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III. Apparatus of experiment
- Calorimeter,
- Stirrer,
- Thermometer,( with SMS1
o
C)
- Steam generator,
- Balance (SMS of balance 0.01 gr)
- Metal sample (Copper, Lead, Iron)
- Water.
IV. Experimental Procedure
1. Fill the heater with water until cover the metal samples.
2. While waiting for hot water, then measure the mass of copper and empty cup calorimeter
with Balance.
3. Then put the copper into the heater (after boiling), hanging the copper a few inches from
the bottom of the heater to avoid direct contact with the plate heater. Copper metal must be
completely entered into the water, but do not touch the bottom plate or the wall heater
4. Next step is pouring cold water (temperature below room temperature) into the calorimeter
and filled with enough water (until half of calorimeter).and measure the calorimeter
containing water into the insulation wrap, then measure the water temperature with a
thermometer.
5. Move quickly the Copper metal into the calorimeter from the heating without water wetted
and the stirring the water in the calorimeter, and record the temperature of equilibrium that
occurs in calorimeter.
6. Repeat steps 2-5 for Lead, and Iron.
V. An arrangement of data
No Measurement Copper( Cu) Lead (Pb) Iron
1 Mass of cube ..gr ..gr ..gr
2 Mass of calorimeter + stirrer (m
1
) ..gr ..gr ..gr
3 Mass of calorimeter + stirrer + water ..gr ..gr ..gr
4 Initial water temperature (t
1
) ..
o
C ..
o
C ..
o
C
5 Final temperature observed ..
o
C ..
o
C ..
o
C
6 Final temperature, for cooling (t
2
) ..
o
C ..
o
C ..
o
C
7 Temperature of boiling water (t) ..
o
C ..
o
C ..
o
C
VI. Technique of data analysis (Calculation)
For measurement using balance with smallest scale 0.001 gram, to determine the mass we
using equation:
SMS m m m m
2
1
t t
For measurement using Thermometer with smallest scale 1
0
C, to determine the mass we
using equation:
SMS t t t t
2
1
t t
To determine the specific heat of metal sample we use equation:
( )
) (
) ( . .
c h metal metal
c f cal cal water water
metal
T T c m
T T c m c m
c
+
+
1
]
1
+
2
1
2
2 1
3 2 1 1 2
2
2 1
3 2 1 1
3 2 1 3 2 1 1
) t - t ( M
) t - t ( ) c m m (
) t - t ( M
) t - t ( ) c m m (
m m c
t t mM t t Mt m
+
1
]
1
+
+
1
]
1
+
2
3
2
2 1
3 2 1 1 2
2
2 1
3 2 1 1
2 1 1
1
3 2 1
) t - t ( M
) t - t ( ) c m m (
) t - t ( M
) t - t ( ) c m m (
t M
t Mt mm t t mm
2
2
2
2 1
3 2 1 1
2
1
2
2 1
3 2 1 1
3 1 1 3 2 1
) t - t ( M
) t - t ( ) c m m (
) t - t ( M
) t - t ( ) c m m (
t t
t Mt mm t Mt mm
1
]
1
+
+
1
]
1
+
+
+ +
2
2
2 1
2
3 2 1 1
2
1
2
2 1
3 2 1 2
2
2 1
3 2
) t - t ( M
) t - t ( ) c m m (
) t - t ( M
) t - t (
) t - t ( M
) t - t (
M m
c
m c
2
2
2
2
2 1
3 2 1 1
2
1
2
2
2 1
3 2 1 1
2
3
2
2 1
1 1
) t - t ( M
) t - t ( ) c m m (
) t - t ( M
) t - t ( ) c m m (
) t - t ( M
c m m -
t t t
+
+
+
+
c
c
x 100 %
VII. Experiment result
No Measurement Copper Cube Lead Cube Iron Cube
1 Mass of Cube
62.55 gr 67.70 gr 23.50 gr
2 Mass of Calorimeter + Stirrer (m
1
)
56.75 gr 81.50 gr 82.82 gr
3 Mass of Calorimeter + Stirrer + Water (m
1
+ m )
178.90 gr 189.41 gr 199.93 gr
4 Initial Water Temperature
26
0
C 26
0
C 26
0
C
5 Final Temperature Observer
29
0
C 29
0
C 29.5
0
C
6 Final Temperature, corrected for cooling (t
2
) 29
0
C 29
0
C 28.5
0
C
7 Temperature of boiling water (t
1
)
104
0
C 100
0
C 100
0
C
VIII. Data Analysis
A. For Lead Cube :
No Measurement Lead Cube
1 Mass of Cube 67.70 gr
2 Mass of Calorimeter + Stirrer (m1)
81.50 gr
3 Mass of Calorimeter + Stirrer + Water (m1 + m )
189.41 gr
4 Initial Water Temperature
26
0
C
5 Final Temperature Observer 29
0
C
6 Final Temperature, corrected for cooling (t
2
) 29
0
C
7 Temperature of boiling water (t
1
) 100
0
C
a. Mass of Lead
M M M t
01 , 0
2
1
70 . 67
2
1
t t SMS M M
M = (67.70 0,005) gram
b. Mass of Water
To find mass of water we subtract
mass of calorimeter that contain with
water with mass of calorimeter (189.41-
81.50 = 97.91 gram)
m m m t
0,01
2
1
97.91
2
1
t SMS m m
m= (97.91 0,005) gram
c. Mass of Calorimeter + Stirrer
1 1 1
m m m t
0,01
2
1
81.50
2
1
1 1
t SMS m m
m
1
= (81.50 0.005) gram
d. Temperature of initial Lead
1 1 1
t t t t
1
2
1
100
2
1
1 1
t SMS t t
t
1
= (100.0 0,5)
0
C
e. Initial temperature of water
t
3
=
3 3
t t t
t
3
= t
3
2
1
SMS= (26.0
2
1
1)
t
3
= (26.0 0,5)
0
C
f. Equilibrium Temperature of Lead and
Water:
t
2
=
2 2
t t t
t
2
= t
2
2
1
SMS=(29.0
2
1
1)
0
C
t
2
= (29.0 0,5)
0
C
c = c =
) t - t ( M
) t - t ( c ) m m (
2 1
3 2 1 1
+
c =
29.0) - (100.0 67.70
26.0) - (29.0 0,215 x 81,50) (97.91+
c
=
3
4.8x10
115.72
c = 0.024
c gr
kal
0
c =
+
+
+ +
2
2
2 1
3 2 1 1
2
1
2
2 1
3 2 1
2
2
2 1
3 2
) t - t ( M
) t - t ( c . ) m m (
) t - t ( M
) t - t (
) t - t ( M
) t - t (
M m
c
m
2
2
2
2
2 1
3 2 1 1
2
1
2
2
2 1
3 2 1 1
2
3
2
2 1
1 1
) t - t ( M
) t - t ( ).c m m (
) t - t ( M
) t - t ( ).c m m (
) t - t ( M
)c m m (-
t t t
+
+
+
+
c =
2
2
2
2
) 005 , 0 (
29.0) - (100.0 67.70
26.0) - 0,215(29.0
) 005 , 0 (
29.0) - (100.0 67.70
26.0) - (29.0
+
2
2
2
2
) 5 , 0 (
29.0) - (100.0 67.70
0.215 )x 81,50 (-97.91
) 005 , 0 (
29.0) - (100.0 67.70
26.0) - (29.0 0.215 x 81.50) (97.91
+
+
+
2
2
2
2
) 5 , 0 (
29.0) - 0 67.70(100.
26.0) - (29.0 0.215 x 81.50) (97.91
) 5 , 0 (
29.0) - (100.0 67.70
26.0) - (29.0 0.215 x 81.50) (97.91 +
+
+
+
c=
25 , 0 10 02 . 8 10 5 , 2 10 40 . 2 10 5 , 2 10 34 . 1 10 5 , 2 10 24 . 6
2
3 5
2
2 5
2
4 5
2
4
+ + + x x x x
25 , 0 10 40 . 2 25 , 0 10 40 . 2
2
2
2
2
+ + x x
c =
4 4 5 8 13 12
10 44 . 1 10 44 . 1 10 60 . 1 10 44 . 1 10 48 . 4 10 74 . 9
+ + + + + x x x x x
c =
4
10 04 . 3
c = 0.017
c gr
kal
0
c =
c c t
= (0,024 0,017)
c gr
kal
0
Relative error:
RE =
,
_
c
c
x 100 %
RE =
,
_
024 . 0
017 . 0
x 100 %
RE = 70%
B. For Copper Cube :
No Measurement Copper Cube
1 Mass of Cube 62.55 gr
2 Mass of Calorimeter + Stirrer (m1)
56.75 gr
3 Mass of Calorimeter + Stirrer + Water (m1 + m )
178.90 gr
4 Initial Water Temperature
26
0
C
5 Final Temperature Observer 29
0
C
6 Final Temperature, corrected for cooling (t
2
) 29
0
C
7 Temperature of boiling water (t
1
) 104
0
C
a) Mass of Copper
M = M M t
01 , 0
2
1
50 . 62
2
1
t t SMS M M
M = (62.55 0,005) gram
b) Mass of Water
To find mass of water we subtract
mass of calorimeter that contain with
water with mass of calorimeter (178.90-
56.75 = 122.15 gram)
m = m m t
m= m
2
1
SMS = (122.15
2
1
0,01)
m= (122.15 0,005) gram
c) Mass of Calorimeter + Stirrer
1 1 1
m m m t
0,01
2
1
56.75
2
1
1 1
t SMS m m
m
1
= (56.75 0,005) gram
d) Temperature of initial Copper
t
1
=
1 1
t t t
t
1
= t
1
2
1
SMS = (104.0
2
1
1)
0
C
t
1
= (104.0 0,5)
0
C
e) Initial temperature of water
t
3
= 3 3
t t t
t
3
= t
3
2
1
NST = (26.0
2
1
1)
0
C
t
3
= (26.0 0,5)
0
C
f) Equilibrium Temperature of Copper
and Water:
t
2
=
2 2
t t t
t
2
= t
2
2
1
SMS = (29.0
2
1
1)
0
C
t
2
= (29.0 0,5)
0
C
c = c =
) t - t ( M
) t - t ( c ) m m (
2 1
3 2 1 1
+
c =
3
4.4x10
115.4
29.0) - (104.0 62.55
26.0) - (29.0 0.215 x 56.75) (122.15
+
c = 0.026
c gr
kal
0
c =
+
+
+ +
2
2
2 1
3 2 1 1
2
1
2
2 1
3 2 1
2
2
2 1
3 2
) t - t ( M
) t - t ( c . ) m m (
) t - t ( M
) t - t (
) t - t ( M
) t - t (
M m
c
m
2
2
2
2
2 1
3 2 1 1
2
1
2
2
2 1
3 2 1 1
2
3
2
2 1
1 1
) t - t ( M
) t - t ( ).c m m (
) t - t ( M
) t - t ( ).c m m (
) t - t ( M
)c m m (-
t t t
+
+
+
+
c=
2
2
2
2
) 005 , 0 (
29.0) - (104.0 62.55
26.0) - 0,215(29.0
) 005 , 0 (
29.0) - (104.0 62.55
26.0) - (29.0
+
2
2
2
2
) 5 , 0 (
29.0) - (104.0 62.55
0.215 )x 56.75 (-122.15
) 005 , 0 (
29.0) - (104.0 62.55
26.0) - (29.0 0.215 x 56.75) (122.15
+
+
+
2
2
2
2
) 5 , 0 (
29.0) - (104.0 62.55
26.0) - (29.0 0.215 x 56.75) (122.15
) 5 , 0 (
29.0) - (104.0 62.55
26.0) - (29.0 0.215 x ) 75 . 56 (122.15 +
+
+
+
c=
25 , 0 10 20 . 8 10 5 , 2 10 46 . 2 10 5 , 2 10 38 . 1 10 5 , 2 10 40 . 6
2
3 5
2
2 5
2
4 5
2
4
+ + + x x x x
25 , 0 10 46 . 2 25 , 0 10 46 . 2
2
2
2
2
+ + x x
c =
4 4 5 8 13 11
10 52 . 1 10 52 . 1 10 68 . 1 10 52 . 1 10 76 . 4 10 02 . 1
+ + + + + x x x
c =
4
10 2 . 3
c = 0.017
c gr
kal
0
c = c c t
c = (0.0262 0.017)
c gr
kal
0
Relative error:
RE=
,
_
c
c
x 100 %
RE =
,
_
0262 . 0
017 . 0
x 100 %
RE = 64%
C. For Iron Cube :
No Measurement Iron Cube
1 Mass of Cube 23.50 gr
2 Mass of Calorimeter + Stirrer (m1)
82.82 gr
3 Mass of Calorimeter + Stirrer + Water (m1 + m )
199.93 gr
4 Initial Water Temperature
26
0
C
5 Final Temperature Observer 29.5
0
C
6 Final Temperature, corrected for cooling (t
2
) 28.5
0
C
7 Temperature of boiling water (t
1
) 100
0
C
a) Mass of Iron
M = M M t
M= M
2
1
NST = (23.50
2
1
0,01) gram = (23.50 0,005) gram
b) Mass of Water
To find mass of water we subtract mass of
calorimeter that contain with water with
mass of calorimeter (199.93-82.82 =
117.11 gram)
m = m m t
m= m
2
1
NST = (117.11
2
1
0,01) gr
m= (117.11 0,005) gram
c) Mass of Calorimeter + Stirrer
1 1 1
m m m t
0,01
2
1
82.82
2
1
1 1
t SMS m m
m
1
= (82.82 0,005) gram
d) Temperature of initial Iron
t
1
=
1 1
t t t
t
1
= t
1
2
1
SMS = (100.0
2
1
1)
0
C
t
1
= (100.0 0,5)
0
C
e) Initial temperature of water
t
3
= 3 3
t t t
t
3
= t
3
2
1
SMS
= (26.0
2
1
1)
0
C
t
3
= (26.0 0,5)
0
C
f) Equilibrium Temperature of Iron and
Water:
t
2
=
2 2
t t t
t
2
= t
2
2
1
SMS
= (29.5
2
1
1)
0
C
t
2
= (29.5 0,5)
0
C
c = c =
) t - t ( M
) t - t ( c ) m m (
2 1
3 2 1 1
+
c =
29.5) - (100.0 23.50
26.0) - (29.5 0.215 x ) 82 . 82 (117.11+
c =
3
1.65x10
150.4
c = 0.091
c gr
kal
0
c =
+
+
+ +
2
2
2 1
3 2 1 1
2
1
2
2 1
3 2 1
2
2
2 1
3 2
) t - t ( M
) t - t ( c . ) m m (
) t - t ( M
) t - t (
) t - t ( M
) t - t (
M m
c
m
2
2
2
2
2 1
3 2 1 1
2
1
2
2
2 1
3 2 1 1
2
3
2
2 1
1 1
) t - t ( M
) t - t ( ).c m m (
) t - t ( M
) t - t ( ).c m m (
) t - t ( M
)c m m (-
t t t
+
+
+
+
c =
2
2
2
2
) 005 , 0 (
28.5) - (100.0 23.50
26.0) - 0,215(28.5
) 005 , 0 (
28.5) - (100.0 23.50
26.0) - (28.5
+
2
2
2
2
) 5 , 0 (
28.5) - (100.0 23.50
0.215 )x 82 . 82 (-117.11
) 005 , 0 (
28.5) - (100.0 23.50
26.0) - (28.5 0.215 x 82.82) (117.11
+
+
+
2
2
2
2
) 5 , 0 (
28.5) - (100.0 23.50
26.0) - (28.5 0.215 x 82.82) (117.11
) 5 , 0 (
28.5) - (100.0 23.50
26.0) - (28.5 0.215 x 82.82) (117.11 +
+
+
+
c =
25 , 0 10 56 . 2 10 5 , 2 10 40 . 6 10 5 , 2 10 20 . 3 10 5 , 2 10 48 . 1
2
2 5
2
2 5
2
4 5
2
3
+ + + x x x x
25 , 0 10 40 . 6 25 , 0 10 40 . 6
2
2
2
2
+ + x x
c =
3 3 4 7 12 11
10 02 . 1 10 02 . 1 10 64 . 1 10 02 . 1 10 56 . 2 10 48 . 5
+ + + + + x x x x x
c =
3
10 2 . 2
c = 0.046
c gr
kal
0
c = c c t
c = (0,091 0,046)
c gr
kal
0
Relative error:
RE =
,
_
c
c
x 100 %
RE =
,
_
091 . 0
046 . 0
x 100 % = 50.5 %
Table Result Calculation
NO Metal Sample Specific Heat (cal /gram
o
C)
1 Lead Cube 0,024 0,017
2 Copper Cube 0.026 0.017
3 Iron Cube 0,091 0,046
IX. Interpretation
Specific heat from the theory as the table:
NO Material Specific Heat (cal /gram
o
C)
1 Lead Cube 0,031
2 Copper Cube 0.092
3 Iron Cube 0,107
A.
To find %error for Lead is following equation:
% 100 % x
Value Theory
Value Theory Value Experiment
error
% 100
031 . 0
031 . 0 024 . 0
% x error
% 100 22 . 0 % x error
% 22 % error
The magnitude of specific heat of Lead that we get from experiment is 0.024 cal/gr
o
C.
While, the specific heat of lead from the theory is 0.031 cal/gr
o
C. Error in this experiment is
high because the are much mistake when we done this experiment. Error in experiment using
Metal sample lead is 22%. because the error more than 10%, so this experiment cant be
accepted or will be rejected.
In this experiment that we done has relative error 70%, so this result not accurately and
this experiment is failed.
B.
To find %error for Copper is following equation:
% 100 % x
Value Theory
Value Theory Value Experiment
error
% 100
092 . 0
092 . 0 026 . 0
% x error
% 71 % 100 71 . 0 % x error
The magnitude of specific heat of copper that we that from experiment is 0.026 cal/gr
o
C.
While, the specific heat of lead from the theory is 0.092 cal/gr
o
C. Error in this experiment is
high because the are much mistake when we done this experiment. Error in experiment using
Metal sample lead is 71%. because the error more than 10%, so this experiment cant be
accepted or will be rejected.
In this experiment that we done has relative error 64%, so this result not accurately and
this experiment is failed.
C.
To find %error for Iron is following equation:
% 100 % x
Value Theory
Value Theory Value Experiment
error
% 100
107 . 0
107 . 0 091 . 0
% x error
% 14 % 100 14 . 0 % x error
The magnitude of specific heat of iron that we that from experiment is 0.091 cal/gr
o
C.
While, the specific heat of lead from the theory is 0.107 cal/gr
o
C. Error in this experiment is
high because the are much mistake when we done this experiment. Error in experiment using
Metal sample lead is 14%. because the error bigger than 10%, so this experiment cant be
accepted or will be rejected.
In this experiment that we done has relative error 50.5%, so this result not accurately and
this experiment is failed.
X. Comment
There are several constraints that occur when we done the experiment, such as when moving
the sample of metal from the heater into calorimeter, the heat from the metal is reduced because
water wetting the metal evaporates into the environment.
Another constraints is about sensitivity of the instrument such as thermometer and balance, in
this experiment the balance that we use not in good condition and the thermometer that we use
has bigger smallest scale(1
0
C) so not to accurately.
Data that we analysis is in decimal number so when we calculation that data the risk of error
in the calculation will be greater.
The largest error source is from the among water that we use is too much so the temperature
increase relatively small and error is offset by a large SMS(smallest scale) of the thermometer so
that the relative error and %error of the experiment is very high. Recommended in next
experiments must using a bits of water.
From the experiment that we have done, the result of the experiment is not accurately and the
value doesnt approach with the theory, its caused by some error that we have when this
experiment did. The error is classified to three, there are:
1. Gross Error (error that caused by human):
among them is missreading when read the scale of the balance and thermometer, and fault
when we calculate the data in analysis the data because the data is in decimal.
2. Systematic errors (error that caused by instrument and environment):
a) Instrumental error: the error that occurs because of tools didnt work, in this
experiment the tool (balance) is not exactly in god condition and not in friction less.
b) Enviromental error: the error that occur because of the disturbance of enviroment such as
the temperature not constant.
3. Random error : due to unknown causes and occur even when all systematic error have been
accounted for
XI. Conclusion
From the experiment that we done we get that the value of specific heat Lead is 0.026 cal/gr
o
C, with accuracy 22%, and relative error 70%. The value of specific heat Copper is 0.026 cal/gr
o
C, with accuracy 71%, and relative error 64%.The value of specific heat Iron is 0.091 cal/gr
o
C,
with accuracy 14%, and relative error 50.5%.
The specific heat of iron is bigger than copper and the specific heat of copper bigger than
Lead.
Questions and Solution:
1. What can you conclude about measuring specific heat of metal?
Solution:
From the experiment that we done we get that the value of specific heat Lead is 0.026 cal/gr
o
C, with accuracy 22%, and relative error 70%. The value of specific heat Copper is 0.026 cal/gr
o
C, with accuracy 71%, and relative error 64%.The value of specific heat Iron is 0.091 cal/gr
o
C,
with accuracy 14%, and relative error 50.5%.The specific heat of iron is bigger than copper and
the specific heat of copper bigger than Lead.
2. Explain the errors of this experiment!
Solution:
1. Gross Error (error that caused by human): among them is missreading when read the scale
of the balance and thermometer, and fault when we calculate the data in analysis the data
because the data is in decimal.
2. Systematic errors (error that caused by instrument and environment):
a) Instrumental error: the error that occurs because of tools didnt work, in this
experiment the tool (balance) is not exactly in god condition and not in friction less.
b) Enviromental error: the error that occur because of the disturbance of enviroment such
as the temperature not constant.
3. Random error : due to unknown causes and occur even when all systematic error have been
accounted for
3. Calculate the percentage errors (the order of accuracy) of this experiment!
To find %error for Lead is following equation:
% 100 % x
Value Theory
Value Theory Value Experiment
error
% 100
031 . 0
031 . 0 024 . 0
% x error
% 22 % 100 22 . 0 % x error
To find %error for Copper is following equation:
% 100 % x
Value Theory
Value Theory Value Experiment
error
% 100
092 . 0
092 . 0 026 . 0
% x error
% 71 % 100 71 . 0 % x error
To find %error for Iron is following equation:
% 100 % x
Value Theory
Value Theory Value Experiment
error
% 100
107 . 0
107 . 0 091 . 0
% x error
% 14 % 100 14 . 0 % x error
Reference
Djonoputro, B.D. 1977. Teori Ketidakpastian. Bandung: Universitas ITB.
Halliday, D., Resnick, R., and Walker, J. (1993), Fundamentals of Physics, 4th edn (extended),
John Wiley & Sons, New York.
Unname.Measure of specific heat. (online)http://www.utc.edu/Faculty/Harold-Climer/
Sheatlab.pdf be access on April 14
th
2011.
Unname.Lab report.(online). http://www.physics.uc.edu/~bortner/labs/sample_lab_report/Lab
%20 Report.htm be access on April 14
th
2011
Unname.Specific of Heat. (online) http://phoenix.phys.clemson.edu/labs/223/spheat/index.html
be access on April 14
th
2011.
Measurement of Specific Heat
(Physics Laboratory II)
Lab Report
WRITTEN BY,
KOMANG GEDE YUDI ARSANA (NIM. 1013021018)
PHYSICS DEPARTMENT OF EDUCATION
FACULTY OF MATHEMATIC AND SCIENCE
GANESHA UNIVERSITY OF EDUCATION
April 2011