaOH contains how many g of NaOH dissolved in 250 ml of solution. a. 402 b. 208 © Weg dose The largest number of molecules is in: a, 64g of nitrogen peroxide b. 34g of carbon dioxide c. 36 g of water d. 70 g of sulphur dioxide Two elements A & B having atomic weights 14 g and 40 g respectively combine to form anew substanceY. If three moles of B combine with 1 mole of A to give one mole of Y, then weight of one mole of X will be a, 54g b. 82g 49, 50. wm . Weight of 1 litre of H, gas at NTP ©. 134g d. None of these The volume of 20g of H, gas at STP ise b, 22.4 litres d. 224 litres a. 5.24 litres c. 112 litres 46 g of sodium metal reacts with methyl alcohol to give a, one mole of hydrogen b. two moles of hydrogen c. two moles of oxygen d. None of these Which of the following has maxi- mum number of atoms? a. 16g of O b. 44 g of CO, c. l6gofH,O — d. 16g of CH, 52. How much CO, is produced when 10g of CaCO, reacts with 01M HCI? b. 224 em? 2240 cm* a. 12er c. 1120 em? a. . The number of atoms in 1g of He- lium is a 6x10" c 4x6x10% d. b. 2x6 x 10" % x6 x 10% 2 moles of H atoms at NTP occupies a volume of:- a. 2 litres b. 11.2 litres c. 22.4 litres d. 44.8 litres . If the vapour density of a gas is 11.2, the volume occupied by 2.4 g of tl a. 0.01 ce. 22.4 b. 0.09 d. None of these |. The number of atoms contained in one mole of sulphuric acid is:- a, 6.023 x 1073 b. 3x 6.023 x 10% Atoms, Molecules and Chemical Arithmetic eo 58. 59, 60. 61. 62. . Tf M i. c. 5 x 6.023 x 10% d. 7 x 6.023 x 10% The mass of an atom of nitrogen is a. l4a.m.u —4 _., 6023x105 28 6.023% 10° © 1 6.023x 10° © In the reaction, 4NH,(g) + 50, (g) —— > 4NO(g) + 6H,O(1) when one mole of NH, and 1 mole of O, are made to react to completion: a. 1 mole of NO is produced b. 1 mole of H,0 is produced ce, all O, will be consumed d. all NH; will be consumed Avogadro’s law finds application in the determination of: a. Molecular weight of gases b. Atomicity of gases ¢. Molecular formula of certain gas- cous compounds d. Allofthe above If the density of a gas at NTPis 3.57g dm™, Its molecular mass will be: a. 35 b. 65 c. 80 d. None of these 2 ¢ of hydrogen will have same number of molecules as present in:- a. 14g of Nitrogen b. 32g of SO, c, 24g of Ozone d. 71g of Chlorine the molecular weight of a dibasic acid, then what will be the equivalent weight of acid? a. M/2 b. M c. 2M d. M2 64. 66. 67. 68. 69. 70. 71. The percentage of oxygen in NaOH is a. 16 b. 32 ©. 40 d. None of these . 24g of metal reacts with an acid to liberate 22.4 litres of hydrogen at STP. The equivalent weight of the metal a, 12 b. 24 c. 48 d. None of these How many grams of H,SO, are present in 0.5 mole of H,S0,? a. 05 bh. 4.9 ec. 49 d. None of these Two different oxides of a metal con- tain 20% and 25% oxygen by weight. This is in accordance with the law of a. constant composition b, reciprocal proportion ¢. conservation of mass d. multiple proportion When 0.5 M of BaCl, is mixed with 1M H,SO,, the maximum amount of BaSO,, precipitated will be: a. 05M bo 1M c. 25M d. None of these How many moles of water is present in 1 x 107! kg of water? 1x 107! ‘i RB b. 1x 10" x 18 1x 107! x02 1x 107! 18 “18x 10° Active mass of 8% solution of com- pound A is 2. Molecular weight of A willbe: a. 20 b. 40 d. 80 1 mole of methane contains:- c. 60 a. 4g of carbon oe IK's MCQs—Chemistry 72. 73. 74, 76. 77, b. 6.023 x 10° atoms of Hydrogen c. 4g atoms of hydrogen d. None of the above Number of water molecules in one litre of pure water i a. 18 x 107 b. 6.023 x 107? c. 3.45 x 10° d. None of these 12 g of Magnesium will react com- pletely with acid to g a. Imoleof Hy b. “mole of Hy c “mole of Hy d. None of these 9g of a trivalent metal combines with 8g of oxygen. The atomic weight of the metal is:- a. 36 b, 27 co. 18 d.9 . Two elements A & B combine to form two compounds in which ‘x’ g of A combines with y, & y,g of B respectively, so according to law of multiple proportion: a, xl y) isa whole no. b. y; & yz isa simple ratio c. y; & yp are equal d. y, & yy have no relation How many moles of KMnO, is required to oxidise one mole of Fe(C,0,) in acidic medium? a. 02 b. 0.4 c 0.6 d. None of these One gram molecular volume of a gas is the volume occupied by: a. 1g of the substance b. 1g molecular weight of the sub- stance c. 22.4 of the substance 78. 79. 80. 81. 82. d. 6.023 x 10°* g of the substance The amount of HS (in g) needed to precipitate 31.75 g of Cu” ions ise a, 15.87 g b. c 34g To prepare 2 litres of 0.5 M solution of HNO,, the volume of 10.5 M so- lution required a. 10.5 ml e. 95.2 ml I7g d. None of these b. 50 ml d. None of these What is the correct order of arrang- ing the following in order of their increasing masses. L 1 atom of nitrogen IL 1 Molecule of oxygen UL 1 x 10'°g molecular weight of oxygen a << Til b. P< Si>Fe>Ca>Al b. O> Fe > Si> Al>Ca c, Si>O>Ca>Fe>Al d. Al> Fe > Ca>O>Si 2. Which of the following does not occur in free state in nature? a.O b.Si- oc. Na d. Ar 3. Which of the following occur in na- tive state? a, Chlorine b. Tin ¢. Magnesium — d. Silver 4, Which of the following is extracted from oxide ore? a. Aluminum b. Iron c. Zine d. Copper . Which of the following metals oce- urs as chloride? a.Na b. Ag c. Ca d. Cu . Bauxite is:- a. Al,O, c. Na,AIF, b. A1,0,2H,0 d. AL{SO,); . The richest ore of iron is: a. Magnetite b. Haemite c. Siderite d. Iron pyrites . Mica contains: a. K b. Al c. Si d. Fe . Which of the following ore is cal- cined to produce metal? a. Cinnabar b. Iron pyrites ec. Bauxite @ IK's MCQs—Chemistry 10. il. 12. 14. 16. 17. d, None of the above Smelting involves the reduction of metal oxide with: a. Carbon b. Carbon monoxide c. Hydrogen d. Lime stone Which of the following metal is present in haemoglobin? a. Magnesium >. ce. Sodium d. Ca Iron ium Which of the following is present in sea? a. Sodium chloride b. Iodine c. Magnesium d. Aluminium . Which of the following is present in human thyroid gland? a, Bromine b. Zine c. Tron d. Iodine Asbestos contains: a, Calcium b. Magnesium c. Silicon d. Aluminum . Which of the following can be obtained by electrolysis of their salts? a, Magnesium —b. Calcium ©. Sodium d. Copper Bessemensation is used in the met- b. Aluminum d. Silver Silver ore is concentrated by mak- ing use of the solubility of its ore ins c. Magnesium a, Ammonia b. Nitric ¢. Potassium cyanide cid 18. 19, 20. 21. 22. 24, d. Hydrochloric acid Which of the following are ores of copper? a. Malachite green b. Willemite c. Dolomite a. Kaolin Froth flotation is used in the metal- lurgy of a. Carbonate ores b. Oxide ores c. Sulphide ores d, Sulphate ores Calcination is carried out by heating the ore in: a. A limited supply of air b. Nitrogen atmosphere c. In excess of air a. None of the above Roasting is carried outin az a. Blast furnace b. Electric furnace c. Reverberatory furnace d. Muffle furnace Which of the following are extracted from sulphide? a. Copper b. Silver c. Zine d. Aluminum . Steel on heating to bright redness and then cooling it suddenly by plunging in oil or water is called: Annealing b. Quenching c. Tempering 4. None of the above In the metallurgy of copper, the roasted ore is mixed with coke and ica and melted in a blast furnace. The function of silica is to:- Elements, their Occurrence and Extraction @ 26. 27. 28. 29, 30. a. Form slag b. Form matte (Cu,8) c. Blister copper d. None of the above . Blister copper is refined by= a. Polling b. Electrolytically c. Heating with carbon d. Heating with hydrogen The impurities of Ag, Au and Pt which are present in blister copper can be separated by: a. Polling b, Electrolytic refining c, Heating in air d. None of the above Gold is isolated from pulverized gold bearing quartz by:- a. Amalgamation process b, Mac Arthur — Forrest Cyanide process c. Ele lytic proc d, None of the above Bessemer converter is used for the manufacture of:- a. Steel b. Pig iron ¢. Cast iron d. Wrought iron Mond process is used for preparing = a. Ni b. CO c. NH; d. HNO, In blast furnace iron oxide is re- duced by: a. Silica b. Carbon ce, Carbon monoxide d. Lime stone . Inaluminothermite process, alumi- num acts asi 32. 34. 36. 37. 38. a. Areducing agent b. An oxidizing agent c. A complex forming agent d. none of the above In the manufacture of aluminum by electrolysis of alumina, cyrolite is added: To increase electrical conductivity. b. To reduce temperature of melt so that the electrolysis can proceed at low temperature c. Because cyrolite complexes with bauxite d. To increase the melting point of alumina . Thermal decomposition method is used to purify: a. Ni ce. Na b. Ti d. Ca Auto reduction process is used in the extraction of = a. Cu and Hg ce, Cu and Al b. Zn and Hg d, Fe and Pb . Which of the following metals is ex- tracted by amalgamation? a. Au b, Fe c. Al a. Cu Which of the following metals can be obtained by the electrolysis of an aqucous solution of their salts? a, Ca b. Al c. Mg d. Na In froth floatation process which of the following is used? b. Pine oil d. None An ore which contains FeCrO, is concentrated by a, Froth flotation a. Lime stone c. Amylalcohol @ IK's MCQs—Chemistry 39. 40. 41. 42. 43. 44, b. Gravity separation ¢. Magnetic separation d, None of the above Which of the following is used as flux forthe smelting of iron and lead ores? a, CaCO, b, CaO c. Na,CO; d. None of the above In the thermite process for the ex- traction of Cr, Mn, ete. which of the following is used? a Bo ob. Ga oc. In d. Al Gold Schmidt’s alumina - thermic process is used for the: Extraction of metals from the cor- responding oxides. b. Extraction of non — metals from the corresponding oxides. c. Welding of metals especially steel. d. None of the above The method of zone refining is used to prepare ultra pure sample of: a Cu be Ag oc. Au d. Ge Impure silver containing impurities of Pb, Cu and Au is purified by elec- trolytic refining. In this process the anode mud obtained contains: a. Pb b. Cu c. Pb,Cu,Au d. Au Lead is extracted from the ore: a, Galena b. Anglesite © Magensite — d. Carnallite . Which of the following ore contains iron? a, Magnetite b. Copper pyrites ce. Azurite d. Willemite 46, 47. 48. 49, 50. Sly Cr,0, can be converted into Cr by reduction with b. Aluminum d. Nickel a, Carbon c. Hydrogen Some metals can be obtained in very pure state by heating with io- dine and then decomposing the formed iodide at higher tempera- ture. This method is known as: a. Poling b. Zone refining c. Van Arkel method d. None of the above Impure nickel is purified by: a. Electrolytic refining b. Mond carbonyl process c. Zone refining method d. Van Arkel Method In the forth floation process, the ore particles float because:- a. they are light b. they are insoluble c. their surfaces are not easily wet- ted by water d. all the above he best method for the purifica- tion of mereury is by:- a. treatment with dil. HNO, b. treatment with dil. H,SO, c. treatment with dil. HCI a. distillation under reduced pres- sure. A powdered ore on treatment with dilute H,SO,, produces a gas which on passing through lime water gives amilky precipitate. The ore can be = b. Calamine c. Zine blended. Willemite Elements, their Occurrence and Extraction @o 52. 54, uw a 56. 57. A powdered ore on treatment with dilute H,SO, gives a gas having smell of rotten eggs. The gas gives a black colour with lead acetate pa- per. The ore can he: b. Zinc blende d. Magens a. Magnetite c. Epsom salt e . A powdered ore gives a brick red colour if its paste in HCI is heated in aflame on a platinum wire. The ore can be: a, Carnallite —_b, Dolomite c. Gypsum d. Corundum A powdered ore on heating with cone. H,S0, and K,Cr,0, crystals produce chromyl chloride. The ore can be: a. Carnallite b. Felspar c. Cassiterite d. Bauxite Which of the following will respond positively to chromyl chloride test? a. Zincite b. Siderite c. Malachite green d. The crude residue obtained by heating sea water to dryness. A solution of an ore in cone. HCI gives a black precipitate on passing HS through it. The ore can be:- a. Malachite green b. Zincite e& siterite d. Cinnabar Which of the following ore can be detected by flame test? a, Carnallite b. Zincite c. Dolomite d. None of the above 60. Treatment of Lassi 58. A mixture of a powdered ore and sand on heating with conc. H,SO, produces oily drops on the side of the test tube. On bringing a moist glass rod near the mouth of the tube, white turbidity is produced. The ore can bes b, Bauxite d. Mica a. Cryolite c. Corundum 59. A powdered ore is fused with Na,CO, and the fused mass ex- tracted with water. In the clear water extract, CO, gas is passed when a white precipitate is obtained. The ore can be:- a. Magnesite b. Bauxite c. Magentite d. Malachite green gne extract of an ore on warming with FeSO , solu- tion and then treatment with a few drops of FeCh, solution gives a blood red colour. The ore can be a, Chile salt petre only b. Zine blend only c. amixture of a and b. d. None of the above 61. Which of the following ore will re- spond positively to the Lassaigne test for the presence of nitrogen? a. Zincite b. Chile salt petre ¢. Cinnabar d. Copper glance 62. A clearsolution of a powdered ore in conc, HNO, gives a yellow pre- cipitate on heating with ammonium molybdate. The ore can be:- a. Sulphide ore © IK's MCQs—Chemistry 63. 64, 65. 66. 67. 68. b, Oxide ore c. Carbonate ore d, Phosphite ore A powdered ore on heating with conc. HjSO,and ethyl alcohol gives vapours which on bringing near a flame gives blue colour. The ore can bes a, Malachite green b, Calamine c. Tinacal d. Cryolite A powdered ore on being subjected to borax — bead test produces a pink bead. The ore may contain: a. Tron b. Copper c. Manganese d. Calcium The presence of which of the fol- lowing ones can be tested with di- lute sulphuric acid? a. Magnesite. Gypsum c. Zinc blended. Anglisite On passing 1,8 gas into a solution of asalt in dilute HCI black precipi- tate is obtained. The salt may con- tains a, Cu b. Pb c. Pe d, Co Which of the following will not re- spond positively to the Lassaigne test for the presence of nitrogen? a. Urea b. Thiourea c. Hydrazine d. Hydroxylamine In acharcoal cavity test, a colourless salt on fusion with cobalt chloride gives agreen mus. The salt contains: a. Ba** b. Zn* c. Fe* d. Na* 69, 70. 71. 72. 74. Which of the following can be de- tected by the flame test? a. Zn* b. Kt c. Ba* The carius method can be used for the estimation of:- b. Carbon d. Oxygen a, Sulphur c. Halogens In ammonical solution, a salt gives a black precipitate with H,S. The salt may be: a, Barium salt b. Magnesium salt c. Cobalt salt d. Nickel salt The presence of iron in ferrous state can be detected by using:- a. Potassium ferrocyanide b. Potassium ferricyanide c. Both a. and b. d. None of the above A salt on warming with dil. H,SO, and subsequent treatment with few drops of dilute KMnO, solution - the colour of KMnO, is discharged. The salt may bez a, a sulphite c. a carbonate b. a sulphate d. a bicarbonate In the ring test fornitrates, the com- position of the ring is:- a. FeSO,NO> b. FeSO, NO c. can be both a and b d. none of the above . A yellow precipitate is obtained by passing HS gas through an acidic solution of: d. Cobalt salt d. Cadmium salt a. Zine salt c. Copper salt Elements, their Occurrence and Extraction oOo la 2. bie 3. d 4. ae 5. a,b 6b la 8. a,byc % & 10. a Il. b 12. a,b,c 13. d 14, a,b,c 15. a,b,c 16. IT, ¢ 18. a Ve. & 20. a 2l.c¢ 22, abe 2 & 24. a 25. a,b 26. b 27. a,b 28. a 29, a 30. ¢ 31. a 32. a,b 33. a 34. a 35. a 36. d 38. © 39. a 40. d dl ajbsc | 420d 44. a 45. ab 46. a 47, ¢ 48. b 50. d b 52. b 53. ¢ S4. a 56. a,c,d d 58. a 59. b 60. ¢ 62. d i 8 64. 65. a,c 66. a,b 68. b 69. b,c 70. a,c 71. ed 72. b Chemical Families—Periodic Properties * Choose the Correet O ption(s) — $$$" 1. The internal bond angle in SO, is:- a. 60° b. 90° c. 109.5% d. 120° » Paramagnetism is exhibited by ele- ments, whose elements have: a. only odd number of electrons b. only even number of electrons c. the d— shell is completely filled d. none of these 3. Which of the following are correct with respect of the atomic rad a. Cl> Br b. Mg>Na ce. Ca> Sr a. PSN 4. Which of the following has maxi- mum ionic character? a. CsCl b. CaCl, c. Sr Cl; d. Ba Cl, 5. In the halogens, which of the fol- lowing increases from iodine to fluorine? a. Electronegativity b. Oxidizing power c. Bond length d. None of the above 6. The boiling point of ICI is higher than that of Br,, This is because: a. ICL isa polar molecule b. ICL is a non — polar molecule ¢. I-Cl bond is stronger than Br ~Br bond. d. The [Clis an unsymmetrical mol- ecule 7. Which of the following compounds have maximum ionic character? @ IK's MCQs—Chemistry a. NaF c. CIF b. NaS d. CsI 8. Formation of an ion from an atom volve: a, Gain or loss of protons b. Gain or loss of electrons c. both a.and b. d. none of the above 9, The electron affinity of the halogens is of the order: a T. Br c. Mg as 11. An element has highest oxidation state of 7. It may belong to:- b. Group 7 d, Group 17 a, Group 2 c. Group 15 12. The diagonal relationship in peri odic table arises due to:- a, Similarity of the size of ions. b. Similarity in electropositive char- acter ¢. Similarity in polarizing power. d. all the above 13. In the long form of periodic table, the elements are arranged depend- ing on thei a, atomic size — b, atomic number c, atomicmass d. oxidation state 14, Which of the following will have the highest ionization energy? b. Chlorine d. Barium a. Neon c. Sodium 15. 16. 18. 19. 20. The correct order of decreasing ra- dii of the elements Si, Al,Na and P ise a. P, Si, Al, Na ec. Na, Al, Si, P b. Na, Si, Al, P d. P, Al, Si, Na A cereal is advertised to contain 100 mg of sodium per 100 g of the cereal, What is the percentage of sodium in the cereal? a. 1.0% b. 10% c. 0.1% d. 1.1% The total energy of electron in an atom a. Zero b. greater than zero c. less than zero d. may be greater or less than zero depending on the nature of the orbital involved An element in third period has:- a. three complete shells b. three complete sub — shells c, three valence electrons d. three electrons less than octet. A coinage metal ha: 4. wo electrons in the valence shell b. eight electrons in the penultimate shell c, eighteen electrons in the penulti- mate shell d. eight electrons in the outermost shell. Which of the following statements is correct? a, Iso = electronic ions may be ob- tained from ions belonging to dif- ferent periods of the periodic table. b. Electron affinity of noble s is zero. Chemical Families-Periodic Properties oO 24. 22. 24. 26. 27. c. Vander waals radii of iodine is more than its covalent radius. d. All the above are correct Atomic volume is the volume occu- pied by a. One atom b. one gram of atom ofan element in gaseous state. c. | gram mole of atoms in a solid state. d. 1 gram mole of atoms in any state. The bond between atoms of two el- ements with atomic number 37 and S3is: a. Electrovalent b. Covalent ce. Coordinate — d. Metallic . The correct orderof decreasing boil- ing points of HCI, HBr, HLand HE iss a, HCl> HBr > HI> HP b. HF>HCI> HBr > HI c. HF>HI> HBr > HCl d. HI> HBr >HCl> HF The correct order of deereasing boil- ing points of Cl, Br, and F, a, Br; >Cl,>F, b. F,>Cl,> Br, ¢. Cl >Bry>F) d. Fy > Br) >Cl; . Inasolid, the magnitude of the lat- tice energy increases if:- a. the ions are small b. the ions are large c. the ions are of equal size d. charges on the ions are small ‘The hydrogen halide with the high- est percentage of ionic character is a. HCl b. HBr ce. HE d. HF Which of the following has highest boiling point? d. All have same boiling point 28. Which of the following compounds has the least tendency to form hy- drogen bonds between molecules? a. HF b. NH,OH c. NH; . CHF 29. Which of the following has coordi- nate bond? H,O* ce. NH; 30. Out of the following resonating structures of CO,, which are cor- rect? b. BEY d. all the above 2—C=Q: HI a. LULMLIV —b. LMIV eo LI d. LIL UI 31. The bond orderin O,' is the same as ins a. Not b. CN™ «. CO ¢. NO* 32. The orderof increasing clectroposi- tive character amongst Cu, Fe and Mgis: a. Cu Ba> Ca> Mg b, Ba > Sr>Ca> Mg c. Mg > Ba > Ca > Sr d. Ba > Sr>Mg >Ca Which of the following elements has the maximum electronegative character? a, Nitrogen b. Oxygen c. Chlorine d. Fluorine Which of the following have isoelec- tronic structure? a, CH; and H,0* b, CH,’ and CH; c. H,O* and CH, d. none of the above . Which of the following are isostruc- tural pairs? a. NF;,NO, b. NF; NU; © NF3,H,07 d. none of the above Which of the following has maxi- mum number of unpaired electrons? aT bv 41. 42. é 44. 45. 46. 41. ce. Ca d. Fe* Which of the following oxides are neutral? a. CO. c. ALO; Which of the following halides is least stable? a. NaCl b. Pbly c. Sn, b. CO; d. SnO; a. allare equally stable In case of alkaline earth metals which of the following property in- creases with atomic number? . electronegative character b. ionization energy c. solubility of sulphates d. solubility of hydroxides An element with atomic number 20 belongs to the: a. s — block b. d -block c. p —block d. f—block Which of the following pairs of atomic numbers represent d - block elements? a. 30 and 31 b. 30 and 39 c. 20 and 21 d. 30 and 32 Which of the following do not ex- hibit photoelectric effect? b. K d. Cs a. Na e Li The reactivity of the alkali metals Li, Na, K, Rb, and Cs towards halo- gen increase in the order a. Li,Na, K, Rb, Cs b. Cs, Rb, K, Na, Li c. Na, K, Li, Rb, Cs Chemical Families-Periodic Properties oO 48. 49, 50. 51. 54, wn a d. K.Na, Li, Rb, Cs Which of the following metals have electronic configuration [Xe] 657? a. Ca b. Ra c. Ba d. Sr Which of the following chloride separates out from aqucous solu- tion as dihydrate? a. Li akK b. Na d. Mg Which of the following metals have diagonal relationship? a, Li-Mg b. Be-Al c. B- Si d. all the above The electronegativity of the follow- ing elements increase in the order a SicCO>Ca_ b, O>Al>Ca ce O>Al>Ca d. O>Ca>Al . Which amongst the following is most soluble? a. Na,SO, b. MgSO, c. BeSO, d. BasO, Which amongst the following has maximum basic character? a. K,O b. NiO ©. MgO d. SrO Which amongst the following has maximum basic character? a. Be(OH), b. Ba(OH)}, c. S(O), d. Mg(OH), Which amongst the hydroxides of the following alkali metals is least basic in nature? a.Na b. Rb c. Li d. Cs 60. 61. z - 64. . Which amongst the following are present in group sixteen of the peri- odic table? a.O bN cS d. Cl . Which of the following is radioac- tive? a. Cs b. Fr ec. Rb da. Li . Which of the following are ampho- teric in nature? a. GeO, b. sn0, c. PhO, d. all the above Which amongst the following be- long to a triad? a. Osmium b, Platinum c. Iridium d. Allthe above Sodium reacts with which of the fol- lowing to liberate hydrogen? b. Ethyl alcohol J. Allthe above a. Water c. Acetylene . Which of the following form cova- lent compound? a. Be ce. Ca b. Ba d. Sr Which of the following carbonates is least stable on heating? a. MgCO; b. CaCO, c. BeCO; d, BaCO, Which of the following oxide is am- photeric in nature? a. BeO b. MgO ©. CaO d, Bad, . Which of the following has maxi- mum Lewis character? a. BP, b. BCI; c. BBr; d. all have equal Lewis character Oo IK's MCQs—Chemistry 66. 67. 68. 69. 70. 71. Which of the following will impart green colour to flame? a, Ca b. Ba c. Sr d. Ra A salt of a metal is soluble in water if its:- a, Hydration energy > Lattice en- ergy b. Hydration energy < Lattice en- ergy c. Hydration energy is equal to Lat- tice energy d. None of the above Which of the followin; the elec- tronic configuration of an alkaline earth metal? [Ne] 3s°, 3px! 3py Which amongst the following is an allotropic form of carbon? b. Graphite Allthe above a. Diamond c. Fulleverene d. Which amongst the following is most stable to heat? a. HCl b. HBr c. HCIO d. HI Which of the following statements are correct? a. On moving down the group of alkali metals (Li— Cs), the atomic and ionic rad increases b. On moving down the group of alkali metals (Li- Cs), the ioniza- tion energies decreases down the group c¢. The atomic and ionic radii ofmem- bers of the alkali metal groups 72. 74, 75. 76. TI. are larger than the corresponding members of the alkaline earth metals. d. Allare correct Which of the following statements is/are correct? a. Alkali metals have the highest ionization energy in each period. b. The second ionization energies of alkali metals are very high. c. The densities of alkali metals in general increase on moving down the group. a. Allare correct . The lattice energy of NaF, NaCl, NaBr, Nal decreases in the order. a, NaF > NaCl > NaBr > Nal b. Nal > NaBr > NaCl > NaF c. NaCl> NaF > Nal > NaBr d. NaBr > Nal > Na F > NaCl The solubility of a salt in water de- pends on its:- a, Lattice energy only b. Hydration energy only c. Both lattice and hydration energy d. None of the above Out of the following alkaline earth metals, the salts of which one does not impart characteristic colour to the flame? a. Mg b. Ca ©. Sr d. Ba Which of the following exhibit a va- lency of 2? a. Na eK The alkali metals are chemically similar due to: b. Ca d. Mg a, the atomicity of all metals is one. Chemical Families-Periodic Properties oO 78. 79. 80. 81. 82. b. the outer most electrons have same energy. . they have same electronic con- figuration d. all the above K* ion and Ca” ion are isoelectronic with: a. Nab. Mg™* c. Ard. Kr Which of the following hydrides is most stable? a. Sify b. Sn, c. PbH, d. CH, Which of the following bonds has highest bond energy? a, C-C b. Ge - Ge ©. Si- Si ds Sn The transition elements belongs to a. s— block b. p block c. d= block d. none of the above The first transition elementis:- a. copper b. nickel c, chromium d, seandium © 2a 3d 4a a 10. bd Ii d 12. d 18. b 19, © 20. d a 26. d 27. a 28. d d 34. b 35. a 36. b a 42. b 43. d 44a ad S50. d Slo a 52. b ae 58. b 59. d 60. d a 66. b 67. a 68. b a 74. ¢ 75. a 16. b,d c 82. d 3. ¢ 84. ¢ 83. 84. 86. 87. Transition elements:- a. do not form alloys b, exhibit dimagnetism ¢. show variable oxidation states d. do not formed coloured salts Which of the following elements ex- hibit highest oxidation state? b Cr oc Mn d.V In which of the following Mn has the highest oxidation state? a, MnO, b. MnO c. KMn0, d, all have same oxidation state a. Fe Transition elements form com- plexes due to: a. large ionic charge b. small cation size c, vacant d — orbitals d. all the above ‘The common oxidation states of lan- thanides are> a2 eek b, as a,b 6a a 8. b b Ido a 5. ¢ l6. ¢ © 22. a d 30. ¢ Bhi 8 32. a d 38. ¢ 39. © 40. d b 46. ¢ 47. a 48. ¢ a 54. ¢ 55. b 56. d d 62. a 63. ¢ 64. a d 70. a 71d 72. bie c 78. c 3/4 80. a c 86. d 87. a,b,c Bonding and Molecular Structure * Choose the Correct Option(s) 1. An element Xhas ground state con- figuration 2, 8, 8. The bond between the atoms of Xis:- a. Tonic b. Covalent c. Metallic d. Vander waals 2. Maximum number of bonds be- tween two atoms of a covalent bond can bes b. Two d. Four a. One c, Three 3. Which one of the following has maximum bond angle? a. BF, b. CH, c. NH; d, 1,0 4. How many electrons are acquired by atoms of all elements, in their outermost shell? a. Four b. Six c. Fight d. Ten The bond between two identical non- metal atoms has a pair of electrons: a. With identical spins b. Equally shared between them c. Unequally shared between them d. Transferred fully from one atom to another 6. The number of electrons involved in the bond formation of nitrogen molecule is:- b. Four dé. Eight a. Two oO IK's MCQs—Chemistry I 10. di. 13. The structure of anmonia molecule a. Trigonal b, Tetrahedral ¢. Pyramidal d. Trigonal pyramidal .. Which of the following is non-direc- tional bond? a, Covalent bond b, Coordinate bond c. Metallic bond d None of the above The weakest interactions are in- volved in> a. Tonic bond b. Covalent bond c, Hydrogen bond d, Vander waal’s interaction Which one of the following bond is more polar? a. CH ce. N-H b. SH d. O-H Which of the following combina- tions is not likely to form predomi- nantly covalent bonds? a, Sodium & hydrogen b. Bromine & fluorine c. Cesium & fluorine d. None of the above . Which one of the following is para- magnetic? aN» b. 05 ce. Ch d. None of the above Which of the following compounds is covalent? a, NaS b. CaO c. KCI d. Hy 14. 17. 18. 20. If element Xis strongly electroposi- tive and element Y is strongly elec- tronegative and both of them are univalent, then the compound formed would be: . X-Y b. X. ¥ » X*Y dye¥* . Out of the following, which one is least ionic? a. KCL b. AgCl ce, CaCl, d. BaCl, In which of the following pairs, repulsion is maximum? a. Lone pair —lone pair electrons b. Lone pair - bond pair electrons ¢. Bond pair — bond pair electrons d. None of the above Anionic solid is a poorconductor of electricity because: a. Ions don’t conduct electricity b. Ions have small charges c. lons don’t move in solid d. None of the above Which of the following has the greatest ionic character? a, NaCl b. KCI c. CsCl d. None of the above In which of the following, the bond angle between two covalent bonds is maximum? a. HO ©. CO; b. NH, d. CH, High stable elements shows: a, High chemical reactivity b, Moderate chemical reactivity c. Very low chemical reactivity d. None of the above Bonding and Molecular Structure oO 21. 22. 23, 24. 26. For electrovalency, most favourable conditions are:- a, Low charge on ions, small cation and large anion b. Low ch and small anion ge on ions, large ion c. High charge on ions, small cation and large anion d. High charge on ions, larg and small anion ation The maximum covalent character in a bond between non-metallic ele- ments is present between:- a, Identical atoms b. Similar atoms c. Atoms of same size d. None of the above Electrovalent compounds are:- a. Low melting b. Insoluble in polar solvents c, Conductors in fused state d. None of the above Which of the following elements can’t attain sp°d hybridisation? a. Arsenic b. Phosphorus c. Nitrogen d. None ofthe above . An element with electronic configu- ration 1s72s"2p°3s*, has the va- leney= a, Zero b. One ce. Two d. None of the above Dipole moment of carbon tetrachlo- ride is zero, while for chloroform, it is 1.05 Debye, because the former is: a, Planar 30. 31. 32. 33. b. Linear c. Tetrahedral in shape d. None of the above . Electronegativity of elements help in predicting:- a. Size of molecules b. Valency of molecules c. Strength of molecules d. Polarity of molecules Ionic compounds don’t conduct electricity ins a. Solution b. Fused state c. Solid state d. None of the above When an element of very low ion- ization potential reacts with an ele- ment of very high electron afi a. A covalent bond is formed b. An ionic bond is formed c. A metallic bond is formed d. No bond is formed Which of the following is soluble in water? a. CCly b. CHCI, c. CH,OH d. CS; Out of the following molecules, which one is linear? a. NO» b. HAS c. CO, a. ClO, The most stable bond a. ss b. s-p cpp d. ped Ifa molecule of MX; has zero dipole moment, the sigma bonding orbit- als used by M (whose atomic num- ber is less than 21) are:- a. sp b. sp? d. None of these o IK's MCQs—Chemistry 34, In which of the following octet rule is not valid? a QO; «. CO, b. H,0 d. CO . Diamond is not conducting electric- ity because of it’s a. Crystalline nature b. 3-D structure c. Compact structure d. None of the above 36. On moving down in a group in a 37. 39, 40. 41. periodic table, ionization potential: a. Increases b. Decreases c. First increases than decreases d, Remains constant Out of the following halides, the highest melting halide is:- a. NaF b. NaCl c. NaBr d. Nal . Which of the following H-bonding is strongest? a. O-II c FH b. Her d. S-H---O Which of the following metals has the lowest interatomic forces? a. Copper b. Silver c. Zine d. Mercury By which of the following hybri- disation, square planar spatial ar- rangement is obtained? a. sp) b. dsp? c. sp*d® d. None of the above In benzene, bond order of carbon- carbon bond is: a. One b. Two 42. 43. 44, 45. 46. 4]. 48. 49. c, Between one & two d. None of the above Which of the following is correct? a, Hace bv. Hele c. HeCI® a. Hele Which of the following is an ionic compound? a. CCL b. SiC, c. CH, d. MgCl, The correet order of bond angles in CH, CO}, NH, & H,0 is: a. H,O>NH,2CO,>CH, b. H,O ionization energy b. Lattice energy + electronaffinity < ionization energy c. Lattice energy + electronaffinity = ionization energy d. None of these Bonding and Molecular Structure oO 78. FD: 80. BL. 82. 83. 84. Which of the following acids exist as dimer? a. HCl b. HNO, ©. H,S0, d., HCOOH In which of the following, C-C bond length is least? a. Benzene c. Ethylene b. Diamond d. Acetylene In BF,, bond angle is a. 90° b. c. 120° d 109°28" 180° Which of the following species has the maximum bond order? a. Or b. OF d. OF When one s- and one p- orbitals are hybridized, which of the following orbitals will be obtained? a, Two mutually perpendicular or- bitals b. Two orbitals at 120° t 180° c. Two orbital d. None of thes Which of the following has linear structure? a, SO, ac In which of the following, the car- bon atoms are sp hybridized? Cel, = CCI, . HC = CCl CH=CH, . CH= C=CH, . None of the above b. SnCl, d. None of these Begs . Which of the following bond is strongest? a, @bond b. bond ¢. Co-ordinate bond d, Hydrogen bond 86. 87. 88. 89. 90. 91. 92. 93. Hybridisation, present in C-C single bond, of HC = C - CH = CH yis= b. sp d. sp7s A triple bond consists of: a. Three sigma bond b. Three pi bonds c. One sigma & two pi bonds d. One pi & two sigma bonds Which of the following molecule is isostructural with CO,? NO, b. BeCl, c. HgCl, d. None of these Which of the following bond has the least ionic character? a. HCl b. PCI c. BrCl d. 0-Cl Which of the following molecule does not exhibit dipole moment? a. CHCl, b. H,0 ec, CCl, d. None of these The paramagnetic nature of oxygen molecule is explained by: a, Valency bond theory b. Heitler~ London theory ¢. Hund ~ Mulliken’s theory d. None of the above The bond angle in H,0 is 104.5° & not 109°28/(as sp° hybridised), be- cause: a. Repulsion between the bond pairs ofelectrons b. Repulsion between the lone pairs of electrons c. Repulsion between the hydrogen atoms d. None of these Which of the following shows the potential energy diagram for varia- oO IK's MCQs—Chemistry 94, 95. 96. tion of energy with internuclear dis- tance between two H atoms? Wr PE. Intemuctear distance (d) —> a b. : \f PE, —=———O \ PE. ss d | _/ PE. Outof the following, which one con- tains both ionic as well as covalent bond? a, HO b. CCl, d. NH,C As the s-orbital character in hybrid orbitals increases, the bond angle: a. Increases b. Decreases c. May increase or decrease d. Doesn't change Which of the following molecule has zero dipole moment? a. $0, >. BCL; ec. CHCI, d. None of these 97, 98. 99. 100. 101. 102. The maximum number of hydrogen bonds in which a water molecule can participate are:- a. One b. Two c. Three d. Four What is the shape of H,0*? a. Triangular b. Triangular pyramidal c, Regular tetrahedral d, None of the above Which of the following molecule has lowest bond angle? a. NH; b. H,0 c. CH, d, CO, For which of the following bonds, bond dissociation energy is highest? a CC bNN ¢ OO d. BF The bonds present in CuSO ,.5H,0 are. a. Electrovalent and co-ordinate b. Covalent and co-ordinate c. Electrovalent and covalent d. Electrevalent, covalent and co-or- dinate Both BF, & NE, molecules are cova- lent but BF; has no dipole moment but NEF; has, because: a. Boron atom has smaller size than nitrogen b. B-F bond is not polar while N-F is polar c, BF;has symmetrical planar struc- ture and NF, has pyramidal shape d. None of these Hydrogen bonds are formed be- tween molecules in which hydrogen is covalently bonded to an clement whose electronegativity and atomic radius, respectively are: Bonding and Molecular Structure oO 104, 106. 107. 108. . High & large b. High & small c. Low & large d. Low & small Which of the following graphs, rep- resent variation of potential energy when two helium atoms are brought closer? aI Internuclear distance (4) — b. t oN RE. a Z RE = d. t PE: _—__ 5. Which of the following bond is trongest? CH ec. C-N b. CC d. CO . Increasing order of size of various hybrid orbitals is: a. sp, sp*,sp* bd. sp’, sp%, c. sp'sp, sp? d. sp’ sp, sp . Which among the following has the greatest bond angle? a. H,0 b. HAS c. HSe d. H,Te sp . SOF ion has the following shape: 109. 110. iil. 112. 113. 114. a. Square planar b. Tetrahedral c, Octahedral d. Hexagonal In which of the following, interac- tion between the molecules is stron- gest? a. CHy b. H,0 c. NH; d. CO, 1 Deby a, 1x 10% e.s.u. em b. 1x 10°? es.u. em c 1x10" e.s.u.em d. None of these Positive dipole moment is present ii a. BF; b. CCl c. CoH ¢. HF Which of the following is an elec- tron defic a, NH, ©. PCl, nt molecule? b. BCI, d. None of these % ionic character can be expressed as a. % ionic character = Uobserved 5 199 u b. % ionic character = Uobserved + Wionie y 199 Unie c. % ionic character T Minnie 199 = Vobserved u d. None of these Which molecule has the highest di- pole moment? a, CHCI; b. CCly oO IK's MCQs—Chemistry 115. 116. 117. 118. 119, 120. 121. c. CHI The Cl-C-Cl bond angle in tetra- chloromethane and 1,1,2.2- tetra- chloroethene respectively is: a, 90° and 120° b. 120° and 109.5° c. 109,5° and 120° d. 109.5° and 90° Which of the following has zero di- pole moment ? a. PCly c. CIF d. None of these b. CICF, d. SiF, In which of the following, hydrogen bonding is not present? a. Phenol b. Water c. Liquid HC] d. Liquid NH, An element, having 4 electrons in its outermost orbit forms bond by: a. Losing electrons b. Gaining electrons c. Sharing electrons d, Any of the above The decreasing order of bond angles for NH, NH; & } a, NH} >NH}>NH, b. NH] >NH,> NH c. NH; >NH;>NH} d. NH, >NH,>NH? Order of decreasing polarisable ions is a. Fe > Be IK b. Cl >F >Br >I c F >> Br >cr d. 1 >Br >Cl>F The intramolecular H-bonding can be obtained in:- a, o-mnitrophenol b. m-nitrophenol 122, 124, 126. 127. 128. ¢. p-nitrophenol d. None of the above Which of the following metals is liq- uid? a. Gallium b. Aluminium c. Germanium — d. None of these ‘3. In which of the following the central atom doesn’t use sp* hybrid orbitals in its bonding? a. NH; c. *OH, b. NH d. BeFy The conductivity of metal decreases . Increase in temperature . Decrease in temperature a. b, c, . First increase & then decrease in iemperature d. None of these 5. Which of the following is an odd electron molecule? a. SO, b. NO, d. None of these Elements with electronegativities 1.2 & 3.0 form:- a. Blectrovalent bond b. Covalent bond c. Co-ordinate bond d. Metallic bond Which of the following molecule exhibits resonance? . b. HF c. SO, d. None of these Valence shell electron pair repul- sion theory was given by a, Sidwiek & Powell b. Sugden c. Davisson & Germer d. None of the above Bonding and Molecular Structure oO 129. 130. 132. 134, Which of the following is least cova- lent in nature? a. LiCl b. BeCl © BCL, d. CCl, Which among the following i uid at room temperature? a. HS b. HaTe c. HSe d, None of the above liq- . Which of the following statement is wrong? a. lonic solids don't conduct elec- tricity b. Ionic compounds conduct elec- tricity in fused state ¢. Covalent compounds are gener- ally soluble in water d. None of the above The correct order of covalent char- acter of Lithium halide i: a. LiF > LiCl > LiBr > Lil b. Lil > LiBr > LiCl > LiF c. Lil> LiCl > LiBr > LiF d. LiF > LiBr > LiCI > Lil 3. In which of the following molecule, two bonded pairs of electrons and two lone pairs of electrons are present? a. CO; b. H,0 ce. NH; d. BP, The following molecule has the highest dipole moment: a. NH, b. PH3 c. SbH, d. AsH, 5. The order of melting points of Lithium halide is: a. LiF > LiC] > LiBr > Lil b. Lil > LiBr > LiCl > LiF 136. 137. 138. 140. i41. c. Lil > LiCl > LiBr > LiF d. LIP > LiBr > LiCl] > Lil NH, & BF, form an adduct readily because:- a. They form a H-bond b. NHgis polar and BP; is non-polar c. They form a dative bond d. None of the above The shape of XeF, a. Trigonal pyramidal b. Triangular planar c. T-shaped d. Linear In which of the following ionic com- pound, the distance between the centres of cations and anions is maximum? a. LiF c. CSF b. Lil d. Csi . The orderof a covalent characterof NaCl, MgCl, & AICI, a, NaCl > MgCl, > AICI, b. AICI > MgCl, > NaCl ¢. NaCl > AICI, > MgCl, d. MgCl, > AICI; > NaCl NH, has higher boiling point than PH, because:- a, NH, isan ionic molecule & PH is acovalent molecule b. NH, is PH, c. NH, forms H-bond while PH, doesn’t smaller in size than d. None of these The shape of SF, is a, Tetrahedral b. Square planar c. Trigonal pyramidal d. Trigonal bipyramidal oO IK's MCQs—Chemistry 142. 143. 144. 145. 146. 147, If N,, is no. of electrons present in the bonding orbitals & N, is no. of electrons present in the anti bond- ing orbitals then molecule will be stable if: d. None of the following Which of the following is not para- magnetic? a0; BN; «NO d. Which of the following is diamag- netic? aN, b NJ «Nz; dN AsF, molecule is trig dal. The orbitals of As atom in- volved in hybridisation are: A. 8. Dy Py Pas ds buys Ss Pas Pys Par 8, Pas Py Py 28, Pes Py Which of the following species has the greatest dissociation energy? V3 b. Nt d. N? Out of the following, which species has unpaired electrons in it? a, NO? b.N ec. KO, d. Ba, d By ¢ 3. a c . dd 10. d llc b c 18, ¢ 19. ¢ c © 26. ¢ 27. d © 34. d 35. d . b 148. Which of the following species doesn’t exist? a. Fy b. Ny ce. Ne, d. None of these 149, Which of the following molecular orbital has the lowest energy? a. Opp, b c. Wp, d. 6%, 150. Which type of hybridization is presen IF,? a, sp*d? b. sp*d? c. sp*a> d. None of these 151. 152. 153. 154, For a homonuclear diatomic mol- ecule, if Z axis is the molecular axis, then which of the following combi- b. 2p, - 2py d. 2p, + 2py Which of the following is diamag- netic? b. OF d. O, Which of the following species is most stable? a, OF b. O, ce. OF d. O; Which type of hybridization is present in SO}? 3 3 a. sp b. sp*d c. sp*d? d. None of these d 6 Ries 8. d © . b 16. b 22a 2 C 2. b 30. ¢ c 32. a a 38. b . d 40. b Bonding and Molecular Structure Oo Alc 42.b 43d 440 45a 46a 47.6 48a 49. d 50. ¢ Sl. c 52. d 53. d S54. d 55. ¢ 56. 57. a 58. a 59. a 60. a 6l. c 62. ¢ 63. b 64. ¢ 65. ¢ 66. d 67. b 68. a 69. © 70. d Tloa 72, ow Bc Th d 75d 7d Ta Bd 7d 806 Bld Be 8c) 86 (Bh BSL a BH BT 88. b 8d Wc 99 ce «992 ba Od SL HL 97.d 98 © 91D, aT dd 102 10 1 los. d 106. a 107. a 108 De dH 13.a 4a HS. c¢ Mod tie 18 c¢ 118 b 120. a 12. 128 dd a 125 HL dD 128. 129. a 130. d 131 ¢ 132. b 133. bh 134. a 135. a 136. ¢ 137. d 138 d 139. b 40 eT 1 eB dM 145. b 146, a 147, ¢ 148. ¢ 149. d 150. ¢ 151. d 152. a 153. a 154. all SELECTED EXPLANATORY ANSWERS No.of e s in bonding m.o.-No.ofe sin antibonding m.o. 81. Bond order = 2 Therefore, For O,, B.O. For 0, B.O. For 02, B.O. For O}, B.O a 235 100. ater the num ber of lone pairs of electrons present on the bonded atoms, greater is the repulsion between them and therefore, lesser is bond dissociation energy. 119. As no.of lone pair of electrons present on N-atom on NHJ, NH; & NHjare 0,1 & 2 respectively 130. HO is liquid whereas H,S, H,Se & He are gases at ordinary temperature because of absence of H-bonding in the later. 135. Since the order of covalent character is:- Lil > LiBr > LiCl > LiF [ Larger anion & hence greater polarisability] therefore reverse is the order of melting point, oO IK's MCQs—Chemistry 146. Bond order of these species are: N,=3.Ni=2.5,N;=25,N} =2 As bond order & bond and therefore N, will have highest Bond dissociation ene nal to each other ssociation energies are directly propor Chemistry of Non-Metals—| * Choose the Correct Option(s) 1. A dilute acidified solution of KMn0O, on treatment with a piece of zine gets decolourized. This is due to the presence of a. Hydrogen b. Nacent hydrogen c. Deuterium d. None of the above 2. Atomic hydrogen can be obtained by> a. Passing electric discharge thro- ugh hydrogen b. The action of Zn on dil, H,S0, c. Fractional distillation of liquid air d. Alithe above methods 3. Deuterium can be obtained by: a, Electrolysis of water w b. Electrolysis of heavy water 9 . The action of sodium on heavy water d. Methods b. and e. }. Which of the following dihydrogen exists at zero Kelvin? a. Only ortho hydrogen b. Only para hydrogen ¢. Only atomic hydrogen d. Allof the above . Hydrogen can be placed in group I of the periodic table because: a. it has one electron in its valency shell b. it shows a marked tendency to loose its valency electron ¢. itexhibits an oxidation state of + 1. oO IK's MCQs—Chemistry d, all the above reasons are correct 6. Hydrogen can be placed in group 7 of the periodic table because:- a. itis short of one electron to achieve nearest inert gas configuration b. itis electronegative in character. c. it displays ~ | oxidation state d. all the above reasons are correct 7. Very pure hydrogen can be ob- tained by: a. Flectrolysis of water containing litte mineral acid or alkali b. Asaby product during the manu- facture ofsodium hydroxide ¢, Action of water on lithium hy- droxide d. All the above methods 8. Oxyhydrogen flame has a tempera- ture of about:- a, 1000 °C b. 2000 °C c. 3000 °C d. 4000 °C 9. The oxidation states exhibited by hydrogen in its compounds is/are: a, — 1 only b. Zero only c+ 1only d, all the above 10. Hydrogen can combine with other elements by a, Gaining an electron an electron c. Sharing an electron d. All the above processes 11, The absorption of hydrogen by platinum is known as:- a, Hydrogenation b. Dehydrogenation c. Occlusion d. Allof the above 12. 13. 14, 15. 16. 18. The ionization energy of hydrogen iss a, 1312 KJ mol | b. 1681 KJ mol! . 1255 KI mot! 4. 520 KI mot! Hydrogen is manufactured by: a, Bosch process b. Lane’s process ec. Zn + H,8O0,—+ZnSO, + H, d. By process a. and b. only is used for the manufac- a, Ammonia b. Methanol c. Synthetic petrol d. Allthe above The ionization of hydrogen atom gives a, Hydronium ion b. Hydride ion c. Proton d. None of the above Water gas is a, CO+H, b. CO,+H, .CO+H,O d. CO,+H,0 is obtained b silent electric discharge through hydrogen at low pres- b. Thermal decomposition of water c. Passing steam over red hot coke d. In nuclear reactions Ortho and parahydrogen differ in their: a, Mass number b. Atomic number c. Nuclear spin d. Allthe above Chemistry of Non-Wetals—| oO 19, 20. 21. 22. 23. Atomic hydrogen is obtained by a. The action of zinc on dilute Hs b. Passing electric discharge thro- ugh hydrogen gas ©. Electrolysis of water d. Thermal decomposition of water The nuclear spin of ortho hydrogen is aw bo c. Zero d. None of the above Atroom temperature hydrogen is a mixture of ortho and parahydrogen the ratio:- a iegl by 22 1 4.921 254 Which of the following statement is/ are correct? a. Like alkali metals hydrogen ex- hibits electropositive character b. Like halogens hydrogen exhibits electronegative character c. The ionization energy of hydro- gen is quite comparable with that of halogens d. All the above are correct The oxides of which of the follow- ing are neutral in nature:- a, Hydrogen b. Halogens c. Alkali metals d. All the above . Which of the following isotopes of hydrogen does not contain neutron in their nucleus? a. Protium b. Deuterium c, Tritium 28. 30. d. None of the above The three isotopes of hydrogen have the same: a, Atomic number b. Electronic configuration ¢. Atomic masses d. None of the above . The reaction of which of the follow- ing with halogen is most facile? a, Protium b, Deuterium ec. Tritium d, All are equal facile . Which of the following will liberate hydrogen on treatment with sodium metal? a. Water b. HCI c. NaOH solution d. Allthe above The relative abundance of hydro- gen, deuterium and tritium in atmo- sphere is of the order:- a, Hydrogen > Deuterium > Tritium b. Hydrogen > Tritium > Deuterium c. Hydrogen > Deuterium = Tritium d. Deuterium > Hydrogen > Tritium . Which of the following is radioac- tive in nature? a. Hydrogen b. Deuterium c. Tritium d. None of the above In which of the following com- pounds hydrogen exhibits an oxida- tion state of + 1? a. HCL b. Nall c. Both a. and b aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. © IK's MCQs—Chemistry d, none of the above 58. Oxygen molecule has 16 electrons 59, 60. 61. 62. 63. and i. a. paramagnetic b. diamagnetic c. both paramagnetic and diamag- netic d. none of the above The oxygen present in the atmo- sphere is produced by:- a, decomposition of ozone b. it is present as such ©. photosynthesis d. all the above methods The most economical method for the production of oxygen is:- a. Fraction distillation of air b. Fractional distillation of liquid air Electrolysis of water containing mineral acid d. The action of water on sodium peroxide Which of the following statements is/are not correct? a, Oxygen is neutral to litmus b, Oxygen is not combustible c. Oxygen supports combustion d. Oxygen is a powerful oxidizing agent Which of the following metals bum in oxygen? a. Na ce Al b. Mg d. Fe Sulphur on heating with oxygen at 723 K at 2 atmosphere gives: a. SO, b. SO, c. a mixture of SO, and SO, 64, 65. 66. 67. 68. 69. 70. d. none of the above Ammonia on heating with oxygen at 1073 K in presence of platinum gauze give a, NO b. NOs c. No d. a mixture of (a), (b) and (©) Hydrogen chloride gas on heating with oxygen at 700 K in presence of cupric chloride: a. Ch b. Hydrochloric acid c. ClO, d. a mixture of all the above prod- wets Which of the following hydrocar- bons bum in oxygen to give carbon dioxide and water? b. Ethylene d. All the above a. Methane c. Acetylene Which of the following is an acidic oxide? a, H,0 ce. Na,O b. POs d. MgO Which of the following is a neutral oxide? a. Fe,03 b. NO c. ALO; d. N,O Arrange the following oxides in or- der of theiracidic nature: a, C1,0,> SO, > SiO, > Na,O b. SO, > C10; > Na,0 > SiO, c. C1,0,> SiO, > SO, > Na,0 d. Na,O > SiO, > SO, > C10; Arrange the following oxides in or- der of their basic strength:- a. Na,O > K,0 > LiO b. K,0 > Na,0 > Li,0 Chemistry of Non-Wetals—| oOo Thy 72. 73. 74. 76. 71, c. Li,0 > K,0 > Na,O d. Na,O > Li,0 > K,O Ozone is formed in the atmosphere by a. The action of ultra violet radia- tion on oxygen s . Ibis present as such . Combination of oxygen atomic oxygen d. All the above methods. ° with Which of the following is amphot- eric oxide? a, FeO, c. BaO> b, CaO d. ALO; Oxygen can be converted into ozone byr a. Oxidation at high temperature b. Catalytic oxidation c. Oxidation under high pressure and temperature d. Silent electric discharge. The presence of ozone can be in- ferred by: . Litmus paper . Benzidine paper . Starch — iodide paper . Allthe above 2egeep . In which compounds of the follow- ing elements oxygen show +ve oxi- dation state? a. N b.Cl c. Na dF Which of the following is a super oxide? a. BaO, b. Fe,0; ©. KO; d. Al,O; The major part of ultra violet rays of the sun do not reach the surface of 78. 79. 80. 81. 82. the earth due to the presence of a layer of:- a. CO, 2 O, b. 0; d. NO, Heavy water is obtained by elec- trolysis of ordinary water. The amount of H,0 required to produce about 1 litre of D0 that is 99% pure is approximately: a. 10,000 litres b. 20,000 litres c. 29,000 litres d, 39,000 litres Out of H,0 and D,0 which will electrolyse faster? a. H,O will electrolyse faster than DO b. D,O will clectrolyse faster than 1,0 . Both will electrolyse at the same rate d. None of these will electrolyse o The degree of hardness of water is defined as the number of parts by weight of CaCO, (orits equivalent) present in:- a. Thousand parts of water by weight b. Hundred parts of water by weight ¢. Million parts of water by weight d. None of the above ‘The permanent hardness of water can be removed by: a. Passing through anion exchange resins b. Passing through a column of so- dium hexametaphosphate c. Using both the methods a. and b. d. None of the method is useful The temporary hardness of water can be removed by: a. Boiling oe IK's MCQs—Chemistry 83. 84. 86. 87. 88. 89, b. CaCO, c. CaCl, d. none of the above The presence of moisture can be detected by a, Taste b. Odour c. Using anhydrous CuSO, which changes colour d, Allthe above methods The dipole moment of wateri a, 184D b. 3.68 D « 0 d none of these . In liquid state the aggregates of water molecules are held due to:- a. Tonic bonds b, Covalent bonds c. Hydrogen bonds d. None of the above Water forms azeotrope with a, Benzene b. Ethyl alcohol c. Carbon tetrachloride d, Chloroform The bond angle, H - 0 - Hin water iss a, 109.5° b. 104.5° c. 100° d. 60° In water molecule, the hybridiza- tion state of oxygen is:- a. sp? b. sp* csp d, none of the above In a nuclear reactor, the moderator used is: a, Water b. Hydrogen 90. 91 92. 93. 95. c. Heavy water 4. none of the above Permanent hardness in water is due to the presence of: a, Sulphates of Na and K b. Sulphates of Mg and Ca c. Bicarbonates of Mg and Ca a. None of the above For drinking purpose watercan be obtained from sea water by: Filtration a b. Distillation c, Steam distillation d. Chromatography Which of the following statements are correct? a. Water is polar in nature. b, Water molecules are held together by intramolecular H — bonds. c. The density of water at 273 K is higher than the density of ice. d. Allthe above statements are cor- rect The reddish brown coloured gas formed when n ric oxide is oxi- |. Which of the following trihalide of 96. nitrogen is least basic? a. NF b. NCI; c. NBr, d. Nis Which of the metal is a typical non— metal? a0 Se bs d. TI Magnesium combines with nitro- gen to form: Chemistry of Non-Wetals—| oO 97, 98. 99, 100. 101. 102. a, Magnesium nitrate b. Magnesium nitrite c. Magnesium nitride d. All the above Oxidation of ammonia in presence of a catalyst yields: a. NO b. NO, c.N> d. NOs Which of the following oxides of nitrogen is/are neutral? a. NO b. N,O, c. NOs d. none of the above The density of nitrogen obtained from airis greater than the one ob- tained chemically. This is due to the presence of:- a. CO, in the atmosphere b. Inert gases in the atmosphere ¢. Ozone in the atmosphere d. None of the above The oxidation state of nitrogen in NAyi a-1 b. -2 +1 d. 0 Nitrogen is present in plants and animals in the form of:- a. NaNO, b. NaNO; c. (NH,),S0, d, Proteins Ammonium dichromate on heating gives: a. Chromium oxide and ammonia b. Chromic acid and ammonia c. Chromium oxide and nitrogen d. None ofthe above 103. 104, 105, 106. 107. 108. 109. 110. Which of the following will give a black precipitate with ferrous sul- phate? a, NO b, NO, c. N,O5 d. N20; Which of the following can be used to remove nitrogen from air? a. POs b. Conc. H,SO, d. Mg Oxalic acid is obtained by heating cane sugar with:- a, HCl c. HNO, b. HNO, d. H,SO, Nitrogen shows diagonal relation- ship with: a. P b Ss c. Se d. none Fixation of nitrogen is meant for a, Liquification of nitrogen b. Isolation of nitrogen from air c. Producing nitrogen from ammo- nium nitrate d. Conversion of nitrogen from the air into important nitrogenous compounds Sodium nitrate on heating with zinc dust and caustic soda yields:- a. NO b. NO, c. NH; dé. N,O Which of the following is acidic in nature? a. NH; b. NoHy ©. NH d. none of the above Cone. HNO, and conc. HCl on heat- ing give: a. Cly o IK's MCQs—Chemistry iii. 112. 14. 115. 116, b, NOC ce H,0 d. all the above Which of the following are correct for nitrogen? a, Itis electronegative in nature b. Itis a nonmetal c. d-orbitals are available for bond- ing d, All the above are correct The product obtained by treatment of ammonia and iodine explodes with noise. The product is:- a, NH.2NI, b. NH,NI © NH;+h d. none of the above 3. Ammonia gives a brown precipitate on treatment with Nessler’s reagent. The precipitate is:- a. KjHgl, b. NH3.NIy c H,N-Hg-O-Hg-1 none of the above d In which of the following the oxida- tion state of nitrogen is 47 a, NO; b. N03 c. N,O d. N,O5 Which of the following oxides of nitrogen is/are intermediate in the manufacture of nitric acid by Ostwald’s process? a. NO b. NO, c. NO, only (a) and (b) The reaction of nitric acid with phosphorus pentoxide gives: a. N05 b. N03 d ec. NO d. N,O 117. Which of the following oxides of nitrogen is a coloured gas? a. NO b. NO; ec. N,O d. none of the above 118. During lightening in the atmo- sphere which of the following is obtained? a. NOs b. NO c. NH3 d. None of the above 119. Pure nitrogen can be prepared from = a. Ca;Ny b. NNO, c. Ba(NO,), a. None of the above 120, Aqua regia is asolution of cone. HCI and cone. HNO, in the rati wm Bel bo1:3 e@ led W223 121. Which of the following oxides of nitrogen are acidic in nature? a. NO b. NO, c. NO d. None of the above 122. The laughing gas is:- a. NO b. N,O c. N33 d. N,O, 123. Haber’s process is used for the manufacture of: a. NH, b.N, c. HNO, d. all the above 124. Ammonia can be dried over a, quick lime Chemistry of Non-Wetals—| oO 126. 127. 128. 17. 25. 33. 4l. b. cone, HSO, c. PO; d. anhyd. CaCl, . Which of the following compound will not give Lassigens test? a. Aniline b. Nitrobenzene c. Hydrazine d. Urea Ammonia molecule has: a. Tetrahedral geometry b. Pyramidal geometry c. Can be either tetrahedral or pyra- midal d. None of the above Ammonia acts as a Lewis base due to: a. The presence of lone pair of elec- trons on the nitrogen atom. b. The solution of ammonia in water is basic. c. Its pyramidal geometry d. None ofthe above Ammonia forms a deep blue solu- tion with coppersulphate solution. This is due to the formation of: a, Cu (OH), b. (NH), SO, c. [Cu (NH,)4] SO, b 24 3.4 4b d 10. d Ile 12, a d 18. ¢ 19. b 20. b a,b 26. a 27.4 28. a d 34. d 35. d 36. b d 2, a 43. b 44. b d. none of the above 129, Nitrogen has five electrons in the 130. 131. 133. valence shell. What is the maximum number of covalent bonds possible in case of nitrogen? a2 b3 e4 as The common oxidation state of ni- trogen in its compounds is:- a.-3 +5 b +3 d, all the above Animals die in an atmosphere of nitrogen due to: a. It’s poisonous in nature b. Absence of oxygen c. It's being inert in nature d. None of the above ty of nitrogen is due a. Small size b. High bond dissociation energy c. Presence of N =N d. d (b) only Nitrogen combines with hydrogen under the condition: a, Low temperature (650 — 800 K) b. High pressure (200 - 900 atmo- sphere) c, Catalyst (Fe) and a promoter (Mo) d. All the above conditions d 6d 7d 8. d 14. d 15. ¢ 16. a d 22. d 23. a 24, a c 30. a 31. b 32. b d 38. b 39. d 40. b b 46. ¢ 47. 4 48. d o& IK's MCQs—Chemistry 49. 57. 65. . 81. 50. 58. 66. 74. 82, 90. 98. 106. 114, 122, 130. Sk 59. 67. 75. 83. bs 99. 107. 115. 123, 131. ceeacrcaacaod 52: 60. 68. 76. 84. ‘92. 100. 108. 116. 124, 132. cases czas 53. 61 69. Ti 85. 93. 11 109. 17. 125. 133. o aeoccand 102, 110. 118. 126. 2 ooo scan 55. 63. WM. 2. 87. 95: 103, 111. 119. 127. Chemistry of Non-Metals—Il (Boron, icon, Phosphorus, Sulphur, Halogens and Nobel gases) * Choose the Correet O ption(s) — $$$" 1. S Which of the following elements does not constitute the boron fam- ily? a. Ba b. Al ce. Ga is FEE Which of the following element of boron family is most abundant? a. Al b. B c, Ga d. TI .. Which of the following elements of boron family is a non - metal? Ga b. In ce. TI dB } Which of the following elements show oxidation state of + 3 only? a. B b. Ga ec. In d. TI 5. Which of the following statements are correct? a. The atomic and ionic radii of group 13 elements are smaller than the corresponding elements of alkaline earth metals. b. The first ionization energies of el- ements of group I3are lower than the corresponding elements of group 2. ¢, The second and third ionization energies of element of group 13 are higher than their first ioniza- tion energies. d. None is correct. ». In diborane, the B - H bonds are of :- a. One type c. Three types b. Two types d. Four types oO IK's MCQs—Chemistry 12. Which of the following statements are correct about diborane? a. It has two types of hydrogen at- oms b, Ithas four terminal hydrogens Ithas two bridged hydrogens d, Diborane burns spontaneously in air . The order of Lewis acid strength of different halides of boron is:- a, BBr;> BCI, > BF; b. BF,> BCI, > BBr, c. BF, > BBr; > BCl; d. BCI,> BBr, > BF, Boron is a:- b. Non ~ metal d. Compound a. Metal c. Metalloid . In the borax bead test which of the following takes part into the reac- tion? a. Anhyd. Borax b. Sodium Metaborate c¢. Boric anhydride All the above d The borax bead test is based on the formation of: b. Boron oxide d. Allthe above a. Boric acid c, Metaborates A blue borax bead formation shows the presence of:- a. Cu oO b. Fe d. Co ng heating, orthobor a, Metaboric acid b, Tetraborie acid Boron trioxide d. Elemental boron 14. 16. 18. 19, 20. The basic character of the following oxides increases in the order:- a. BO; > Al,O, > Ga,0,> TIO, b, Al,O,> B,O,> Ga,0,> TIO, c. Ga,O,> B,0, > A1,0, > TIO, d. TIO; > Al,O;> B,0;> Ga,0, The basic character of the following hydroxides increase in the order:- AI(OH);> B(OH), > TIOH > Ga(OH); b. Ga(OH),> TIOH > B(OH), > ALO), c. B(OH); > AI(OH), > Ga(OH), > TIOH d. AIOH),> Ga(OH), > TIOH > BOF), a. Boron forms:- a, Covalent compounds only b. lonic compounds only c. Covalent as well as ionic com- pounds d. None of the above Amongst group 13 elements which element (i) forms acidic oxides; (ii) forms covalent compounds and (iii) has highest ionization energy? a. B b. Al ce. Ga 4, TI Which of the following elements resemble boron the most? a. Al b. Ga c. Fe d. Si Which of the following exhibit allot- ropy? a B b. Si ok d. Na B,O,is:- a. Acidic b. Basie c. Amphoteric —d, None of these Chemistry of Non-Metals— oO 21. 22. 23. 24. In B3H, a. There is a direct boron — boron bond b. The boron atom e linked thro- h hydrogen bridges. u c, The structure is similar to C,H. d. All the atoms are in one plane. The oxidation state of boron is: a+ be +2 ce +3 d.-2 Which of the following statements are correct for silicon? a. It is the first most abundant e! ment in the earth’s crust. b. It occurs as SiO, in the form of sand, quartz, rock crystal ete. c. Itis soluble in sodium hydroxide. d. It decomposes steam on red heat. Which of the following statements is/are correct? a. The atomic radii of group 14 ele- ments are smaller than the cor sponding elements of group 13 b. The first ionization energies of group I4elements are higher than those of the corresponding group 13elements. c. The group 14 elements are less electropositive than group 13 ele- ments. d. The group 14 elements are more electronegative than group 13 elements. . The tendency for the catenation decreases in the order: a, C>Si>Ge>Sn C > Ge > Sn > Si c, C> Sn > Si>Ge d, C > Si>Sn>Ge = 26. 29. 30. 31. 32. Which of the following tetrachlo- rides are not hydrolysed by water? a. CCly b, PbCl, c. Pbly d. All of them Which of the following oxides are acidic? a. CO; c. GeO; . The nature of bonds in compounds of carbon and silicon is mostly:- a, electrovalent b, covalent c. covalent as well as electrovalent d. metallic Catenation is a process of: a. Formation of long chains of iden- tical atoms b. Formation of long chains of differ- ent atoms c. Formation of cations d. None of the above Elements of group 14 have elec- tronic configuration of their outer shell asz- a, ns? np* b. ns* np® eon d. ns? np? Carborundum a. SiC b. Cac, ©. ALC, d. none of the above The high temperature polymers of silicon are called:- . Silicates P b. Silicones c. Silanes d. None of the above oO IK's MCQs—Chemistry 33. Which of the following statements 34. 35. 36. 37. is/are correct? a, The atomic radii of the elements of group 15 are smaller as compared to elements of group 14. b. The ionization energies of the el- ements of group 15 are much higher than the corresponding elements of group 14. c. Group 15 elements are more elec- tronegative than group 14 ele- ments. d. The density of group 15 elements increase regularly from top to bot- tom. Arrange P, Sb and Bi in order of increase in metallic character:- a. Bi > Sb > P b, Sb > Bi > P c. P> Sb > Bi d. Bi>P>Sb Which of the following hydride has abond angle of 94°? a. NH; b. PH; c. SDH, d. AsHy The thermal stabilities of the fol- lowing hydrides decreases in the order:- a. NH,, PH,, AsH,, SbH,, BiH, b. PH;. NH;, AsH,, SbH,, BiH; c. AsHy, SbH, BiHs,NH,, PH, d. NH,, PH,, SbH,, AsH,, BiH, The reducing character of the fol- lowing hydrides increase in the or- der: a. PH, AsH,, SbH,, Bill, b. AsH,, PH;, SbH, BiH, c. SbH,, AsH, BiH, PH, d. BiH, SbH;, AsH,, PH; . In which of the following phospho- rus has an oxidation state of + 4? 39. 40. 41. 44. 46. a. P4Oy b. POs e PyO1n d. none of the above Orthophosphoric acid is b. dibasic c. Iribasic d. a, monobasic tetrabasic In which of the following phospho- rus has oxidation state of +4? a. HPO, b. H,PO; c. HyP,O, c. H,PO, Which of the following is strongest reducing agent? . SbH; b. ASH, c. BiHy d. PH, Molecular phosphorus exists as:- a. P b. Ps ce. Py d. Py The acid which forms two series of salts a, HPO, b. H;PO, c. H,PO, d. none of the above Phosphorus reacts with conc. HNO; to give: a. HsPO, c. H5PO, . The P-P-P bond angle in white phosphorus a, 60° b. 90° c. 109°,28” d. 120° The phosphorus used in the manu- facture of safety matches is: a. White P b. Violet P ec. Red P d. Any type ean be used Chemistry of Non-Metals— oOo 47. 48. 49. wn 52. In the reaction P, + 3KOH + 30,0 —+3KI,PO, + PH,, phosphorus is . Only oxidized a b. Only reduced c, Oxidized as wellas reduced d . Neither oxidized nor reduced Which of the following allotropes of P show phosphorescence? a. White P b. Red P c. Both white P and red P d. Neither white P nor red P The element sulphur belongs to the:- a. Oxygen family b. Nitrogen family c. Carbon family d. Boron family . Which is the electronic configura- tion of sulphur? a. [He] 2s” 2p! b. [Ne] 3s? 3p? c. [Ne] 3s? 3p* d. [Ne] 3s? 3p! Sulphurreacts with halogen to form: a. Monohalides b. Dihalides c, Tetrahalides d. None of the above Which of the following oxyacids of sulphur is unstable and cannot be isolated? a. Sulphurous acid b. Sulphuric acid c, PeroxymonosuIphuric acid d. Allare stable and can be isolated .. Which of the following hydrides has a bond angle of 92.1°2 a. H,0 b. HLS 54, 60. c. H,Se d. HyTe The electronegatives of O,S,Se, and Te inerease in the order: a, O>S>Se>Te b. S>O>Se>Te c. Te >Se>S>0O d. Se>Te>O>S . The maximum covalency of sul- phuri a2 b4 6 d.8 . Magnesium sulphate is soluble in water whereas barium sulphate is sparingly soluble because: a, The hydration energy of magne- sium sulphate is more than its lattice energy . The lattice energy of barium sul- phate is more than its hydration energy s c. The lattice energy has no role to play in solubility d. The hydration energy has no role to play in solubility '. There is no S -S bond in: In which of the following oxyacids, sulphur has an oxidation state + 6? b. H,SO, d. H,SO5 . Which of the following is most vola- tile? a. H,Se b. HTe c. HS d. H,0 Which of the following has highest bond energy? a. 0-0 c. Se-Se b S-S d. Te-Te oO IK's MCQs—Chemistry 61. 62. 64, 66. 67. 68. The high viscosity of H,SO, is due tor a. Hydrogen bonding b. Its structure ¢, Both (a) and (b) d. None of the above Oleum is formed by combining H,SO,with: a, SO; b. SO; ° § d. HS . The oxidation state of S in oleum is a. +3 b. +4 & +5 d. +6 Oleum is> b. H,SO, d. H,S0,+ SO, . Which of the following has least reducing character? a. HyTe b. H,Se ©. HS d All have the same reducing char- acter Sulphur dioxide acts a a. An oxidizing agent only b. A reducing agent only c. An oxidizing as well as reducing agent d. None of the above When SO, is passed through an acidified KMnO, solution: a. KMnQ, is oxidised KMaQO, is reduced SO, is reduced KMaQ, solution turns green s aoe 9 - BBN, a regioselective reagent contains: aS bhSi oP dB 69, 70. 71. 72 74. 75. 76. The reaction of ILSO, with PCI; gives: a, Sulphur monochloride b. Sulphur dichloride Iphuryl chloride 4. Thiony! chloride Which of the following is Caro’s acid? a. Peroxymonosulphuric acid b. Thiosulphuric acid c. Dithionie acid a. Peroxydisulp hurie acid Which of the following halide of sulphuris used in vulcanization of rubber? a. SF, b. SF, ce. SsCly d. all the above Wittig reagent contains:- aS bP aN 4O . Which of the following elements does not show an oxidation state higher than +2? a, Oxygen b. Sulphur c. Selenium d. Telerium Oxygen and sulphur are alike as bot a, Can form covalent compounds with metals b. Exist in diatomic state c. Have atoms of same size d. Can form covalent hydrides Which of the following is radioac- tive? a, Cl ob, Br oT d. At Which of the following statements are correct? a, Halogens have the smallest ionic radii in their respective periods Chemistry of Non-Metals— oO 71. 78. 79. 80. SL 82. 83. b. The ionization energises of halo- gens is very high . All halogens have maximum elec- tron affinities in their respective periods d. All the above are correct The electron affinity of halogens is of the order: a. F< Cl>Br>1 b. F Bry >H.>N> b. Bry>Cl,>H,>N, c. Ny >H,> Cl)> Bry d. N)>Hy> Bry> Ch Which of the following halogens has lowest dissociation energy? a. Fy b. Cly c. Bry db Which of the following hydride of halogen is thermally most stable? a. HF b. HCL c. HBr d. HI Arrange HE, HCl, HBr and HI in order to their reducing character: a. HI< HBr HCl> HBr >HI b. HCI> HBr > HI> HF ec. HI > HBr > HCl> HF d. HF > HC)> HBr > H1 . Which of the following can be easily dissociated? a. HF b, HCI ce. HBr d. HI In which of the following bromine has an oxidation state of + 4? a. Br,O b. BO» c. BrOs d. none of the above In which of the following oxyacids, chlorine, has an oxidation state of +3? a. HCIO b. HCIO, c. HCIO, 4. HCIO, The acidic character of the following oxyacids, increases in the order: a, HCIO CIOH > BrOH b. CIOH > BrOH > IOH c. BrOH > IOH > CIO d. IOH > BrOH > CIOH oO IK's MCQs—Chemistry 91, 92. 93. 94, 95, 96. 97. 98, Which of the following is the weak- est acid? a, HF c. HBr d. b. HCI HL Which of the following has maxi- mum acid character? a, HCIO b. HCIO, c. HCIO; d. HCIO, Which of the following halogen has some metallic character? a. F b. Cl c. Br dt Bromine shows oxidation state of: a, -land +1 b +3 2S d. +7 The ionic character of metal -halo- gen bond decreases in the order a. M-F>M-CI>M-Br>M-I b. M-1>M-Br>M-Cl>M-F ec M-Cl>M-Br>M-F>M-I d. M-F>M-Br>M-I>M-Cl Which of the following oxyacid is the strongest? a, HCIO b. HBrO ¢. HIO d. all are equally strong Arrange the oxyacids of chlorine in order of their oxidizing power:- a. HCIO < HClO, < HClO,;< HClO, b. HCIO,< HCIO,S>P>B b. B>P>S>Cl c. S>CI>P>B d. P>Cl>S>B Pont a. ns” np . Arrange B, Si and P in the increas- ing order of their ato radi a. B> Si>P b. P>Si>B c SiI>P>B d. B>P> Si Charring of sugarin conc. H,SO, is due tox a. Oxidation of sugar b. Reduction of sugar c. Hydrolysis of sugar a. Dehydration of sugar A disease Phossy Jaw is caused due tor a. White phosphorus b. Phosphine c. Phosphorium iodide d. None of the above Chemistry of Non-Metals— oO loa 2a 3.d 4a 5. a,b,c 6. Toa,b,ed & a 9. b 10. ¢ Il. ec 12. d 13. ¢ 14. a 15..'¢ 16. a 17. a 18. d 20. a 21.b 22. ¢ 23. bed 24. a,bved 26. a 27. a,b 28. b 20. a 30. d 32. b 34. a 35. b 36. a 37. a 38. b 40. ¢ 42. d 43. bd 44. a 46. ¢ 48. a aa 50. d 52. a S4.a 55. ¢ 56, a,b 58. b 60. b 6l.a 62. b 64. a 66. ¢ 67. b 68. d 70. a 72. b 73. a 74. d 76. d 78. b 9. a RO. ¢ 81. d 82. a 84. ¢ 85. d 86. b 87. b 88. d 80. a 90. d Ola 92. d 93. d 94. a,b,e,d 95. a 96. a 97. b 98. ab,c,d 99, b 100. a 101. a 102. a 103. d 104. a 105. b 106. ¢ 107. d 108. b 109. b 110. a,b,e,d Ill. a 2. € 113. a 114. b 115. b 116, b 117. a 118. a 119. a 120. d 121. a 122. b 123. d 124, ¢ 125. a,b 126. a 127. b 128. b 129. d 130. a 131. b 132. d 133. a Chemistry of Lighter Metals © Choose the Correct Option(s) 1. The ionization energies of Na, K, Rb and Cs increase in the order:- a. Na>K>Rb>Cs b. Cs> Rb>K>Na c. K>Na>Cs>Rb d. Rb>Cs>Na>K 2. Which of the following has the high- estionization energy? a. Li b.Na ocak d. Rb 3. The density of Na, K, Rb and Cs decrease in the order:- a. Na>K> Rb >Cs b. Cs> Rb>K>Na ©. K>Na>Cs> Rb d. Rb >Cs>Na>K 4. Which of the following is the light- est element? a.Na be K ¢ Rb d. Li ir compounds, Na and K ex- hibit oxidation state of a. + Lonly b. - Lonly ec. Both + | and -1 d. +2only Which of the following imparts pale violet colour to the flame? ali b Rb cK 4s . The lattice energy of the chlorides of Li, Na, K and Rb decreases in the order:- a. Rb >K>Na>Li b. Li>Na>K> Rb ce. K>Rb>Li>Na d, Na>Li>Rb>K @ IK's MCQs—Chemistry 8. 13. 14. The lattice energy of NaF, NaCl, NaBr and Nal decreases in the order: a, NaF > NaCl > NaBr > Nal b. NaCl > NaF > Nal > NaBr c, Nal> NaBr > NaCl > NaF d. NaBr > Nal > NaF > NaCl . The basic nature of the hydroxides of Li, Na, K and Rb increase in the order a. KOH > RbOH > LiOH > NaOH b. RbOH > KOH > NaOH > LiOH c. NaOH > LiOH > RbOH > KOH d. LiOH > NaOH > KOH > RbOH Which is the most stable hydride? a. LiH b. NaH c. KH d, RbH « Which of the following is the stron- gest reducing agent? a Na bK c. Rb d. Li . The raw materials used in solvays process for the manufacture of so- dium carbonate are: a. NaCl + CO, b. NH, +CO, c, NaCl + CaCO, + CO; d. NaCl + CaCO; +NH, Naand K belong to the a, s—block d. p —block c. d—block d. f=block Which of the following is used in photoelectric cell? a Na bK c Rb d. Li . Which of the following alkali metal ions is hydrated to the maximum extent? a. Li* b. Na* c. Kt d. Rb* . Alkali metals dissolve in liquid ammonia to give blue solutions 17. 20. z,. 22. . Sodium tl which are conducting in nature. The conducting nature is due to the for- mation of:- a. Ammoniated cation b. Ammoniated electron c, Both (a) and (b) d, none of the above Soda ash is:- a. NaHCO, c. NasCO, b. Na,CO,H,0 d. KOH iosulphate is used in pho- tography to: a, Reduce AgBr to Ag b. Remove unreduced Ag c. Remove unreacted AgBr as a so- luble silver thiosulphate complex d. None of the above Na,CO, reacts with SO, in aqueous medium to give a, NallSO, b. NaH SO, c. Na,SO, d. none of the above Seildlitz pow dercontai a, Na,CO; b. NaHCO; c. Both (a) and (b) d. None of the above Saturating a solution of common salt in water by bubbling HCI gas precipitates NaCl. This method uses the principle:- a. Lechatelier’s principle b. Common ion effect c. Law of mass action 4d. Displacement law Which of the following is used in making toilet soaps? a. NaOH b. KOH Chemistry of Lighter Metals od c. KCl d. Na,CO, 23, _K,CO, cannot be manufactured by 24. 26. 27. 28. Solvay’s process like Na,CO, be- caus a. KHCO, is less soluble than NaHCO, b. KHCO, is more soluble than NaHCO, c. It exists as. a polymeric chain d. None of the above Which of the following elements are alkaline earth metals? a.Na b.K ¢Mg 4. Ca . Which of the following statements is/are correct? a. The ionic radii of alkaline earth metals are smaller than the corre- sponding alkali metals. b. The atomic radii of alkaline earth metals are larger than the co! sponding alkali metals. c, The alkaline earth metals are strongly electroposilive in nature than the corresponding alkali metals. d. None is correct. Which of the salts of the following metals impart brick red colour to the flame? a.Na b. K co Mg d. Ca Which of the following is the stron- gest base? a, Ca(OH)» b. Mg(OH), c. Sr(OH), d. Ba(OH), Dolamite is: a. MgCO, b. Caco, c. MgCO4.CaCO, d. MgO 29. 30. 31. 34. 35. 36. Plaster of Paris is: a. CaSO, b, CaSO,.H,0 c. CaSO,.%4H,0 d. CaSO,.7H,0 Epsom salt i: a. Na,SO,.10H 4 b. MgSO,,7H,0 c. Ab (S04); d. none of the above Magnesium is present in:- a. Vitamin By b. Chlorophyll c. Haemoglobin d. None of the above The main constituent of bones i a. CaCl, b. CaF, ©. CaSO, d PO,), In comparison to alkali metals, al- kaline earth metals are: a, Less reactive b. More basic c, Less reducing d. More reducing A mixture of MgO and MgCl, is called: a. Portland cement b. Sorel Cement ¢, Double salt d. None of these Calcium is obtained by: a. Electrolysis of an aqueous solu- tion of CaCl, b. Electrolysis of molten CaCl,. c, Reduction of lime stone. d. Reduction of calcium chloride. Which of the following are gener- ally used for making tooth paste? oe IK's MCQs—Chemistry 37. 38. 39. 40. 41. 42. 43. a. MgCO; b. Mg(OH), ce CaSO, d. CaCl, Which of the following form ionic compound? a. Na b. K c. Be d. all the compounds Which of the following will react with sodium to give hydrogen gas? a. Methane b, Ethane c. Acetylene d. 1-Butyne Which of the following alkaline earth metal is least reactive? a. Mg b. Ca co St d. Be Which of the following alkaline earth metal has lowest density? a, Mg b. Sr ec. Ca d. Be Which of the following alkaline earth metal has maximum reduc- n potential? a. Be b. Mg Which of the following statements is/are correct? First ionization energy of Na is less than that of Mg. b. First ionization energy of Na is more than that of Mg c. Second ionization energy of Na is less than that of Mg. «Cad. Sr d. Second ionization energy of Na is more than that of Mg Arrange BaCl,, MgCl, BeCl,, CaCl, in increasing character:- a. BeCl, MgCl», CaCl, BaCly b. BaCl,, Mg Cl, CaCl, BeCl c. MgCl), CaCl, BaCl,, BeCl, d. BeCl,, MgCl, BaCly, CaCl, 46. 41. 48. 49. . Which out of following has maxi- mum ionic mobil a. Mgt b. Ba e. Ca** d. all have same ionic mobility ly in water? |. Which of the following is used as an antacid in medicine? a. Milk of Magnesia b. Milk of lime c. Lime water a. Soda lime Which of the following metals does not liberate hydrogen when treated with acids? aCa ob. Mg oc. The standard oxidation potential of alkaline earth metals increase in the order: a. Be, Mg, Ca, Sr, Ba b. Mg, Be, Ca, Ba, Sr c. Ba. Sr, Ca, Mg, Be d. Ca, Ba, Sr, Be, Mg Ba d. Be Calcium is ob ined bys a, Electrolysis of fused Ca(OH), b. Electrolysis of anhyd, CaCl, and KCI (15%) c. Reduction of CaO d. None of the above Magnesium is obtained by:- a. Ca lowed by reduction of the formed MgO. b. Electrolysis of aqueous solution of MgCl. c. Electrolysis of fused mixture of anhydrous MgCl, NaCl and CaCl, (3:1:1.5) d. None of the above methods, cination of magnesite ore fol- Chemistry of Lighter Metals & 50. 51. Anhydrous MgCl, can be obtained by> a, Heating MgC1;.6H,0 b. Heating MgCl,.6H,0 in presence of HCl gas c. Heating Mg O+ C+ Cl, d. From sea water The well known grignard reagents contain: a.Ca b.Mg oc. Nad. Sr . The alloy duralumin used for mak- 54. wu a 56. ing airships contains:- a. Alb. Mg ce. Mn Which of the follo d. Cu gis used asa a. MgSO4.7H,0 b. CasO, c. MgCl, d. None of the above Epsom salt (MgSO,.711,0) on heat- ing above 200° C gives: a. MgSO,H,0 —b. MgSO, c. MgO d. Mg On heating strongly MgCl,.6H,0 gives a, MgCl.2H,0—b. MgOCl, c. MgO d. MgCl, Slaked lime is:- a. CaO b, Ca(OH), b, CaCO, d. CaSO, . Slaked lime on reaction with chlo- rine in cold gives: a. Bleaching powder b. CaCl, e. Ca(OCl); d. Ca(Cl0;), . Gypsum is: a. CaSO, b. Ca SO,.H,0 59, 60. 61. 62. 63. c. €a80,.2H,0 d. Ca$O,.4H,0 Which of the following are bad con- ductors of electricity in the molten state? a. CaCl, b. SrCl, c. MgCly J. BeCly Out of the following which is least electropositive? a Al b.Na oc Cad. Sr Which of the following forms the basis for the manufacture of alumi- num by serpecks process? a, Al,O3.2H,0 + 2NaOQH——~ 2NaAl0, + 31,0 b, Al;O3 + Na,CO;——+2NaAI10, + co, c, ALO; +3C+Ny d. None of the above 2AIN +3CO Alumina can be reduced electroni- cally to give pure aluminum. The main problems in the reduction is: a, Pure alumina is a bad conductor of electricity, b. The fusion temperature of alu- mina is about 2000°C, at this tem- perature the aluminum formed vapaurises. Both (a) and (b) d, Alumina cannot be reduced elee- tronically. The electrolytic reduction of alu- mina to get aluminum is carried out in presence of cryolite and fluor- spar. This is because addition of cryolite and fluorspar makes: a. The mixture good conductor of electricity b. The fusion temperature is consid- erably reduced (900°C) @ IK's MCQs—Chemistry 65. 66. 67. 68, 69. 70. ¢. Both (a) and (b) d. None is correct . Which of the follow ing are correct? a, ZnSO,+ AL Al(SO4), + Zn b. CuSO4+ AI——+AL(SO,), + Cu c. Mn,O,+ AL Mn+ A103 d. Al+H,O——AIOH),+H, Anhydrous AICI fumes in mi due to the evolution of: a HCl b. Cl, ¢. HOC! d. None of the above Which of the following represents common alum? a. (NH4)>S04.Al;(SO4)3.24H ,O b. K,SO,.Al,($O,4);.24H 0 ¢. K,80,.Cr, (SO ,);.24H 0 d. (NH,),S04.Fe (SO,)).24H 0 Which of the following clements is present in maximum amount in human bedy? a. Na ob K c Mg d. Ca In the human system, the sodium and potassium pump ensures de- sired ratio of Na* and K* concentra- tions in the extra and intercellular spaces. Typically, the ratio is K* to Na’ in red blood cells (RBC) of hu- man being is in the ratio a, 7:1 bo 1:7 6.13 5 a. ESI Which of the following perform a variety of functions in animals and plants? a. Na* b. Kt c. Mg” d. Ca** Which of the following ions play a role in regulating muscle contrac- 7 72, 73s, 74. 76. 71, tion, transmitting nervous impulses and acts as an agent for blood co- agulations? a. Na* b. K* c. Mgt d. Ca¥ The main pigment for the absorp- tion of light in plant is chlorophyll which contains: a. Na bo K c. Mg d. Ca Cement contains silicates and alu- minates of calcium as the major constituent. Their percentage is ap- proximately:- a, 90 2. 70 b. 80 d. 60 Portlant cement contains maximum percentage of: a, CaO b. SiO, c. AlOs d. MgO White cement does not contain:- b. SiO, FeO, a, Cement b. Sand c. Gravel d. Iron rods Reinforced concrete contains:- . Cement b. Sand ce. Gravel d. Iron rods Cement is manufactured by heating a powdered mixture of lime stone, clay and gypsum. The function of gypsum is to: a. Decrease the setting time of ce- meat, b. Increase the setting time of ce- ment. c. Increase the calcium content of cement. Chemistry of Lighter Metals o& d. None of the above b. The Alatom is tetrahedrally sur- 78. Which of the following statements rounded by 4 chlorine atoms. is/are correct for aluminum chlo- c. Each aluminium atom form 3 co- ride? valent bonds and | coordinate a. It exists as adimer in benzene and bond carbon tetrachloride solutions. d. In water it gives AMOH); and HCI la 2a 3b 4d a 6. b 7b 8a 9b 10. a Med 12. d 13. a 14. d I5.a 16. ¢ Ike 18. ¢ 19. d 20. b 21. b 22. b 23. b 24. ed 25. a 26. d 2.4 2B ¢ 20. ¢ 30. b 31. b 32. d 33. a,e 34. b 35. b 36. a,b 37. a,b 38. od 39. d 40, ¢ 41. a 42. a,d 43.4 44. b 45. a 46.4 4a 48. b 49. ae 50. b,o,d Sl. b 52. a,b,c,d 53. a 54. ¢ 55. ¢ 56. b She 38. ¢ 59. d 60. a 6l.c 62. ¢ 63. ¢ 64. a,bc,d 65. a 66. b 67. d 68. 2 69. a,b,e,d 70. d Tle Ra Boa TA. d 75. ab.c 76. aybye,d 77. a 78. a.b.ed Chemistry of Heavier Metals * Choose the Correet O ption(s) — $$$" 1 Which of the following are transi- tion metals? a, Cu, Ag. Au b. Zn, Hg c. Sn, Pb d. None of the above . Iron belongs tox a.s-group ——_-b. p=group c.d-group — d. f-group . Which out of the following is the most abundant element in the earth's crust? a. Fe ob. Al oc Cu d. Au }. In its compounds, iron has oxida- tion state: a+] b. +2 oe +S d. +4 5. The ionic radius of Fe* and Fe** is > a, Fe = Fe b. Fe**> Fe* c, Pe < Fe d, Can be (b) or (©) 6. The iron obtained from the blast furnace is called:- a. Pig iron b. White cast iron ¢. Grey cast iron d. Wrought iron 7. Which of the following contain maximum percentage of carbon? a. Pig iron b. Cast iron c. Wrought iron @ IK's MCQs—Chemistry 8. = 10. 1. 13. 14, d, Steel Besides iron, stainless steel con- tains: a. Cr c W b. Ni d. Al For making cutting tools which of the following is used? a, Nickel steel b. Manganese steel c. Tungsten steel d. Chrome steel Which of the following has the high- est mp? a, Cast iron >. Wroughtiron c. Steel d. Pig iron Which of the following is known as Green Vitriol? a. FeSO,.7H,O b. c. MgSO,.7H,0 CuSO,.5H,0 d. ZnSO,.7H1,0 . Iron reacts with which of the follow- ing acids to give SO,? a. Dilute HCl or Dilute H,SO, b. Cone. H,S0, c. Dilute HNO, d. Cone. HNO, In the reaction of FeSO, with water FeSO, + 2H,0=—=Fe (OH), + H,SO, the resultant solution is:- ». Alkaline d. Either (a) or (b) Anhydrous ferric chloride is pre- pared by: a. Heating hydrated ferric chloride b. Pa heated iron fillings. a. Acidic ¢. Neutral dry chlorine gas over ¢. Action of hydrochloric acid on ferric carbonate 17. 20. 21. 4, Heating hydrated ferric chloride with thionyl chloride. . Which of the following statements are correct about anhyd. ferric chlo- ride? . Wis a soluble in ether, alcohol b. It is dimeric in nature. c. Its structure possesses covalent bonds and chlorine bridge struc- lure. d, It acts as a reducing agent. Tron forms which of the following oxides? a. FeO c. Fe,O, b. Fe,O, d. Fe,O, rendered passive by treating a. HCI b. HO, c. HNO, 4. all the above acids . The Bessimer converter is used in the manufacture of: a, Pig iron b. Cast iron . Wroughtiron d. Steel The transition metal copper belongs tor a. 3d series b. 4d series d. 6d series . 3d series The addition of ammonia to a cupric salt gives a blue colour due to the formation of: a. [Cu (OH), b. (Cu (NH,),P* ©. [Cu (H,0) (NF3) 1° d. none of the above Silver ornaments get tarnished in airdue to the reaction of Ag with: a. O5 b.N, Chemistry of Heavier Metals Oo 23. 24, 26. 27, 28. 29. d. HAS ng point of Cu, Ag and Au follow the order . Cu>Aur>dg . CU>Ag>Au . Au>Cu>Ag . Ag>Cu>Au Begs Lunar caustic i: a. Ag,O c. Cu (NO) b. Ag OH d. AgNO, Conc. HNO may be stored in acon- tainer of b.Zn oc. Al a, Cu d. Sn . Treatment of ferric chloride with potassium ferrocyanide gives:- a. Prussian blue b. Turnbulls blue c. Zeise salt d. None ofthe above Anhydrous copper sulphate is:- a. Blue c. White b. Green d. Black When copper sulphate is treated with NH,OH, the product obtained is called:- a. Tollen’s reagent b. Febling reagent c. Schwitzer’s reagent d. None of the above Which of the following has highest ionization energy? a. Cu b. Ag c. Au d. All have same ionization energy Hair dye contains: a. AgNO, b. CuNO,; 30. 31. 32. 33. 34. 35. 36. c. CuSO, d. None of the above Semiprecious stone is basically: a. Sodium aluminosilicate b. Prussian blue c. Ba d. Zine cobaltate sic copper carbonate Squashes are stored by adding:- a. Citric acid b. NaCl ¢. Na,SO, d. Sodium metabisu Iphite Blister copper is refined to 99.9 % purity by: a. Polling b. Electrolytic refining c, Heating with Carbon d. Heating in air The boiling point of Cu, Ag and Au follow the order: a. Au>Cu>Ag b. Cu> Au > Ag c. Au > Ag >Cu d. Ag>Cu> Au When copper is exposed to air and moisture it is converted into a green film due to the formation of:- a. CuSO,3Cu(OH), b. CuCl,.3Cu(OH), ©. CuCO,Cu(OH), d. Cu,0 NO, is evolved by heating copper with: a. dil HNO, c. HBr b. conc.HNO, d. acetic acid Designs can be made on copper plates by using: a. FeCl, aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. oO IK's MCQs—Chemistry 66. 67. 68. 69, 70. 71, 72. b, Variable oxidation states c. Allions are colourless d, Partially filled d — orbitals The transition metal in gunmetal is a, Cu b. Sn c. Zn d. none of the above The composition of rust is: a, FeO b. Fe,03 c, Fe,0, + Fe(OH); d, Fe,03.xH,0 FeSO, forms brown ring with:- a. NO b. NO, c. N;0 d. none of the above dd-transition series ¢ ns cle- ments having atomic number from: a, 21-30 b. 39 - 48 c. 72-80 d. 104 — 105 Rusting of iron can be prevented by applying a coating of:- a, Paint b. Zine metal Allofthem Which of the following metal is present in zieglar— natta catalyst? c. Tin metal d a. Titanium b. Zine ce. Zirconium d. Silver Which of the following statements are correct about photography? a. A photographic plate is prepared by coating an emulsion of AgBr in gelation on to a plate b. On exposing the film, AgBr gets converted into Ag 73. 74, 76. 71. c. The role of hypo solution is to remove the unchanged silver bro- mide as a complex d. The print can be toned by dipping in gold chloride or potassium hexachloropalatinate solution to impart gold or platinum colour Mercury belongs to b. 4d series d. 6d series a. 3d series c. Sd series Mercury has an oxidation state of:- a. +1 only b. + only c. Both +1 and +2 d. None of the above |. Which of the following statement is/ are correct? a. Granulated zine is obtained by pouring melted zinc dropwise in water, b. Zinc sheets are obtained by heat- ing the zine metal at 150°C and the soit metal is rolled into sheets. c. Zine oxide, commonly called philosphers wool is obtained by heating zine in oxygen d. Zine is strongly electropositive metal and displaces Pb, Cu, Ag and Au from their solutions. Zinc oxide on heating with cobalt nitrate gives a green pigment known as Ril mann’s Green. The colouw due tox a, CoO b. ZnO c. Cozn0, 4, None of the above Zinc oxide a. Acidic b. Basic aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. oO IK's MCQs—Chemistry 120. 121. 122. ©. PbO, d. None of the above White lead is: a. PCO, b. 2PbCO,.Pb (OH); c. 2PbSO,.PbO d. PbCO,PbO Plumo ~ solvency means dissolu- tion of lead in: a. Pure air free water b. Ordinary water ©. Acids d. Alkalis In case a person is injured by gun shot, and all the pellets are not re- moved, it may cause poisoning by: a, Fe b. Pb ce As d. Cu 123. 124, Chloroplumbic acid is: a b. d. H5PbCL, (NH,),PbCl, PbCL, None of the above Red - lead is obtained by:- . Heating lead in carbon dioxide. . Heating lead sulphide in air, . Heating lead oxide (PbO) in oxy- gen at 470°C. None of the above is used to make steel . Annealing . Tempering . Quenching . None of the above PTS ah) 13, 19, 25. a 37. 43. 49. 2 55. 61 67 Te 79. 85. OL oT, a bie Rue 308 a 8. a,b 9% od a 14. b,d 15. a; bye: a 20. b 21d a 26. ¢ 27: € d 32. b 33. a a 38. b 39. a,b c 44. ¢ 45. a a,d 50. ¢ Sly & b 56. a 57. b d 62. a 63. ¢ d 68. a 69. b © 74. ¢ 75. a,b.od a 80. b 81. d c 86. ¢ 87. d c 2. ¢ 93. d c 98. d 99. © 4. be 5b 6a 10. b Ila 12.b 16. a,b,c Tr}, 18. d 22. a 23. d 24. © 28. ¢ 29. a 30, a 34. a,b,c 35. b 36. a,b,c 40. ed 4loa 42. od 46. b 47. c¢ 48. a 52. a,b,c,d 53. d 54. b 58. a,b 59. c,d 60. ¢ 64. 65. b 66. 10. 4 Toa 72 76. © 77. 78. a 82. ¢ 83. d 84. a 88. a 89. a 90. ¢ O4. a 95. d 96. a 100. ¢ 101. a,b,c 102. ¢ Chemistry of Heavier Metals oO 103. a 104. a,byc,d 105. bye 106. a 107. ¢ 108. c,d 109. ¢ 110. a lll. a 112. ed 113. a ll4. ¢ 115. b 116. b 17. d 118. © 119, a 120. b 121. b 122. b 123. a 124. 125. a Chemistry of Representative Elements 1, The representative elements be- long to: a, §— block only b. p — block only c. sand p ~ blocks d. d — block only 2. The s — block elements belong to: a, Group | only b. Group 2 only c. Group 3 only d. Group | and 2 only 3. The p-block elements belong a. Groups | and 2 b. Groups 3 to 12 c. Groups 13 to 18 d. None of the above * Choose the Correet O ption(s) — $$$" 4. The general electronic configura- on ns*np! “is that of elements of a. s — block b. p —block ce. d—block d. f—block 5. The representative elements: a. belongs to alkali metals and alka- line earth metals series. b. Boron, carbon and nitrogen fami- lies. c. O, halogen and nobel gases fam- ily. d. All the above 6. The compound of the elements of p block are:- a. predominantly ionic b. covalent in nature c. ionic as well as covalent oO IK's MCQs—Chemistry d, neither ionic nor covalent 7. Which of the following statements is/are correct? a. The highest oxidation state of s— block elements is equal to the group number in which the ele- ment is placed. b. The highest oxidation of p — block elements is equal to the group number (in which a particular element is placed) minus 10. c. In case of p — block elements (group 13-17), the stability of the highest oxidation state decreases. d. All the correct 8. Out of the elements in 2" and 3 period, diagonal relationship is ob- served in the case of which of the following? a, Li-Mg b. Be - Al « B-Si d. Be - Si 9. Which of the following metals of alkaline earth metals form oxides of the type MO,? a, BeandMg — »b. Ca ¢ SrandBa d. Rn 10. Which of the following metals react with cold water? a. Mg b. Cu c. Sr 11. Which of the following statements is/are correct? d. Ba a, Alkali metals react more vigor- ously with water compared to al- kaline earth metals. b. Alkali metals react less vigor- ously with water compared to al- kaline earth metals. ce, Thealkaliand alkaline earth met- als react with water with equal ease. 12. 14. 16, d. None of the above is correct. The hydroxide of which of the fol- lowing is amphoteric in nature? a. Be b. Mg c. Ca, Ba d. St . Alkaline earth metal hydroxides are less basic as compared to the hy- droxides of alkali metals. This is due to:- a. High ionization energy of alka- line earth metals. b. Smallionic sizes of alkaline earth metals. c. Greater lattice energies of alkaline earth metals d. None of the above The solubility of the alkaline earth metal hydroxides increases with increase in atomic number down the group from Be to Ba. This is because the: The lattice energy decreases down the group and the hydration en- ergy of the corresponding cations remains almost unchanged. b. The lattice energy increases down the group and the hydration en- ergy remain the same. c. The lattice energy is almost equal to the ionic energy. d. None of the above . Which of the following do not react directly with hydrogen to form the hydride? a, Na b. Cac. Mg” d. Be Beryllium chloride can be obtained bys a, Be + 2HCI—+BeCl, + Hy b. BeO + 2HC1——-+BeCl, + H,O Chemistry of Representative Elements oO 17. 800-1000" c. BeO + Cl, BeCl, +O 800-1000° d. BeO+C1, +€. BeCl, + CO The solu ly of the sulphates of alkaline earth metals decreases down the group. This is because a. The magnitude of lattice energy remain almost the same in the al- kaline earth metals. b. The hydration energy decreases from Be** to Ba?* down the group. c. A combination of (a) and (b). d. None of the above . Which of the following statements 19. 20. 21. are correct about the carbonates of alkaline earth metals? a. These can be prepared by passing CO, through the solution of alka- line metal hydroxides. b. These can be prepared by adding NayCO, or (NHq)) CO; oa solu- tion of alkaline earth metal salts. c. The solubility of the carbonates decrease down the series from BeCO, to BaCO,, d. The stability of the carbonates increases down the series from BeCO, to CaCO. The oxides and hydroxides of which of the following metals are amphoteric? a.Be ob Alc. Sr d. Ba The carbides of which of the follow- ing metals react with water to give acetylene gas? a. Ca b, Be c Bad. Al Which of the following elements is a non-metal? a. Be b.B c. Al d. TI 22. 24. 28. 29, Which of the following elements show oxidation state of + 1 as well as +3? a.B b. Al ec Gad. In . The atomic and ionic radii of B, Al, Ga, In, TI increase in the order: a, B> Al>Ga>In>TI b. B>Ga>In>TI>Al c. Tl>In>Ga> Al>B d. Tl> In>Ga>B>Al Which of the following characteris- tic of alkaline earth metals are larger than the corresponding alkali metals? a. Atomic and ionic radii b. First ionization energies c. Electrop ositive character d. Electronegativity . Which of the following form cova- lent compound? a.Ga b. In c B d. Al . On moving down the group Al, Ga, In, Th The reducing power a. ncreases, b. The value of the oxidation poten- tial increases. 2 . The density increases. d. The density decreases. . Which of the following does not combine with hydrogen to form hydride? aBo ob. Alc Be d.Ca Which of the following oxides are amphoteric in nature? a. BO; b. A103 c. Ga,0; d. Inj03 Which of the following hydroxides are amphoteric in nature? a. BOOH); b. AKO); oO IK's MCQs—Chemistry c, Ga(OH), d. In(OH), 30. Boron differs from aluminum and 31. 32. 34. other members of Group 13 be- cause boron h a. small atomic size b. high electronegativity c. low ionization energy d. all the above Boron forms: a. Only ionic compounds b. Only covalent compounds ¢. Both pounds ionic and covalent com- d. None of the above Which of the following combine with magnesium on heating? a. B b. Si c. Sn d. Pb . Which of the following characteris- ic of group 14 elements are smaller than the corresponding elements of group 13? a, Atomic rad b. First ionization energies c. Blectronegativity d. Blectrop ositive character Which of the following elements form tetracovalent compounds? aC b. Si ce. Sn d. Pb . As we go down in the 14 group from C to Ph: a. the stability of +4 oxidation state decreases b. the stability of +4 oxidation state increases. c. the stability of + 2 oxidation state increases. d. the stability of + 2 oxidation state decreases 36, 37. 38. 39 40. 41, 42, In which of the following the N is sp° hybridized? a, N(CH)s b. N(SiH); . Both (a) and (b) d. None of the above Which of the following form less stable hydride? aC bSi «Ge d Sn Which of the following oxides are amphotericin nature? a. SiO; b. GeO, c. $n0, d. PbO, Carbon, compared to other mem- bers of group 14 elements has: a, smaller size b. highest electronegativity c. remarkably property of catena- lion d. non ~ availability of d — orbital Which of the following characteris- tics of group 15 elements are higher (or more) than those of the corre- sponding group 14 elements? a, atomic radii b. ionization energies c. electronegativity d. all the above Which of the following characteris- tics decrease as we go down the group 15 from N to Bi? a. lonization energies b. Metallic character c. Blectronegativity d. Density As we go down in group 15 form N to Bi a, the stability in + 3 oxidation state increases, Chemistry of Representative Elements oO 43. 44. 46. 47. b. the stability of + 3 oxidation state decreases. . the stability of + 5 oxidation state nereases d. the stability of + 5 oxidation state 4 The order of the strength of covalent bonding in case of N, P, As, Sb, Bi follow the order: a. N > P > As> Sb > Bi b. Bi> Sb> As > P>N c, N> As>P>Sb>Bi d. P>As>N>Bi>Sb In the case of elements of group 15, which of the following characteris- ses. tics inerease as we go down the group from N to Bi? a. Thermal stability b. Reduci c. Basie character character d. All increase . In which of the following the phos- phorus is sp° - hybridized? a. PCl, b. PCls cc. Both (a) and (b) d. None of the above In which of the following the ele- ment (of group 15) has oxidation state of +4? a. NO, b. PO, c. As,O; d. Bi,O; Nitrogen differs from other mem- bers of the group because of its:- a. small size b. high electronegativity c. non ~availability of d —orbitals in valence shell d. none of the above 48. 49. Which of the following are termed metalloid? a. Pb ce. Se b S$ d. Te Which of the following is radioac- tive? aO bS ce Te d. Po . Which of the following are correct about the electronic configuration of members of oxygen famil a. The electronic configu tion of 4 the outermost shell is s*p*, b. The four electrons in p ~ orbital are distributed as py p) p! ce. The four electrons in p — orbital are distributed as pk py Pus d. The four electrons in p ~ orbital are distributed as py py Pz- . Which of the following characteris- tics of elements of 16 group are smaller (or lower) than those of the corresponding elements of group 15? a. Atomic radii b. First ionization energy c. Second ionization energy d. Electronegativity . In going down the 16 group, from O to Po, which of the following charac- teristics increase? a. Atomicradii b. Metallic character c. Electronegativity d. Electron affinity . Sulphur, selenium and tellurium in their compounds show oxidation state of a.-2 b +2 +4 +6 Oo IK's MCQs—Chemistry 54, 57, 58. 59, 60. . Sulphur form hexahalide wii As we do down group 16 from O to Te, which of the characteristic of the hydrides (1,0, HS, H,Se and H,Te) increase? a. Thermal stability b. Acidic character ©, Reducing character d. Allofthem . Which of the following elements of group 16 form hexafluorides? a. O b S ce, Se d. Te a. Cl, d. Fy Which of the following elements of group 16 do not form a monoxide (MO)? et b. Br, oc. Ly b. Se c. Te d. Po Oxygen differs from other mem- bers of group 16 in having: a, Small size b. Higher electronegativity c Non ~ availability of d ~ orbitals in the electronic configuration d. Large size The halogens chlorine, bromine and iodine exhibit oxidation state of a, -l only b. -L and +1 only c. +3 and +5 only d. -1, +1, +3 and +5 Which of the following statements is correct regarding the halogens (F, Cl, Brand 1)? a, The atomic radii increases from F tol b. The ionization energy value de- creases from F to ¢. All halogens are non ~ metallic in nature 61. 62. 64. 65. 66. 67. 68. d. Allhalogens are highly electrone- gative As we go down the group from F to I, there i a. Melting point c. Volatility increase in:- b. Boiling point d. All of them Which of the following halogen has the highest electron affinity? aFo obCl cBr dal 3. Which of the following characteris- tie deerease as we go down the group from F to I? a. The tendency to form ionic bonds . The oxidizing power c. Reactivity d. The ionic character of M—X bond Which of the following is least stable? . HE b. HCI . HBr d. HI Which of the follo mum bond dissociation energy? a. HF b. HCL c. HBr d. HE ing has maxi- In which of the following halogen has an oxidation state of + 1? a. OF, b. CLO c. Br,O d. clo, Acid strength of the follow ing halo- gen acids increase in the order:- a, HCIO,> HCIO;> HCIO, > HCIO b. HCIO > HCIO, > HCIO, > HClO, ce, HCIO;>HCIO,> HCIO > HCIO, d. HCIO, >HCIO > HClO, > HCO, Which of the following oxyacids of chlorine has the maximum oxidiz- ing power? a. HCIO, b. HClO, aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. oe IK's MCQs—Chemistry 83. 84, 85. 86. 87. 88. The relative order of heats of fusion of D,,T, and Hy a. T,>D,>H, b, D,>T,>H, © H)>T,)>D, d. D,>Hy>T) The radioactive isotope tritium emits:. a. O-particles b. B-particles c. Grays d. none of the above The absorption of hydrogen by platinum is known as:- a. Reduction b. Hydrogenation ¢. Oceulsion d, None of the above Hydrogen can combine with other elements by: a. Gaining an electron b. Losing an electron c. Sharing an electron d. All the above Atomic hydrogen can be obtained a. Electrolysis of water b. Action of granulated Zn on dil. H,SO, Passing hydrogen electric arc 9 through an d. None of the above Like alkali metals hydrogen: a. Is electropositive b. Shows oxidation state of + | in its compounds c. Acts as a reducing agent d. None of the above 89. 90. 91. 92. 94, 95. Like halogens, hydrogen a. Combines with non — metals to form covalent compounds b, Has a tendency to accept electron, . Form a neutral oxide (HO) as C1,0. d, Form hydride ion, The relative abundance of deute- rium in hydrogen is: a. 0.5-1% b. 0.2 % ec. 0.1% d. 0.01 % In which of the following hydrogen is obtained as a by product? a. Bosch process b. Lane process c. Electrolysis of HjO d, Manufacture of NaOH Nacent hydrogen is obtained by: a. Passing hydrogen through an electric are. b. Electrolysis of water. c. Action of Zn on dil, sulphuric acid d. None of the above The D, line observed in the yellow region of the sun’s spectrum is due to the presence of a. Na b. Ne c. He d. Kr Which of the following make lumi- nous paint? a. BaS b. ZnS c. MnS d. None of the above Stains of iodine can be removed by:- a. Soap b. Turmeric powder aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. ® IK's MCQs—Chemistry 9 10. LE 12. 13. 14. . Paramagnetism is common i In which of the following com- pounds iron has the lowest oxida- tion no.? a, Fes; b, Fe,0 ©. Fe (CO}s d. FeO, Transition metals are generally coloured because:- a. they absorb electromagnetic ra- diations b. their penultimate d-subshells are fully filled ce. of d-d transition d. none of the above Formation of interstitial compound makes the transition metals more:- soft ductile maleable eBags none of the above Which of the following ions doesn’t give coloured solution? a. Fe* b. Mn c. Zn d. Cr Which of the following ion is coloured? a. cuprous ion b. cupric ion c. both of them d. none of them The purest form of iron is: a, cast iron b. stainless steel ©. wrought iron d. none of these a, s-block elements b. p-block elements c. d-block elements 16. 18. 19. 20, 21, 22, d. any of them Which of the following element exhibits more than one oxidation state? aK bv Al cMg d. fe Atomic radii of d-block elements in a series a, decreases with increase in atomic number b. increases with increase in atomic number c. remains constant d. none of the above Lunar caustic is a, Ag OH ec. Ag;0 b. Agcl d. AgNO, German silver is an alloy made up of a. Cu.Ni.Mg — b. Cu, Fe,Mg ce. NiZn,Mg — d. Cu. Ni, Zn Which metal has the lowest melting point? a. Cu b. Cs c. Hg d. Mn Transition metals in complexes act ast a. Lewis acid b. Lewis base ce, Neutral d. None of the above Rutile is an ore of a. Manganese b. Chromium c. Titanium 4. None of these . In gun metal alloy, which of the fol- element is lowing — transi present? aCu ob,Ni aMg d ion Zn aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. ® IK's MCQs—Chemistry 76. 77, 78. 79. 80. 81. . Sold c. They have small charge size ra- tio d. They provide em pty d-orbitals ris an alloy of: a. Sn-Pb b, Sn-Zn c. Zn-Cu d. None of these Copper displaces the correspond- ing metal from salt solutions of: a. FeSO, b. ZnSO, c. AgNO, d. None of the above The Colour of Ti* ion is:- a. Pink c. Blue b. Green d. Colourless Metallic lusture in silver is due to :- a, It is coated with silver oxide b. Valence electrons absorb and eject white light c. Valence electrons absorb white light but no reflection d. None of the above Which of the following statements, regarding K,Cr,O, is wrong? It is soluble in water. b. Itis a powerful oxidising agent. c. It reduces ferric sulphate to fer- rous sulphate d. None of these Which of the following element would be attracted to a magnetic field? a Hg ob Sr oc. Mn d. Cd Iron obtained from a blast furnace Is; a. Cast iron b. Pig iron c. Wrought iron d. None of these 82. 83. 84. 86. 87. 88. 89. The electronic configuration of ele- ment having atomic number 64 is:- a. [Xe] 4f° 5d>6: b. [Xe] 4f 5d? [Xe] 4f7 sa! 6s? d. [Xe] 4 5d” 6s? The highest oxidation state exhib- ited by a transition element 6: a. +5 b. +6 +7 d. +8 Which of the following metals is ferromagnetic? a, Cd b. Cu ce. Ni d. None of these . Which of the following order of Melting points of Cu, Ag and Au is correct? a. Cu>Ag>Au b. Ag> Au>Cu c. Cu>Au>Ag d. Au>Ag>Cu Atomic radii of second and third transition series are almost same because: a, diagonal relationship b. lanthanide contraction c. shielding effect d. none of these Which of the following is an acidic oxide? a, MnO b. MnO, c. Mn,O, d. Mn,0, Which of the follow ing forms inter- compounds ? b. Ni d. None of these a. Fe ce. Co Which one of the following has the low melting point? a Ag ob Cu oc Au d. Zn aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. 137. 138. 139. IK's MCQs—Chemistry a, increases b. decreases ©. remains constant d. first ir ses then decreases Platinum metal can be dissolved in:- a, Hot & conc. HCI b. Hot & cone. HNO, c. Hot & cone. H,80, d. Mixture of cone. HCland HNO, Which of the following elements belong to actinide series? a.Ta bY c U de Li Which of the following transition metals is used as promotor in the manufacture of ammonia? a. Fe b. Co c Mo d. Ni loa 25 ¢ 3. d 4b Re 10. ¢ Hb 12. ¢ Ia 18. d 19. d 20. ¢ 5. oe 26. d 27. d 28. d € 34, ¢ 35. ¢ 36. b .d 42. Dd 4B. 44. a ie 30. ¢ Sl. ¢ geod 2b 58. ¢ 59. a 60. d dd 66. d 67. ¢ 68. d 4 14. d 75. b 76. ¢ b 82. ¢ 83. d 84. ¢ 89. d 90. a Ol. 92. ¢ 97. a 98. b 9.¢ 100. b 105. b 106. d_ 107, bs :108. 3c 4b 11s. 116. b I21.c 122,¢ 123d 124. ¢ 129. d 130. a 131. b = ¢ 137, d 138, ¢ 139. ¢ 140. ¢ 140. 141. 142. 93, 101 109. 117. 125. 133. 141 Gradual filling of f-orbitals is in- volved in: a. Lanthanides b. Transition metals Actinides d. None of these The common oxidation states of Titanium are:- |. +2, 43 b. +2, +3, +4 ce, +3, +4 d. None of these Equivalent weight of KMnO, in al- kaline medium is:- a. 31.6 b. 52.67 c. 158 d. None of these d 6. ¢ & Boa b Ide IS. c 16. d a 22, ¢ 3. a 24. d d 30. b 31. b 32. ¢ a 38. d 39. a 40. b € 46. ¢ 41. a 48. d d 54. b 55. b 56. ¢ c 62. ¢ 63. ¢ 64. b b 70. d Tle T20¢ d 78. b B. ¢ 80. ¢ c 86. b 87. d 88. ¢ b 94. ¢ 95. a 96. b b 102. b 103, a 104. b © WOd hb 2a a Ube 1% 120. d © 126.d 127. d 128. b d 134. d 136. a c 142. ¢ aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. @® IK's MCQs—Chemistry 37. 38. 39, 40, 41. 42. a, [Co(en)s]; SO, b. [Co(en); SO4] ©. [Cofen);] SO, d. [Coles], (SO,); A complex with large dissociation constant a. Highly stable b. Highly unstable c, Stable in solid state d. None of these TUPAC name for ONAN 2; (NH), Co Co (NH4)4)** isi- \nofé a, tetraammine cobalt (If-u-imido- ‘0 tetraammine cobalt (ID) ion if b. bis [tetraammine}-u-imido-u-nitro cobalt (II) ion bis [tetraammine]-u-imido-u-nitro cobalt (III) ion d. tetraammine cobalt (II1)-u-imido- u-nitrotetraam mine cobalt (II) ion The complex cis-[Pt (NHL),CI,] is used in treatment of cancer under the name: a. Platin b. Cisplatin e. Cancerian d. Cis cancerian Wilkinson’s catalyst contains:- a, Cobalt b. c. Rhodium Iron d. Aluminium Which of the following metals form the most stable complex? a, Co* b. Ni* c. Fe d. Mn** Vitamin B,, contains:- b. Nickel d. Cobalt a. Magnesium c. Iron 43, 44. 45, 46, 47. 43. 49, ‘A white precipitate of AgCl is solu- ble in liquid ammonia due to the formation of:- a. AgOH b. Ag (NH,)CI c. AgNH) d. [Ag (NH,),] Cl Trans effect is shown to maximum extent by: aH b. NH, & eF d. CN Which of the following is a zincate ion? b. ZnO; d. None of these Which of the follo not show opti a. trans [CoCl, (en )5]* b. cis [CoCh (en),)” ec, [Cofedta}] d. Allof these ng complex will 1 isomerism? The number of isomers of the com- plex [Rh (en), CLI" is: b. Two d, Four a, One c. Three Stable complexes are formed by those metals which are:- a. Low electropositive b. High electropositive c. Low electronegative d. High electronegative Which of the following valency is directional? a. Primary valency b. Secondary valency c. Both a & b d. None of the above . Which of the following is nota com- plex? a, Potassium ferrocyanide b. Ferrous ammonium sulphate aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. ® IK's MCQs—Chemistry 86. 87, 88. 89. 90. 91. ce. 4n +2 d. 4n +3 The radiocarbon dating method was developed by a. Yukawa b. J.J. Thomson Willard Libby None of these a6 d In the nuclear reactor, which of the following is used as neutron ab- sorber? a, Water b. Deuterium e. Cadmium d. None of these The binding energy in ,;P' nu- cleus, if its mass defect is 0.092 a.m.u is:- a, 1.35 x 10 ergs/ nucleus b. 9.2 x 10“ ergs/ nucleus c. 11.48 x 10+ ergs/ nucleus d. 2.14 x 10 ergs/ nucleus 92U?"8 emits an o—particle, the prod- uct has atomic number and mass number:- a, 234, 90 b. c. 238, 90 d. ™P has a half life of a 350 years. 100 mg of asample containing “P is re- duced to 25 mg i a, 175 years b. c. 700 years d. 1050 years The theory of radioactive disinte- gration was given by: a, Rutherford & Thomson b. Rutherford & Soddy Soddy & Fajans d. Hahn & Strassman 92. 93. 94. 95. 96. 97. 98. Radioactive disintegration differs from a chemical change in being: a. aunimolecular first order reaction b. a nuclear process . a spontancous d. none of these Transuranic elements are the ele- ments with atomic number: a, <92 b. 93-105 c, >105 d. None of these (4n+1) radioaetive series is called as: a, uranium series b. neptunium series c. actinium series d. thorium series After 24 hours, only 0.25 g out of the initial quantity of 2g of a radioiso- tope remains behind. Its half-life will be: a. 4 hrs b. 8 hrs c. 12 hrs d. 16 hrs An c-particle is emitted from the atom ,U*, The no. of neutrons in the atom of daughter clement will bes a. 138 b. 140 ¢. 144d, 150 Which of the following radioisotope is used to detect anaemia? a, P-32 b. Fe-59 c. Na-24 d. Co-60 Na-24 radioisotope is used:- a, for the treatment of Leukemia b. for the treatment of Thyroid c. lo detectanaemia 4. to locate the defect in blood circu- lation aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable 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Atomic Structure @ ANSWERS Ld Ze aa 4a id &c Ted & b Qa 1a b Ate fd lia Id. a lia io. b lec 41k. d 19d 20. b 2La 22d 23. a 24. ¢ 2d 26. ¢ 2La 22 b 22. b 30. a ald a2. € 33. b 34. b 35. ¢ 36d au b 38 b 3a¢ 40. a 4b 42. 8 43a 44. b 45. a 46. © 47. b 48. ¢ 4c Sha Sl 52a Sac 54. b Sic 56. a shed ik b sac 60. c ole oud 63. b 64. b oc oo d o2 b 68. d Oa TW. b dL. ¢ Rd Bc 74. b 75. d 76. b qd 7. d Da 80. ¢ Bloc Bla 83. b 84. a 85. ¢ 86. a 82 b 8B. ¢ 89. b oO. a OL b 92. b 93. b 94. b 95. d 96. ¢ 97. d 98. ¢ 99, a 100. ¢ 101. b 102. a 103. d 104. ¢ 105. d 106. d 107. ¢ 108. b 109. d 110. ¢ Hl. b li2d 113. ¢ d oS.c¢ 6c 11% e 118. ¢ 1 121. d 123. b 124. a 125. d 126d 12: 129,d 130. ¢ 131. ¢ 132,¢ 133, a 134. & 136, 137,d 138. ¢ 139.d «140. ds 14t, a 142. 144, 145. ¢ 146. a 147. ¢ 148. d 149. b 150. d 152. ¢ 153. b 154. b 155, d 156, b 157. ¢ 158. d 160. ¢ 161. d 162. b 163, a 164. b 165. ¢ 166. ¢ 168. a 169. ¢ 170. ¢ 71. d 172. d 173. d 174. d 176. ¢ 177. b 178. ¢ 179. d 180. d 181. b 182. a 184. ¢ 185. a 186. b 187. ¢ 188. ¢ 189. b 190. b 192. d 193, d 194. d 195. ¢ 196. bs: 197. b SELECTED EXPLANATORY ANSWERS 26. The electronic configuration of atom having 2K, 8L, 11M & 2N electrons is 1s? 2s? 2p* 357 3p° 3d4 4s? Therefore Total number of electrons = 8 34. E,, = -const/ n+ & therefore ~ve values 47, B=hv=he/ A Therefore Ej/ Ey = Ax dy = 6000/ 3000 = 221 65. By using formula, v= = aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing 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Chemical Thermodynamics @ Choose the Correet 0 ption (6) $$ 1. 2. The study of transfer of energy be- tween a system and its surround- ings is called: a. Thermochemistry b. Thermodynamics Chemical kinetics The pometery eee Thermodynamic quantity is: One which is used in thermo- chemistry e b. One which obeys all the laws of thermodynamies c. A quantity whose value depends only on the state of system d. A quantity which is used in mea- suring thermal change Which of the following is an inten- sive property? b, Mass d. Temperature a, Enthalpy c. Volume } An endothermic reaction is one which a. is accompanied by a flame b. is accompanied by absorption of heat c. is accompanied by evolution of heat d. None of the above . Which one of the following system is an example of a closed system? a, Hot water in a open beaker b, Hot water in a closed container which is not insulated Hot water in a closed container o which is insulated d. None of the above aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. Chemical Thermodynamics @ 44. 45. 46. 47. 48. 49, ¢. Boltzman d. None of the above The likelihood of a process increases ase a. AS=0 b, AS>0 c. AS< 0 d. None of the above Unit of work is: a. kgm b. kgm ce. kgm's d. None of the above Which of the following expression is correct? a. q= AE + PAV b. q=AE-PAV c. q=-AE - PAV d. q=-AB+ PAV In which case, a reaction is impos- sible at any temperature? a. AH >0, AS >0. b. AH >0, AS< 0 c. AH< 0, AS< 0 d. None of the above When the gas is ideal and the pro- cess is isothermal then: a. By = Ey b. H, 4H, c W=0 d. None of the above The heat capacity (c) of a system whose temperature is increased by dT when a very small amount of heat dq is added to it, is shown by: a. dq/ dT b. dT/dq c. dq+dT d. dq aT wn a . For the reaction, N , (2) + 3H, (g)—~ 2NH; (g), which of the following is correct? a, AH = AE b, AH > AE ce. AH < AE d. None of the above . Which of the following is correct? a. Melting ofice causes a decrease in randomness b. Evaporation of water causes an increase in disorder of the system c. Condensation of steam causes an increase in disorder of the system d, None of the above . Calorie is defined as the quantity of heat required to raise the tempera- ture of a. | mole of water through 1°C b. 1g of water through I°C c. | kg of water through 1°C d. None of the above . At constant volume, 600 joule of heat was supplied to increase the temperature of the system from 30° to 40°C. The change in internal en- ergy of the system is: a. 6000 J b. 600 J c. 60F d. None of the above . Which of the following is a path function as well as the extensive property? a. Temperature b, Heat capacity c. Internal energy d. None of the above aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. Chemical Thermodynamics ® 112. 113. 114, 116. Which of the following is not the definition of 2" law of thermody- namics? a. The entropy of universe is con- tinuously increasing b. The complete conversion of heat into work is imposs le without leaving some effect elsewhe c. A spontancous process can be easily reversed d. None ofthe above Standard enthalpy of sublimation is given by: AH (Sublimation) = AH°(Fusion) — AH “(vapourisation) b. AH°(Sublimation) = AH*(Fusion) + AH “(vapourisation) ec. AH°(Sublimation) = AH'(Combustion) — AII*(Dissociation) d. None of the above A sample of an ideal gas is allowed to escape reversibly & isothermally into vacuum. Which of the follow- ing statement is correct? a. AE=0,q= b. w= 0, AB =q . q=0,AE d. w=q=AF=0 5. Which of the following is correct about spontaneous reaction:- a. Its occurs instantaneously b, Itdoesn't require any initiation to start c. It can proceed on its own or on initiation d. None of the above Entropy changes of chemical reac- tions are usually measured at: 7. 118. 119. a, Constant temperature b. Constant pressure ¢. Constant volume d. Constant te: perature & pre ure Which of the following graphical representation is not correct? Fe isobaric + P vo b. t sochoric ve c. t Adi Pp jabatic v= di; Cy st bs v= In which of the following reactions, AH = AV? a. NO, (g) —+2NO, (g) b. H,0 (J) —+H,0 (g) c. Hy (g) + L,(g-—2H 1 (g) d. None of the above In a bomb calorimeter, amount of heat absorbed on formation of solid CaCO, on reaction of CO, on solid CaO is measured. It gives a direct b. AH d. AS aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. © IK's MCQs—Chemistry d, None of the above 28, 0.1 N KCI solution is placed be- 29. 30. 31. 32. tween two platinum electrode Lem apart and 2.0 sq. em. area of cross section and having 20 © resistance. The equivalent conductivity of solu- tion a. 140 Q* cm? eq b. 250 2! cm? eq c¢. 334 Q7 cm? eq” d. None of the above If the conductivity of | M H,SO, solution is 34 x 107 Q" em", its equivalent conducti a, 340 Q'emteq! b. 170 O! em? eqt c. 346 Q! cm? eq d. None of the above I The molar conductivity of an elec- trolyte A, B, at infinite dilution is:- a xh ty dy bo yAQ.tx Ay © Nga + Age d. None of the above ‘The molar conductance of Al {SO 4) and molar ioni¢ conductance of SO} ions at infinite dilution is 88 7 cm? mol and 154 OQ" cm’mol' respectively, the molar ionic conductance of Al” ions at this dilution is: a, 387Q' cm> mol! b, 193.5 Q! cm? mot! c. 180.3 Q! em? mol! d. None of the above Molar conductivity of acetic acid at a concentration of 1 mole in 1000 ite dilution is 49 & litres and at int 33. 35. 36. 397 QO"! em? mol respectively. Per cent age dissociation of 0.001 M ace- tic acid is: a. 14.12 % b. 8.10 % c. 0.14 % d. None of the above Molar conductivities of NH,Cl, NaCl and NaOH at infinite dilution are 134.3, 107.8 and 213.7 Q7 cm? respectively and molar conductivity of a centinormal solution of NEO. is 9.74 QO cm*. The dissociation constant of NIL,OH will be: a. 24.66 % b. 14.64 % c. 4.05 % d. None of the above Amount of electricity required to reduce 1 mole of MnO* to Mn” is: a, 96500 C b, 193000 © c. 386000 C d. 482500 C Number of coulombs required to deposit 34.5 g of aluminium from AL(SO,); is a. 37x 10°C b. 24x 105°C c. 18x 10°C d, 0.94 x 10°C Amount of Nickel deposited at cath- ode of an electrolytic cell con 2 Ni(NO,); [at.mass of Ni = 58.7] solu- tion by using a current of 4 ampere for 20 minutes is: a. 0.024 g b. 0.048 g c. 1.46 g d. 292g . The maximum work obtainable from the Daniell Cell if Fey is 1.10 voltis:- a, 106.15 kJ aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. Surface Chemistry © Choose the Correet Option (§) $$$ 1. The zig-zag motion of colloidal par- ticles was first observed by: a. Ostwald b. Robert Brown ¢. John Tyndall d. None of the above 2. Which of the following is not an ex- ample of adsorption? a. Silica gel in environment of water b. Ammonia in contact with char- coal ¢. Calcium chloride in environment of water d. None of the ahove 3. When the substance gets uniformly distributed into the bulk of the solid and at the same time, its concentra tion is higher at the surface than in the bulk, the phenomenon is called as: a. adsorption b. absorption c. sorption d. None of the above }. The number of phases in a colloidal system is: a. l b. 2 3 a4 .. The size of colloidal particles is in the range of: a, 1000nm—10000nm b. 100nm-1000am ¢. Inm-100nm d. 0.Inm-Inm aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. Surface Chemistry @® 39. 40. 41. a2. 43, d. None of the above Colloidal particles exhibit Tyndall effect due to: a. Reflection of light b. Polarization of light c. Scattering of light d. Refraction of light A dispersion of silver chloride in wateris: a. alcosol b. an emulsion c. hydrophilic colloid d. hydrophobic colloid Addition of a catalyst in a system: a. Increases the equilibrium concen- tration b. Decreases the equilibrium con- centration c. Has no effect on equilibrium con- centration d. None of these Ferric chloride is applied to stop bleeding cut, because: a. Fe* jon coagulates blood which is a negatively charged sol b. Fe** ion coagulates blood which is a positively charged sol c. Cl ion coagu lates blood which is a positively charged sol d. Cl ion coagulates blood which is a negatively charged sol The gold number of Gelatin, Hae- moglobin, Egg albumin & gum Ara- ic is 0.005 - 0.01, 0.03 - 0.07, 0.1 — 0.2 & 0.15 - 0.25 respectively. Which of the following is the best protec- tive colloid? a. Gelatin b. Haemoglobin 44. 45. 46. 47, 48. 49. c. Egg albumin d. Gum Arabic Fog is acolloidal solution of: a. Gas in solid b. Gas in liquid c. Liquid in gas d. Solid in gas The movement of colloidal particles under the influence of applied elec- tric field is called: a. Dialysis b. Emulsion c. Tyndall effect d. Electrophoresis Which of the following electrolytes will be most effective in causing the coagulation of a positively charged ferric hydroxide sol? a. KCI b. K,SO, c. Na,CO, d. K,Fe(CN), A gold sol is prepared by: a. Dissolving gold in aqua-regia b. Double decomposition of AuCl, ¢. Bredig’s are method d. None of the above An emulsifier is an agent which: a, stabilizes the emulsion b. floeculates the emulsion c, homogenizes an emulsion d, accelerates the dispersion Ferric hydroxide precipitate in pres- ence of water containing some fer- ric chloride becomes colloidal on shaking. This is an example of: a. Coagulation b. Electrophoresis c. Peptization d. None of the above aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. Assertion and Reasons ® o, 13. 14, 15, 19. . AH Root mean square velocity Uy, of carbon dioxide has smaller value than carbon monoxide. Liquids diffuse slowly as compared to gases. For a fixed amount ofa gas at con- stant tem perature, volume and tem- perature ratio is constant. . The pressure exerted by a sample of dry air decreases when water vapour is added to it For real gases, compressibility fac- tor is always less than one. Surface tension of water than that of ether. s higher Viscosity increases with rise in tem- perature. In calculating the internal energy of a substance, gravitational energy is usually neglected. . Tea placed in the thermos-flask can’t lose or gain heat or matter to the surroundings. Work is a state function Work done on a system is a nega- tive quantity. Enthalpy change AH for an exo- thermic reaction is negative. At constant volume, heal change is equal to internal energy change. . Out of carbon, methane & butane, methane is a better fuel. rusion is always negative. Entropy of any elementary sub- stance in the standard s ate is zero. Hy, iS inversely proportional to molar mass. Intermolecular forces are greater in gas At constant temperature, the volume of a creases or de- given amount of a gas, Lo. . a7q fits volume at 0°C. ‘The change in pressure is due to pressure creases by exerted by water vapours. Real gases always exert higher pressure than expected. Intermolecular forces between molecules of water is less than that of ether. By increasing the temperature resistance between liquid layers increases. It is very small as compared to the other forms of energy Thermos-flask is a closed system. The amount of work performed depends upon the path followed. Energy is transferred from the system into the surroundings. Enthalpy of a system is an extensive prop- erty. No expansion or contraction work is in- volved. Methane has the lowest calorific value. Heat energy is required to overcome the intermolecular forces between the con- stituent particles of a solid. At absolute zero degree, the particles be- come completely motionless. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. ® IK's MCQs—Chemistry 117. 118 119, 120. In Hydrogen atom, the transition of _ nz and ng are closer to nucleus than ny. electrons from ny > nz will emit greater energy than ny n3. Rate of emission of photoelectron No. of photoelectrons emitted increases increases with increase in the fre- with increase in the intensity of incident quency of incident light. light. In Rutherford experiments, few & Most of the space in the atom is empty. particles are deflected. Debroglic equation has signifi- Debroglie wavelength is inversely propor- cance for any microscopic particles. tional to the mass of the object. ANSWER R (b) (c) (a) fa) Both assertion and reason are true but reason is not the correct explanation of assertion. Plot of PV against P is a straight line because PV is constant at different pressures. Assertion is true but reason is false. Under identical conditions of tem perature and pressure, the rate of effusion of a gas is inversely proportional to the square root of its density (Graham's Law of effusion). Both assertion and r true and reason is the correct explanation of ason ar assertion According to Graham’s Law, at any temperature, average kinetic energy ofany gas is same, hence out of the two gases the one with lower molar mass will have higher speed. Both assertion and reason are true & reason is the correct explanation of assertion. sve [E hence Hjng (COs) < Heme (CO) Assertion is true but reason is false. & + isinversely related to molar mass & Liquids diffuse slowly than the gases because, intermolecular forces in liquids are greater than that in gases Both assertion and reason are true and reason is the correct explanation of 273 +t ve 273 assertion. Atconstantn & P, Vp= v(t + a) 2B aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. Assertion and Reasons ® 63. (b) 64. (e) 66. (a) 67. 68. (b) For ideal solutions, AH ,,,ing Must be zero as there is no change in the magni- inde of the attractive forces in the two components present. Both assertion and reason are true but reason is not the correct explanation of assertion Relative lowering of vapour pressure depends only on the number of solute particles but not on the nature of the solute and so it is a colligative property. [Colligative properties are the properties of the solutions which depend only on the number of solute particles but not on the nature of the solute), Assertion is false but reason is true. m= CRT -«. Tftwo solutions have same concentration, they must have same osmotic pressure at the same temperature. And such solutions having same osmotic pressure are called isotonic solutions. Assertion is true but reason is false. In benzene solvent, benzoic acid exists as dimer pow Oy C.Hs— O-H- (enzoic aia) So total number of molecules in solution become less than number of mol- ecules of the benzoic acid added and hence colligative properties will be lower. Since the colligative properties are inversely proportional to the molar mass of solute, the molar mass of benzoic acid will be greater than the theo- retical value. Both assertion and reason are true and reason is the correct explanation of assertion. aCl,,m = 3 Bi mm For CaCl;,m yop 2 Assertion is false but reason is true. The elevation in boiling point of these solutions can’t be same as number of solute particles in both of the solutions are different and a colligative property (ie. elevation in boiling point) depends upon number of particles. NaCl is ionic and give more number of particles due to ionization than the sugar. Both assertion and reason are true but reason is not the correct explanation of assertion. Osmotic pressure measurement is preferred over other methods as osmotic pressure can be measured at room temperature, on the other hand, elevation in boiling point is measured at high temperature whereas depression in aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. Copyrighted material aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. Sample Papert (509 } 49, Neoprene is a polymer of:- 50. Rutile is an ore of: a. Isoprene a. Titanium b. Propylene b. Cobalt ©. Chloroquine c. Magnesium d. Chloroprene d. None of these la 2, & BS 4d Sy & 2b Bc ob 10. b ll. a 12. a 13. d 15. d 16. b 7a 18. ¢ 19. b 20. 21. d 23. a 24. b 25. ¢ 26. ¢ 27. d 28. We Sleve 32. b 33. d 34. b 35. d 36. 37. d 39. d 40. d 4lic a 43. ¢ 44a 45. b 46. 6 47. a 48. 6 49. d 50. a aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. @ IK's MCQs—Chemistry Ra22>—_+,,Pb2™ ares a, 50, 4B b. 40, 5B. c. 30, 48 d. None of the above . In industrial processes, transition elements and their oxides are used asi a. surfactants b. insecticides c. catalyst d. Allofthem 36. Rutherford’s experiment on seatter- 37. 39. 40. 41. ing of particles showed for the first time that atom has:- a. electron b. protons © neutrons d. nucleus Which of the following is most reac- tive towards nucleophilic substitu- tion reaction? a, CH,= CH -Cl b. CH; -CH = CH - Cl c. CyHs—C d. Cl-CH,-CH =CH, . Which of the following alcohols is most reactive with HCl in presence of ZnCl? a. (CH,);C - OH b. (CH4),CH —~OH c. (CH,),C - CH,OH d. CH,OH Acetamide reacts with NaOBr in alkaline medium to form:- a NH b. CH,CN c. CH,NH d. None of these The chemical formula of Laughing gas a. NO b. N,O c. N,O; d. NO, Oxidation number of iodine varies from:- 42, 44, 46. 47. 48. a.-lto+7 b.-lto+5 ce -1to+] d. None of the above Which of the following aminoacids has acidic chain? a. lysine b. phenylalanine c. proline d. asparatic acid Nylon-66 is obtained from:- a. Adipic acid and phthalic acid b. Ethylene glycol and terephthalic id . Hexamethylene diamine and adi- pic acid d. Caprolactum Percentage of gold in 18 carat gold ise a, 20% b. 38.67% c. 75% d. 80% . Which of the following amines gives carbylamine reaction? a. (CoH5)3N b. (C3H5))NH c. C)H,NH —CH, a. CsHs NHy A 50% of reaction gets completed in 18 minutes, What fraction of reac- tion would occurin 36 minutes? a, 60% b. 75% ©. 90% d. 100% Which of the following is a colliga- tive property? a. boiling point b. vapour pressure c. osmotic pressure d. None of these TiCI has CsCl structure. The coordi- nation number of Titanium is: a4 b. 6 aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. ® IK's MCQs—Chemistry 33. 34. 36. 38. Which of the following complexes has sp*d? hybridisation? a. [Cr(NH,)oh** b, [Fe(CN),}* c. [Fe(CN) pI d. [Cor After 24 hours, only 0.25 g out of the initial quantity of 2 g of a radioiso- tope remains behind. Its half life will be: a. 4 hrs b. 8 hrs c. 12 hrs d. 16 hrs . Which of the following metal is present in Zieglar-Natta catalyst? a. Ni b. Cu c. Zn d. Ti For elementary substances, AH’, is a. any “#ve’ value b. any ‘ve’ value ©. zero d. any ‘tve’ or ‘ve’ value |. Cobalt - 60 is used in the treatment of b. Leukaemia Thyroid a, Pneumonia c. Cancer a. Hydrogenation of benzoyl chloride in presence of Pd on BaSO, gives:- a, Phenol b. Benzyl alcohol c. Benzaldehyde d. Benzoie acid pound is formed by elements A and B crystallizes in the cu arrangement in which atoms A are at the corners and atoms B are at the face centres. The formula of the compound is:- a. ASB >. ABy 40. 41, 42. 44. 45, c. ASB d. ABs Which of the following is indepen- dent of temperature? a. normality b. molarity c. molality 4. None of these For the electrolyte CaCl,, the degree of dissociation («) is equal to: ail )) c. #a-1 4. None of the above [where i= Van’t Hoff factor] Nitrobenzene gives N-phenyl hy- droxylamine by: a, Sn/ HCI c. Hy Pd—-C b. Zn/ NaOH d. Zn/ NHC] Which of the following is an organo- metallic compound? a. (C3H;0),Ti b. BOOCH,); c. Ky{Zn(CN),] d. C,H, TOC,H,), The relation, Degree of Am Am (a= [where a‘, = molar conductivity of a solution at any cone. C & a2, = molar conductivity of a solution at infinite dilution] hold good for: a. Any electrolyte b. weak electrolytes c. strong ctrolytes d. depends upon the nature of clee- wolyte Which of the following metal is used in X-ray tubes? aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. sample Paper—4 (525 } 20. 21. 22. 23. 24. When concentration quotient (Q) i: smaller than equilibrium constant:- a. Reaction will be in equilibrium b. Reaction will proceed in forward direction ° . Reaction will proceed in back- ward direction d. None ofthe above The equivalent weight of Cr,0,7 in an acidic medium is a. M/2 b. M/3 c. M/6 d. M/9 In Metallic conductors, with in- crease of temperature, electri conduction: a. Increases b, Decreases c, Remains constant d. First increases then decreases For the reaction, H +1, 2H a. AH >AE b. AH. 5 d.9 If the average osmotic pressure of human blood is 7.8 bar at 37° C, the concentration of an aqueous NaCl solution that could be used in the blood stream is: a, 0.16 mol/L b. mol/L c, 0.45 mol/L d. 0.60 mol/ L I AH for CO, (g) , H,0 (g) and C,H, g(0) are - 490 - 240 and + 160./ mol respectively, how much energy is released when 6 mole of octane is b. - 20.0 kJ d. 374k For the equilibrium H,O () == H,0(g) at 1 atm and 298 K:- a, Free energy change is less than zero (AG* <0) b. standard free energy change is equal to zero (AG® = 0) Siandard free energy change is less than zero (A G° < 0) d. Standard free energy change is greater than zero (AG° > 0) What is the crystal system of a com- pound having unit cell dimensions a= 0.387, b = 0.387 and ¢= 0.504 am and o = B= 90° and y= 120°? a, Cubic b. Hexagonal c. Orthorhombic d, Rhombohedral . For glycine, if Ka, = 4.5 x 10°} and Ka, = 1.7 x 10" at 298 K, what will be the pH of 0.01 M glycine solu- tion? a. 3.0 b. 6.1 36. 37. 38. ce. 7.2 d. 10.0 Which of the following change will shift the reaction towards the prod- uct? 1, = 21 (g), AH” (at 298 K)= + 150 kJ a. Increase in temperature b. Increase in total pressure c. Increase in concentration of | d. Decrease in concentration of Ib Which of the following statements is true for the electrochemical Daniel cell? a. Cal electrode ons move towards copper b. Cations move toward zinc elec- trode. c. Electrons flow from copper elec- trode to zinc electrode d. Current flow from zinc electrode to copper electrode The biodegradable polymer is: a. polythene b. Polyvinyl chloride c. Nylon -6 4. Cellulose For the reaction N,O3(g) > 2NO, (2) + 4 O, (g), the rate constant is 2.3 x 10°? s7*, Which of the following equation describes the change of (N,0,] with time? [N,O,], and [N05], correspond to concentration of NOs initially and at time (t) re- spectively? a. [NOs], = [N,O.], + kt b. [N:O5], = [N205ke' c. logio IN305}, = log jo [N05], — kt IN2Oslo _ 4g dn = IN2 05h aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. Solved Papers of Previous Three Years {AlIMS—Chemistry] @ 172 —S os F016 WL 20.0821 x 310 me 2 32. For the reaction, Cy H\y+ s 0, >8C0,+9H,0 34. 35. 36. 37. 8X IC +0, 4 COg,,,; AH} =~ 490 I mol] > (a) 9x (2H + 4 0; + H,0,): AH} =~ 2401 mol] > (b) [8C + 9H, 9 C, Hy: AH? = + 160 / mol] > (c) Above reaction is obtained by subtracting from (a) and (b). Ke) Heat evolved during the combustion of one mole of Cy Hig = (- 490 x 8) + (240 x 9) = ( + 160) = — 6080 + 160 = — 5920) for 6 mole = 6 x — 5920 J= ~ 35520 J 35.52 kJ In the crystal system when a=b #c and @= B= 90°. y= 120°; then the crystal system is hexagonal For glycine, Ka, =4.5x 107 and Ka, = 1.7 x 101° at STP K relation strength = {= so the pH of solution =6.1 For the reaction, Ih 4) = 2jps H7(298 K) = + 150 kJ This is endothermic process, so increase in the temperature of the system will shift the reaction towards the product. In the Daniel cell electrons moves from zinc electrode to copper electrode, and hence current moves from copper electrode to zine electrode [the direction of current is opposite to direction of flow of electron] From the salt bridge cations move towards copper electrode. Direction of flow of current A Daniel cell aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. Test Paper Il A.LI.M.S. . Which of the following is a para- magnetic specie? a. KO, «. TiO, b. SiO, d. ZrO, . Which of the following reagent is commonly used to determine hard- ness of water titrimetrically? a, oxalic acid b. disodium salt of EDTA c. tartaric acid d. sodium thiosulphate Which of the following statement is true for the acids of phosphorus IL,PO,, H,PO, and H1,P0,? a. the order of their acidity is HPO, > HyPO;>H,PO, b. all of them are in + 3 oxidation state c. all of them are dibasic acids d. the geomeiry of phosphorusis tet- rahedral in all the three }. Which of the following ion is not tetrahedral in shape? a. BF, b. C1OS ¢. Cu(NHy) — d. NiCIZ . Which of the following complex is used as an anticancer agent? a. mer- [Co(NH3),Ch] b. cis - [P/CI{NH 3)3] c. cis - Ky [PrC1(NH bo] d. Nay [PtCl] . Which of the following is a colour- less specie? aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. Solved Papers of Previous Three Years (AlIMS—Chemistry) @® ASSERTION AND REASON QUESTIONS 4. 42. 43. 44, 45. 46. In the following questions (41-60), a statement of assertion (A) is fol- lowed by a statement of reason (R) — If both Assertion and Reason are true and the reason is the correct explanation of the assertion, then mark a. If both Assertion and Reason are true but the reason is not the cor- rect explanation of the assertion, then mark b. If Assertion is true statement but Reason is false, then mark c. If both Assertion and Reason are false statements, then mark d. A:Taemoglobin is an oxygen carrier R: Oxygen binds as O3 to Fe of hac- moglobin. A:zBenzyl bromide produces benzyl alcohol, when kept in acetone water. R: The reaction follows SN* mecha- nism. A:N(CH,); is a stronger ligand than NF,. R:NF, ionizes to give F ions in aque- ous solution At Activity of an enzyme is pH-de- pendent. R:Change in pH affects the solubility of the enzyme in water. A: Solution of Na,CrO, in water is intensely coloured, R: Oxidation state of Cr in Na,CrO, is+6 A:Hydroxyketones are not directly used in Grignard reaction. R:Grignard reagents react with hy- droxyl group. 47. 48. 49. A: When one mole of water vapou- rizes at | atm and 373 K the increase in internal energy (AE) is zero R: For all isothermal processes AE =0. ‘A: Barium is not required for normal biological function in human. R: Barium shows only +2 oxidation state A: Pbl, isa stable compound. R: Iodide stabilizes higher oxidation state, A: Alkyl benzene is not prepared by Friedel-Crafts alkylation of benzene. R: Acyl halides are more reactive than alkylhalides. . Ar AH and AE are almost same for the following reaction: N,(g) + Ox(g) = 2NO (g) R: All reactants and products are gases. A Me. > i7Na emits a positron to give R: In B* emission neutron is trans- formed into electron A: Cis: exists in boat conformation. 1,3-dihydroxy cyclohexane R: In the chair form, there will not be any hydrogen bonding between the two hydroxyl groups. A: Photochemical smog is produced by nitrogen oxides. R: Vehicular pollution is a major source of nitrogen oxides A: BaCO, is more soluble in HNO; than in water. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. © IK's MCQs—Chemistry 47, 48. 50. Si. 52. When one mole of water vapourizes at 1 atm and 373 K the increase in internal energy (AE) is zero because for all isothermal process internal energy is zero. Itis true that barium isnot required for normal biological function in human beings and it isalso true that jt only shows +2 oxidation state [its electronic configuration is [Xe]6s"] Due to screening effect, as we move down the group, lower oxidation state becomes more stable, So both assertion and reason are false because PbI, is not a stable compound and iodine cannot stabilize higher oxidation states. Pb shows (II) oxi- dation state more frequently than Pb (IV) due to inert pair effect, The alkyl benzene is not prepared by Friedel Craft’s alkylation of benzene because the monoaikyl product formed undergo further alkylation to produce polyalky lated benzene. NXg) + 02g) = 2NO (g) AH = AE+ AnRT Here An=2-2=0 — Hence, AnRT =0 Therefore, AH = AE Na > 7]Mg + :B". So, 77Na emits a B- particle to give 7]Mg. Also, positron (B") emission converts proton into neutron a pl > onl +.B Both assertion and reason are false because cis-1, 3-dihydroxy cyclohexane exist in chair conformation and in chair conformation hydrogen bonding is present. Photochemical smog is formed as a result of photochemical reaction between oxides of nitrogen and hydrocarbons forming aldehydes, ozone and peroxyacylnitrates (PAN). Barium carbonate is more soluble in HNO, than in water because the H* ion of HNO, reacts with carbonate (weak base) causing the barium salt to dissociate. BaCO, + 2HNO, > Ba(NO,), +CO,+H,0 Both assertion and reason are false. O,F, and H,O, have similar structures but the O—O bond length is shorter in O,Fythan in HO due to higher electronegativity of F.H,Q3 is a non-ionic compound When the sodium stearate is pe of it is held by surrounding water. dded to the dirty surface, the non-polar hydrocarbon t dissolves in oil or grease on which dirt is held and the polar carboxylate part |_—+ Polar group |» Dil or grease }—> Non-polar group [Water (Micelle formed by sodium stearate) aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. ® IK's MCQs—Chemistry c. mordant dye d. Both ‘a’ and ‘b’ 34. Enz. a, apoenzyme b. haloenzyme c. allosteric enzyme s with two sites are called d. conjugate enzyme 35, Teflon is a polymer of a, tetrafluorethylene b. tetrachlorothylene c. tetrabromoethylene d. tetraiodoethylene 36. Lucas testis used for the determina- tion of a. alcohols c. aldehydes Which of the following in Sandmayer’s reaction? a, ammonium salt b. alkyl halides d. ketones 37. involved b. Cuproammonium salt 38. 39. 40. c. diazonium salt d. None of the above The intermediate formed in aldol b. carbocation c. carbanion d. none of the above Which of the following compound is most suitable for the preparation of cyanohydrin:- a, GH s—-G.H, b. C.H.COC.H, c. CoHsNH, — d. C;H,COOH In the reaction C,H,CHO + C,H,NH, > C,H,-CH=N-C,H, + H,0, the compound C,H,-CH=N-C,H,_ is known as a. aldol b. c. Schiff's reagent chiff’s base a. Benedict reagent ASSERTION AND REASON QUESTIONS Dircetions (Qs. 41 to 60): These ques- tions consist of two statements cach, printed as Assertion and Reason. While answering these questions you are required to choose any one of the following five responses. a. If both the Assertion and Reason are true and the Reason is a cor- rect explanation of the Assertion b. If both the Assertion and Reason are true but the Reason is not a correct explanation. c. If the Assertion is true but the Reason is fal d. If both the Assertion and Reason are false. 41. a2. e. If the Assertion is false but the Reason is true. A:The halogens absorb visible light. R: All hal AzAtoms can neither be created nor destroyed. gens are coloured R: Under similar condition of tem- perature and pressure, equal volume of gases does not contain equal num- ber of atoms. A: Dinegative anion of oxygen ( is quite common but dinegative anion of sulphur (S”) is less common. Reason: C valency of oxygen is two. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. Solved Papers of Previous Three Years (AlIMS—Chemistry) @ 38. 39, 40. 41. 42. 43. 44, 46. 47. NH, N3cD GE Nano, cua, ; HCL HCI (68-71%). NO, NO, NO, During the condensation of acetaldehyde, first of all a carbanion is formed by abstraction of G-H from aldehyde. Then, this ion reacts with a second molecule of acetaldehyde to produce aldol. Thus carbanion is formed as an intermediate in aldol condensation. Cyanohydrin is prepared most suitably by carbonyl compounds. In the given reaction, aldehyde (C,H ;CHO) reacts with aniline (CJH,NH,) to produce C,H,—CH = N—C,H, (Schiff’s base). The halogens are coloured due to the absorption of vii ible light and the comple- mentary colour is emitted. Hence, both the Assertion and Reason are true and the Reason is a correct explanation of the Assertion. According to Dalton’s atomic theory, atoms can neither be created nor be destroyed. and Berzelius hypothesis is that under similar conditions of temperature and pr Assertion is true but the Reason is false. Because of the high electronegativity of oxygen it is more ionic than sulphur and so the dinegative anion of O7 is quite common but the dinegative anions of S is less common. The covalency of oxygen is two because it cannot expand its valency shell beyond the octet, So, both the Assertion and Reason are true but the Reason is not a correct explanation of the Assertion. In an adiabatic process, there is no change in the heat i.e. no heat enters or leaves the system. The system is completely insulated from its surroundings. According to first law of thermodynamics, change in internal energy (AE) = g- W =0-W= -W. Since the work is done at the expense of internal energy, internal energy of the system decreases and hence, the temperature of the gas falls. So, the Assertion is ue but Reason is false. sure, equal volumes of all gas 's contain equal number of atoms, Hence, the For Balmer series of hydrogen spectrum, the highest wavelength is between n, =2 and n= 3. And for Balmer series of hydrogen spectrum, the value of m, =2 and ny = 3, 4,5. Hence, the Assertion is false but the Reason is true. In amides, strong intermolecular hydrogen bonding is present among their mol- ecules and so their metting points and boiling points are higher than the corre- sponding acides. Hence, both the Assertion and Reason are true and the Reason ig correct explanation of the Assertion. Phenol is a strong acid than ethanol, The groups with +M effect and —I effect decrease the acid ity at p-position. However, at m-position, the acidity is increased due to leffect [As no M-effect in case of m-]. Hence both, Assertion and Reas n are false aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. Solved Papers of Previous Three Years (CBSE-PMT—Chemistry) @ 17. 20. 24. . How many chiral MH - 2.18 x 1078 Jatom™ and h ~ 6.625 x 1074 Js) 0.617 x 10° s b. 1.28 x 100 c. 2.34x 10° 5! d. 3.08 x los! Why camphor is used in molecular mass determination? a. it is volalile b. it is cheap ailable c. it is readily d. it has a very high eryoscopic con- stant carbons are present in B - D - (+) -glucose? a. three b. four c. five d. six . Which of the following bonds stabi- lized the helical structure of pro- tein? a. ether bonds b. ester bonds c. hydrogen bonds d. peptide bonds In a nucleophilic sustitution reac- tion, the least reactive compound is:- a. CH; CH,Cl b. (CH,); CCI c. CH= CHCI d. CH CH CH,CI Why I1,0 is dipolar, whereas BeF, is not? a, H,0 is linear and BeF) is angular b. 11,0 is angular and BeF, is linear c. the electronegativity of Fis greater than that of O d. H,0 involves hydrogen bonding whereas BeP; is a diserete mol- ecule. 22. nv 3. te Pa 26. . The criterion for the spontaneity of any proces in terms of entrop: a. AS, b. AS, © AScystem A Ssurcoundings > © d. ASgysiem +A Ssurroundings > © system > O only surroundings > © only . Ionic radii are a. directly proportional to effective nuclear charge b. inversely proportional to effective nucle arge c. directly proprtional to souare of effective nuclear charge d. inversely proportional to square of effective nuclear charge . CN7is a strong field ligand because a, it carries negative charge b. it is a pseudohalide c. it forms high spin complexes with metal species d. itcan accept electrons from metal species . If H,O behaves as a weak field ligand then how many no. of un- paired electrons are present in [Mn (H,0),?* (At. no. of Mn = 25)? a, two b. d. five three ©. four The OH group of an alcohol or the - COOH group of a carboxylic acid can be replaced by - Cl using a. chlorine b. hydrochloric acid id d. phosphorus pentach loride ¢. hypochlorous . HBron reaction with propene in the presence of peroxide gives: - a. allyl bromide b. n- propyl bromide aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. ® IK's MCQs—Chemistry 12. 13. 19, For a first order reaction, half life is: 0.693 k 46.2 min Rape linkage le CN linkage H H H H Phot d td For exam ple, -"N-C-C-N-C-C-N-C-C- Phothk otd ° oO oO |. Primary aleohol on oxidation gives aldehyde whereas secondary aleohol on oxi- dation gives ketone. OH cu, d-cH, a Propanone . For hydrogen atom. 218x107? =-—,—_ J atom n Energy emitted when the electron falls from n = 4 to n =2 is:- AE =E,-E; =~ 218 x 10°” (. = 4.09 x 105 AE Frequency = 5= [+ AE=hvl -19 4.09 x 10 9 = _, = 0.617 x 10° * ¥ = 0.617 x 10" 6.625 x 10 CH,OH H O. OH H on I OH H H OH (B-D+(+)Glucose) Hence five chiral carbons are present in B— D ~ (+) glucose. The helical structure of protein is stabilized by hydrogen bonding. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. @® IK's MCQs—Chemistry c¢, [CoCl(NH,); (H,0),|C1, d. [Co(NH,),(H,0),ICl, 6. Which of the following statement is true? a. Bond energy of Fyis less than Cl, b. Silicon exhibits 4 co-ordination number in its compound c. Mn(II[) oxidation state is more stable than Mn(II) in aqueous state d, Elements of 15th group shows only +3 and +5 oxidation state 7. Which of the following order is wrong? a, Li + (rhonot (alesaidehyde) Major) CHO (pydimeybenzatichyte) ‘Minor It is a rosenmund reduction. Aldehyde is obtained by this method and further reduction to alcohol is prevented as barium sulphate poisons the palladium cata- lyst. R—C—Cl tame” R—CHO+HCI PayBas0, Oo Oxidation of n-propylalcohol and isopropyl alcohol with potassium dichromate gives different products. lo} CH,—CH,—CH,0H Seb cH,—CH,—CHO n-Propyl alcohol . CH,—CH—CH, > CH. Hs | OH o isopropylalcohol It is a dehydrohologenation reaction of gem-dihalides. NaNH, CH,—CH,—CHC1, 2“ CH,—C = CH +2 NaCl +2NHy CH,—CH,—cl “+ CH,—cH,—CN—““* CH,—CH,—CH,—NH, (A) (B) | Acetic anhydride 2 CHE CH CH=CH, 9 1 I These are resonating structures, aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. @ IK's MCQs—Chemistry 10. 1. 13. 14. 15. b. 2x 107 d. 8x 107 a 1x 107 4x 107 . Which of the following molecule have largest dipole moment? a. CHy b. CC c. CHC, d. CHI, . Which of the following compound will produce when calcium acetate is distilled? a, CH,CHO ec, CH COOH >. CH,COCH, d, all of these . The electronic configuration of noble gas a. nscnp? b. ns*np* 29S 256 ce. nsnp a. nstnp' Which of the following formula will represent sodium pyrophosphate? a, Na,P,04 b. NasP,05 c. Na,P,05 d. Na,P,0; Which one of the following com- pounds can produce hydrogen when treated with metallic sodium? a CH.NH, b. CoH NH, OH ),NH d. CH,CONH, PCI, on hydrolysis gives: a. PH, b. POCI; c. HPO; d. H;PO, The co-ordination number of body centred cube a4 b. 6 co 8 d. 12 Which of the following gas evolved when magnesium is treated with very dilute solution of HNO,? a. Hy b. No ¢. H,0 d. NO, Aromatic properties are shown by the following amino ac 16. 18. 19. 20. 21. 22, b. Serine d. Valine a, Leucine c. Tyrosine Which of the following pairs is a Buffer’s solution? a. NaCl + NaOH b. H,SO, + CuSO, c. CH,COONa + CH,COOH @. CH,COONH,+CH,COOH PCI, reacts with cold water to pro- duce:- a. H5PO, b. HPO, . HsPO, d. HyP,O,; Carbonyl compounds can be con- verted into hydrocarbons by: a. Hof Pt b. LiAIH, ec. Zn-Hg/ HCI a. K,Cr,0,/ H,SO, Which of the following compounds is produced when calcium acetate is heated? a. Diethyl ether b. Acetaldehyde c. Aceton d. Ethylacetate No. of neutrons present in tritium nucleus are:- a0 b. 1 2 a3 Ilow many protons are present in 10g of calcium carbonate (Ny = 6.023 x 107)? a. 2.01 x 10% e. 4.06 x 10% b. 3.01 x 10" d. 6.08 x 10% When 5 g substance is dissolved in 30 g of water, the decrease in freez~ ing point is 1.2°C. If molal depres- sion is 1.85°C, the molecular weight of substance will be: a. 15.42 b. 154.2 c. 1542 d. None of these aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. Solved Papers of Previous Three Years (CPT, UP—Chamistry) @® 44. 46. 47. 49. 50. Soaps can he classified as salts of fatty acids. Soaps are formed by the alkaline hydrolysis (NaOH) of oils or fats which produce sodium salt of fatty acids (soaps) and glycerol . In presence of UV light, chlorine molecule is cleaved homolytically to give two chlorine radicals ch 5 cr +r These free radicals interact with methane molecules generating CH} Free radical so chain reaction goes on, 56 Number of moles of Ny = 22 = 2 er of moles of No = 32 44 N ber of I FCO, = =1 umber of moles o . : 16 Number of moles of CH, = 16 =1 Total number of moles =2+1+41=4 Mole fraction of CH, = 4 4 Partial pressure of CH, = mole fraction of CH, x total pressure = i x 720 = 180 atm Cu can be recovered by Fe metal from a solution of CuSO,, because Fe is more reactive than Cu hence it replaces Cu easily. Electronegativity decreases down the group. Gravity separation process is used for the concentration of haematite, which is an oxide of iron, Fe;0, aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. Solved Papers of Previous Three Years (CPT, UP—Chamistry) @® ld 2a 3.b 4.d Sic od 8a 9d 10. d ll. b 12. b 13. ¢ ld. c 16. b 17, a 18. b 19. ¢ 20, d 21. a 22. ¢ 24, ¢ 25. d 26. a 27. d 28. b 29. d 30. a 32. d 33. b 34. d 35. b 36. b SF. & 38. d 40. b 41. hb 42. 4 43. a 44. b 45. bh 46. d 48. d 40. a 50. ¢ EXPLANATIONS FOR TEST PAPER II 1, Half-life of the element tye N years. 2303 a of atoms of the element remaining after time (t). 0 - N The time-period of decay of a substance (t) = logiy yr (where N is the no. When element undergoes complete decay, then N = 0. N 208 login nN = e (infinity). 3. Principal quantum number (7)=/+ 1 Therefore, 1 = Azimuthal quantum number (/) = 2. n=2+1=3 4, Binding energy of hydrogen atom (Ey) = 13.6eV. The number of electrons in helium (He = By, X(2) = 13.6x4 So, binding energy of a singly ionized helium atom (Ey..+ = 54.4 eV. 7. Volume of solution of hydrogen peroxide (H_0,) at STP = 10 em> and volume of oxygen (O,) on decomposition of hydrogen peroxide at STP = 150 cm’, Strength of HO, is expressed in terms of the volume of Q, liberated by decompo- sition of | em* of HO; Since 10 cm? H,O,, on decomposition, gives 150 cm? of 04, lem} of 11,0, will give ton = 1Sem} of O4. So, the volume strength of H,O, is 15 em*. 8 Initial volume (V,) = 300 ce; Initial temperature (T,) = 27°C = 300 K: Initial pressure (P,) =620 mm; Final tem perature (T,) = 47°C = 320 K; Final pressure (P,) =640 mm. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. Solved Papers of Previous Three Years (CPT, UP—Chamistry) ® 46. 47. 48. 49. a. 26,78 b. 30.52 ce. 32.43 d. None of these If the ratio of co-ordination no. A to that of B be X; Y, then the formula of the solid is a. A,B, oy Age By b. A,B, d. A,2B,2 The compound A on reaction with excess of methyl magnesium iodide followed by acidification gives t-bu- tanol. What is compound A? a, methanol b. ethanol e. propanol d. methyl ethanoate 0.1 mole of the chloride of an ele- ment A requires 200 ml of LM aque- ilver nitrate for complete pre- cipitation of the chloride ion. Ele- ment M is: a. sulphur ous b. aluminium c. silicon d. phosphorus A G.M. counter is used to study the radioactive process. In the absence c 2c 3b 4.d . a 1d, b ll. b 12. d b 18. a 19, ¢ 20. a a 26. a 27. ¢ 28. ¢ a 34,4 35. d 36. ¢ « 42. a 43. d 44. b . dd 50. a 13. 21. 29. 45. of radioactive substance A, it counts 3 disintegration per second (dps) while in the presence of A, at the start, it records 23 dps; and after 10 minutes 13 dps. The half life of A, and dps count after 20 minute will be respectively = a. Sdps, 5 min. b. Sdps, 10 min. c. 5dps, 20 min d. 8 dps, 10 min }. In a 20 litres flask, 2 mol of N, and 3 mol of H, gas are allowed to react at 400 K and after complete conyer- sion of H, into NH, 10 litres of H,O was added and temperature is re- duced to 300 K. What will be the pressure of the gas after the reac- tion? 300R 300R “10 a) 3x300R 3x300R “10 20 d 6. d Tek 8a d I4. ¢ 15. a 16. d d 22 ¢ 23. b 24. b b 30. b 3L b 32. d b 38. b 39. a 40. d © 46. b 47. dé 48. a aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. aa You have either reached a page that is unavailable for viewing or reached your viewing limit for this book. Solved Papers of Previous Three Years (CPT, UP—Chemistry] @ 47. Tertiary alcohols can be obtained from reaction of Grignard reagent with either ketones or esters. In the options, only ester (no ketone) is methyl ethanoate. 6 OCH, ‘ CH,—C—OCH, + CH,M,1—+ | CH,—C—6 Mg I —+ CH,—C—CH, + Mg (0. GH) Senge, Rae —_ CH, i ve a CHy—C—CH, + CHyMg1—» CH;—C—O Mg 42° cHy ‘ OH +Mg (OHI | cH, CH, (ter-butanol) 48. 1000 ml of AgNO, contains—1 mole of AgNO, 200 ml of AgNO, contains 0.2 moles of AgNO}. 0.1 mole of A requires 0.2 moles of AgNO, i.e. | :2 ratio ie. A is the divalent element hence it is sulphur. 49. In the absence of A,G.M counter counts 3dps and so 3 dps is an error. Initial = 20 dps [(23-3) dps} After 10 minutes = 10 dps [(13 - 3) dps] As fall is 50% in 10 minutes and so its half life is 10 minutes After 20 minutes = 5 dps but recorded reading will be 5+ 3=8 dps 50. Reaction is:- N.+ 3H, > 2NH; Initial = 2mol 3 mol = Final Imol - 2mol Since NH, is dissolved in water and so only gas left behind is 1 mol of Ny and so pressure is due to this Ny gas only. Volume of the flask is 20 litres but as 10 litres of water is added to it so volume of the flask available for the N, gas = 10 litres. 300R AsP=" rt, « P=! yrx3002 Vv 10 10

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