Txy Diagram for mixture of D and E

Total Pressure (mm Hg):

760

Antoine Coefficients for Compound D

A=
B=
C=

7.2
1533
222

Antoine Coefficients for Compound E

A=
B=
C=

8.1
1750
235

Boiling Point of Pure D: 132.928

Boiling Point of Pure E: 100.3013

BUBBLE POINT CALCULATIONS:

0
0.01
0.02
0.03
0.04
0.05
0.06
0.07
0.08
0.09
0.1
0.11
0.12
0.13
0.14
0.15
0.16
0.17
0.18
0.19
0.2
0.21
0.22
0.23
0.24

xE
1
0.99
0.98
0.97
0.96
0.95
0.94
0.93
0.92
0.91
0.9
0.89
0.88
0.87
0.86
0.85
0.84
0.83
0.82
0.81
0.8
0.79
0.78
0.77
0.76

TBubble

P*D

P*E

100.3013
100.4777
100.6555
100.8347
101.0153
101.1974
101.3809
101.5659
101.7524
101.9405
102.13
102.3212
102.514
102.7084
102.9045
103.1023
103.3018
103.5031
103.7062
103.9111
104.1179
104.3267
104.5374
104.7501
104.9649

277.7029
279.3718
281.0621
282.7742
284.5084
286.2653
288.0451
289.8485
291.6758
293.5275
295.4043
297.3066
299.2351
301.1902
303.1727
305.1831
307.2222
309.2907
311.3892
313.5185
315.6795
317.8728
320.0994
322.3602
324.656

759.9986
764.817
769.699
774.6456
779.6581
784.7379
789.8863
795.1045
800.3942
805.7569
811.1941
816.7075
822.2988
827.9698
833.7225
839.5587
845.4806
851.4902
857.5897
863.7815
870.0678
876.4513
882.9344
889.5197
896.2102

SEbp
3.28827E-12
2.42537E-09
9.42516E-09
2.11611E-08
3.78407E-08
5.97088E-08
8.70358E-08
1.20104E-07
1.59197E-07
2.04581E-07
2.56494E-07
3.15128E-07
3.80617E-07
4.53016E-07
5.32292E-07
6.18304E-07
7.10791E-07
8.09359E-07
9.13472E-07
1.02244E-06
1.13543E-06
1.25141E-06
1.36924E-06
1.48759E-06
1.60498E-06

140

Temperature ( deg C)

xD

135
130
125
120
115
110
105
100
95
90

0.25
0.26
0.27
0.28
0.29
0.3
0.31
0.32
0.33
0.34
0.35
0.36
0.37
0.38
0.39
0.4
0.41
0.42
0.43
0.44
0.45
0.46
0.47
0.48
0.49
0.5
0.51
0.52
0.53
0.54
0.55
0.56
0.57
0.58
0.59
0.6
0.61
0.62
0.63
0.64
0.65
0.66
0.67
0.68
0.69
0.7
0.71
0.72
0.73

0.75
0.74
0.73
0.72
0.71
0.7
0.69
0.68
0.67
0.66
0.65
0.64
0.63
0.62
0.61
0.6
0.59
0.58
0.57
0.56
0.55
0.54
0.53
0.52
0.51
0.5
0.49
0.48
0.47
0.46
0.45
0.44
0.43
0.42
0.41
0.4
0.39
0.38
0.37
0.36
0.35
0.34
0.33
0.32
0.31
0.3
0.29
0.28
0.27

105.1818
105.4008
105.6221
105.8456
106.0714
106.2995
106.5301
106.7631
106.9986
107.2367
107.4774
107.7209
107.967
108.216
108.4679
108.7227
108.9805
109.2413
109.5053
109.7725
110.0429
110.3166
110.5938
110.8744
111.1585
111.4463
111.7377
112.0328
112.3318
112.6347
112.9415
113.2523
113.5673
113.8864
114.2098
114.5375
114.8697
115.2064
115.5476
115.8936
116.2443
116.5998
116.9603
117.3259
117.6966
118.0726
118.454
118.8409
119.2334

326.9878
329.3565
331.7632
334.2089
336.6946
339.2215
341.7907
344.4034
347.0609
349.7643
352.5149
355.3142
358.1635
361.0641
364.0177
367.0255
370.0893
373.2107
376.3911
379.6324
382.9363
386.3045
389.739
393.2415
396.8141
400.4587
404.1775
407.9725
411.8459
415.8
419.8371
423.9596
428.17
432.4708
436.8646
441.3543
445.9426
450.6324
455.4268
460.3289
465.342
470.4695
475.715
481.0822
486.5749
492.1973
497.9536
503.8484
509.8865

903.0085
909.9177
916.9408
924.0809
931.3415
938.7257
946.2372
953.8795
961.6564
969.5717
977.6294
985.8336
994.1885
1002.698
1011.368
1020.202
1029.204
1038.381
1047.737
1057.276
1067.006
1076.93
1087.055
1097.387
1107.932
1118.695
1129.684
1140.905
1152.365
1164.071
1176.03
1188.249
1200.737
1213.502
1226.551
1239.894
1253.539
1267.495
1281.772
1296.381
1311.33
1326.632
1342.297
1358.338
1374.765
1391.594
1408.836
1426.507
1444.622

1.71983E-06
1.83043E-06
1.93496E-06
2.03155E-06
2.11832E-06
2.19336E-06
2.25483E-06
2.30098E-06
2.33019E-06
2.34104E-06
2.33233E-06
2.30319E-06
2.25306E-06
2.18179E-06
2.08968E-06
1.97748E-06
1.84649E-06
1.69855E-06
1.53606E-06
1.362E-06
1.1799E-06
9.93878E-07
8.08551E-07
6.29025E-07
4.60814E-07
3.09771E-07
1.81981E-07
8.36538E-08
2.09897E-08
3.59553E-11
2.65236E-08
1.05698E-07
2.42135E-07
4.39563E-07
7.00659E-07
1.02688E-06
1.41829E-06
1.8734E-06
2.38899E-06
2.96008E-06
3.57979E-06
4.23937E-06
4.92818E-06
5.63381E-06
6.34224E-06
7.03807E-06
7.70479E-06
8.32523E-06
8.88197E-06

0.74
0.75
0.76
0.77
0.78
0.79
0.8
0.81
0.82
0.83
0.84
0.85
0.86
0.87
0.88
0.89
0.9
0.91
0.92
0.93
0.94
0.95
0.96
0.97
0.98
0.99
1

yD
0
0.01
0.02
0.03
0.04
0.05
0.06
0.07
0.08
0.09
0.1
0.11
0.12
0.13
0.14
0.15
0.16

0.26
0.25
0.24
0.23
0.22
0.21
0.2
0.19
0.18
0.17
0.16
0.15
0.14
0.13
0.12
0.11
0.1
0.09
0.08
0.07
0.06
0.05
0.04
0.03
0.02
0.01
0

yE
1
0.99
0.98
0.97
0.96
0.95
0.94
0.93
0.92
0.91
0.9
0.89
0.88
0.87
0.86
0.85
0.84

119.6317
120.0359
120.4462
120.8627
121.2857
121.7153
122.1517
122.5953
123.0462
123.5047
123.9712
124.446
124.9294
125.4219
125.924
126.436
126.9587
127.4924
128.038
128.5962
129.1676
129.7531
130.3537
130.9704
131.6042
132.2563
132.9279

516.0729
522.413
528.9125
535.5775
542.4145
549.4306
556.6333
564.0307
571.6316
579.4456
587.4829
595.7548
604.2736
613.0527
622.1067
631.4518
641.1055
651.0872
661.4181
672.1217
683.2236
694.7521
706.7384
719.2167
732.2246
745.8034
759.9986

1463.196
1482.247
1501.793
1521.854
1542.449
1563.602
1585.337
1607.678
1630.655
1654.297
1678.638
1703.712
1729.559
1756.222
1783.747
1812.186
1841.593
1872.032
1903.569
1936.279
1970.244
2005.555
2042.31
2080.619
2120.604
2162.396
2206.141

9.35792E-06
9.73688E-06
1.00042E-05
1.01476E-05
1.01575E-05
1.0028E-05
9.75751E-06
9.349E-06
8.81051E-06
8.15523E-06
7.40146E-06
6.57219E-06
5.69436E-06
4.79786E-06
3.91403E-06
3.074E-06
2.30661E-06
1.63631E-06
1.08096E-06
6.49902E-07
3.42557E-07
1.47867E-07
4.50291E-08
5.9802E-09
1.06273E-10
1.62701E-09
3.52221E-12

RMS=

0.001604133

Tdew

P*D

P*E

100.3013
100.7831
101.2595
101.7305
102.1963
102.657
103.1126
103.5634
104.0094
104.4507
104.8875
105.3197
105.7476
106.1713
106.5907
107.0061
107.4174

277.7029
282.2804
286.8664
291.4605
296.0624
300.672
305.289
309.9132
314.5443
319.1823
323.8269
328.478
333.1355
337.7993
342.4692
347.1453
351.8274

759.9986
773.2187
786.4764
799.7709
813.1012
826.4666
839.8662
853.2993
866.7653
880.2636
893.7935
907.3548
920.9468
934.5691
948.2215
961.9036
975.615

SEdp
3.23084E-12
1.31252E-12
2.48912E-11
8.65425E-11
1.88038E-10
3.20688E-10
4.68421E-10
6.12003E-10
7.33147E-10
8.17685E-10
8.57428E-10
8.50662E-10
8.01525E-10
7.18586E-10
6.13033E-10
4.96824E-10
3.81066E-10

0.17
0.18
0.19
0.2
0.21
0.22
0.23
0.24
0.25
0.26
0.27
0.28
0.29
0.3
0.31
0.32
0.33
0.34
0.35
0.36
0.37
0.38
0.39
0.4
0.41
0.42
0.43
0.44
0.45
0.46
0.47
0.48
0.49
0.5
0.51
0.52
0.53
0.54
0.55
0.56
0.57
0.58
0.59
0.6
0.61
0.62
0.63
0.64
0.65

0.83
0.82
0.81
0.8
0.79
0.78
0.77
0.76
0.75
0.74
0.73
0.72
0.71
0.7
0.69
0.68
0.67
0.66
0.65
0.64
0.63
0.62
0.61
0.6
0.59
0.58
0.57
0.56
0.55
0.54
0.53
0.52
0.51
0.5
0.49
0.48
0.47
0.46
0.45
0.44
0.43
0.42
0.41
0.4
0.39
0.38
0.37
0.36
0.35

107.8248
108.2284
108.6283
109.0245
109.4171
109.8061
110.1918
110.574
110.9529
111.3286
111.701
112.0704
112.4367
112.7999
113.1602
113.5176
113.8721
114.2237
114.5727
114.9189
115.2624
115.6033
115.9416
116.2774
116.6106
116.9414
117.2698
117.5957
117.9194
118.2407
118.5597
118.8765
119.191
119.5034
119.8137
120.1218
120.4278
120.7319
121.0338
121.3338
121.6319
121.928
122.2222
122.5146
122.8051
123.0937
123.3806
123.6657
123.9491

356.5155
361.2094
365.9091
370.6146
375.3258
380.0426
384.7649
389.4928
394.226
398.9645
403.7084
408.4573
413.2114
417.9705
422.7345
427.5033
432.2769
437.0552
441.838
446.6253
451.417
456.213
461.0132
465.8176
470.6261
475.4385
480.2549
485.0752
489.8992
494.727
499.5585
504.3935
509.2321
514.0742
518.9198
523.7688
528.6211
533.4768
538.3358
543.198
548.0635
552.9321
557.8039
562.6789
567.557
572.4381
577.3224
582.2096
587.0999

989.3555
1003.125
1016.922
1030.748
1044.602
1058.484
1072.393
1086.329
1100.292
1114.282
1128.298
1142.339
1156.407
1170.499
1184.617
1198.76
1212.926
1227.117
1241.332
1255.57
1269.831
1284.115
1298.421
1312.749
1327.1
1341.471
1355.865
1370.279
1384.714
1399.17
1413.646
1428.142
1442.658
1457.193
1471.749
1486.323
1500.917
1515.529
1530.161
1544.811
1559.479
1574.166
1588.871
1603.594
1618.335
1633.094
1647.871
1662.665
1677.477

2.74822E-10
1.844E-10
1.13138E-10
6.16075E-11
2.81182E-11
9.41832E-12
1.4495E-12
6.32893E-14
1.61786E-12
3.40649E-12
3.89783E-12
2.79269E-12
9.21149E-13
1.62785E-14
2.40749E-12
1.06766E-11
2.73169E-11
5.4428E-11
9.34713E-11
1.451E-10
2.09074E-10
2.84251E-10
3.68657E-10
4.59611E-10
5.53897E-10
6.4797E-10
7.38163E-10
8.20902E-10
8.92899E-10
9.51319E-10
9.93915E-10
1.01912E-09
1.0261E-09
1.01478E-09
9.8579E-10
9.40452E-10
8.8066E-10
8.08791E-10
7.27584E-10
6.4001E-10
5.49145E-10
4.58048E-10
3.69641E-10
2.86609E-10
2.11314E-10
1.45724E-10
9.13658E-11
4.92977E-11
2.00957E-11

0.66
0.67
0.68
0.69
0.7
0.71
0.72
0.73
0.74
0.75
0.76
0.77
0.78
0.79
0.8
0.81
0.82
0.83
0.84
0.85
0.86
0.87
0.88
0.89
0.9
0.91
0.92
0.93
0.94
0.95
0.96
0.97
0.98
0.99
1

0.34
0.33
0.32
0.31
0.3
0.29
0.28
0.27
0.26
0.25
0.24
0.23
0.22
0.21
0.2
0.19
0.18
0.17
0.16
0.15
0.14
0.13
0.12
0.11
0.1
0.09
0.08
0.07
0.06
0.05
0.04
0.03
0.02
0.01
0

124.2307
124.5107
124.789
125.0656
125.3406
125.614
125.8858
126.1561
126.4248
126.692
126.9576
127.2219
127.4846
127.7459
128.0058
128.2642
128.5213
128.777
129.0313
129.2843
129.5359
129.7863
130.0353
130.2831
130.5296
130.7748
131.0189
131.2616
131.5032
131.7436
131.9828
132.2208
132.4576
132.6933
132.9279

591.9932
596.8895
601.7887
606.6909
611.5959
616.5039
621.4148
626.3285
631.2451
636.1645
641.0867
646.0117
650.9394
655.8699
660.8031
665.7389
670.6775
675.6187
680.5625
685.5089
690.4579
695.4094
700.3635
705.32
710.279
715.2405
720.2043
725.1706
730.1392
735.1101
740.0833
745.0588
750.0365
755.0165
759.9986

1692.307
1707.153
1722.017
1736.898
1751.796
1766.711
1781.643
1796.591
1811.556
1826.538
1841.536
1856.55
1871.581
1886.628
1901.69
1916.769
1931.864
1946.974
1962.099
1977.241
1992.397
2007.569
2022.756
2037.958
2053.175
2068.407
2083.654
2098.915
2114.19
2129.48
2144.784
2160.102
2175.435
2190.781
2206.141

RMS =

3.8641E-12
2.58676E-13
8.52537E-12
2.75507E-11
5.59201E-11
9.19847E-11
1.33929E-10
1.79843E-10
2.27789E-10
2.75866E-10
3.22275E-10
3.65364E-10
4.03679E-10
4.35996E-10
4.61351E-10
4.79053E-10
4.88693E-10
4.90143E-10
4.83543E-10
4.69285E-10
4.47989E-10
4.20474E-10
3.87718E-10
3.50831E-10
3.11006E-10
2.69488E-10
2.27531E-10
1.8636E-10
1.47142E-10
1.10949E-10
7.87353E-11
5.1313E-11
2.93359E-11
1.32863E-11
3.46842E-12
1.85034E-05

Txy Diagram
140
135

Bubble Curve

130
Dew Curve

125
120
115
110
105
100
95
90
0

0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9

Mole Fraction D