Chemistry 1045 Name: ID Number:

Exam 2 Lab Instructor

Fall 2012

1. These tests are machine grades; therefore, be sure to use a No. 1 or 2 pencil for marking the answer sheets. Completely blacken the answer circle. If you change an answer, erase the previous mark completely. 2. Write your last name (family name) in the first box of the section marked "NAME". Skip one box and then in the next box write your first name. Example: if a student's name is John L. Doe then his answer sheet would look like this: NAME (LAST FIRST, M.I. D | O| E O | H| N L If your whole name does not fit, put as much as will fit. Then blacken the corresponding letters below each space on the answer sheet. 3. Fill in your ID number in the space provided, beginning with 00 followed by your panther ID# in space "A". Column J will remain blank. Then blacken the circles corresponding to the numbers below each space. 4. In the "Grade or Educ" section, indicate the color of the test form you were given: Mark in Grade or Educ. Test Color Stripe Color Blue Blue 1 VI V2 Gold Yellow 2 V3 Gray Green 3 4 V4 Ivory Orange Pink V5 Pink 5 Brown 6 V6 Tan Make sure that you mark in "Grade or Educ" your test color, AND that the color mark above your name on the answer sheet is the same as your test color. It is your responsibility to make sure that colors match. You also need to fill in the test color number in the vertical strip next to the name field.
G R
A D E OR E D U C

In special Code column P, bubble in your section number, MWF9:30AM bubble 1 MWF 11:00 AM bubble 2 MWF 12:30 PM bubble 3 MWF 2:00 PM bubble 5 MW 6:25 PM bubble 6 The time limit on this test is about 1 hr 35 min. 2 hours less the administration time. READ THE TEST CAREFULLY. You should find 21 questions on the exam.

CHM 1045 EQUATIONS

1km = 0.6214 mi 1 atm = 760 mm Hg 1 m = 39.37 in = 1.094yds 1 mm Hg = 1 torr 1 in = 2.54 cms 1 kg = 2.205 Ibs 1 oz = 28.35 g KE = '/2 mv2 N A 6.022x10 23 q = nAH = 3*10 8 m/s = mcAT
c

Formula and Constant Sheet

l f t = 30.48 cm

c = Av

E = hv

E=

hc_

E =b

l l b = 453.59 g

h = 6.626* 10' 34 Js RH =1.097xlO~2

Cwater=4.184J/gC

H20 ~ gC

4.184.7

E = - 2 . 1 8 x l O - 1 8 J ( l / n 2 ) MW = 1 L.atm = 101.325 J 1 cal = 4.184 J R = 0.0821 L.atm/mol.K q = C x AT R = 8.314J/molK lL=1.057qt 1 gallon = 3.785 L

dRT P

PlVl_P2V2
n2T2

Pa = XaPT
; volcylMer =nr2h

d=

PM RT
] ]

Pressure(P) = F/A = m*a/A PV= nRT AE = q+ w w = - PAY q = AE+ PAY

-AH vap R T i2 T i}
J

where0 =8.85xlO' 12 C2/J.m

Periodic Table
IA

SA
2

H
1.01

He
4.00

2A
3 4

3A
5

4A
6

5A
7

6A
8

7A
9
10

Li
6.94

Be
9.01

B
10.81

C
12.01

N
14.01

O
16.00

F
19.00

Ne
20.18

11

12

13

14

15 P

16

17

18

Na
22.99

Mg
24.31 3B 4B
22

Al
26.98 SB
23

Si
28.09

s
32.06
34

Cl
35.45

Ar
39.95

30.97

B
24

7B
25

SB
26

SB
27

SB
28

IB
29

2B
30 31 32 33 35 36

19

20

21

K
39.10

Ca
40.08

Sc
44.96

Ti
47.87

V
50.94

Cr
52.00

Mn
54.94

Fe
55.85

Co
58.93

Ni
58.69

Cu
63.55

Zn
65.39
48

Ga
69.72

Ge
72.61

As
74.92

Se
78.96

Br
79.90

Kr
83.80

37

38

39

40

41

42

43

44

45

46

47

49

50

51

52

53 I

54

Rb
85.47

Sr
87.62

Y
88.91

Zr
91.22

Nb
92.91

Mo
95.94

Tc
(98)

Ru
101.07

Rh
102.91

Pd
106.42

Ag
107.87
79

Cd
112.41

In
114.82

Sn
118.71

Sb
121.76

Te
127.60

Xe
131.29

126.90

55

56

57

72

73

74

75

76

77

78 Pt

80

81

82

83

84

85

86

Cs
132.91

Ba
137.33

La
138.91

Hf
178.49

Ta
180.95

w
183.84
106

Re
186.21

Os
190.23

Ir
192.22

Au
196.97

195.08

200.59

Hg

TI
204.38

Pb
207.2

Bi
208.98

Po
(209)

At
(210)

Rn
(222)

87

88

89

104

105

107

108

109

Fr
(223)

Ra
(226)

Ac
(227)

Rf
(261)

Db
(262)

Sg
(266)

Bh
(264)

Hs
(269)

Mt
(268)

58

59

60

61

62

63

64

65

66

67

68

69

70

71

Ce
140.12

Pr
140.91

Nd
144.24

Pm
(145)

Sm
150.36

Eu
151.96

Gd
157.25

Tb
158.93

Dy
162.50

Ho
164.93

Er
167.26

Tm
168.93

Yb
173.04

Lu
174.97

(atomic mass) In parentheses refers to the atomic mass of the most stable isotope

90

91

92

Th
232.04

Pa
231.04

93

94

95

96

97

98

99

100

101

102

103

Np
(237)

Pu
(244)

Am
(243)

Cm
(247)

Bk
(247)

Cf
(251)

Es
(252)

Fm
(257)

Md
(258)

No
(259)

Lr
(262)

238.03

CHM 1045-A11 Sections

Exam 2A

Fall 2012

Unit 2

Stoichiometry, Aqueous Solutions, & Gas Laws

Chapters 3-5

1 . Which of the following statements is/are true? is a strong acid ii. NaH is a strong base iii. HC1O3 is a strong acid A. i only B . iii only C. i and iii EL i and ii LE/) ii and iii 2. Which of the following statements is/are true according to the Kinetic Molecular Theory? i. decreasing the amount of gas molecules decreases the pressure by decreasing the frequency of the collisions ii. increasing the temperature of a gas increases pressure by increasing the force of the collisions iii. decreasing the volume of a gas increases pressure by increasing the force of the collisions i only ii only iii only i and ii i and iii

J7

A. B. <C. D. E.

3 . Sulfuric acid cannot be stored in an aluminum container because sulfuric acid dissolves aluminum metal. The following equation shows the reaction: 2 Al(s) + 3 H2SO4 (aq) > A12(SO4)3 (aq) + 3 H2 / ^Calculate the volume of sulfuric acid that would be required to completely dissolve a 7.182 g block of aluminum if you were given a 0.92M H2SC>4 solution.

43402!
D. 468.74mL

A!

E. 399.30^

,
t

Page 1, vl

4. The ratio of effusion rates of some gas A to gas B is defined as: the rate of effusion of gas A/ rate of effusion of gas B.

What is the ratio of effusion rates of argon to chlorine? A. 0.750 B/1.77 /t. 0.560 V Ax1-93 (E?)1.33
5. A flasjc contains 14.182 grams of nitrogen monoxide (NO), 19.628 grams of carbon dioxide and 29.543 grams of sulfur trioxide (SO3). The total pressure in the flask is measured 25.9 atm. What is the partial pressure of nitrogen monoxide in the flask?

o
o

A. 15.0 atm
B. 8.97 atm CL 7.42 atm (by 9.51 atm E. 5.80 atm

|U

-X \

6. Which of the following statements is/are true? . Agl is insoluble l/ii. Co(C2H3O2)2 is soluble is insoluble . . A. B. C. . ionly i,iiandi ii and iii i and iii ) i and ii

<f

7. Calculate the amount of 0.138 M phosphoric acid, H3?O4, that would be required to 'completely neutralize 28.625 mL of 0.228 M sodium hydroxide. \\u \i

r4Q3POM#Vlxo

ffc,^ V

AX7.293mL 0 ^ 23.647 mL

8. If 8.558 g of nitrogen is allowed to react with 2.236 g of hydrogen at 0fi$C and the percent yield for the reaction is 42.56%, how much ammonia would be produced? The reaction proceeds as follows: N 2 (g) + 3H 2 (g)> 2NH 3 (g) A. 5.352 g B. 10.41 g C. 12.58 g . 3.633 g V.430 g

p . Page , 2, vl

A solution is created by dissolving 8.2.87 grams of potassium permanganate,KMnO4, in water to a final volume of 53.8 mL. What is the molarity of ions in this solution?

" "

C. 0.978 M
/ Eb N 0.154M

(EJ1.95M

10.

Consider the following reaction equations. Which is/are redox reactions? (s) + 6NaOH (aq) --;> 2Na3BO3 (aq) + H2O (1)
xv

,\. Mne2H3O2)2 (aq) + 2LiOH (aq) -

u (s) + 4HNO3 (aq) ----> Cu(NO3)2 (aq) + 2NO2 (g) + 2H2O (1)

--O
tQ

C J iii only i and ii E. i and iii

11. Aereosol cans carry warnings against incineration because of the high pressures that can

^velop upon heating. Suppose you have a can that contains a residual amount of gas at a 'pressure of 550 mmHg and a temperature of 25 C. What would the pressure be if the can j> were heated to 1025 C? p /- J\' A. . C. D. E. 3.15 atm 29.7 atm 2.25 x 104 atm 0.166 atm 2.49 atm
^ _

1^

55O
"^ ^~

-MMK

, is)

12. If you were to add together ALL of the coefficients after balancing the following chemical equation it would be (note: please treat a compound without a coefficient as 1) J_C 3 H 5 (OH) 3

-H20
L (S

'

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13. Copper can be "roasted" from ore to form copper(I) oxide through the following reaction: 2Cu2S + 3O2 > 2Cu2O + 2SO2 How much copper(I) oxide could be formed theoretically from 12.0 g of Cu2S reacted with excess oxygen gas? 12.0 g BJlO.Sg 13-3 g D. 5.39 g E. 7.19 g 14. Which of the following would be a strong electrolyte: i.HCl V"* ii. H2H3O2 X aClO4 A. i only B. ii only CL i and ii b. j i and iii E: ii and iii 15. An unknown gas is weighed and found to have a density of 5.6564 g/L at a temperature of 8.26C and a preure of 4.655 atm. Which of the following is the best choice for the identity of the / A. Ar B. NO2

T>

E. c3H8

ras.037

16./Calculate the concentration of an oxalic acid (^^204) solution when 80.7 mL of water is added to 28.2 mL of a 2.39 M oxalic acid solution? ^B. 0.619 M D. 1.28M E. 9.23 M

e: 1.77 M

Page4,vl

17. Lithium nitride, Li3N is an interesting salt. It is a fast ion condutor and it has also been studied as an anode material for batteries. Lithium nitride is produced according to the following reaction: 6 Li (s) +N2(g) > 2 Li3N (s) If the percent yield of this reaction at 75.00 C is 56.25% and the reaction yields 13.625 g of lithium nitride from an experimental quantity of lithium, how much lithium nitride would theoretically be expected in the experiment? j 3 .fc> S TV n'*> ^ ~ A. 0.413g 7.664 g 27.89 g 24.22g E. 15.74 g O'S^^S 9M-^'

18. Automobile air bags inflate following a serious impact. The impact triggers the following chemical reaction 2NaN3 (s) -> 2Na (s) + 3N2 (g) If an automobile airbag has a volume of 8.40 L, what mass of NaN3 is required to fully inflate the ah^oag upon impact under conditions of atmospheric pressure (1.00 atm) and room terflperature(25C).
'/F^ 111 A g (B./14.88 g Tl 33.49 g D. 9.620 g E. 22.32 g

19. Consider a gas in a container with an initial pressure,'temperature and volume. What will happen to the pressure of the gas if the number of moles are increased 7 times (7x), the vojmne is tripled and the temperature is quadruple. the pressure will increase by 9.3 times the pressure will increase by 5.3 times C. the pressure will remain unchanged D. the pressure will increase by 1.7 times E. the pressure will increase by 14 times

/ | j , \ 0 >0$*

20. Which of the following statements is true regarding straight chain hydrocarbons?

/ i.

the chain containing 7 carbons and one double bond is named heptene ii. the chain containg 4 carbon bonds and only single bonds is named propane iii. CH3(CH2)4CH3 is named hexane

i only iii only i and iii i and ii E. ii and iii

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