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2. COMPOSITION/INFORMATION ON INGREDIENTS
Natural Gasoline C4-C8 is a complex combination of saturated aliphatic hydrocarbons (predominantly C2 through C8) separated as a liquid from natural gas in a gas recycling plant, by processes such as refrigeration or absorption. Product information:
Name CAS Number Weight % ACGIH Exposure Limits: = 300 ppm TWA = 500 ppm STEL OSHA - Vacated PELs - Time Weighted Ave = 300 ppm TWA = 900 mg/m3 TWA = 1500 mg/m3 STEL = 500 ppm STEL Other:
8006-61-9
100
Component Information:
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Name
CAS Number
Weight %
Normal Butane
106-97-8
1-50
Iso-Pentane Propane
78-78-4 74-98-6
10-45 15-35
OSHA - Vacated PELs - Time Weighted Ave = 1000 ppm TWA = 1900 mg/m3 TWA Aliphatic Hydrocarbon = 800 ppm TWA Gas [Alkane C1-C4] = 600 ppm TWA = 1000 ppm TWA = 1000 ppm TWA Aliphatic Hydrocarbon = 1800 mg/m3 TWA Gas [Alkane C1-C4] = 1000 ppm TWA Aliphatic Hydrocarbon Gas [Alkane C1-C4] = 600 ppm TWA = 1800 mg/m3 TWA = 600 ppm TWA = 2250 mg/m3 STEL = 750 ppm STEL = 1000 ppm TWA Aliphatic Hydrocarbon Gas: [Alkane C1-C4] Skin - potential significant contribution to overall exposure by the cutaneous route = 0.5 ppm TWA = 2.5 ppm STEL
Other:
Mixture 75-28-5
10-30 1-20
Normal Pentane
109-66-0
15-20
C8 Hydrocarbons Ethane
Mixture 74-84-0
0-10 1-10
Benzene
71-43-2
0-1
OSHA Exposure Limit as specified in 1910.1028: =1.0 ppm TWA = 5 ppm STEL = 0.5 ppm Action Level
Notes:
The manufacturer has voluntarily elected to reflect exposure limits contained in OSHA's 1989 air contaminants standard in its MSDS's, even though certain of those exposure limits were vacated in 1992.
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Inhalation:
Exposure to high vapor concentrations can cause respiratory irritation, headache, dizziness, nausea, narcosis, incoordination and loss of consciousness. At extremely high concentrations and excessive exposure conditions some components of this product may produce cardiac sensitization. Ingestion may result in nausea, vomiting, diarrhea and central nervous system depression. Aspiration (inadvertent suction) of liquid into the lungs must be avoided as even small quantities in the lungs can produce chemical pneumonitis, pulmonary edema/hemorrhage and even death. Prolonged and repeated liquid contact can cause defatting and drying of the skin and can lead to irritation and/or dermatitis. Eye irritation may result from contact with the liquid or exposure to the vapor at concentrations above the TLV.
Ingestion:
IARC Carcinogens: Marathon Natural Gasoline C4-C8 Monograph 45 [1989] 8006-61-9 (overall evaluation upgraded from 3 to 2B with supporting evidence from other data relevant to the evaluation of carcinogenicity and its mechanisms)
Name
NTP Carcinogens:
ACGIH Carcinogens:
Notes:
The International Agency for Research on Cancer (IARC) has determined that there is inadequate evidence for the carcinogenicity of gasoline in humans. IARC determined that limited evidence of carcinogenicity in animals exists. IARC`s overall evaluation of gasoline, in spite of limited carcinogenicity evidence, has resulted in the IARC designation of gasoline as possibly carcinogenic to humans (Group 2B) because gasoline contains benzene.
Component Information:
MSDS ID NO.: 0202MAR001 Product name: Marathon Natural Gasoline C4-C8 Page 3 of 12
Notes:
The International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP), and OSHA have determined that there is sufficient evidence for the carcinogenicity of benzene in humans (Group 1A).
Specific hazards:
Flash point: Autoignition temperature: Flammable limits in air - lower (%): Flammable limits in air - upper (%): NFPA rating: Health: 2
MSDS ID NO.: 0202MAR001
Flammability: 4 Reactivity: 1 Special: *See Section 8 for guidance in selection of personal protective equipment.
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Lifetime inhalation studies with full vaporized gasoline (67, 292 and 2,056 ppm) produced kidney damage and kidney tumors in male rats but not in female rats or male and female mice. Female mice developed a slightly higher incidence of liver tumors compared to controls at the highest exposure level. Results from separate studies with compounds producing similar effects, i.e., 1,4-dichlorobenzene and perchloroethylene, have shown that the kidney damage and kidney tumors develop via the formation of alpha-2u-globulin, a mechanism unique to the male rat. Humans do not form alpha-2u-globulin, therefore, tumors resulting from this mechanism are not relevant in humans. The biologic significance of the mouse liver tumor response with regard to human health risk is questionable. Summary of health effect data on gasoline components: This product contains benzene at a level of >0.1%. Repeated or prolonged exposure to benzene at concentrations in excess of the TLV may cause serious injury to blood-forming organs. Significant chronic exposure to benzene vapor has been reported to produce various blood disorders ranging from anemia to certain forms of leukemia (cancer) in man. Benzene produced tumors in rats and mice in lifetime chronic toxicity studies, but the response has not been consistent across species, strain, sex or route of exposure. Animal studies on benzene have demonstrated immune toxicity, chromosomal aberrations, testicular effects and alterations in reproductive cycles and embryo/fetotoxicity, but not teratogenicity.
UN/Identification No: Hazard Class: Packing group: DOT reportable quantity (lbs): TDG (Canada): Proper shipping name: UN/Identification No: Hazard Class: Packing group: Regulated substances:
EPA Superfund Amendment & Reauthorization Act (SARA): SARA Section 302:
Name Normal Butane Iso-Pentane Propane C6-C7 Hydrocarbons Iso-Butane Normal Pentane C8 Hydrocarbons Ethane Benzene
This product contains the following component(s) that have been listed on EPA's Extremely Hazardous Substance (EHS) List:
CERCLA/SARA - Section 302 Extremely Hazardous Substances and TPQs NA NA NA NA NA NA NA NA NA
This product contains the following component(s) identified either as an EHS or a CERCLA Hazardous substance which in case of a spill or release may be subject to SARA reporting requirements:
CERCLA/SARA - Hazardous Substances and their Reportable Quantities NA NA NA NA NA NA NA NA = 10 lb final RQ = 4.54 kg final RQ
Name Normal Butane Iso-Pentane Propane C6-C7 Hydrocarbons Iso-Butane Normal Pentane C8 Hydrocarbons Ethane Benzene
The following EPA hazard categories apply to this product: Acute Health Hazard Chronic Health Hazard Fire Hazard
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This product contains the following component(s) that may be subject to reporting on the Toxic Release Inventory (TRI) From R:
CERCLA/SARA 313 Emission reporting: None None None None None None None None = 0.1 % de minimis concentration
State and Community Right-To-Know Regulations: The following component(s) of this material are identified on the regulatory lists below: Normal Butane Louisiana Right-To-Know: California Proposition 65: New Jersey Right-To-Know: Pennsylvania Right-To-Know: Massachusetts Right-To Know: Florida substance List: Rhode Island Right-To-Know: Michigan critical materials register list: Massachusetts Extraordinarily Hazardous Substances: California - Regulated Carcinogens: Pennsylvania RTK - Special Hazardous Substances: New Jersey - Special Hazardous Substances: New Jersey - Environmental Hazardous Substances List: Illinois - Toxic Air Contaminants New York - Reporting of Releases Part 597 List of Hazardous Substances: Iso-Pentane Louisiana Right-To-Know: California Proposition 65: New Jersey Right-To-Know: Pennsylvania Right-To-Know: Massachusetts Right-To Know: Florida substance List: Rhode Island Right-To-Know: Michigan critical materials register list: Massachusetts Extraordinarily Hazardous Substances: California - Regulated Carcinogens: Pennsylvania RTK - Special Hazardous Substances: New Jersey - Special Hazardous Substances: New Jersey - Environmental Hazardous Substances List: Illinois - Toxic Air Contaminants New York - Reporting of Releases Part 597 List of Hazardous Substances: Propane Louisiana Right-To-Know: California Proposition 65:
MSDS ID NO.: 0202MAR001
Not Listed Not Listed Listed Listed Listed Not Listed. Listed Not Listed. Not Listed Not Listed Not Listed Listed Listed Not Listed Not Listed
Not Listed Not Listed Listed Listed Listed Not Listed. Not Listed Not Listed. Not Listed Not Listed Not Listed Listed Listed Not Listed Not Listed
New Jersey Right-To-Know: Pennsylvania Right-To-Know: Massachusetts Right-To Know: Florida substance List: Rhode Island Right-To-Know: Michigan critical materials register list: Massachusetts Extraordinarily Hazardous Substances: California - Regulated Carcinogens: Pennsylvania RTK - Special Hazardous Substances: New Jersey - Special Hazardous Substances: New Jersey - Environmental Hazardous Substances List: Illinois - Toxic Air Contaminants New York - Reporting of Releases Part 597 List of Hazardous Substances: C6-C7 Hydrocarbons Louisiana Right-To-Know: California Proposition 65: New Jersey Right-To-Know: Pennsylvania Right-To-Know: Massachusetts Right-To Know: Florida substance List: Rhode Island Right-To-Know: Michigan critical materials register list: Massachusetts Extraordinarily Hazardous Substances: California - Regulated Carcinogens: Pennsylvania RTK - Special Hazardous Substances: New Jersey - Special Hazardous Substances: New Jersey - Environmental Hazardous Substances List: Illinois - Toxic Air Contaminants New York - Reporting of Releases Part 597 List of Hazardous Substances: Iso-Butane Louisiana Right-To-Know: California Proposition 65: New Jersey Right-To-Know: Pennsylvania Right-To-Know: Massachusetts Right-To Know: Florida substance List: Rhode Island Right-To-Know: Michigan critical materials register list: Massachusetts Extraordinarily Hazardous Substances: California - Regulated Carcinogens: Pennsylvania RTK - Special Hazardous Substances: New Jersey - Special Hazardous Substances: New Jersey - Environmental Hazardous Substances List: Illinois - Toxic Air Contaminants New York - Reporting of Releases Part 597 List of Hazardous Substances:
MSDS ID NO.: 0202MAR001
Listed Listed Listed Not Listed. Listed Not Listed. Not Listed Not Listed Not Listed Listed Listed Not Listed Not Listed
Not Listed Not Listed Not Listed. Not Listed. Not Listed. Not Listed. Not Listed Not Listed. Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed
Not Listed Not Listed Listed Listed Listed Not Listed. Not Listed Not Listed. Not Listed Not Listed Not Listed Listed Listed Not Listed Not Listed
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Normal Pentane Louisiana Right-To-Know: California Proposition 65: New Jersey Right-To-Know: Pennsylvania Right-To-Know: Massachusetts Right-To Know: Florida substance List: Rhode Island Right-To-Know: Michigan critical materials register list: Massachusetts Extraordinarily Hazardous Substances: California - Regulated Carcinogens: Pennsylvania RTK - Special Hazardous Substances: New Jersey - Special Hazardous Substances: New Jersey - Environmental Hazardous Substances List: Illinois - Toxic Air Contaminants New York - Reporting of Releases Part 597 List of Hazardous Substances: C8 Hydrocarbons Louisiana Right-To-Know: California Proposition 65: New Jersey Right-To-Know: Pennsylvania Right-To-Know: Massachusetts Right-To Know: Florida substance List: Rhode Island Right-To-Know: Michigan critical materials register list: Massachusetts Extraordinarily Hazardous Substances: California - Regulated Carcinogens: Pennsylvania RTK - Special Hazardous Substances: New Jersey - Special Hazardous Substances: New Jersey - Environmental Hazardous Substances List: Illinois - Toxic Air Contaminants New York - Reporting of Releases Part 597 List of Hazardous Substances: Ethane Louisiana Right-To-Know: California Proposition 65: New Jersey Right-To-Know: Pennsylvania Right-To-Know: Massachusetts Right-To Know: Florida substance List: Rhode Island Right-To-Know: Michigan critical materials register list: Massachusetts Extraordinarily Hazardous Substances: California - Regulated Carcinogens: Pennsylvania RTK - Special Hazardous Substances: New Jersey - Special Hazardous Substances: New Jersey - Environmental Hazardous Substances List:
MSDS ID NO.: 0202MAR001
Not Listed Not Listed Listed Listed Listed Not Listed. Listed Not Listed. Not Listed Not Listed Not Listed Listed Listed Not Listed Not Listed
Not Listed Not Listed Not Listed. Not Listed. Not Listed. Not Listed. Not Listed Not Listed. Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed
Not Listed Not Listed Listed Listed Listed Not Listed. Listed Not Listed. Not Listed Not Listed Not Listed Listed Listed
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Illinois - Toxic Air Contaminants New York - Reporting of Releases Part 597 List of Hazardous Substances: Benzene Louisiana Right-To-Know: California Proposition 65: New Jersey Right-To-Know: Pennsylvania Right-To-Know: Massachusetts Right-To Know: Florida substance List: Rhode Island Right-To-Know: Michigan critical materials register list: Massachusetts Extraordinarily Hazardous Substances: California - Regulated Carcinogens: Pennsylvania RTK - Special Hazardous Substances: New Jersey - Special Hazardous Substances: New Jersey - Environmental Hazardous Substances List: Illinois - Toxic Air Contaminants New York - Reporting of Releases Part 597 List of Hazardous Substances: Canadian Regulatory Information: Canada DSL/NDSL Inventory:
Not Listed Listed Listed Listed Listed Not Listed. Listed Listed carcinogen; extraordinarily hazardous Not Listed Listed Listed Listed Listed Listed
This product and/or its components are listed either on the Domestic Substances List (DSL) or are exempt.
Canada - WHMIS: Classifications of Substances: A, B1 B2 A, B1 A, B1 B2 A, B1 B2, D2A, D2B Canada - WHMIS: Ingredient Disclosure: 1%
Name Normal Butane Iso-Pentane Propane Iso-Butane Normal Pentane Ethane Benzene
1% 0.1 %
The information and recommendations contained herein are based upon tests believed to be reliable. However, Marathon Oil Company (MOC) does not guarantee their accuracy or completeness nor shall any of this information constitute a warranty, whether expressed or implied, as to the safety of goods, the merchantability of the goods, or the fitness of the goods for a particular purpose. Adjustment to conform to actual conditions of usage maybe required. Marathon assumes no responsibility for results obtained or for incidental or consequential damages, including lost profits arising from the use of these data. No warranty against infringement of any patent, copyright or trademark is made or implied. End of Safety Data Sheet
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