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1. (p. 87) How many grams of sodium fluoride (used in water fluoridation and manufacture of insecticides) are needed to form 485 g of sulfur tetrafluoride? 3SCl2(l) + 4NaF(s) SF4(g) + S2Cl2(l) + 4NaCl(s) a. 1940 g b. 1510 g c. 205 g d. 51.3 g E. 754 g
2. (p. 77) A compound containing chromium and silicon contains 73.52 mass percent chromium. Determine its empirical formula. a. Cr3Si b. CrSi3 c. Cr2S d. Cr2Si3 E. Cr3Si2
3. (p. 119) Select the net ionic equation for the reaction between lithium hydroxide and hydrobromic acid. LiOH(aq) + HBr(aq) H2O(l) + LiBr(aq) a. LiOH(aq) Li+(aq) + OH-(aq) b. Li+(aq) + Br-(aq) LiBr(aq) C. H+(aq) + OH-(aq) H2O(l) d. Li+(aq) + OH-(aq) + H+(aq) + Br-(aq) H2O(l) + LiBr(aq) e. HBr(aq) H+(aq) + Br-(aq)
4. (p. 125) Calculate the oxidation number of the chlorine in perchloric acid, HClO4, a strong oxidizing agent. a. +4 b. None of these is the correct oxidation number. c. +5 d. -1 E. +7
5. (p. 112) Which of the following is most soluble in water? a. hexane, C6H14 b. ethane, C2H4 C. potassium nitrate, KNO3 d. carbon tetrachloride, CCl4 e. benzene, C6H6
6. (p. 82) Balance the following equation: Ca3(PO4)2(s) + SiO2(s) + C(s) CaSiO3(s) + CO(g) + P4(s) a. 2Ca3(PO4)2(s) + 6SiO2(s) + 10C(s) 6CaSiO3(s) + 10CO(g) + 4P4(s) B. 2Ca3(PO4)2(s) + 6SiO2(s) + 10C(s) 6CaSiO3(s) + 10CO(g) + P4(s) c. Ca3(PO4)2(s) + 3SiO2(s) + 8C(s) 3CaSiO3(s) + 8CO(g) + P4(s) d. Ca3(PO4)2(s) + 3SiO2(s) + 14C(s) 3CaSiO3(s) + 14CO(g) + P4(s) e. Ca3(PO4)2(s) + 3SiO2(s) + 8C(s) 3CaSiO3(s) + 8CO(g) + 2P4(s)
7. (p. 116) Select the precipitate that forms when aqueous ammonium sulfide reacts with aqueous copper(II) nitrate. a. NH4NO3 b. NH4(NO3)2 C. CuS d. CuSO4 e. Cu2S
8. (p. 111) How many sodium ions are present in 325 mL of 0.850 M Na2SO4? a. 1.57 1024 Na ions b. 1.66 1023 Na ions c. 4.99 1023 Na ions d. 6.20 1023 Na ions E. 3.33 1023 Na ions
9. (p. 120) A 0.00100 mol sample of Ca(OH)2 requires 25.00 mL of aqueous HCl for neutralization according to the reaction below. What is the concentration of the HCl? Equation: Ca(OH)2(s) + 2HCl(aq) CaCl2(aq) + H2O(l) a. None of these choices is correct. b. 4.00 10-5 M c. 0.0200 M d. 0.0400 M E. 0.0800 M
10. (p. 94) Tetraphosphorus hexaoxide ( with oxygen gas. P4(s) + 3O2(g) P4O6(s)
If a mixture of 75.3 g of phosphorus and 38.7 g of oxygen produce 43.3 g of P4O6, what is the percent yield for the reaction? a. 38.0% b. 16.3% C. 48.8% d. 57.5% e. 32.4%
11. (p. 125) Which one of the following is a redox reaction? a. Na2CO3(s) + 2HCl(aq) 2NaCl(aq) + CO2(g) + H2O(l) b. Ba2+(aq) + SO42-(aq) BaSO4(s) c. H2O(l) H+(aq) + OH-(aq) D. 2Na(g) + Cl2(g) 2NaCl(s) e. K2Cr2O7(aq) + 2KOH(aq) 2K2CrO4(aq) + H2O(l)
12. (p. 114) In the following reaction, what ions, if any, are spectator ions? Pb(NO3)2(aq) + 2NaCl(aq) PbCl2(s) + 2NaNO3(aq) A. Na+(aq), NO3-(aq) b. Pb2+(aq), NO3-(aq) c. There are no spectator ions d. Pb2+(aq), Cl-(aq) e. Na+(aq), Cl-(aq)
13. (p. 120) Automobile batteries use 3.0 M H2SO4 as an electrolyte. How much 1.20 M NaOH will be needed to neutralize 225 mL of battery acid? H2SO4(aq) + 2NaOH(aq) 2H2O(l) + Na2SO4(aq) a. 0.28 L b. 0.90 L c. 0.56 L D. 1.1 L e. 0.045 L
14. (p. 77) Hydroxylamine hydrochloride is a powerful reducing agent which is used as a polymerization catalyst. It contains 5.80 mass % H, 20.16 mass % N, 23.02 mass % O, and 51.02 mass % Cl. What is its empirical formula? a. H4NOCl2 B. H4NOCl c. H2N7O8Cl18 d. HN3O4Cl9 e. H2N2O2Cl
15. (p. 125) Identify the oxidizing agent in the following redox reaction. Hg2+(aq) + Cu(s) Cu2+(aq) + Hg(l) A. Hg2+(aq) b. Cu(s) c. Hg2+(aq) and Cu2+(aq) d. Hg(l) e. Cu2+(aq)
16. (p. 116) Select the precipitate that forms when the following reactants are mixed. Na2CO3(aq) + BaCl2(aq) A. BaCO3 b. NaCl2 c. Ba2CO3 d. NaCl e. BaO
17. (p. 111) How many moles of ions are released when 0.27 mol of cobalt(II) chloride, CoCl2, is dissolved in water? a. 0.27 mol b. 0.090 mol c. 0.54 mol d. 0.18 mol E. 0.81 mol
18. (p. 116) Select the correct name and chemical formula for the precipitate that forms when the following reactants are mixed. CuCl2(aq) + Na2CO3(aq) a. copper(I) carbonate, Cu2CO3 b. copper(II) carbonate, Cu2CO3 c. copper(I) carbonate, CuCO3 D. copper(II) carbonate, CuCO3 e. sodium chloride, NaCl
19. (p. 111) How many moles of H+(aq) ions are present in 750 mL of 0.65 M hydrochloric acid? a. 0.98 mol b. 1.2 mol C. 0.49 mol d. 0.87 mol e. 0.65 mol
20. (p. 111) Potassium carbonate, K2CO3, sodium iodide, NaI, magnesium oxide, MgO, methanol, CH3OH, and ammonium chloride, NH4Cl, are soluble in water. Which produces the largest number of dissolved particles per mole of dissolved solute? a. NH4Cl b. MgO c. NaI D. K2CO3 e. CH3OH