Heat treatment of welded joints

Job Knowledge
Heat treatment is an operation that is both time consuming and costly. It can affect the strength and toughness of a welded joint, its corrosion resistance and the level of residual stress but is also a mandatory operation specified in many application codes and standards. In addition it is an essential variable in welding procedure qualification specifications. Before discussing the range of heat treatments that a metal may be subjected to, there is a need to clearly define what is meant by the various terms used to describe the range of heat treatments that may be applied to a welded joint. Such terms are often used incorrectly, particularly by nonspecialists; for a metallurgist they have very precise meanings. Solution treatment Carried out at a high temperature and designed to take into a solution elements and compounds which are then retained in solution by cooling rapidly from the solution treatment temperature. This may be done to reduce the strength of the joint or to improve its corrosion resistance. With certain alloys it may be followed by a lower temperature heat treatment to reform the precipitates in a controlled manner (age or precipitation hardening). Annealing This consists of heating a metal to a high temperature, where recrystallisation and/or a phase transformation take place, and then cooling slowly, often in the heat treatment furnace. This is often carried out to soften the metal after it has been hardened, for example by cold working; a full anneal giving the very softest of microstructures. It also results in a reduction in both the yield and the tensile strength and, in the case of ferritic steels, usually a reduction in toughness. Normalising This is a heat treatment that is carried out only on ferritic steels. It comprises heating the steel to some 30-50C above the upper transformation temperature (for a 0.20% carbon steel this would be around 910C) and cooling in still air. This results in a reduction in grain size and improvements in both strength and toughness. Quenching This comprises a rapid cool from a high temperature. A ferritic steel would be heated to above the upper transformation temperature and quenched in water, oil or air blast to produce a very high strength, fine grained martensite. Steels are never used in the quenched condition, they are always tempered following the quenching operation. Tempering A heat treatment carried out on ferritic steels at a relatively low temperature, below the lower transformation temperature; in a conventional structural carbon steel this would be in the region of 600-650C. It reduces hardness, lowers the tensile strength and improves ductility and toughness. Most normalised steels are tempered before welding, all quenched steels are used in the quenched and tempered condition. Ageing or Precipitation hardening A low temperature heat treatment designed to produce the correct size and distribution of precipitates, thereby increasing the yield and tensile strength. It is generally preceded by a solution heat treatment. For steel, the temperature may be somewhere between 450-740 degree C, an

aluminium alloy would be aged at between 100-200C. Longer times and/or higher temperatures result in an increase in size of the precipitate and a reduction in both hardness and strength. Stress relief As the name suggests, this is a heat treatment designed to reduce the residual stresses produced by weld shrinkage. It relies upon the fact that, as the temperature of the metal is raised, the yield strength decreases, allowing the residual stresses to be redistributed by creep of the weld and parent metal. Cooling from the stress relief temperature is controlled in order that no harmful thermal gradients can occur. Post heat A low temperature heat treatment carried out immediately on completion of welding by increasing the preheat by some 100C and maintaining this temperature for 3 or 4 hours. This assists the diffusion of any hydrogen in the weld or heat affected zones out of the joint and reduces the risk of hydrogen induced cold cracking. It is used only on ferritic steels, where hydrogen cold cracking is a major concern i.e. very crack sensitive steels, very thick joints etc. Post Weld Heat Treatment (PWHT) So what does the term 'post weld heat treatment' mean? To some engineers it is a rather vague term that is used to describe any heat treatment that is carried out when welding is complete. To others however, particularly those working in accordance with the pressure vessel codes such as BS PD 5500, EN 13445 or ASME VIII, it has a very precise meaning. When an engineer talks of post weld heat treatment, annealing, tempering or stress relief it is therefore advisable. Heat treatment following welding may be carried out for one or more of three fundamental reasons:

to achieve dimensional stability in order to maintain tolerances during machining operations or during shake-down in service to produce specific metallurgical structures in order to achieve the required mechanical properties to reduce the risk of in-service problems such as stress corrosion or brittle fracture by reducing the residual stress in the welded component The range of heat treatments to achieve one or more of these three objectives in the range of ferrous and non-ferrous metals and alloys that may be welded is obviously far too extensive to cover in great detail within these brief Job Knowledge articles. The emphasis in the following section will be on the PWHT of carbon and low alloy steels as required by the application standards although brief mention will be made of other forms of heat treatment that the welding engineer may encounter in the ferrous alloys. There are two basic mechanisms that are involved, firstly stress relief and secondly microstructural modifications or tempering. Stress Relief Why is it necessary to perform stress relief? It is an expensive operation requiring part or all of the welded item to be heated to a high temperature and it may cause undesirable metallurgical changes in some alloys. As mentioned above there may be one or more reasons. The high residual stresses locked into a welded joint may cause deformation outside acceptable dimensions to occur when the item is machined or when it enters service. High residual stresses in carbon and low alloy steels can increase the risk of brittle fracture by providing a driving force for crack propagation. Residual stresses will cause stress corrosion cracking to occur in the correct environment eg carbon and low alloy steels in caustic service or stainless steel exposed to chlorides. What causes these high residual stresses? Welding involves the deposition of molten metal between two essentially cold parent metal faces. As the joint cools the weld metal contracts but is restrained by the cold metal on either side; the residual stress in the joint therefore increases as the temperature falls. When the stress has reached a sufficiently high value (the yield point or proof strength at that

temperature) the metal plastically deforms by means of a creep mechanism so that the stress in the joint matches the yield strength. As the temperature continues to fallre the yield strength increases, impeding deformation, so that at ambient temperature the residual stress is often equal to the proof strength (Fig 1). To reduce this high level of residual stress, the component is reheated to a sufficiently high temperature. As the temperature is increased the proof strength falls, allowing deformation to occur and residual stress to decrease until an acceptable level is reached. The component would be held at this temperature (soaked) for a period of time until a stable condition is reached and then cooled back to room temperature. The residual stress remaining in the joint is equal to the proof strength at the soak temperature. Figure 1 shows that residual stress in a carbon manganese steel falls reasonably steadily from ambient to around 600 degree C but that the high strength creep resistant steels need to be above 400 degree C before the residual stress begins to fall. Stainless steel is hardly affected until the temperature exceeds 500 degree C. There is therefore a range of soak temperatures for the various alloys to achieve an acceptable reduction in residual stress without adversely affecting the mechanical properties of the joint. In carbon manganese steels this temperature will be between 550-620 degree C, in creep resistant steels somewhere between 650-750 degree C and for stainless steels between 800-850 degree C.

Effects of Alloying Elements in Steel

Carbon
The basic metal, iron, is alloyed with carbon to make steel and has the effect of increasing the hardness and strength by heat treatment but the addition of carbon enables a wide range of hardness and strength.

Manganese
Manganese is added to steel to improve hot working properties and increase strength, toughness and hardenability. Manganese, like nickel, is an austenite forming element and has been used as a substitute for nickel in the A.I.S.I 200 Series of Austenitic stainless steels (e.g. A.I.S.I 202 as a substitute for A.I.S.I 304)

Chromium
Chromium is added to the steel to increase resistance to oxidation. This resistance increases as more chromium is added. 'Stainless Steel' has approximately 11% chromium and a very marked degree of general corrosion resistance when compared with steels with a lower percentage of chromium. When added to low alloy steels, chromium can increase the response to heat treatment, thus improving hardenability and strength.

Nickel
Nickel is added in large amounts, over about 8%, to high chromium stainless steel to form the most important class of corrosion and heat resistant steels. These are the austenitic stainless steels, typified by 18-8, where the tendency of nickel to form austenite is responsible for a great toughness and high strength at both high and low temperatures. Nickel also improves resistance to oxidation and

corrosion. It increases toughness at low temperatures when added in smaller amounts to alloy steels.

Molybdenum
Molybdenum, when added to chromium-nickel austenitic steels, improves resistance to pitting corrosion especially by chlorides and sulphur chemicals. When added to low alloy steels, molybdenum improves high temperature strengths and hardness. When added to chromium steels it greatly diminishes the tendency of steels to decay in service or in heat treatment.

Titanium
The main use of titanium as an alloying element in steel is for carbide stabilisation. It combines with carbon to for titanium carbides, which are quite stable and hard to dissolve in steel, this tends to minimise the occurrence of inter-granular corrosion, as with A.I.S.I 321, when adding approximately 0.25%/0.60% titanium, the carbon combines with the titanium in preference to chromium, preventing a tie-up of corrosion resisting chromium as inter-granular carbides and the accompanying loss of corrosion resistance at the grain boundaries.

Phosphorus
Phosphorus is usually added with sulphur to improve machinability in low alloy steels, phosphorus, in small amounts, aids strength and corrosion resistance. Experimental work shows that phosphorus present in austeniticstainless steels increases strength. Phosphorus additions are known to increase the tendency to cracking during welding.

Sulphur
When added in small amounts sulphur improves machinability but does not cause hot shortness. Hot shortness is reduced by the addition of manganese, which combines with the sulphur to form manganese sulphide. As manganese sulphide has a higher melting point than iron sulphide, which would form if manganese were not present, the weak spots at the grain boundaries are greatly reduced during hot working.

Selenium
Selenium is added to improve machinability.

Niobium (Columbium)
Niobium is added to steel in order to stabilise carbon, and as such performs in the same way as described for titanium. Niobium also has the effect of strengthening steels and alloys for high temperature service.

Nitrogen
Nitrogen has the effect of increasing the austenitic stability of stainless steels and is, as in the case of nickel, an austenite forming element. Yield strength is greatly improved when nitrogen is added to austenitic stainless steels.

Silicon
Silicon is used as a deoxidising (killing) agent in the melting of steel, as a result, most steels contain a small percentage of silicon. Silicon contributes to hardening of the ferritic phase in steels and for this reason silicon killed steels are somewhat harder and stiffer than aluminium killed steels.

Cobalt
Cobalt becomes highly radioactive when exposed to the intense radiation of nuclear reactors, and as a result, any stainless steel that is in nuclear service will have a cobalt restriction, usually aproximately 0.2% maximum. This problem is emphasised because there is residual cobalt content in the nickel used in producing these steels.

Tantalum
Chemically similar to niobium and has similar effects.

Copper
Copper is normally present in stainless steels as a residual element. However it is added to a few alloys to produce precipitation hardening properties.