Documenti di Didattica
Documenti di Professioni
Documenti di Cultura
BY M. Osama Adil Rabia Raza Khan Noureen Naz PP-30 PP-19 PP-37
Group-8
Overview
Introduction Polyurethane Foam and their Chemistry Applications Selection Aims and Objectives Mold and Tools Designing Experiments Testing Results and Comparison Profit Estimation Conclusion and Future Work
03/12/2012
Introduction
Foam Classification of f oam o Open cell foam
03/12/2012
03/12/2012
1) Isocyanates
03/12/2012
03/12/2012
03/12/2012
Applications Selection
Major automotive applications of PU Foam we discussed 1. Tyres 2. Headliners 3. Seats
SEATS
Car Seats
Final Selection
Bike Seats
03/12/2012
Applications Selection
Comparison between bike seat and car seat
Motorbike Seat 1. Product divisions 1 Part: Seat Car Seat 4 Parts: Seat base, Backrest, Headrest and Armrest Supports More than 3000 PKR
So after doing general feasibility analysis, bike seat was selected to proceed our project
03/12/2012
10
disturbing its mechanical properties o To reduce the production cost of PU foam for bike seats
03/12/2012
11
03/12/2012
12
03/12/2012
13
03/12/2012
2 14
03/12/2012
15
03/12/2012
16
03/12/2012
17
Experiments
Composition of reactants Composition of Polyol Composition of Isocyanate
Components
Polyol
Co-polymer polyol Silicon Surfactant
Parts by weight
70.000
30.000 1.000
Component
ELASTOFLEX Diphenylmethane4,4'-diisocyanate (MDI)
Parts by weight
90
Water, Blowing agent Dimethanol Amine, Pure, Chain Extender Amine Catalyst Tin Catalyst
4.2000 1.700
0.1
10
0.5
03/12/2012
19
Experiments
Formulations
Sample No Polyol (A) (gm) Isocyanate (B) (gm) Mixing time (sec) Curing time (min) Mixing Speed (rpm) Foam Weight (gm) Density (lb/ft3) A/B Ratio Remarks
A1 A2 A3 A4 A5
30 30 30 30 30
15 16 17 18 19
5 5 5 5 5
4 4 4 4 4
Polyol remains in bottom Still Polyol remains in bottom Polyol odor in foam
A6
A7 A8 A9 A10 A11 A12 A13 A14
30
30 30 30 30 30 30 30 30
20
21 22 23 24 25 26 27 28
5
5 5 5 5 5 5 5 5
4
4 4 4 4 4 5 5 7.8
700
700 700 700 700 700 700 700 700
24.55
24.06 23.56 23.71 24.7 26.13 27.45 27.82 28.1
3.4539
3.3947 3.3242 3.3453 3.4850 3.6868 3.8730 3.9252 3.9647
1.5
1.42 1.36 1.30 1.25 1.20 1.15 1.11 1.07 Unstable Unstable, yellowish, isocyanate is visible Fail, Settling time is very high, unstable Fail, Iso everywhere un-reacted
A15
30
29
700
28.26
3.9873
1.03
A16
30
30
Infinity
700
28.49
4.0198
03/12/2012
20
Experiments
Formulations
Sample No B1 Polyol (A) (gm) 30 Isocyanate (B) (gm) 15 Mixing time (sec) 3 Curing time (min) 4 Mixing Speed (rpm) 875 Foam Weight (gm) 25.97 Density (lb/ft3) 3.6642 A/B Ratio 2 Remarks Polyol remains in bottom, Still Polyol remains in bottom Polyol odor in foam
B2
30
16
875
25.49
3.5965
1.87
B3
30
17
875
24.85
3.5062
1.76
30 30 30 30 30 30 30 30 30 30 30
18 19 20 21 22 23 24 25 26 27 28
3 3 3 3 3 3 3 3 3 3 3
4 4 4 4 4 4 4 4 4 6 8.5
875 875 875 875 875 875 875 875 875 875 875
24.67 24.41 24.25 24.02 23.91 24.55 25.46 26.93 27.38 28.08 28.23
3.4808 3.4441 3.4215 3.3891 3.3736 3.4639 3.5922 3.7997 3.8632 3.9619 3.9831
1.66 1.57 1.5 1.42 1.36 1.30 1.25 1.2 1.15 1.11 1.07
Unstable Unstable, yellowish, isocyanate is visible Fail, Settling time is very high, unstable
B15
30
29
Infinity
875
28.57
4.0311
1.03
B16
30
30
Infinity
875
28.74
4.0550
Fail, Isounreacted
03/12/2012
21
Experiments
Formulations
Sample No Polyol (A) Isocyanate (B)
(gm)
(gm)
Mixing time Curing time Mixing Foam Density (sec) (min) Speed (rpm) Weight (gm) (lb/ft3)
C1
30
15
1050
26.47
3.7348
C2
30
16
1050
25.81
3.6416
1.87
30 30 30 30 30 30 30 30 30 30 30 30
17 18 19 20 21 22 23 24 25 26 27 28
3 3 3 3 3 3 3 3 3 3 3 3
4 4 4 4 4 4 4 4 4 4 6 8.5
1050 1050 1050 1050 1050 1050 1050 1050 1050 1050 1050 1050
25.36 24.72 24.51 24.27 24.02 23.87 23.92 24.01 25.67 26.74 27.32 27.65
3.5781 3.4878 3.4582 3.4243 3.3891 3.3679 3.3750 3.3877 3.6219 3.7729 3.8547 3.9012
1.76 1.66 1.57 1.5 1.42 1.36 1.30 1.25 1.2 1.15 1.11 1.07
C15
30
29
Infinity
1050
27.92
3.9393
1.03
Unstable Unstable, yellowish isocyanate is visible Fail, Settling time is very high, unstable Fail, Iso- unreacted
C16
30
30
Infinity
1050
28.13
3.9690
03/12/2012
22
Experiments
Observations
Density (lb/ft3) 4 Density (lb/ft3) 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 Isocyanate (gm) 4.5 4.2 4 3.8 3.6 3.4 3.2 3 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 Isocyanate (gm)
3.5
3
Graph of A Series Samples -Iso (gm) vs. Density (lb/ft3) at 700 rpm
4.2 4 3.8 3.6 3.4 3.2 3
Graph of B Series Samples -Iso (gm) vs. Density (lb/ft 3) at 875 rpm
Density (lb/ft3)
15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 Isocyanate (gm)
Graph of C Series Samples -Iso (gm) vs. Density (lb/ft 3) at 1050 rpm
03/12/2012
23
03/12/2012
24
Density
4 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3 Sample Sample Sample Average 1 2 3
03/12/2012 Automotive application of polyurethane foam 25
IFD
1000 900 800 700 600 500 400 300 200 100 0
Comfort Factor
0.5 0.4
lbf/50 in2
OEM's Foam
ALTERED FOAM
0.3 0.2
0.1
0
IFD@25%
IFD@65%
Comfort Factor
03/12/2012
26
200 180
160
140
CFD (Kgf)
120 100 80
60
40 20 0
6 5 4 3 2 1 0
Tear resistance
0.31
0.3 0.29 0.28 0.27
0.26
0.25
Profit Estimation
1. Density
1. Seat Weight 1. Seat Volume
3.85 lb/ft3
1.76 lbs 0.458 ft3
3.34 lb/ft3
1.53 lbs 0.458 ft3
1. Polyol/Iso Ratio
1/0.85
1/0.73
03/12/2012
30
Profit Estimation
13.07 %
13.07% X 0.13X
X-0.13X
Y Y+0.13X
03/12/2012
31
Conclusion
Successfully reduced foam density Better mechanical properties of reduced density foam are achieved
03/12/2012
32
Future Work
03/12/2012
33
03/12/2012
35