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INTERMEDIATE PUBLIC EXAMINATION Jr. INTER CHEMISTRY MODEL PAPER (ENGLISH VERSION)
TIME: 3 HOURS SECTION - A Note: 1. Answer ALL questions. 2. Each question carries TWO marks. 3. All are Very short answer type questions. 10 2 = 20 MAX. MARKS: 60

1. Give the ratio of RMS, average and most probable speeds of gas molecules. 2. How many number of moles of glucose are present in 540 grams of glucose? 3. The pKa of acetic acid and pKb of ammonium hydroxide are 4.76 and 4.75 respectively. Calculate the pH of ammonium hydroxide solution. 4. Give two uses of Plaster of paris.

5. What is the oxidation state of K in KO2? 6. SiO2 is solid while CO2 is gas. Explain. 7. How is synthesis gas is prepared?

8. What is Ozone hole? Where was it first observed? 9. What is PAN? What effect is caused by it? 10. Write IUPAC names of the following a) b)
II
O

Note: 1. Answer any SIX questions.

t e n . a h b i t a r p u d a n e e . w w w
SECTION - B 2. Each question carries FOUR marks. 3. All are Short answer type questions. 6 4 = 24 b) State third law of thermodynamics.

11. State and explain Graham's Law of diffusion. 12. Balance the following equation by ion electron method -2 OH- - Cr(OH)3 + IO3 I + CrO4 13. a) What is 'entropy'?

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14. What is 'homogeneous equilibrium' and 'heterogeneous equilibrium'? Give one example each. 15. Discuss the principle and the method of softening of hard water by synthetic, ion exchange resins. 16. Explain two methods of preparation of diborane. How does it reacts with a) CO b) NH3? 17. What are 'conformational isomers'? Explain conformational isomers of ethane. 18. CH2 = CH2 alc.KOH Br2 Br2 A B C CCl4

Give the equations and names of A, B, C.

Note: 1. Answer any TWO questions.

19. (a) Explain de Broglie's hypothesis and how it justifies Bohr's atomic theory.

(b) What will be the de Broglie wavelength of a ball of mass 0.1 kg moving with a velocity of 10 m/s? (h = 6.626 10-34 JS) 20. a) Explain hybridization of PCl5 and SF6.

21. Write an essay on the classification of elements into s, p, d and f blocks in the periodic table.

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SECTION - C 2. Each question carries EIGHT marks. 3. All are Long answer type questions. 2 8 = 16

b) Draw the molecular orbital diagram of O2 molecule. Calculate its bond order of O2. What type of magnetism is shown by O2?

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REG - MP - 13

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