0 valutazioniIl 0% ha trovato utile questo documento (0 voti)
128 visualizzazioni6 pagine
Fabricio Guayaquil Sosa is a Ph.D. Student at The University of Western Ontario. He is currently working on a project to develop New Semiconductor Materials for hydrogen production using solar energy. Sosa graduated from the university of aut' onoma Metropolitana in 2012.
Fabricio Guayaquil Sosa is a Ph.D. Student at The University of Western Ontario. He is currently working on a project to develop New Semiconductor Materials for hydrogen production using solar energy. Sosa graduated from the university of aut' onoma Metropolitana in 2012.
Copyright:
Attribution Non-Commercial (BY-NC)
Formati disponibili
Scarica in formato PDF, TXT o leggi online su Scribd
Fabricio Guayaquil Sosa is a Ph.D. Student at The University of Western Ontario. He is currently working on a project to develop New Semiconductor Materials for hydrogen production using solar energy. Sosa graduated from the university of aut' onoma Metropolitana in 2012.
Copyright:
Attribution Non-Commercial (BY-NC)
Formati disponibili
Scarica in formato PDF, TXT o leggi online su Scribd
Department of Chemical & Biochemical Engineering Claudette MacKay-Lassonde Pavilion, Room 1320 The University of Western Ontario London, ON N6A 5B9 k jguayaqu@uwo.ca Born June 20, 1986. Mexico. Education. 2013-present Ph.D. in Chemical & Biochemical Engineering The University of Western Ontario (UWO) Chemical Reactor Engineering Centre (CREC) development of new semiconductor materials for hydrogen production using solar energy. Advisor: Dr. De Lasa, Hugo. 2010-2012 Master of Science, Chemical Engineering, Average 9.8 out of 10 Universidad Aut onoma Metropolitana (UAM) adsorbents design for removal of model nitrogen compounds representative for diesel cuts. 2005-2009 Bachelor Degree, Chemical Engineering, Average 9.7 out of 10 Universidad Aut onoma Metropolitana (UAM) recovery of solvent used in Enhanced Oil Recovery (EOR). Scientic & Technological Research Jan-Mar 2013 Visiting Graduate Student (Research) The University of Western Ontario, Canada. Department of Chemical and Biochemical EngineeringChemical Reaction Engineering Centre (CREC). Engineering of New Semiconductor Materials for Photocatalysis. Advisor: Dr. De Lasa, Hugo. Teaching Assistant (TA), Department of Chemical & Biochemical Engineering, Faculty of Engineering, The University of Western Ontario (UWO) a . a Key: W = Winter Term, S = Spring Term, F = Fall Term. F 2013 F 2014 CBE 3315a-LAB Green Process Engineering (GPE) - Reaction Engineering Lecturer: Dr. Hugo de Lasa W 2014 CBE 3319B- Introduction to Plant Design and Safety Lecturer: Dr. Anand Prakash 1 Teaching Assistant (TA), Process Engineering and Hydraulics Department, Chemical Engineering, UAM a . a Key: W = Winter Term, S = Spring Term, F = Fall Term. S 2012 S 2011 Design and Process Laboratory III & Final Project III. Lecturers: Ph.D. Hugo
Avila-Paredes & Ph.D. Antonio de los Reyes-Heredia. W 2012 W 2011 Design and Process Laboratory II & Final Project II. Lecturers: Ph.D. Hugo
Avila-Paredes & Ph.D. Antonio de los Reyes-Heredia. F 2012 F 2011 Design and Process Laboratory I & Final Project I. Lecturers: Ph.D. Hugo
Avila-Paredes & Ph.D. Antonio de los Reyes-Heredia. S 2010 Introduction to Chemical Engineering. Lecturers: Ph.D. Hugo J.
Avila-Paredes & Prof. Uriel Arechiga-Viramontes. Research Experience. 2014 64th Canadian Chemical Engineering Conference P. J. Valades-Pelayo & F. Guayaquil-Sosa, Predictive Monte Carlo Simula- tions and Kinetic Modelling Applied to the Scale-up of an Annular Photo- catalytic Reactor. Advisor: Dr. Hugo de Lasa The absorption eld and degradation rate of a Photo-CREC Water I Reactor (PCW-I), a 10 L photoreactor are modeled by Monte Carlo (MC) and Finite Element (FE) method. The parameters used by the kinetic and radiative model were validated in a 2.62 L photo-CREC Water II (PCW-II) reactor. The PCW-I consists of an annular slurry region encircled by four equally spaced reectors. Each reector houses two 15 W UVA lamps. The Monte Carlo (MC) model is developed and compared with irradiance measurements at dierent axial and azimuth locations for dierent external irradiance conditions and photocatalyst loadings. The MC method is developed considering: 1) Lambertian emission, 2) reection, refraction and absorption at all interfaces, 3) absorption and scattering coecients and 4) a Henyey-Greenstein(H-G) phase function. The FE method is used to compute free-radical distribution, considering: 1) convection, 2) diusion, 3) generation, 4) recombination and 5) depletion by degradation. Free-radical generation is linked to the radiation absorption eld. Good agreement between the simulated and experimental data is found for irradiance and degradation proles. 2 2014 64th Canadian Chemical Engineering Conference G. Che-Galicia & F. Guayaquil-Sosa, Modelling Study of the Oxidative Dehydrogenation of Ethane over Ni-loaded Y Zeolite Catalyst in Packed Bed Reactor. Advisors: Ph.D. R.S. Ruz-Martnez, Ph.D. Felipe L opez-Isunza & Ph.D. C.O. Castillo-Araiza. Oxidative dehydrogenation of ethane (ODH-Et) is considered as an alternative to complement and even replace the current processes for the production of ethylene. We investigate the theoretical performance of an industrial wall-cooled packed-bed reactor for ODH-Et on a Ni-loaded Y zeolite catalyst (Ni/KY). A kinetic model based on a Langmuir-Hinshelwood-Hougen-Watson mechanism is developed for the ODH-Et on Ni/KY. A 2D pseudo-heterogeneous model that couples heat and mass transport phenomena to kinetics is used to describe the ODH-Et on a Ni/KY that is supposed to be packed in a industrial wall-cooled packed-bed reactor. The simulations are carried out at conditions relevant for industry: length and reactor diameter of 9 m and 2.5 m, respectively; coolant temperature of 450-600
C; reaction mixture inlet temperature of 200
C, inlet molar concentration of 9/7/84 for C 2 H 6 /O 2 /Inert; and particle Reynold number of 1400. Predictions indicate that the studied industrial reactor leads to ethylene selectivity from 68-75 % without presence of hot spots, suggesting that this reactor technology represents a promising alternative for producing ethylene via ODH-Et. 2012 American Institute of Chemical Engineers Annual Meeting (AIChE) J.F. Guayaquil-Sosa, Denitrogenation of Diesel Fuel by Adsorption On MCM-41, Al-MCM-41 and Cu-MCM-41: A Kinetic Study. Advisors: Ph.D. C.O. Castillo-Araiza, Ph.D. Felipe L opez-Isunza & Ph.D. Antonio de los Reyes-Heredia. In this work a serie of adsorbents based on mesoporous molecular sieves; for instance, MCM-41, Al-MCM-41 and Cu-MCM-41 were synthesized, characterized and evaluated, adsorbing model molecules (quinoline and indole) for remotion of nitrogen compounds present in diesel fuel. Experiments in a laboratory batch stirred tank (15 ml) agitated at 300 rpm, room temperature, and a concentration of nitrogen-containing molecule of 300 ppmw dissolved in a mixture of hexadecane-toluene (1:1) were carried out. Materials were characterized by using DRX, N 2 Physisorption, Temperature- Programmed Desorption of Pyridine (TPD-Py) and High-Resolution Transmission Electron Microscopy (HR-TEM). Kinetic models based on Langmuirian mechanism were developed. The adsorption parameters were estimated by using the Levenberg-Marquardt method, and they suggested that the quinoline was more adsorbed selectively than indole. Quinoline adsorption constants for Al-MCM-41 adsorbent were higher than the ones for the commercial adsorbent, suggesting that the synthesized material could be used as industrial adsorbent to remove quinoline. 3 2012 22nd International Symposium on Chemical Reaction Engineering (ISCRE) J. F. Guayaquil-Sosa, Adsorption Kinetics of Nitrogen Compounds for Remotion in Gas Oil Cuts. Advisors: Ph.D. C.O. Castillo-Araiza, Ph.D. Felipe L opez-Isunza & Ph.D. Antonio de los Reyes-Heredia. A set of adsorbents based on silicoaluminates (SiAl) were synthesized, characterized and evaluated for removal of nitrogen compounds presents in diesel. Adsorption results were compared with a commercial adsorbent (selexsorb CDX). The best material (A100) adsorbs 43.7 mg N/g meanwhile the CDX 28.7 mg N/g. The proposed kinetic model according to the equilibrium constants suggested that the synthesized materials have a higher adsorption capacity than the commercial one. 2012 20th International Congress of Chemical and Process Engineering (CHISA) J.F. Guayaquil-Sosa, Adsorption of nitrogen compounds using silicoaluminates: process modeling. Advisors: Ph.D. C.O. Castillo-Araiza, Ph.D. Felipe L opez-Isunza & Ph.D. Antonio de los Reyes-Heredia. A kinetic study was carried out accounting for quinoline and indole adsorption on silicoaluminates exhibiting the highest adsorption capacity. The kinetics indicated that SiAl presented higher adsorption capabilities than the commercial. Besides, kinetic models based on Langmuirian mechanism were developed. 2012 XXXIII Encuentro Nacional y III Congreso Internacional de la AMIDIQ G. Che-Galicia and J.F. Guayaquil-Sosa, Adsorption of Basic Dye from Aqueous Solution by a Low-Cost Adsorbent: Packed-Bed Modelling. Advisors: Ph.D. R.S. Ruz-Martnez & Ph.D. C.O. Castillo-Araiza. The adsorption of a basic dye (Rhodamine B) onto natural zeolite (clinoptilolite- mordenite) has been studied using packed-bed adsorbed model. A pseudo heterogeneous model has been utilized to predict the packed-bed breakth- rough curves. This model considers both external and internal mass transfer resistances as well as axial dispersion. A parametric sensitivity study was carried out in order to determine the eect of inlet dye concentration, ow rate, bed height and particle diameter upon breakthrough curves. The kinetic parameters were obtained throughout experiments in a batch adsorber by tting the experimental data with theoretical model. Simulations results suggest that adsorption process using a low-cost natural zeolite is feasible to be applied at industrial scale. Awards. 2013 University Medal of Merit, Master of Science in Chemical Engineering. for High Performance in the generation 2010-2012, UAM Mexico. 2010 University Medal of Merit, Bachelor degree in Chemical Engineering. for High Performance in the generation 2005-2009, UAM Mexico. 2010 Best Graduate Degree in Chemical Engineering fromthe Institution in 2009. National Association of Colleges and Engineering Schools, UAM Mexico. 4 2009 Outstanding Academic Performance Along the Bachelor in Chemical Engineering. General Direction, UAM Mexico. 2008 Outstanding Performance During the Third Year of Bachelor in Chemical Engineering. Division of Basic Science and Engineering, UAM-I Mexico. 2007 Outstanding Performance During the Second Year of Bachelor in Chemical Engineering. Division of Basic Science and Engineering, UAM-I Mexico. Professional development. 2013 Teaching Assistant Training Program (TATP). Teaching Support Centre, The University of Western Ontario. 2012 Kinetics and Parameter Estimation. Ph. D. Carlos O. Castillo-Araiza, Division of Basic Science and Engineering, UAM-I Mexico. 2011 Workshop Teaching Strategies. Division of Basic Science and Engineering, UAM-I Mexico. Scholarships. 2013-2017 Government Scholarship for International PhD Studies. The National Council for Science and Technology, CONACyT Mexico. 2013 Supplement Scholarship for International PhD Studies. Secretariat of Public Education, Mexico. 2013 Awared for Outstanding Academic Records. The Mexican Provincial Council for Science and Technology, COMECyT. 2012 Scholarship for 2012 AIChE Annual Meeting . American Institute of Chemical Engineers (AIChE). 2010-2012 Government Scholarship for Graduate Studies. The National Council for Science and Technology, CONACyT Mexico. 2007 Government Scholarship for Undergraduate Studies. Secretariat of Public Education, Mexico. 5 Generation Line and Knowledge Application a . a These are my elds of work with CONACyT. Sep 2014 Photocatalytic Hydrogen Production Via Water Splitting. Predictive Monte Carlo Simulations and Kinetic Modelling Applied to Photo- catalytic Reactors. Sep 2011 Adsorption, Synthesis of New Materials, Characterization of Solid Materials and Heterogeneous Catalysts From Structure to Surface Reactivity Kinetics. Nov 2010 Teaching and Research. Languages. Spanish Native Speaker. English Certicate of International English Language Testing System (IELTS) by British Council, Test date & location; February 23, 2013. Humber College North Campus, Toronto, Ontario. Academic module; Good user. Computer Skills. Programming Languages L A T E X, Fortran, HTML, and Java. Familiarized with Linux OS, Mac OS, and programming oriented to visualization, development and objects. Software COMSOL Multiphysics, CorelDraw, Fluent, GaussView, Kile, MATLAB, MestRe-C, Oce, OriginPro, Quantachrome ASiQ, SimSci-PRO/II, Texmaker, Wolfram Mathematica. Relevant Courses. Chemical Engineering Material and Energy Balance, Process Dynamics and Control, Chemical Reaction Engineering, Processes and Design Laboratory, Fluid Mechanics, Unit Operations, Separation Processes, Selected Topics of Heat and Mass Transfer, Thermodynamics, Heat Transfer, Mass Transfer. Mathematics Linear Algebra, Dierential and Integral Calculus, Ordinary Dierential Equations, Partial Dierential Equations, Mathematical Methods in Process Engineering, Probability and Statistics. Chemistry Chemical Kinetics, Structure of Matter, Coordination Chemistry, Inorganic Chemistry, Organic Chemistry, Chemical Transformations. Graduate Advanced Fluid Mechanics, Applied Mathematics in Chemical Engineering, En- gineering of Catalytic and Chemical Reactors, Instrumental Methods of Analy- sis for Engineers, Physical Principles of Environmental Engineering, Solid State Chemistry, Selected Topics of Chemical Engineering, Thermodynamics, Heat and Mass Transfer. 6