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92%
2%
2%
1%
2%
1%
100%
Pressure
Temperature
Basis
Desired Production Rate
4743
1500
psig
F
kgmol/hr Mixed
Tonnes/day
Stream Factor
Operating hours
345
8280
days
hours
Naphtha
4743
Total
100
8.06
C
H
46 53.9
1.17
hours
552 108
5.44 665
6.649
Pre Reformer
Naphtha
Temperature
Pressure
Pressure Drop
HC to Steam Ratio
Reaction 1
Reaction 2
Reaction 3
Selectivity
4743
763 K
psig
psig
3.5
Components
Carbon
Hydrogen(H2)
Hydrogen gas
Carbon monoxide
Carbon dioxide
Methane
Steam
Total
Steam Consumed
Steam un reacted
CO produced
Mol. Wt
12
2
2
28
44
16
18
2193.57
6713.29
2180.831
4888.1358 31584.586
47.43
Co consumed
CO 2 produced.
Ch4 Produced
Components
Methane
Ethane
Propane
Butane
Nitrogen
Carbon dioxide
Carbon monoxide
Hydrogen
Oxygen
Steam
Naphtha
1286.691
894.1409
12.73951
1273.951
0.00
Pre- Ref
Components
Methane
Ethane
Propane
Butane
Nitrogen
Mol. Wt
16
30
44
58
28
Mol%
0.00%
0.00%
0.00%
0.00%
0.00%
Mol%
Mole Flow accomodat
(kgmol/hr)
ed
0.00
0.00%
0.00
0.00%
0.00
0.00%
0.00
0.00%
0.00%
Carbon dioxide
Carbon monoxide
Hydrogen
Oxygen
Steam
Naphtha
44
28
2
32
18
659.46
KJ/Kmol
Del H specific
-37716.9
Del H
-3E+08
Heat of Formation Summation
Heat Supply required
0.00%
0.00%
3.13%
0.00%
0.00%
0.00%
0.00
153.20
0.00
7632.91
47.43
7833.54
0.00%
0.00%
1.96%
0.00%
97.44%
0.61%
100.00%
Gjoules/hr
-295.457
-1933.06
0.024047
rxn heat
1
Pre reformer
2
Stream 2 (Steam)
Mole
Mass
Flow
Flow
Mol% (mol/hr) (kg/hr)
100
100
7632.91 1E+05
7632.91 1E+05
& Cp coefficients
D
API Gravity 74.7682
Sp. Gravity
0.686
Heating value17924.2 BTU/Lb
41602 J/kg
27434.8 kj/mol
n
m
45.98
53.85
M.wat
659.46
Heat of Formation
-1840303.279
-0
0
-0
0
-0
0
-0
0
0
4000
0 -115700
0
-3100
0
8300
0 -22700
0 12100
Pre- Reformer Inlet
T
initial
1036
1036
1036
1036
1036
T final
298.00
298.00
298.00
298.00
298.00
Tau
0.288
0.288
0.288
0.288
0.288
Cp
55.6878
93.3467
133.742
174.321
30.5673
<Cp>
0
0
0
0
0
H0f
0.00
0.00
0.00
0.00
0.00
1036
1036
1036
1036
1036
1405
763
763
110.9
298.00
298.00
298.00
298.00
298.00
77.00
1405.4
0.288
0.288
0.288
0.288
0.288
-
50.9067
0
31.15
0
29.3709 0.5744
33.0101
0
36.9174 35.9719
2404.84 14.5607
51.107
0.00
0.00
0.00
0.00
-235624.67
-11142.55
-246767.22
Pre-Reformer Outlet
Mol%
0.00%
0.00%
0.00%
0.00%
0.00%
Mole
Flow
Mol%
(kgmol/hr accomod
T
)
ated
initial
1273.95 12.77% 298
0.00
0.00%
298
0.00
0.00%
298
0.00
0.00%
298
0.00
0.00%
298
T final
783.00
783.00
783.00
783.00
783.00
Tau
2.628
2.628
2.628
2.628
2.628
Cp <Cp>
49.35 6.304
81.38
0
116.6
0
152.4
0
30.92
0
0.00%
0.00%
100.00%
0.00%
100.00%
200.00%
12.74
894.14
1079.02
6713.29
0.13%
8.97%
10.82%
0.00%
67.31%
298
298
298
298
298
783.00
783.00
783.00
783.00
783.00
2.628
2.628
2.628
2.628
2.628
21.6
29.81
30.95
26.94
38.34
9973.14 100.00%
KJ/Kmol Gjoules/hr
Del H specific
18508.49
Del H
1.85E+08 184.588
Heat of Formation Summation
-1822.17
0.028
2.672
3.349
0
25.81
38.16
510.00 Temp C
H0f
-9519.05
0.00
0.00
0.00
0.00
Mol%
0.00%
0.00%
0.00%
0.00%
0.00%
-502.66
-9909.10
0.00
0.00
-162776.59
0.00%
0.00%
0.00%
0.00%
0.00%
-182707.41 0.00%
12.74
0.13%
894.14
8.97%
1079.02 10.82%
0.00
0.00%
6713.29 67.31%
0.00
9973.14 100.00%
KJ/Kmol Gjoules/hr
Del H specific
7864.26
lue Gas Convection section
Del H
7.8E+07 78.4313
783
783
783
783
783
973.00
973.00
973.00
973.00
973.00
1.243
1.243
1.243
1.243
1.243
Cp <Cp>
66.52 8.497
114
0
163.4
0
212.2
0
31.67
0
H0f
-9519.05
0.00
0.00
0.00
0.00
51.05
32.08
30.23
33.57
39.64
0.065
2.876
3.271
0
26.68
41.39
-502.66
-9909.10
0.00
0.00
-162776.59
0.00
-182707.41
N.Gas
0%
Naphtha
100.0%
Temperature
Pressure
Pressure Drop
HC to Steam Ratio
N.Gas Flow rate
Steam
Reaction 1
Reaction 2
Reaction 3
Reaction 4
Reaction 5
750
575
10
3
4
75%
100%
100%
100%
40%
Total
165214.7057 kg/hr
Components
Methane
Ethane
Propane
Butane
Nitrogen
Carbon dioxide
Carbon monoxide
Hydrogen
Oxygen
Steam
Argon
CO Production
Reaction 1
Reaction 2
Reaction 3
Reaction 4
Total
CO Consume
Mol. Wt
16
30
44
58
28
44
28
2
32
18
40
Del H Rxn
955.46
0
0
0
1849.60
kgmol/hr
kgmol/hr
kgmol/hr
kgmol/hr
1.96647E+11
0
0
0
Reaction 5
739.841654 kgmol/hr
CO2 Produced
Reaction 5
739.841654 kgmol/hr
H2 Produced
Reaction 1
Reaction 2
Reaction 3
Reaction 4
Reaction 5
Total
2866.38979
0
0
0
739.841654
4685.25
-30456321543
kgmol/hr
kgmol/hr
kgmol/hr
kgmol/hr
kgmol/hr
kgmol/hr
Steam consumption
Reaction 1
955.463262 kgmol/hr
Reaction 2
0 kgmol/hr
Reaction 3
0 kgmol/hr
Reaction 4
0 kgmol/hr
Reaction 5
739.841654 kgmol/hr
Total
1695.30492 kgmol/hr
1.6619E+11
166.1904388
6504.28
H20
1849.60
a
4654.67
b
-0.3
CO conc eqlib
-8498.41
17412.14
-29020.236
Keq
Conv.
CO2
H2
12.73951016
c
6026509.804
CO conc. Eq
0.7
37.43%
3945.41
-415.3315507
692.2192511
Heat of Formations & Cp coefficients
Components
Methane
Ethane
Propane
Butane
Nitrogen
Carbon dioxide
Carbon monoxide
Mol. Wt
16
30
44
58
28
44
28
Heat of
Formations
-74520
-83820
-104680
-125790
0
-393509
-110525
A
1.702
1.131
1.213
1.935
3.28
5.457
3.376
B
0.009081
0.019225
0.028785
0.036915
0.000593
0.001045
0.000557
Hydrogen
Oxygen
Steam
2
32
18
0
0
-241818
3.249
3.639
3.47
0.000422
0.000506
0.00145
Primary Reforme
Components
Mol. Wt
Methane
Ethane
Propane
Butane
Nitrogen
Carbon dioxide
Carbon monoxide
Hydrogen
Oxygen
Steam
16
30
44
58
28
44
28
2
32
18
Mol%
12.77%
0.00%
0.00%
0.00%
0.00%
0.13%
8.97%
10.82%
0.00%
67.31%
100.00%
Mol%
accomodate
Mole Flow (kgmol/hr)
d
1273.95
13.05%
0.00
0.00%
0.00
0.00%
0.00
0.00%
0.00
0.00%
12.74
0.13%
894.14
9.16%
1079.02
11.05%
0.00
0.00%
6504.28
66.61%
9764.13
KJ/Kmol
Gjoules/hr
-25346.966
Del H
-247491055 -247.491055
Heat of Formation Summation
-1771.6238
Heat Supply required
245.3708166
3.926253962 Gjoules per ton Ammonia
Del H specific
Compressor Section
Pin
14.7
Gamma
r-1/r
Del H specific
Del H
Pout
298
589.7
1.43
0.3006993
Oxygen
Nitrogen
T in
M.Wt
32
28
Tin
904
Mol %
21.00%
79.00%
Tf
Del H required
1023.00
510.74
1921.37
2432.11
mol%
21.00%
79.00%
KJ/Kmol
Gjoules/hr
3854.43525
9374411.56 9.374411561
Mol. Wt
Components
Methane
Ethane
Propane
Butane
Nitrogen
Carbon dioxide
Carbon monoxide
Hydrogen
Oxygen
Steam
Mol. Wt
16
30
44
58
28
44
28
2
32
18
Heat of
Formations
-74520
-83820
-104680
-125790
0
-393509
-110525
0
0
-241818
B
0.009081
0.019225
0.028785
0.036915
0.000593
0.001045
0.000557
0.000422
0.000506
0.00145
1.702
1.131
1.213
1.935
3.28
5.457
3.376
3.249
3.639
3.47
Secondary Reform
Components
Methane
Ethane
Propane
Butane
Nitrogen
Carbon dioxide
Carbon monoxide
Hydrogen
Oxygen
Steam
Mol. Wt
16
30
44
58
28
44
28
2
32
18
KJ/Kmol
Del H specific
-23503.703
Del H
-324983283
Heat of Formation Summation
Heat Requirement
Mol%
2.73%
0.00%
0.00%
0.00%
0.00%
6.45%
9.51%
40.13%
0.00%
41.19%
100.00%
Gjoules/hr
-324.983283
-1584.54769
15.24551817
Mol%
accomodate
Mole Flow (kgmol/hr)
d
38.22
0.28%
0.00
0.00%
0.00
0.00%
0.00
0.00%
1921.37
13.90%
752.58
5.44%
1109.76
8.03%
4685.25
33.89%
510.74
0.00%
4808.97
34.78%
13826.90
reax
60%
408.951361
8015
0.03355079
12189.0233
195.0403136
Naphtha
Heating value Of Fuel
Fuel required
10556
44187.416
0.044187416
9254.928168
9.254928168
0.148090954
kcal/kg
Kj/kg
Gj/kg
kg/hr
Tons/hr
Tons/Ton Ammonia
Secondary Reformer
C
psig
psig
1200.80 C
565 psig
10 psig
Exit Temperature
Pressure
Pressure Drop
6
Primary Reformer
7
based CH4
based C2H6
based C3H8
based C4H10
based on CO
Mol%
100
100
Secondary
Reformer
Air
205813
3464061
498559
650962
-41166
Stream 5 (Steam)
Mole Flow
Mass Flow
(mol/hr)
(kg/hr)
-209.014336 -3762.25805
-209.014336 -3762.25805
Reaction 1
Reaction 2
Reaction 3
Reaction 4
Mol%
2.73
0.00
0.00
0.00
0.00
6.45
9.51
40.13
41.19
Stream 6
Mole Flow
(kgmol/hr)
318.49
0.00
0.00
0.00
0.00
752.58
1109.76
4685.25
4808.97
Mass Flow
(kg/hr)
5095.80
0.00
0.00
0.00
0.00
33113.57
31073.35
9370.51
86561.47356
100
11675.05586
165214.7057
CO Production
Reaction 1
216.57 kgmol/hr
CO Consumption
Reaction 4
511.13 kgmol/hr
CO2 Production
Reaction 2
63.70
Reaction 4
511.13
H2 production
Reaction 1
649.72
H2 Consumed
Reaction4
255.57
Steam Consumption
1800
1192
1474 Reaction 1
216.57
982.2222222 644.4444444 801.1111111
Steam Production
Reaction 4
255.57
Reaction 2
127.40
O2 Consumption
GJ
Reaction 2
127.40
Reaction 4
383.35
s & Cp coefficients
C
-0.000002164
-0.000005561
-0.000008824
-0.000011402
0
0
0
D
0
0
0
0
4000
-115700
-3100
kgmol/hr
kgmol/hr
kgmol/hr
kgmol/hr
kgmol/hr
0
0
0
8300
-22700
12100
T initial
973
973
973
973
973
973
973
973
973
973
T final
298.00
298.00
298.00
298.00
298.00
298.00
298.00
298.00
298.00
298.00
Tau
0.30626927
0.30626927
0.30626927
0.30626927
0.30626927
0.30626927
0.30626927
0.30626927
0.30626927
0.30626927
Cp
54.18115362
90.55173505
129.7579981
169.2460049
30.41382177
50.57961785
31.00266192
29.26416652
32.86706685
36.54326732
<Cp>
7.069154181
0
0
0
0
0.065992526
2.839039333
3.233948066
0
24.34292669
37.55106079
H0f
-9722.82
0.00
0.00
0.00
0.00
-513.42
-10121.22
0.00
0.00
-161084.61
-181442.07
Tout
904 K
631 0C
H required
Tin
904
904
s & Cp coefficients
T required
1023.00
1023.00
Tau
Cp
1.131212078 34.04764749 7.150005973
1.131212078 32.0670063 25.33293498
Cp
32.48294095
0.00
0.00
C
-0.000002164
-0.000005561
-0.000008824
-0.000011402
0
0
0
0
0
0
D
0
0
0
0
4000
-115700
-3100
8300
-22700
12100
T initial
1023.00
1023.00
1023
1023
1023
1023
1023
1023
1023
1023
T final
298.00
298.00
298.00
298.00
298.00
298.00
298.00
298.00
298.00
298.00
-233.8797714 Gj/hr
at Provided by Radiation
TonAmmonia
Tau
0.291300098
0.291300098
0.291300098
0.291300098
0.291300098
0.291300098
0.291300098
0.291300098
0.291300098
0.291300098
Cp
55.38076461
92.77996548
132.9360584
173.2944119
30.53557519
50.84025585
31.11959813
29.34876333
32.98076072
36.84010737
<Cp>
0.153076388
0
0
0
4.243182714
2.76717323
2.497694363
9.944849017
0
12.81292543
32.41890114
H0f
-205.98
0.00
0.00
0.00
0.00
-21418.22
-8870.86
0.00
0.00
-84103.88
-114598.94
ns/Ton Ammonia
Ammonia Production
62.49489181 TPH
39.62414966
econdary Reformer
2O = CO + 3H2
2 = CO2 + 2H2O
O2 = 2CO2
+H2= 2CO2 + H2O
Mol%
79
21
0
100
Stream 7 (Air)
Mole Flow
(kgmol/hr)
1921.37
510.74
0
2432.11
Mass Flow
(kg/hr)
53798.27914
16343.78
-
Mol%
0.27
13.57
9.38
5.76
35.88
0.00
35.14
Stream 8
Mole Flow
(kgmol/hr)
38.22
1921.37
1327.41
815.20
5079.40
0.00
4975.36
70142.06
100
14156.96
235356.77 kg/hr
235356.77 kg/hr
N2:H2 Ratio
3.0000379
2.4385
3
0.999987356
2.438469167
2.4577876 For mix feed
2.462481 For 100% n.gas
2.4385 For 100% naphtha
Mol%
2.73%
0.00%
0.00%
0.00%
0.00%
6.45%
9.51%
40.13%
0.00%
41.19%
100.00%
Mole Flow
(kgmol/hr)
38.22
0.00
0.00
0.00
0.00
752.58
1109.76
4685.25
4808.97
11394.79
KJ/Kmol
25286.27402
Del H
288131697.2
Heat of Formation Summation
Mol%
accomodated
2.73%
0.00%
0.00%
0.00%
0.00%
6.45%
9.51%
40.13%
0.00%
41.19%
Gjoules/hr
Del H specific
288.1316972
-1566.893622
T initial
298
298
298
298
298
298
298
298
298
298
T final
1023.00
1023.00
1023.00
1023.00
1023.00
1023.00
1023.00
1023.00
1023.00
1023.00
Mol%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
Mole Flow
(kgmol/hr)
38.22
0.00
0.00
0.00
1921.37
1327.41
815.20
5079.40
0.00
4975.36
14156.96
Mol%
accomodated
0.27%
0.00%
0.00%
0.00%
13.57%
9.38%
5.76%
35.88%
0.00%
35.14%
T initial
298
298
298
298
298
298
298
298
298
298
T final
1473.80
1473.80
1473.80
1473.80
1473.80
1473.80
1473.80
1473.80
1473.80
1473.80
1200.80
KJ/Kmol
Del H specific 40553.09296
Del H
574108572.3
Heat of Formation Summation
Gjoules/hr
574.1085723
-1818.427466
15.24551817
m8
Mass Flow
(kg/hr)
611.50
53798.28
58406.02
22825.70
10158.81
0.00
89556.47
235356.77
Mol%
92%
2%
2%
1%
2%
1%
0
0
0
0
0
100.00%
Natural Gas
Mole Flow
(kgmol/hr)
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Mass Flow
(kg/hr)
0
0
0
0
0
0
0
0
0
0
168976.96
0.00
0.00
r Outlet
Tau
3.432885906
3.432885906
3.432885906
3.432885906
3.432885906
3.432885906
3.432885906
3.432885906
3.432885906
3.432885906
Cp
55.38076461
92.77996548
132.9360584
173.2944119
31.81189175
13.92279939
30.1304528
31.99712019
25.73766425
40.70096496
<Cp>
1.510750402
0
0
0
0
0.897472073
2.864024505
12.84059174
0
16.76478062
34.87761934
H0f
-2032.86
0.00
0.00
0.00
0.00
-25365.83
-10505.86
0.00
0.00
-99605.15
-137509.69
er Outlet
Tau
4.945637584
4.945637584
4.945637584
4.945637584
4.945637584
4.945637584
4.945637584
4.945637584
4.945637584
4.945637584
Cp
64.84253338
109.390407
156.0686441
202.6610967
33.48966608
-0.50510527
30.73521444
33.9634395
23.47096982
45.13191265
<Cp>
0.175050723
0
0
0
4.545180361
-0.04736055
1.769832595
12.18580763
0
15.86127744
34.48978819
H0f
-201.18
0.00
0.00
0.00
0.00
-36896.87
-6364.39
0.00
0.00
-84985.15
-128447.58
Temperature
Pressure
Pressure Drop
599
38.43537415
SR outlet stream
HTS
9
Reactions in HTS
CO+H2O = CO2 + H2
Reaction 1
Components
Methane
Nitrogen
Carbon dioxide
Carbon monoxide
Hydrogen
Steam
Mol. Wt
Mol%
0.27
13.57
9.38
5.76
35.88
35.14
100
16
28
44
28
2
18
Total
CO Consume
Reaction 1
CO2 Produced
Reaction 1
H2 Produced
Reaction 1
Steam Consume
Reaction 1
Components
Methane
Ethane
Propane
Butane
80% based on CO
652.16 kgmol/hr
652.16 kgmol/hr
652.16 kgmol/hr
652.16 kgmol/hr
Mol. Wt
16
30
44
58
Heat of
Formations
-74520
-83820
-104680
-125790
Nitrogen
Carbon dioxide
Carbon monoxide
Hydrogen
Oxygen
Steam
Components
Methane
Ethane
Propane
Butane
Nitrogen
Carbon dioxide
Carbon monoxide
Hydrogen
Oxygen
Steam
28
44
28
2
32
18
0
-393509
-110525
0
0
-241818
Mol. Wt
16
30
44
58
28
44
28
2
32
18
Mol%
0.27%
0.00%
0.00%
0.00%
13.57%
9.38%
5.76%
35.88%
0.00%
35.14%
100.00%
3.28
5.457
3.376
3.249
3.639
3.47
Mole Flow
(kgmol/hr)
38.22
0.00
0.00
0.00
1921.37
1327.41
815.20
5079.40
0.00
4975.36
14156.96
0.000593
0.001045
0.000557
0.000422
0.000506
0.00145
0
0
0
0
0
0
KJ/Kmol
Gjoules/hr
Del H specific
-32828.16852
Del H
-464747115 -464.747115
Heat of Formation Summation
0
Heat Supply required
-464.747115
rxn heat
Methane
Ethane
Propane
Butane
Nitrogen
Carbon dioxide
Carbon monoxide
Hydrogen
Oxygen
Steam
Mol. Wt
16
30
44
58
28
44
28
2
32
18
Heat of
Formations
-74520
-83820
-104680
-125790
0
-393509
-110525
0
0
-241818
A
1.702
1.131
1.213
1.935
3.28
5.457
3.376
3.249
3.639
3.47
B
C
0.009081
-2.164E-06
0.019225
-5.561E-06
0.028785
-8.824E-06
0.036915 -1.1402E-05
0.000593
0
0.001045
0
0.000557
0
0.000422
0
0.000506
0
0.00145
0
Methane
Ethane
Propane
Butane
Nitrogen
Carbon dioxide
Carbon monoxide
Hydrogen
Oxygen
Steam
Mol. Wt
16
30
44
58
28
44
28
2
32
18
Mol%
0.27%
0.00%
0.00%
0.00%
13.57%
9.38%
5.76%
35.88%
0.00%
35.14%
100.00%
Mole Flow
(kgmol/hr)
38.22
0.00
0.00
0.00
1921.37
1327.41
815.20
5079.40
0.00
4975.36
14156.96
Mol%
accomodate
d
0.27%
0.00%
0.00%
0.00%
13.57%
9.38%
5.76%
35.88%
0.00%
35.14%
T initial
588
588
588
588
588
588
588
588
588
588
315
315
KJ/Kmol
Gjoules/hr
-9480.381971
Del H
-134213401.8 -134.213402
Heat of Formation Summation
-1818.42747
Heat Supply required
-0.48060121
Del H specific
rxn heat
-26.846931
Methane
Ethane
Propane
Butane
Nitrogen
Carbon dioxide
Carbon monoxide
Hydrogen
Oxygen
Steam
Mol. Wt
16
30
44
58
28
44
28
2
32
18
Heat of
Formations
-74520
-83820
-104680
-125790
0
-393509
-110525
0
0
-241818
A
1.702
1.131
1.213
1.935
3.28
5.457
3.376
3.249
3.639
3.47
B
C
0.009081
-2.164E-06
0.019225
-5.561E-06
0.028785
-8.824E-06
0.036915 -1.1402E-05
0.000593
0
0.001045
0
0.000557
0
0.000422
0
0.000506
0
0.00145
0
Stream 10 (HTSC ou
Components
Methane
Ethane
Propane
Butane
Nitrogen
Mol. Wt
16
30
44
58
28
Mol%
0.27%
0.00%
0.00%
0.00%
13.57%
Mole Flow
(kgmol/hr)
38.22
0.00
0.00
0.00
1921.37
Mol%
accomodate
d
0.27%
0.00%
0.00%
0.00%
13.57%
T initial
543
543
543
543
543
Carbon dioxide
Carbon monoxide
Hydrogen
Oxygen
Steam
44
28
2
32
18
13.98%
1.15%
40.49%
0.00%
30.54%
100.00%
KJ/Kmol
Gjoules/hr
Del H specific
-8098.750514
Del H
-114653698.5 -114.653699
Heat of Formation Summation
-1845.2744
Heat Supply required
-1.20079189
1979.57
163.04
5731.57
0.00
4323.20
14156.96
13.98%
1.15%
40.49%
0.00%
30.54%
543
543
543
543
543
270
270
rxn heat
-5.3693862
Exit Temperature
Pressure
Pressure Drop
10
11
LTS
Reactions in LTS
Reaction 1
CO+H2O = CO2 + H2
fficients
D
0
0
0
0
80% based on CO
130.43 kgmol/hr
130.43 kgmol/hr
130.43 kgmol/hr
130.43 kgmol/hr
4000
-115700
-3100
8300
-22700
12100
(SR Inlet) Cool down to reactor Inlet temp
T final
588.00
588.00
588.00
588.00
588.00
588.00
588.00
588.00
588.00
588.00
599
fficients
D
0
0
0
0
4000
-115700
-3100
8300
-22700
12100
Tau
0.398968652
0.398968652
0.398968652
0.398968652
0.398968652
0.398968652
0.398968652
0.398968652
0.398968652
0.398968652
Cp
71.68583919
122.0200634
174.034758
225.5388899
32.3585737
54.14940403
32.83732269
30.64178195
34.55685721
41.29586686
<Cp>
0.193525104
0
0
0
4.391669757
5.077249898
1.890878756
10.99402374
0
14.51312747
37.06047473
H0f
-201.18
0.00
0.00
0.00
0.00
-36896.87
-6364.39
0.00
0.00
-84985.15
-128447.58
T final
298.00
298.00
298.00
298.00
298.00
298.00
298.00
298.00
298.00
298.00
Tau
0.506802721
0.506802721
0.506802721
0.506802721
0.506802721
0.506802721
0.506802721
0.506802721
0.506802721
0.506802721
Cp
43.93977376
70.8133391
101.191459
132.7812718
29.5027472
47.80831182
30.08177233
28.66760656
31.84165231
34.33753975
<Cp>
0.118621047
0
0
0
4.004080151
4.482685464
1.732205295
10.28570557
0
12.06767479
32.69097231
H0f
-201.18
0.00
0.00
0.00
0.00
-36896.87
-6364.39
0.00
0.00
-84985.15
-128447.58
Mol%
0.27%
0.00%
0.00%
0.00%
13.57%
13.98%
1.15%
40.49%
0.00%
30.54%
100.00%
Mole Flow
(kgmol/hr)
38.22
0.00
0.00
0.00
1921.37
1979.57
163.04
5731.57
0.00
4323.20
14156.96
599
KJ/Kmol
Del H specific11342.81057
Del H
160579731.6
Heat of Formation Summation
fficients
D
0
0
0
0
4000
-115700
-3100
8300
-22700
12100
Stream 10 (HTSC outlet)
T final
298.00
298.00
298.00
298.00
298.00
Tau
0.548802947
0.548802947
0.548802947
0.548802947
0.548802947
Cp
<Cp>
42.62668421 0.115076193
68.20804357
0
97.37932321
0
127.9077245
0
29.40496939 3.990809854
H0f
-201.18
0.00
0.00
0.00
0.00
Mol%
0.27%
0.00%
0.00%
0.00%
13.57%
Mole Flow
(kgmol/hr)
38.22
0.00
0.00
0.00
1921.37
298.00
298.00
298.00
298.00
298.00
0.548802947
0.548802947
0.548802947
0.548802947
0.548802947
47.23241509
29.96738454
28.61595497
31.67236135
34.10607948
6.604522854
0.345123695
11.58541244
0
10.41517951
33.05612455
-55024.48
-1272.88
0.00
0.00
-73845.42
-130343.96
14.90%
0.23%
41.41%
0.00%
29.62%
100.00%
2110.00
32.61
5862.00
0.00
4192.76
14156.96
518
KJ/Kmol
Del H specific8393.205954
Del H
118822292.8
Heat of Formation Summation
T initial
298
298
298
298
298
298
298
298
298
298
Gjoules/hr
T final
654.48
654.48
654.48
654.48
654.48
654.48
654.48
654.48
654.48
654.48
Tau
2.196241611
2.196241611
2.196241611
2.196241611
2.196241611
2.196241611
2.196241611
2.196241611
2.196241611
2.196241611
Cp
45.83519859
74.54801233
106.6420192
139.7469414
30.44034473
25.71732341
29.63607223
30.38969341
27.5906417
37.07875369
<Cp>
0.123737989
0
0
0
4.131329847
3.596061093
0.34130809
12.30352551
0
11.32296298
31.81892552
H0f
-201.18
0.00
0.00
0.00
0.00
-55024.48
-1272.88
0.00
0.00
-73845.42
-130343.96
381.48 Temp C
160.5797316
-1845.2744
-0.48060121
T initial
298
298
298
298
298
T final
563.00
563.00
563.00
563.00
563.00
Tau
1.889261745
1.889261745
1.889261745
1.889261745
1.889261745
Cp
<Cp>
43.21327815 0.116659779
69.37365838
0
99.0858329
0
130.0895449
0
30.09987713 4.085121961
H0f
-201.18
0.00
0.00
0.00
0.00
14.90%
0.23%
41.41%
0.00%
29.62%
Gjoules/hr
118.8222928
-1850.64378
298
298
298
298
298
563.00
563.00
563.00
563.00
563.00
1.889261745
1.889261745
1.889261745
1.889261745
1.889261745
290.00 Temp C
-1.20079189
28.64515109
29.51334909
29.99067191
28.05061776
36.17958977
4.269376924
0.067978946
12.41829178
0
10.71504591
31.6724753
-58650.00
-254.58
0.00
0.00
-71617.48
-130723.23
Mol%
0.27%
0.00%
0.00%
0.00%
13.57%
13.98%
1.15%
40.49%
0.00%
30.54%
100.00%
Mole Flow
(kgmol/hr)
38.22
0.00
0.00
0.00
1921.37
1979.57
163.04
5731.57
0.00
4323.20
14156.96
KJ/Kmol
Mol%
accomodate
d
0.27%
0.00%
0.00%
0.00%
13.57%
13.98%
1.15%
40.49%
0.00%
30.54%
T initial
654.48
654.48
654.48
654.48
654.48
654.48
654.48
654.48
654.48
654.48
Gjoules/hr
Del H specific-3827.45032
Del H
-54185066.6 -54.1850666 Heat Surplus
Heat of Formation Summation -1845.2744
T final
543.00
543.00
543.00
543.00
543.00
543.00
543.00
543.00
543.00
543.00
Tau
0.8296663
0.8296663
0.8296663
0.8296663
0.8296663
0.8296663
0.8296663
0.8296663
0.8296663
0.8296663
Cp
52.88656225
88.48138466
126.9986797
165.7660314
30.28624321
48.70825215
30.79084697
29.24652926
32.40792591
36.26242287
<Cp>
0.142774048
0
0
0
4.11041536
6.810889596
0.354607219
11.8407058
0
11.07367511
34.33306713
H0f
-201.18
0.00
0.00
0.00
0.00
-55024.48
-1272.88
0.00
0.00
-73845.42
-130343.96
Cooler Separator
C
555 psig
psig
Temperature
Pressure
Pressure Drop
Assumptions:
Water Condensed
CO2 Solubility in Water
Components
100%
0%
Mol. Wt
Methane
Nitrogen
Carbon dioxide
Carbon monoxide
Hydrogen
Steam
16
28
44
28
2
18
Total
Mol%
0.27
13.57
14.90
0.23
41.41
29.62
100
CO2 Removal
C
555 psig
10 psig
Temperature
Pressure
Pressure Drop
Stream from
Cooler Separator
Lean Solvent
Assumptions:
Solvent Used
Rich Solvent Loading
Lean Solvent Loading
Solution Strength
12
14
MDEA
Total
Total Mass in
1297601.56 kg/hr
Components
Methane
Nitrogen
Carbon dioxide
Carbon monoxide
Hydrogen
MDEA
Water
1297601.56 kg/hr
1104.577235 m3 /hr
Partial pressure at Top of Abs.
Total pressure bar g
H2O condensed
16.87
9.81
Components
Methane
Ethane
Propane
Butane
Nitrogen
Carbon dioxide
Carbon monoxide
Hydrogen
Oxygen
Steam
Components
Methane
Ethane
Propane
Butane
Nitrogen
Carbon dioxide
Carbon monoxide
Hydrogen
Oxygen
Steam
Heat of
Formations
-74520
-83820
-104680
-125790
0
-393509
-110525
0
0
-241818
Mol. Wt
16
30
44
58
28
44
28
2
32
18
Mol. Wt
Mol%
0.38%
0.00%
0.00%
0.00%
19.28%
21.18%
0.33%
58.83%
0.00%
0.00%
100.00%
16
30
44
58
28
44
28
2
32
18
KJ/Kmol
Gjoules/hr
Del H specific
489.8471763
Del H kjoules/hr
4880933.833 4.880933833
Heat of Formation Summation
0
Heat Supply required
0
BTU/lb
Heat of Absorption
577
Mol%
accomodated
0.38%
0.00%
0.00%
0.00%
19.28%
21.18%
0.33%
58.83%
0.00%
0.00%
Kwatt
1355.81
Kj/kg
Kj/hr
1339.217
Kwatt
Strea
Heat of Absorption
Enthalpy of Lean
34536.99588
15488.7195
124333185.2
55759390.19
K
Temp of Rich solution out 298.0108983
Heat Exchanger
Flow rate
Lean MDEA sol. From Stripper
Rich MDEA sol. From Absorber
Cooler
Lean MDEA sol. From Stripper
Water
T in
K
1137714.6
1230554.8
389.0
298.0
1137714.6
4303529.0
353.0
303.0
Methane
Ethane
Propane
Butane
Nitrogen
Carbon dioxide
Carbon monoxide
Hydrogen
Oxygen
Steam
Mol. Wt
16
30
44
58
28
44
28
2
32
18
Heat of
Formations
-74520
-83820
-104680
-125790
0
-393509
-110525
0
0
-241818
A
1.702
1.131
1.213
1.935
3.28
5.457
3.376
3.249
3.639
3.47
B
0.009081
0.019225
0.028785
0.036915
0.000593
0.001045
0.000557
0.000422
0.000506
0.00145
COOLER SEPERA
Components
Methane
Ethane
Propane
Butane
Nitrogen
Carbon dioxide
Carbon monoxide
Hydrogen
Oxygen
Mol. Wt
16
30
44
58
28
44
28
2
32
Mol%
-
Mole Flow
(kgmol/hr)
38.22
0.00
0.00
0.00
1921.37
2110.00
32.61
5862.00
0.00
Mol%
accomodated
0.27%
0.00%
0.00%
0.00%
13.57%
14.90%
0.23%
41.41%
0.00%
Steam
18
0.00%
4192.76
14156.96
KJ/Kmol
Gjoules/hr
-3523.913277
Del H
-49887904.29 -49.8879043
Heat of Formation Summation
0
29.62%
100.00%
Del H specific
Gjoules/hr
-255.5087114
rxn heat
Sat. steam
sat. water
2801.9425
959.86
-1842.0825
1
13
3
Cooler
Condenser
12
Mol%
0.38
19.28
21.18
0.33
58.83
0.00
100
Stream 12
Mole Flow
(kgmol/hr)
38.22
1921.37
2110.00
32.61
5862.00
0.00
9964.20
Mass Flow
(kg/hr)
611.50
53798.28
92840.21
913.03
11724.00
0.00
159887.01
235356.77
15
Treated Gas
CO2 Removal
Stripper
16
Rich Solvent
MDEA M.wt
119.7
H20
18
CO2
44
Stream 14 (Lean Solvent)
Mole Flow
Mass Flow
Mol%
(kgmol/hr)
(kg/hr)
0.00
0.00
0.00
0.00
0.00
0.00
0.00
468.89
20631.16
0.00
0.00
0.00
0.00
0.00
0.00
0.00
4688.90
558541.70
0.00
31030.09
558541.70
36187.88
1137714.55
kpa
Mol%
0.49
24.46
0.00
0.42
74.64
0.00
0.00
100
& Cp coefficients
C
-2.164E-06
-5.561E-06
-8.824E-06
-1.1402E-05
0
0
0
0
0
0
7.777
6.624
0.868728121
5.754455076
4601.3
7.06 127.0079625
D
0
0
0
0
4000
-115700
-3100
8300
-22700
12100
600
Cp
35.56821927
53.98298133
76.44538172
101.1240889
29.17315617
36.61442408
29.17930816
28.90457273
29.30262954
33.73214972
<Cp>
0.136424948
0
0
0
5.625374731
7.753420272
0.095490169
17.0047384
0
0
30.61544852
H0f
-285.83
0.00
0.00
0.00
0.00
-83328.93
-361.70
0.00
0.00
0.00
-83976.45
T out
K
0.0%
& Cp coefficients
C
-2.164E-06
-5.561E-06
-8.824E-06
-1.1402E-05
0
0
0
0
0
0
D
0
0
0
0
4000
-115700
-3100
8300
-22700
12100
T initial
563.00
563
563
563
563
563
563
563
563
T final
458.60
458.60
458.60
458.60
458.60
458.60
458.60
458.60
458.60
Tau
0.814564831
0.814564831
0.814564831
0.814564831
0.814564831
0.814564831
0.814564831
0.814564831
0.814564831
Cp
48.00491689
78.94244115
113.1205742
148.0378723
29.87373033
47.3353733
30.36729276
28.98166792
31.91851899
<Cp>
0.129595421
0
0
0
4.054429569
7.055035241
0.069945859
12.00049167
0
H0f
-201.18
0.00
0.00
0.00
0.00
-58650.00
-254.58
0.00
0.00
563
458.60
200
290
0.814564831 35.26595326
10.44446083
33.75395859
392
0
Heat of Condensation
J/mol
-33157.485
-1.39022E+11
-139.0215185
-71617.48
-130723.23
Mol%
0.49%
0.00%
0.00%
0.00%
24.46%
0.00%
0.42%
74.64%
0.00%
0.00%
100.00%
Mole Flow
Mol%
(kgmol/hr) accomodate
38.22
0.49%
0.00
0.00%
0.00
0.00%
0.00
0.00%
1921.37
24.46%
0.00
0.00%
32.61
0.42%
5862.00
74.64%
0.00
0.00%
0.00
0.00%
7854.19
100.00%
KJ/Kmol
Gjoules/hr
Del H specific376.8811455
kwatt
Del H
2960097.032 2.960097032 822.2491754
Heat of Formation Summation
0
Cp
35.47157627
53.78590048
76.15411779
100.7512189
29.16199085
36.71043942
29.17528357
28.8914872
29.31771402
33.70266249
329.88 Temp C
Flow rate
kg/hr
T oprational T ref
K
K
3.77
3.77
0.878863636
kj/kg
Mole Flow
(kgmol/hr)
38.22
0.00
0.00
0.00
1921.37
2110.00
32.61
5862.00
0.00
330.6
389.0
367.8
-
298.0
298.0
298
-
2133 174401.6235
-
psi
System pressure
164.4 temp
8498.056974
Vapor pressure
A
8.14019
Mol%
-
1230554.8
1137714.6
92840.21
Mol%
accomodate
d
0.27%
0.00%
0.00%
0.00%
13.57%
14.90%
0.23%
41.41%
0.00%
Deg C
K
185.6
458.6
C
1810.94
244.485
Vap. Pressure
8502.251881
T initial
458.60
458.6
458.6
458.6
458.6
458.6
458.6
458.6
458.6
T final
315.22
315.22
315.22
315.22
315.22
315.22
315.22
315.22
315.22
Tau
0.687357659
0.687357659
0.687357659
0.687357659
0.687357659
0.687357659
0.687357659
0.687357659
0.687357659
164
Cp
40.63784599
64.2452437
91.57177042
120.4815756
29.28615871
45.58720927
29.77557609
28.59519593
31.26552737
0.00%
4192.76
14156.96
KJ/Kmol
29.62%
Gjoules/hr
458.6
315.22
0.687357659 33.84269306
42.22 Temp C
32
<Cp>
0.172604827
0
0
0
7.133883057
0
0.121126601
21.56324286
0
0
28.99085734
Enthalpy
Kj/hr
H0f
-362.61
0.00
0.00
0.00
0.00
0.00
-458.87
0.00
0.00
0.00
-821.48
Kwatt
2% radiation loss
151372965.9
390315731.4
5695253.0
124333185.2
42048.04608
108421.0365
1582.014732
34536.99588
371998663 103332.9619
K
1.000493631
<Cp>
0.10970707
0
0
0
3.974685
6.794482552
0.068582941
11.84046452
0
H0f
-201.18
0.00
0.00
0.00
0.00
-58650.00
-254.58
0.00
0.00
98%
10.02294421
32.81086629
-71617.48
-130723.23
Methanator
400 C
460 psig
10 psig
Temperature
Pressure
Pressure Drop
Reaction 1
Components
Methane
Nitrogen
Carbon monoxide
Hydrogen
Steam
Mol. Wt
16
28
28
2
18
Total
CO Consume
Reaction 1
H2 Consume
Reaction 1
CH4 Produced
Reaction 1
Steam Produced
Reaction 1
Components
Methane
Ethane
Propane
Butane
Nitrogen
Carbon dioxide
Carbon monoxide
Hydrogen
100%
32.61 kgmol/hr
97.82 kgmol/hr
32.61 kgmol/hr
32.61 kgmol/hr
Mol. Wt
16
30
44
58
28
44
28
2
Oxygen
Steam
Components
Methane
Ethane
Propane
Butane
Nitrogen
Carbon dioxide
Carbon monoxide
Hydrogen
Oxygen
Steam
32
18
Mol. Wt
16
30
44
58
28
44
28
2
32
18
KJ/Kmol
-8412.4524
Del H
-66073020
Heat of Formation Summation
Heat Supply required
0
-241818
Mol%
0.49%
0.00%
0.00%
0.00%
24.46%
0.00%
0.42%
74.64%
0.00%
0.00%
100.00%
3.639
3.47
0.000506
0.00145
Mole Flow
Mol%
(kgmol/hr) accomodate
38.22
0.49%
0.00
0.00%
0.00
0.00%
0.00
0.00%
1921.37
24.46%
0.00
0.00%
32.61
0.42%
5862.00
74.64%
0.00
0.00%
0.00
0.00%
7854.19
Gjoules/hr
Del H specific
Components
Methane
Ethane
Propane
Butane
Nitrogen
Carbon dioxide
Carbon monoxide
Hydrogen
Oxygen
Steam
Components
Methane
Ethane
Propane
Butane
Nitrogen
Carbon dioxide
Mol. Wt
16
30
44
58
28
44
28
2
32
18
-66.07302011
-6.452059187
-0.209185006
Mol. Wt
16
30
44
58
28
44
rxn heat
Mol%
0.91%
0.00%
0.00%
0.00%
24.67%
0.00%
Mole Flow
(kgmol/hr)
70.83
0.00
0.00
0.00
1921.37
0.00
Mol%
accomodate
d
0.91%
0.00%
0.00%
0.00%
24.67%
0.00%
Carbon monoxide
Hydrogen
Oxygen
Steam
28
2
32
18
KJ/Kmol
Del H specific
-8923.3681
Del H
-69503901
Heat of Formation Summation
Latent Heat of Condensation
Gjoules/hr
-66.687284
0.00%
74.00%
0.00%
0.42%
100.00%
0.00
5764.17
0.00
32.61
7788.98
0.00%
74.00%
0.00%
0.42%
Gjoules/hr
-69.50390139
-13.1632376
Sat. steam
sat. water
Enthalpy of condensation
rxn heat
2801.9425
959.86
-1842.0825
17
Methanator
Cooler and
Separator
18
19
based on CO
Stream 17 (Methanator outlet)
Mole Flow
Mass Flow
Mol%
(mol/hr)
(kg/hr)
0.91
70.83
1133.23
24.67
1921.37
53798.28
0.00
0.00
0.00
74.00
5764.17
11528.35
0.42
32.61
586.95
100
7788.98
67046.80
Cp coefficients
C
-2.164E-06
-5.561E-06
-8.824E-06
-1.1402E-05
0
0
0
0
D
0
0
0
0
4000
-115700
-3100
8300
Mol%
0.91
24.77
0.00
74.32
0.00
100.00
Stream 18
Mole Flow
(mol/hr)
70.83
1921.37
0.00
5764.17
0.00
7756.37
Stream 19 (Knock o
Mass Flow
(kg/hr)
1133.23
53798.28
0.00
11528.35
0
66459.85
Mol%
0.00
0.00
0.00
0.00
100.00
100
0
0
T initial
588.5555556
588.5555556
588.5555556
588.5555556
588.5555556
588.5555556
588.5555556
588.5555556
588.5555556
588.5555556
-22700
12100
T final
298.00
298.00
298.00
298.00
298.00
298.00
298.00
298.00
298.00
298.00
315.5555556
315.5555556
Tau
0.506324335
0.506324335
0.506324335
0.506324335
0.506324335
0.506324335
0.506324335
0.506324335
0.506324335
0.506324335
Cp
43.95583296
70.8451132
101.2379035
132.8406393
29.50397879
47.81471433
30.08316558
28.66829498
31.84360354
34.34047126
<Cp>
0.213889252
0
0
0
7.217543394
0
0.124895842
21.39666271
0
0
28.9529912
H0f
-362.61
0.00
0.00
0.00
0.00
0.00
-458.87
0.00
0.00
0.00
-821.48
Mol%
0.91%
0.00%
0.00%
0.00%
24.67%
0.00%
0.00%
74.00%
0.00%
0.42%
100.00%
600
Del H specific
Del H
Heat of Formation Summa
-6.71117841
Cp coefficients
C
-2.164E-06
-5.561E-06
-8.824E-06
-1.1402E-05
0
0
0
0
0
0
T initial
605.00
605
605
605
605
605
D
0
0
0
0
4000
-115700
-3100
8300
-22700
12100
T final
298.00
298.00
298.00
298.00
298.00
298.00
System pressure
Vapor pressure
Tau
0.492561983
0.492561983
0.492561983
0.492561983
0.492561983
0.492561983
Cp
<Cp>
44.4295088 0.40400612
71.78131826
0
102.6058244
0
134.5890846
0
29.540659 7.287023311
47.99771414
0
H0f
-677.62
0.00
0.00
0.00
0.00
0.00
Mol%
0.91%
0.00%
0.00%
0.00%
24.67%
0.00%
605
605
605
605
298.00
298.00
298.00
298.00
200
332
0.492561983
0.492561983
0.492561983
0.492561983
30.12423103
0
28.68913941 21.23118557
31.90008202
0
34.42792515 0.144130688
29.06634569
0.00
0.00
0.00
-1012.36
-1689.98
0.00%
74.00%
0.00%
0.42%
100.00%
392
Del H specific
Del H
Heat of Formation Summa
0
Heat of Condensation
J/mol
-33157.485 -1081203800
-1.0812038
Input
Out put
67046.8
67046.80
Mole Flow
Mol%
(kgmol/hr) accomodate
70.83
0.91%
0.00
0.00%
0.00
0.00%
0.00
0.00%
1921.37
24.67%
0.00
0.00%
0.00
0.00%
5764.17
74.00%
0.00
0.00%
32.61
0.42%
7788.98
100.00%
T initial
298.00
298.00
298.00
298.00
298.00
298.00
298.00
298.00
298.00
298.00
T final
605.00
605.00
605.00
605.00
605.00
605.00
605.00
605.00
605.00
605.00
KJ/Kmol
Gjoules/hr
9317.657708
72575013.52 72.57501352
at of Formation Summation-13.1632376
psi
192.5765668 temp
9956.339507
por pressure
A
8.14019
Mole Flow
(kgmol/hr)
70.83
0.00
0.00
0.00
1921.37
0.00
Mol%
accomodate
d
0.91%
0.00%
0.00%
0.00%
24.67%
0.00%
Tau
2.030201342
2.030201342
2.030201342
2.030201342
2.030201342
2.030201342
2.030201342
2.030201342
2.030201342
2.030201342
Cp
44.4295088
71.78131826
102.6058244
134.5890846
30.2561915
27.30093637
29.56969334
30.17386936
27.83943504
36.59241098
332.00 Temp C
-0.20918501
Deg C
25
B
298
C
1810.94
244.485
Vap. Pressure
26.31400976 0.508968347
T initial
298.00
298
298
298
298
298
T final
315.22
315.22
315.22
315.22
315.22
315.22
Tau
1.057792692
1.057792692
1.057792692
1.057792692
1.057792692
1.057792692
Cp
35.60756139
54.063194
76.56391861
101.2758359
29.177705
36.57530672
0.00
5764.17
0.00
32.61
7788.98
0.00%
74.00%
0.00%
0.42%
KJ/Kmol
Gjoules/hr
500.4279353
3897821.245 3.897821245
at of Formation Summation-13.1632376
298
298
298
298
315.22
315.22
315.22
315.22
1.057792692
1.057792692
1.057792692
1.057792692
29.18094781
28.90990388
29.29648401
33.74416304
42.22 Temp C
629.6
<Cp>
0.40400612
0
0
0
7.46352926
0
0
22.329949
0
0.153192193
30.35067657
H0f
-677.62
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
-1012.36
-1689.98
K
0.00264294
<Cp>
0.323786445
0
0
0
7.197490635
0
H0f
-677.62
0.00
0.00
0.00
0.00
0.00
0
21.39456069
0
0.141268154
29.05710592
0.00
0.00
0.00
-1012.36
-1689.98
Temperature
Pressure
Pressure Drop
24
From Methanator
Ammonia
Converter
18
Reaction 1
Iteration No. 1
Components
Methane
Nitrogen
Hydrogen
Ammonia
Mol. Wt
16
28
2
17
Total
H2 Consume
Reaction 1
N2 Consume
Reaction 1
NH3 Produced
Reaction 1
3701.55 kgmol/hr
3701.55
R /F
7756.4
0.01
15%
378.65
29380.98
3.787982016
Note: This indicates that at the start-up, until the system get stabilized, recycle is required after that all the stream s
ammonia price
dollar
Total Input
23
Recycle Stream
Ammonia
Converter
20
Cooler and
Ammonia
Separator
21
Liquid Ammonia
22
Sep. Efficiency 65%
kgmol/hr
mol%
mol%
Methane
Nitrogen
Hydrogen
NH3
kgmol/hr
kgmol/hr
N2 :H2
Mol%
18.72%
18.66%
55.97%
6.65%
100.00%
Purge Stream 23
Mole Flow
Mass Flow
(kgmol/hr)
(kg/hr)
70.83
1133.23
70.65
1978.09
211.94
423.88
25.19
428.18
378.65
66459.85
66458.27
7756.4
4054.82
quired after that all the stream should be purged.
62494.89 kg/hr
1499.9 Tonnes/day
1.0
e desired production rate.
Purge Stream
62.49489181 TPH
1.59
3963.37
Stream 22 (Liquid A
Mol%
0.00%
0.00%
0.00%
100.00%
100.00%
Recycle Stream
Mol%
18.72%
18.66%
55.97%
6.65%
100.00%
Required
4743.387682
31538.7847
1.981525046
31.5387847
Nh3/ton naphtha
Put Basis
2265.2595
756.9308328
1.981525046
0.504661802
792.6100185
287.9482168
504.6618017
145.3164659
1133.23
1.447523411
311560.00
-0.14
Stream 1 (Pre-R1)
Mol. Wt
Carbon
H2
Stream 2 (Pre-R2)
306.3978 -
26169.9768
5108.211
Methane
Ethane
Propane
Butane
Nitrogen
Carbon dioxide
Carbon monoxide
Hydrogen
Oxygen
Steam/Water
Argon
MDEA sol.
16
30
44
58
28
44
28
2
32
18
40
Ammonia
Total
Stream 3 (Pre-R3)
20383.22
560.54
25035.94
2158.04
137392.3782
31584.5856
120839.2201
-
137392.3782
168976.9638
0
Total Input
235356.8
Total output 235356.8
Input
St 1
St 5
St 2
N.gas input
output
31584.5856
-3762.258051
137392.3782
0
co2 out
st 13
st 19
st 23
92840.20825
75469.75693
586.9464585
3963.374505
St 7
70142.06014 st 22
235356.7659
62494.89181
1.587933805
235356.7659
235.3567659
235356.7659
Stream 5 (P-R5)
-
120839.2201
-
5095.80
0.00
0.00
0.00
0.00
33113.57
31073.35
9370.51
Stream 7 (S-R7)
53798.27914
-
-3762.258051
16343.781
86561.47 -
168976.9638
kg/hr
kg/hr
Stream 6 (P-R6)
-3762.258051
165214.7057
0
70142.06014
0.000674692
Shift Convertors
Stream 8 (S-R8)
Stream 9 (S-C9)
611.50
Stream 10 (S-C10)
Stream 11 (S-C11)
611.50
611.50
611.50
53798.28
58406.02
22825.70
10158.81
0.00
89556.47
53798.28
58406.02
22825.70
10158.81
0.00
89556.47
53798.28
87101.18
4565.14
11463.13
53798.28
92840.21
913.03
11724.00
77817.54
75469.75693
235356.7659
0
235356.7659
235356.7659
235356.7659
Water Seperator
Stream 12 (C-S12)
Stream 13 (C-S13)
Stream 14 (C-S14)
Stream 15 (C-A15)
611.50
611.50
53798.28
92840.21
913.03
11724.00
53798.28
20631.16
913.03
11724.00
75469.75693
558541.70
558541.70
159887.009
75469.75693
0
1137714.552
1297601.561
67046.80071
ion Stripping
Methanator
Stream 16 (C-A16)
Stream 17 (M-R17)
Stream 18 (M-R18)
1133.23
1133.23
53798.28
53798.28
11528.35
11528.35
Stream 19 (M-R18)
113471.37
558541.70
586.95
586.95
558541.70
1230554.76
1297601.561
0
67046.80071
66459.85425
586.9464585
0.00
Input
Stream 20 (S-L20)
Stream 21 (S-L21)
Stream 22 (S-L22)
Stream 23 (S-L23)
89129.64
89129.64
1133.23
155464.92
155464.92
1978.09
33314.33
33314.33
423.88
96145.99
374054.8868
33651.10
311559.995
62494.89
62494.89181
428.18
3963.374505
Stream 24 (S-L24)
Stream 25 (S-L25)
87996.41
89129.64
153486.84
207286.57
32890.45
44419.11
33222.91
307596.6205
33219.70838
374055.0273
235355.2
Pre Reformer
Del H
Tin
T out
Pin
Pout
Adiabetic
Primary reformer
Gj/hr
245.3708166
490
700
510.00
750